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MX2019005749A - Composicion de polietileno para moldeo por soplado con resistencia al agrietamiento por tension alta. - Google Patents

Composicion de polietileno para moldeo por soplado con resistencia al agrietamiento por tension alta.

Info

Publication number
MX2019005749A
MX2019005749A MX2019005749A MX2019005749A MX2019005749A MX 2019005749 A MX2019005749 A MX 2019005749A MX 2019005749 A MX2019005749 A MX 2019005749A MX 2019005749 A MX2019005749 A MX 2019005749A MX 2019005749 A MX2019005749 A MX 2019005749A
Authority
MX
Mexico
Prior art keywords
polyethylene composition
blow molding
cracking resistance
high stress
stress cracking
Prior art date
Application number
MX2019005749A
Other languages
English (en)
Inventor
Lothar Marczinke Bernd
Meier Gerhardus
Schueller Ulf
Dötsch Diana
Damm Elke
Fibla Claudio
Original Assignee
Basell Polyolefine Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basell Polyolefine Gmbh filed Critical Basell Polyolefine Gmbh
Publication of MX2019005749A publication Critical patent/MX2019005749A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/06—Polyethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/001—Multistage polymerisation processes characterised by a change in reactor conditions without deactivating the intermediate polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/14—Monomers containing five or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/646—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/646—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64
    • C08F4/6465—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64 containing silicium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/647—Catalysts containing a specific non-metal or metal-free compound
    • C08F4/649—Catalysts containing a specific non-metal or metal-free compound organic
    • C08F4/6491—Catalysts containing a specific non-metal or metal-free compound organic hydrocarbon
    • C08F4/6492—Catalysts containing a specific non-metal or metal-free compound organic hydrocarbon containing aliphatic unsaturation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/647—Catalysts containing a specific non-metal or metal-free compound
    • C08F4/649—Catalysts containing a specific non-metal or metal-free compound organic
    • C08F4/6494—Catalysts containing a specific non-metal or metal-free compound organic containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
    • C08L23/0815—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/04—Broad molecular weight distribution, i.e. Mw/Mn > 6
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/07—High density, i.e. > 0.95 g/cm3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/09—Long chain branches
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/12—Melt flow index or melt flow ratio
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/17—Viscosity
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/26—Use as polymer for film forming
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2308/00—Chemical blending or stepwise polymerisation process with the same catalyst
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2314/00—Polymer mixtures characterised by way of preparation
    • C08L2314/02—Ziegler natta catalyst

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Emergency Medicine (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

Una composición de polietileno particularmente adecuada para producir artículos huecos moldeados por soplado, que tiene las siguientes características: 1) una densidad entre 0,948 y 0,952 g/cm3 determinada de conformidad con la ISO 1183-1 a 23°C; 2) relación de MIF/MIP de 12 a 25; 3) 10 MIF de 18 a 40 g/10 min.; 4) Mz igual o mayor 1.200.000 g/mol; 5) ?0.02 de 35,000 a 55,000 Pa.s; 6) índice de ramificación de cadena larga, LCBI, menor o igual a 0,55; 7) relación (?0.02/1000)/ LCBI de 55 a 75.
MX2019005749A 2016-11-24 2017-10-30 Composicion de polietileno para moldeo por soplado con resistencia al agrietamiento por tension alta. MX2019005749A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP16200492 2016-11-24
PCT/EP2017/077798 WO2018095702A1 (en) 2016-11-24 2017-10-30 Polyethylene composition for blow molding having high stress cracking resistance

Publications (1)

Publication Number Publication Date
MX2019005749A true MX2019005749A (es) 2019-08-12

Family

ID=57421659

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2019005749A MX2019005749A (es) 2016-11-24 2017-10-30 Composicion de polietileno para moldeo por soplado con resistencia al agrietamiento por tension alta.

Country Status (12)

Country Link
US (1) US10920050B2 (es)
EP (1) EP3545007B1 (es)
JP (1) JP6896074B2 (es)
KR (1) KR102233320B1 (es)
CN (1) CN109963880B (es)
BR (1) BR112019009762B1 (es)
CA (1) CA3044313C (es)
ES (1) ES2929988T3 (es)
MX (1) MX2019005749A (es)
PL (1) PL3545007T3 (es)
RU (1) RU2722013C1 (es)
WO (1) WO2018095702A1 (es)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BR112021004198B1 (pt) * 2018-09-20 2024-01-30 Basell Polyolefine Gmbh Composição de polietileno para filmes
WO2024056727A1 (en) 2022-09-15 2024-03-21 Basell Polyolefine Gmbh Polyethylene composition for blow molding having an improved swell behavior
EP4587491A1 (en) 2022-09-15 2025-07-23 Basell Polyolefine GmbH Polyethylene composition for blow molding having an improved swell behavior
US12351706B2 (en) 2022-09-15 2025-07-08 Basell Polyolefine Gmbh Polyethylene composition for blow molding having an improved swell behavior
WO2024056725A1 (en) 2022-09-15 2024-03-21 Basell Polyolefine Gmbh Polyethylene composition for blow molding having an improved swell behavior

Family Cites Families (22)

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NL162661B (nl) 1968-11-21 1980-01-15 Montedison Spa Werkwijze om een katalysator te bereiden voor de poly- merisatie van alkenen-1.
YU35844B (en) 1968-11-25 1981-08-31 Montedison Spa Process for obtaining catalysts for the polymerization of olefines
US3835201A (en) 1972-08-29 1974-09-10 Uniroyal Inc Thermoplastic blend of copolymer rubber and polyolefin plastic
IT1096661B (it) 1978-06-13 1985-08-26 Montedison Spa Procedimento per la preparazione di prodotti in forma sferoidale solidi a temperatura ambiente
IT1098272B (it) 1978-08-22 1985-09-07 Montedison Spa Componenti,di catalizzatori e catalizzatori per la polimerizzazione delle alfa-olefine
FI80055C (fi) 1986-06-09 1990-04-10 Neste Oy Foerfarande foer framstaellning av katalytkomponenter foer polymerisation av olefiner.
IT1230134B (it) 1989-04-28 1991-10-14 Himont Inc Componenti e catalizzatori per la polimerizzazione di olefine.
JP2879347B2 (ja) 1989-10-02 1999-04-05 チッソ株式会社 オレフィン重合用触媒の製法
ES2213898T3 (es) 1997-03-29 2004-09-01 Basell Poliolefine Italia S.P.A. Aductos de dicloruro de magnesio/alcohol, procedimiento para su preparacion y componentes catalizadores obtenidos a partir de estos.
KR101167538B1 (ko) * 2003-05-29 2012-07-20 바셀 폴리올레핀 이탈리아 에스.알.엘 촉매 성분의 제조 방법 및 그로부터 수득된 성분들
BRPI0413229B1 (pt) * 2003-08-20 2015-05-05 Basell Poliolefine Srl Processo para preparar um polietileno de larga distribuição de pesos moleculares
WO2005058982A1 (en) * 2003-12-19 2005-06-30 Basell Polyolefine Gmbh Process for the (co)polymerization of ethylene
US20070010626A1 (en) 2005-07-11 2007-01-11 Shankernarayanan Manivakkam J Polyethylene compositions
RU2444546C2 (ru) * 2006-04-07 2012-03-10 ДАУ ГЛОБАЛ ТЕКНОЛОДЖИЗ ЭлЭлСи Полиолефиновые композиции, изделия из них и методы их получения
DE102007031449A1 (de) 2007-07-05 2009-01-08 Basell Polyolefine Gmbh PE-Formmasse zum Blasformen von Kleinhohlkörpern mit niedriger Dichte
EP2909264B1 (en) * 2012-10-22 2020-11-25 Basell Polyolefine GmbH Polyethylene composition having high swell ratio
BR112015008932B1 (pt) 2012-10-22 2021-03-30 Basell Polyolefine Gmbh Composição de polietileno, artigos manufaturados compreendendo a mesma e processo para sua preparação
MX342762B (es) * 2013-02-27 2016-10-12 Basell Polyolefine Gmbh Procesos de polietileno y sus composiciones.
EP2818508A1 (en) * 2013-06-25 2014-12-31 Basell Polyolefine GmbH Polyethylene composition having high impact and stress cracking resistance
EP2818509A1 (en) 2013-06-25 2014-12-31 Basell Polyolefine GmbH Polyethylene composition for blow molding having high stress cracking resistance
BR112017010058A2 (pt) 2014-11-13 2018-01-02 Total Res & Technology Feluy artigo rotomoldados compreendendo pelo menos uma camada compreendendo uma resina de polietileno catalisada com metaloceno
ES2834034T3 (es) * 2016-11-24 2021-06-16 Basell Polyolefine Gmbh Composición de polietileno para moldeado por soplado que tiene alta resistencia a la rotura por tensión

Also Published As

Publication number Publication date
CN109963880A (zh) 2019-07-02
RU2722013C1 (ru) 2020-05-26
KR102233320B1 (ko) 2021-03-30
US10920050B2 (en) 2021-02-16
KR20190078611A (ko) 2019-07-04
EP3545007A1 (en) 2019-10-02
CA3044313C (en) 2022-07-12
ES2929988T3 (es) 2022-12-05
US20190309148A1 (en) 2019-10-10
PL3545007T3 (pl) 2022-12-27
JP6896074B2 (ja) 2021-06-30
EP3545007B1 (en) 2022-10-19
WO2018095702A1 (en) 2018-05-31
CA3044313A1 (en) 2018-05-31
BR112019009762A2 (pt) 2019-08-13
BR112019009762B1 (pt) 2022-09-20
JP2019535875A (ja) 2019-12-12
CN109963880B (zh) 2021-08-03

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