[go: up one dir, main page]

MX9605431A - Procedimientos de polimerizacion de acrilato. - Google Patents

Procedimientos de polimerizacion de acrilato.

Info

Publication number
MX9605431A
MX9605431A MX9605431A MX9605431A MX9605431A MX 9605431 A MX9605431 A MX 9605431A MX 9605431 A MX9605431 A MX 9605431A MX 9605431 A MX9605431 A MX 9605431A MX 9605431 A MX9605431 A MX 9605431A
Authority
MX
Mexico
Prior art keywords
polymerization processes
resins
thermoplastic resin
free radical
containing thermoplastic
Prior art date
Application number
MX9605431A
Other languages
English (en)
Inventor
Michael K Georges
Marko D Saban
Peter M Kazmaier
Richard P N Veregin
Gordon K Hamer
Karen A Moffat
Original Assignee
Xerox Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Xerox Corp filed Critical Xerox Corp
Publication of MX9605431A publication Critical patent/MX9605431A/es

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/04Polymerisation in solution
    • C08F2/06Organic solvent
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/10Esters
    • C08F20/12Esters of monohydric alcohols or phenols
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/04Azo-compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Graft Or Block Polymers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Polymerization Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

La presente invencion se refiere a un procedimiento de polimerizacion para la preparacion de resina o resinas termoplásticas que contienen acrilato homopolimérico, que comprende calentar una mezcla constituida por un iniciador de radicales libres, un agente de radicales libres estable oxo nitroxido, al menos un compuesto de monomero acrilato polimerizable y opcionalmente un solvente, para formar una resina o resinas termoplásticas que contienen acrilato homopolimérico con una alta conversion de monomero a polímero y una restringida polidispersidad.
MX9605431A 1994-05-13 1995-05-02 Procedimientos de polimerizacion de acrilato. MX9605431A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/242,490 US5412047A (en) 1994-05-13 1994-05-13 Homoacrylate polymerization processes with oxonitroxides
PCT/US1995/005559 WO1995031484A1 (en) 1994-05-13 1995-05-02 Acrylate polymerization processes

Publications (1)

Publication Number Publication Date
MX9605431A true MX9605431A (es) 1997-12-31

Family

ID=22914975

Family Applications (1)

Application Number Title Priority Date Filing Date
MX9605431A MX9605431A (es) 1994-05-13 1995-05-02 Procedimientos de polimerizacion de acrilato.

Country Status (12)

Country Link
US (1) US5412047A (es)
EP (1) EP0759039B1 (es)
JP (1) JP3496764B2 (es)
KR (1) KR970703370A (es)
CN (1) CN1147820A (es)
AT (1) ATE188221T1 (es)
AU (1) AU2469195A (es)
BR (1) BR9507868A (es)
CA (1) CA2187754C (es)
DE (1) DE69514222T2 (es)
MX (1) MX9605431A (es)
WO (1) WO1995031484A1 (es)

Families Citing this family (60)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6258911B1 (en) * 1994-08-18 2001-07-10 Xerox Corporation Bifunctional macromolecules and toner compositions therefrom
US5545504A (en) * 1994-10-03 1996-08-13 Xerox Corporation Ink jettable toner compositions and processes for making and using
FR2730241B1 (fr) 1995-02-07 1997-02-28 Atofina Procede de fabrication d'une composition comprenant un polymere vinylaromatique et un caoutchouc par polymerisation en presence d'un radical libre stable
FR2730240A1 (fr) * 1995-02-07 1996-08-09 Atochem Elf Sa Stabilisation d'un polymere par un radical libre stable
US5627248A (en) * 1995-09-26 1997-05-06 The Dow Chemical Company Difunctional living free radical polymerization initiators
US5552502A (en) * 1995-11-16 1996-09-03 Xerox Corporation Polymerization process and compositions thereof
CN1209817A (zh) * 1996-01-25 1999-03-03 Basf公司 嵌段共聚物
DE19602541A1 (de) * 1996-01-25 1997-07-31 Basf Magnetics Gmbh Magnetische Aufzeichnungsträger
DE19602544A1 (de) * 1996-01-25 1997-07-31 Basf Ag Als Dispergierharze geeignete Polymerisate
DE19613994A1 (de) * 1996-04-09 1997-10-16 Basf Ag Stabilisierte wäßrige Dispersionen von Polymeren mit ethylenisch ungesättigten Gruppen
FR2748484B1 (fr) * 1996-05-13 1998-07-24 Atochem Elf Sa Polymerisation en presence d'un radical libre stable et d'un initiateur de radicaux libres
US5723511A (en) * 1996-06-17 1998-03-03 Xerox Corporation Processes for preparing telechelic, branched and star thermoplastic resin polymers
US5711767A (en) * 1996-07-11 1998-01-27 Ciba Specialty Chemicals Corporation Stabilizers for the prevention of gum formation in gasoline
EP0919569B1 (en) * 1996-07-25 2002-11-13 Mitsubishi Rayon Co., Ltd. Process for the preparation of poly(meth)acrylic acid ester
FR2754535A1 (fr) * 1996-10-16 1998-04-17 Atochem Elf Sa Polymeres greffes a viscosite controlee
DE19648811A1 (de) * 1996-11-27 1998-05-28 Basf Ag Verfahren zur Polymerisation vinylischer Monomerer
US5744560A (en) * 1997-01-21 1998-04-28 Xerox Corporation Metal accelerated polymerization processes
US6281311B1 (en) * 1997-03-31 2001-08-28 Pmd Holdings Corp. Controlled free radical polymerization process
US6111025A (en) * 1997-06-24 2000-08-29 The Lubrizol Corporation Block copolymer surfactants prepared by stabilized free-radical polymerization
US6156858A (en) * 1997-06-25 2000-12-05 Xerox Corporation Stable free radical polymerization processes
DE19727502A1 (de) 1997-06-27 1999-01-07 Basf Ag Verfahren der radikalisch initiierten wäßrigen Emulsionspolymerisation zur Herstellung einer wäßrigen Polymerisatdispersion
DE19727505A1 (de) 1997-06-27 1999-01-07 Basf Ag Verfahren der radikalisch initiierten wäßrigen Emulsionspolymerisation zur Herstellung einer wäßrigen Polymerisatdispersion
US5817824A (en) * 1997-08-01 1998-10-06 Xerox Corporation Processes for stabel free radicals
JP2001513523A (ja) 1997-08-07 2001-09-04 ビーエーエスエフ アクチェンゲゼルシャフト 望ましくないラジカル重合に対する(メタ)アクリル酸エステルの安定化法
US5891971A (en) * 1997-08-15 1999-04-06 Xerox Corporation Polymerization processes
CA2307580A1 (en) 1997-10-31 1999-05-14 Cabot Corporation Particles having an attached stable free radical, polymerized modified particles, and methods of making the same
US6368239B1 (en) 1998-06-03 2002-04-09 Cabot Corporation Methods of making a particle having an attached stable free radical
US6068688A (en) * 1997-11-12 2000-05-30 Cabot Corporation Particle having an attached stable free radical and methods of making the same
DE19752394A1 (de) * 1997-11-19 1999-05-20 Basf Ag Verfahren zur Herstellung von Pfropfpolymerisaten
FR2773158B1 (fr) 1997-12-30 2000-02-04 Atochem Elf Sa Procede de polymerisation radicalaire controlee faisant intervenir une faible quantite de radical libre stable
CA2265345A1 (en) * 1998-03-25 1999-09-25 The Lubrizol Corporation Vinyl aromatic-(vinyl aromatic-co-acrylic) block copolymers prepared by stabilized free radical polymerization
DE19813353A1 (de) 1998-03-26 1999-09-30 Bayer Ag Verfahren zur Herstellung von Telechelen, so hergestellte Telechele und ihre Verwendung
US6103380A (en) 1998-06-03 2000-08-15 Cabot Corporation Particle having an attached halide group and methods of making the same
US6864313B2 (en) * 1998-06-25 2005-03-08 Ciba Specialty Chemicals Corp. Use of 2,2,6,6 tetraalkylpiperidine-N-oxyl radicals having long alkyl chains as polymerization regulators
TWI246519B (en) 1998-06-25 2006-01-01 Ciba Sc Holding Ag Use of 2,2,6,6 tetraalkylpiperidine-N-oxyl radicals having long alkyl chains as polymerization regulators
DE69917311T2 (de) 1998-07-10 2004-12-09 E.I. Du Pont De Nemours And Co., Wilmington Mikrogele und verfahren zu deren herstellung
US6518326B1 (en) 1998-07-31 2003-02-11 Ciba Specialty Chemicals Corporation Open chain alkoxyamine compounds and their use as polymerization regulators
WO2000017242A1 (en) * 1998-09-23 2000-03-30 The Dow Chemical Company Preparation of a water-soluble polymeric dispersant having low polydispersity
WO2000024795A1 (en) * 1998-10-26 2000-05-04 The Lubrizol Corporation Radial polymers prepared by stabilized free radical polymerization
DE19858103A1 (de) * 1998-12-16 2000-06-21 Basf Ag Verfahren zur lebenden freien radikalischen Polymerisation
US6143820A (en) * 1998-12-18 2000-11-07 The Dow Chemical Company Preparation of a low polydisperse water-soluble polymeric composition
US6355756B1 (en) 1999-05-18 2002-03-12 International Business Machines Corporation Dual purpose electroactive copolymers, preparation thereof, and use in opto-electronic devices
DE19939031A1 (de) * 1999-08-18 2001-02-22 Basf Ag N-Oxyl-Radikale
US6569968B1 (en) * 1999-08-19 2003-05-27 Kurita Water Industries Ltd. Polymer of a water-soluble radical-polymerizable monomer, process for producing the polymer and flocculant comprising the polymer
US6713552B1 (en) 1999-08-23 2004-03-30 Rohm And Haas Company Pressure sensitive adhesive with improved peel strength and tack
EP1083169B1 (de) 1999-09-07 2003-10-29 Bayer Ag Funktionalisierte Alkoxyamin-Initiatoren
US7034079B2 (en) * 1999-10-20 2006-04-25 The Lubrizol Corporation Radial polymers prepared by stabilized free radical polymerization
WO2001038407A1 (fr) * 1999-11-19 2001-05-31 Mitsubishi Rayon Co., Ltd. Composition de resine
DE10016651A1 (de) 2000-04-04 2001-10-11 Basf Ag Verfahren zur Herstellung von Polymeren
TWI225492B (en) 2000-09-25 2004-12-21 Ciba Sc Holding Ag Composition and process for enhancing controlled free radical polymerization
US20030153708A1 (en) * 2002-01-11 2003-08-14 Caneba Gerald Tablada Free radical retrograde precipitation copolymers and process for making same
EP1375457A1 (en) 2002-06-25 2004-01-02 Bayer Aktiengesellschaft One-pot process for the preparation of functionalized alkoxyamines
EP1375476A1 (en) * 2002-06-25 2004-01-02 Bayer Aktiengesellschaft A new process for the synthesis of alkoxyamines active in controlled radical polymerization
EP1496091A1 (en) * 2003-07-08 2005-01-12 Rohm And Haas Company Aqueous polymer composition
JP2008504411A (ja) 2004-07-01 2008-02-14 ウニベルズィタイト・ヘント (アルキル)アクリル酸部分を含有する単分散性ポリマー、前駆体およびその作製方法ならびにその適用
JP5425623B2 (ja) 2006-07-11 2014-02-26 チバ ホールディング インコーポレーテッド カラーフィルター組成物
CN107810204B (zh) 2015-06-17 2020-04-14 巴斯夫欧洲公司 用于立即终止自由基聚合的组合物
JP6822863B2 (ja) * 2016-03-31 2021-01-27 三井化学株式会社 熱硬化性組成物、これを含む封止剤、有機el素子用枠封止剤、及び有機el素子用面封止剤、並びにその硬化物
JP6989116B2 (ja) * 2016-12-27 2022-01-05 学校法人福岡大学 細胞シートの製造方法及び細胞培養支持体
CN109232595B (zh) * 2018-09-25 2020-03-03 万华化学集团股份有限公司 一种罗丹明b类自由基荧光探针、制备方法及其在丙烯酸及酯生产过程中自由基检测的应用

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4736004A (en) * 1983-04-05 1988-04-05 Green Cross Corporation Persistent perfluoroalkyl free radicals useful as polymerization catalyst
US4581429A (en) * 1983-07-11 1986-04-08 Commonwealth Scientific And Industrial Research Organization Polymerization process and polymers produced thereby
US4546160A (en) * 1984-02-29 1985-10-08 S. C. Johnson & Son, Inc. Bulk polymerization process for preparing high solids and uniform copolymers
US5059657A (en) * 1990-08-06 1991-10-22 E. I. Du Pont De Nemours And Company Polymerization of selected vinyl monomers
US5268437A (en) * 1992-01-22 1993-12-07 Rohm And Haas Company High temperature aqueous polymerization process
US5322912A (en) * 1992-11-16 1994-06-21 Xerox Corporation Polymerization processes and toner compositions therefrom

Also Published As

Publication number Publication date
ATE188221T1 (de) 2000-01-15
DE69514222T2 (de) 2000-05-11
BR9507868A (pt) 1997-09-23
EP0759039A1 (en) 1997-02-26
JPH10500170A (ja) 1998-01-06
EP0759039B1 (en) 1999-12-29
WO1995031484A1 (en) 1995-11-23
JP3496764B2 (ja) 2004-02-16
CA2187754C (en) 2000-01-11
CN1147820A (zh) 1997-04-16
EP0759039A4 (es) 1997-03-26
AU2469195A (en) 1995-12-05
CA2187754A1 (en) 1995-11-23
KR970703370A (ko) 1997-07-03
DE69514222D1 (de) 2000-02-03
US5412047A (en) 1995-05-02

Similar Documents

Publication Publication Date Title
MX9605431A (es) Procedimientos de polimerizacion de acrilato.
NZ337938A (en) Controlled free radical polymerization process
MY134744A (en) Polymerization processes and toner compositions therefrom
EP0735052A3 (en) Rate enhanced polymerization processes for producing polymers having narrow polydispersitylydispersität
CA2164032A1 (en) Polymerization Processes
CA2107621A1 (en) Soluble anionic polymerization initiators and products therefrom
SG50421A1 (en) Process for the manufacture of a composition comprising a vinylaromatic polymer and a rubber
BR9403185A (pt) Copolímeros com viscosidade de solução particularmente baixa, processo para a sua preparação, sua aplicação e lacas
CA2055379A1 (en) Heat-curable resin composition containing acrylic polymer having alicyclic epoxide functions
EP0814095A3 (en) Process for producing a shaped product
CA2256083A1 (fr) Procede de polymerisation radicalaire controlee faisant intervenir une faible quantite de radical libre stable
EP0826697A3 (en) Polymerization processes and resin particles formed thereby
JPS5699216A (en) Highly adherent resin composition
EP0754196A4 (en) AQUEOUS POLYMERIZATION PROCESSES
EP1000954A4 (en) POLYMERS AND METHOD FOR PRODUCING POLYMERS
PT75954A (en) Reactive acrylic adhesives
ES479356A1 (es) Un procedimiento para la preparacion de resinas de estireno.
JPS57185309A (en) Preparation of modified olefinic polymeric particle
JPS53129284A (en) Resin composition exhibiting elastomeric properties by polymerization
Di Silvestro et al. Can Propylene Polymerize by a Radical Mechanism?
JPS57117505A (en) Preparation of polymer having ultrahigh molecular weight
GB2368343B (en) Resin material for deture base
MX9500040A (es) Adhesivos acrilicos estructurales.