MX349113B - Procesos para producir ciertos 2-piridin-3-il) tiazoles. - Google Patents
Procesos para producir ciertos 2-piridin-3-il) tiazoles.Info
- Publication number
- MX349113B MX349113B MX2014014882A MX2014014882A MX349113B MX 349113 B MX349113 B MX 349113B MX 2014014882 A MX2014014882 A MX 2014014882A MX 2014014882 A MX2014014882 A MX 2014014882A MX 349113 B MX349113 B MX 349113B
- Authority
- MX
- Mexico
- Prior art keywords
- iii
- compound
- thiazoles
- pyridine
- processes
- Prior art date
Links
- WPCSNGBKVXKBPU-UHFFFAOYSA-N 2-pyridin-3-yl-1,3-thiazole Chemical class C1=CSC(C=2C=NC=CC=2)=N1 WPCSNGBKVXKBPU-UHFFFAOYSA-N 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 abstract 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 abstract 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 abstract 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 abstract 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 abstract 2
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 abstract 2
- QAEDZJGFFMLHHQ-UHFFFAOYSA-N trifluoroacetic anhydride Chemical compound FC(F)(F)C(=O)OC(=O)C(F)(F)F QAEDZJGFFMLHHQ-UHFFFAOYSA-N 0.000 abstract 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 239000012024 dehydrating agents Substances 0.000 abstract 1
- 235000019253 formic acid Nutrition 0.000 abstract 1
- 239000000543 intermediate Substances 0.000 abstract 1
- 230000000361 pesticidal effect Effects 0.000 abstract 1
- 229920000137 polyphosphoric acid Polymers 0.000 abstract 1
- 239000003586 protic polar solvent Substances 0.000 abstract 1
- 238000000746 purification Methods 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 238000003786 synthesis reaction Methods 0.000 abstract 1
- -1 thiazole amides Chemical class 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
- A01N43/78—1,3-Thiazoles; Hydrogenated 1,3-thiazoles
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D417/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00
- C07D417/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing two hetero rings
- C07D417/04—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing two hetero rings directly linked by a ring-member-to-ring-member bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
- C07D213/83—Thioacids; Thioesters; Thioamides; Thioimides
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Agronomy & Crop Science (AREA)
- General Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Plural Heterocyclic Compounds (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Thiazole And Isothizaole Compounds (AREA)
- Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
Abstract
La invención descrita en este documento se refiere al campo de los procesos para producir ciertos 2-piridina-3-iI)tiazoles como intermediarios para la síntesis de amidas de tiazolamidas pesticidas. En el etapa a, los compuestos (l) y (ll) se hacen reaccionar para producir el compuesto (lll). La reacción se lleva a cabo en un solvente prótico polar. Los ejemplos de tales incluyen mas no se limitan, ácido fórmico, n-butanol, isopropanol, n-propanol, etanol, metanol ácido acético y agua. En la etapa b, el compuesto (lll) se cicla usando un agente deshidratante. Los ejemplos de tales agentes deshidratantes incluye mas no se limitan a POCl3, H2SO4, SOCl2, P2O5, ácido polifosfórico, ácido p-toluensulfónico y anhídrido trifluoroacético. Una ventaja de las etapas a y b respecto del arte es que el compuesto (lll) y (lV) se producen en general como sólidos sustancialmente puros que no necesitan procedimientos de purificación adicionales.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201261655086P | 2012-06-04 | 2012-06-04 | |
PCT/US2013/043208 WO2013184476A2 (en) | 2012-06-04 | 2013-05-30 | Processes to produce certain 2-(pyridine-3-yl)thiazoles |
Publications (2)
Publication Number | Publication Date |
---|---|
MX2014014882A MX2014014882A (es) | 2015-11-16 |
MX349113B true MX349113B (es) | 2017-07-12 |
Family
ID=49671038
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2014014882A MX349113B (es) | 2012-06-04 | 2013-05-30 | Procesos para producir ciertos 2-piridin-3-il) tiazoles. |
Country Status (18)
Country | Link |
---|---|
US (2) | US9108952B2 (es) |
EP (1) | EP2855467B1 (es) |
JP (1) | JP6181166B2 (es) |
KR (1) | KR102063532B1 (es) |
CN (1) | CN104507935B (es) |
AR (1) | AR091246A1 (es) |
AU (1) | AU2013272007B2 (es) |
BR (1) | BR112014030091B1 (es) |
CA (1) | CA2874110C (es) |
CO (1) | CO7141403A2 (es) |
HK (1) | HK1208674A1 (es) |
IL (1) | IL236031A (es) |
MX (1) | MX349113B (es) |
NZ (1) | NZ701950A (es) |
PL (1) | PL2855467T3 (es) |
RU (1) | RU2647853C2 (es) |
WO (1) | WO2013184476A2 (es) |
ZA (1) | ZA201408654B (es) |
Families Citing this family (39)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
MX355782B (es) | 2010-11-03 | 2018-04-30 | Dow Agrosciences Llc | Composiciones pesticidas y procesos relacionados a las mismas. |
KR102006039B1 (ko) | 2011-10-26 | 2019-07-31 | 다우 아그로사이언시즈 엘엘씨 | 살충 조성물 및 그와 관련된 방법 |
US9282739B2 (en) | 2012-04-27 | 2016-03-15 | Dow Agrosciences Llc | Pesticidal compositions and processes related thereto |
US9708288B2 (en) | 2012-04-27 | 2017-07-18 | Dow Agrosciences Llc | Pesticidal compositions and processes related thereto |
NZ700595A (en) | 2012-04-27 | 2016-04-29 | Dow Agrosciences Llc | Pesticidal compositions and processes related thereto |
KR102063532B1 (ko) | 2012-06-04 | 2020-01-09 | 다우 아그로사이언시즈 엘엘씨 | 특정 2-(피리딘-3-일)티아졸의 제조 방법 |
WO2013184480A2 (en) | 2012-06-04 | 2013-12-12 | Dow Agrosciences Llc | Processes to produce certain 2-(pyridine-3-yl)thiazoles |
MX2016004940A (es) | 2013-10-17 | 2016-06-28 | Dow Agrosciences Llc | Proceso para la preparacion de compuestos plaguicidas. |
JP2016539095A (ja) | 2013-10-17 | 2016-12-15 | ダウ アグロサイエンシィズ エルエルシー | 有害生物防除性化合物の製造方法 |
EP3057426A4 (en) | 2013-10-17 | 2017-03-29 | Dow AgroSciences LLC | Processes for the preparation of pesticidal compounds |
CN105636445B (zh) | 2013-10-17 | 2018-12-07 | 美国陶氏益农公司 | 制备杀虫化合物的方法 |
CA2925595A1 (en) | 2013-10-17 | 2015-04-23 | Dow Agrosciences Llc | Processes for the preparation of pesticidal compounds |
MX2016004941A (es) | 2013-10-17 | 2016-06-28 | Dow Agrosciences Llc | Proceso para la preparacion de compuestos plaguicidas. |
JP2016535008A (ja) | 2013-10-17 | 2016-11-10 | ダウ アグロサイエンシィズ エルエルシー | 有害生物防除化合物の調製法 |
RU2016119566A (ru) | 2013-10-22 | 2017-11-28 | ДАУ АГРОСАЙЕНСИЗ ЭлЭлСи | Синергетические пестицидные композиции и относящиеся к ним способы |
MX2016005304A (es) | 2013-10-22 | 2017-03-01 | Dow Agrosciences Llc | Composiciones pesticidas sinergicas y metodos relacionados. |
AU2014340409B2 (en) | 2013-10-22 | 2017-09-07 | Dow Agrosciences Llc | Synergistic pesticidal compositions and related methods |
WO2015061163A1 (en) | 2013-10-22 | 2015-04-30 | Dow Agrosciences Llc | Pesticidal compositions and related methods |
JP2016535739A (ja) | 2013-10-22 | 2016-11-17 | ダウ アグロサイエンシィズ エルエルシー | 農薬組成物および関連する方法 |
MX2016005317A (es) | 2013-10-22 | 2016-08-12 | Dow Agrosciences Llc | Composiciones pesticidas y metodos relacionados. |
EP3060054A4 (en) | 2013-10-22 | 2017-04-05 | Dow AgroSciences LLC | Synergistic pesticidal compositions and related methods |
TW201519774A (zh) | 2013-10-22 | 2015-06-01 | Dow Agrosciences Llc | 協同性殺蟲組成物及相關方法(六) |
TW201519773A (zh) | 2013-10-22 | 2015-06-01 | Dow Agrosciences Llc | 協同性殺蟲組成物及相關方法(五) |
AR098105A1 (es) | 2013-10-22 | 2016-05-04 | Dow Agrosciences Llc | Composiciones plaguicidas y métodos relacionados |
AU2014340412B2 (en) | 2013-10-22 | 2017-04-20 | Dow Agrosciences Llc | Synergistic pesticidal compositions and related methods |
JP2016535025A (ja) | 2013-10-22 | 2016-11-10 | ダウ アグロサイエンシィズ エルエルシー | 相乗的有害生物防除組成物および関連する方法 |
WO2015061151A1 (en) | 2013-10-22 | 2015-04-30 | Dow Agrosciences Llc | Pesticidal compositions and related methods |
JP2016535026A (ja) | 2013-10-22 | 2016-11-10 | ダウ アグロサイエンシィズ エルエルシー | 相乗的有害生物防除組成物および関連する方法 |
EP3060044A4 (en) | 2013-10-22 | 2017-04-05 | Dow AgroSciences LLC | Synergistic pesticidal compositions and related methods |
KR20160074585A (ko) | 2013-10-22 | 2016-06-28 | 다우 아그로사이언시즈 엘엘씨 | 상승작용적 살충 조성물 및 관련 방법 |
TW201519786A (zh) | 2013-10-22 | 2015-06-01 | Dow Agrosciences Llc | 殺蟲組成物及相關方法(一) |
AR098108A1 (es) | 2014-07-31 | 2016-05-04 | Dow Agrosciences Llc | Proceso para la preparación de 3-(3-cloro-1h-pirazol-1-il)piridina |
WO2016018442A1 (en) | 2014-07-31 | 2016-02-04 | Dow Agrosciences Llc | Process for the preparation of 3-(3-chloro-1h-pyrazol-1-yl)pyridine |
CN106488908A (zh) | 2014-07-31 | 2017-03-08 | 美国陶氏益农公司 | 制备3‑(3‑氯‑1h‑吡唑‑1‑基)吡啶的方法 |
EP3183238A4 (en) | 2014-08-19 | 2018-01-10 | Dow AgroSciences LLC | Process for the preparation of 3-(3-chloro-1h-pyrazol-1-yl)pyridine |
KR20170058388A (ko) | 2014-09-12 | 2017-05-26 | 다우 아그로사이언시즈 엘엘씨 | 3-(3-클로로-1h-피라졸-1-일)피리딘의 제조 방법 |
WO2016170130A1 (en) | 2015-04-22 | 2016-10-27 | Basf Se | Molluscicide and bait composition comprising a molluscicide |
EP3562807B1 (en) | 2016-12-29 | 2022-08-03 | Corteva Agriscience LLC | Processes for the preparation of pesticidal compounds |
US10233155B2 (en) | 2016-12-29 | 2019-03-19 | Dow Agrosciences Llc | Processes for the preparation of pesticide compounds |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5219824A (en) * | 1987-02-09 | 1993-06-15 | Monsanto Company | Substituted 2,6-substituted pyridine compounds useful as herbicides |
RU2083562C1 (ru) * | 1993-02-05 | 1997-07-10 | Исихара Сангио Кайся Лтд. | Производные пиридина, способ их получения, инсектицидная композиция |
AU5692398A (en) * | 1996-12-09 | 1998-07-03 | Proscript, Inc. | Substituted 5-amino-1,3,4-thiadiazole-2-thiones |
GB0701426D0 (en) * | 2007-01-25 | 2007-03-07 | Univ Sheffield | Compounds and their use |
UA107791C2 (en) * | 2009-05-05 | 2015-02-25 | Dow Agrosciences Llc | Pesticidal compositions |
KR102063532B1 (ko) | 2012-06-04 | 2020-01-09 | 다우 아그로사이언시즈 엘엘씨 | 특정 2-(피리딘-3-일)티아졸의 제조 방법 |
-
2013
- 2013-05-30 KR KR1020147033734A patent/KR102063532B1/ko active IP Right Grant
- 2013-05-30 MX MX2014014882A patent/MX349113B/es active IP Right Grant
- 2013-05-30 US US13/905,220 patent/US9108952B2/en active Active
- 2013-05-30 CN CN201380039893.4A patent/CN104507935B/zh active Active
- 2013-05-30 RU RU2014153131A patent/RU2647853C2/ru active
- 2013-05-30 BR BR112014030091-7A patent/BR112014030091B1/pt active IP Right Grant
- 2013-05-30 CA CA2874110A patent/CA2874110C/en active Active
- 2013-05-30 NZ NZ701950A patent/NZ701950A/en unknown
- 2013-05-30 AU AU2013272007A patent/AU2013272007B2/en active Active
- 2013-05-30 PL PL13800850T patent/PL2855467T3/pl unknown
- 2013-05-30 EP EP13800850.3A patent/EP2855467B1/en active Active
- 2013-05-30 WO PCT/US2013/043208 patent/WO2013184476A2/en active Application Filing
- 2013-05-30 JP JP2015516068A patent/JP6181166B2/ja active Active
- 2013-06-03 AR ARP130101942 patent/AR091246A1/es active IP Right Grant
-
2014
- 2014-11-25 ZA ZA2014/08654A patent/ZA201408654B/en unknown
- 2014-12-02 IL IL236031A patent/IL236031A/en active IP Right Grant
- 2014-12-03 CO CO14265675A patent/CO7141403A2/es unknown
-
2015
- 2015-06-19 US US14/744,673 patent/US20150284377A1/en not_active Abandoned
- 2015-09-23 HK HK15109331.2A patent/HK1208674A1/xx unknown
Also Published As
Publication number | Publication date |
---|---|
CN104507935A (zh) | 2015-04-08 |
BR112014030091A2 (pt) | 2017-06-27 |
JP2015520189A (ja) | 2015-07-16 |
EP2855467B1 (en) | 2016-12-07 |
NZ701950A (en) | 2016-04-29 |
AR091246A1 (es) | 2015-01-21 |
IL236031A (en) | 2016-10-31 |
EP2855467A2 (en) | 2015-04-08 |
IL236031A0 (en) | 2015-02-01 |
RU2647853C2 (ru) | 2018-03-21 |
US9108952B2 (en) | 2015-08-18 |
MX2014014882A (es) | 2015-11-16 |
RU2014153131A (ru) | 2016-08-10 |
HK1208674A1 (en) | 2016-03-11 |
KR20150016297A (ko) | 2015-02-11 |
JP6181166B2 (ja) | 2017-08-16 |
US20130324737A1 (en) | 2013-12-05 |
PL2855467T3 (pl) | 2017-06-30 |
CN104507935B (zh) | 2016-10-19 |
CA2874110A1 (en) | 2013-12-12 |
EP2855467A4 (en) | 2015-12-30 |
AU2013272007B2 (en) | 2017-02-16 |
WO2013184476A2 (en) | 2013-12-12 |
AU2013272007A1 (en) | 2014-12-04 |
CA2874110C (en) | 2020-07-14 |
ZA201408654B (en) | 2017-06-28 |
BR112014030091B1 (pt) | 2019-01-15 |
KR102063532B1 (ko) | 2020-01-09 |
CO7141403A2 (es) | 2014-12-12 |
WO2013184476A3 (en) | 2014-01-30 |
US20150284377A1 (en) | 2015-10-08 |
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