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MX2016014076A - Copolimeros de propileno-etileno aleatorios y proceso para su preparacion. - Google Patents

Copolimeros de propileno-etileno aleatorios y proceso para su preparacion.

Info

Publication number
MX2016014076A
MX2016014076A MX2016014076A MX2016014076A MX2016014076A MX 2016014076 A MX2016014076 A MX 2016014076A MX 2016014076 A MX2016014076 A MX 2016014076A MX 2016014076 A MX2016014076 A MX 2016014076A MX 2016014076 A MX2016014076 A MX 2016014076A
Authority
MX
Mexico
Prior art keywords
ethylene copolymers
preparation
random propylene
content
ethylene
Prior art date
Application number
MX2016014076A
Other languages
English (en)
Other versions
MX388983B (es
Inventor
Piemontesi Fabrizio
Cathelin Caroline
Guidotti Simona
Liguori Dario
Morini Giampiero
Tartari Davide
Vitale Gianni
Original Assignee
Basell Poliolefine Italia Srl
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=50639342&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=MX2016014076(A) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Basell Poliolefine Italia Srl filed Critical Basell Poliolefine Italia Srl
Publication of MX2016014076A publication Critical patent/MX2016014076A/es
Publication of MX388983B publication Critical patent/MX388983B/es

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04Monomers containing three or four carbon atoms
    • C08F210/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/34Polymerisation in gaseous state
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/38Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/642Component covered by group C08F4/64 with an organo-aluminium compound
    • C08F4/6421Titanium tetrahalides with organo-aluminium compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/642Component covered by group C08F4/64 with an organo-aluminium compound
    • C08F4/6423Component of C08F4/64 containing at least two different metals
    • C08F4/6425Component of C08F4/64 containing at least two different metals containing magnesium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/646Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64
    • C08F4/6465Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64 containing silicium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/04Broad molecular weight distribution, i.e. Mw/Mn > 6
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/12Melt flow index or melt flow ratio
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/26Use as polymer for film forming

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Copolímeros de propileno-etileno que muestran un contenido de etileno entre un 0,1% y un 10% en peso, una distribución del peso molecular (MWD), expresada en términos de Mw/Mn, mayor a 3,0 y un contenido de fracción soluble en xileno (XS) y contenido de etileno (C2) tal que el punto definido por los valores cae debajo de la línea dada por la ecuación XS= 1,0296·e0,435C2 muestran una alta transparencia y una temperatura de fusión baja.
MX2016014076A 2014-05-06 2015-05-06 Copolimeros de propileno-etileno aleatorios y proceso para su preparacion. MX388983B (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP14167178 2014-05-06
PCT/EP2015/059919 WO2015169831A1 (en) 2014-05-06 2015-05-06 Random propylene-ethylene copolymers and process for their preparation

Publications (2)

Publication Number Publication Date
MX2016014076A true MX2016014076A (es) 2017-02-14
MX388983B MX388983B (es) 2025-03-20

Family

ID=50639342

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2016014076A MX388983B (es) 2014-05-06 2015-05-06 Copolimeros de propileno-etileno aleatorios y proceso para su preparacion.

Country Status (9)

Country Link
US (1) US9676883B2 (es)
EP (1) EP3140328B1 (es)
JP (1) JP6307178B2 (es)
KR (1) KR101764561B1 (es)
CN (1) CN106232643B (es)
BR (1) BR112016024633B1 (es)
MX (1) MX388983B (es)
RU (1) RU2662152C2 (es)
WO (1) WO2015169831A1 (es)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015169653A1 (en) 2014-05-06 2015-11-12 Basell Poliolefine Italia S.R.L. Random propylene-ethylene copolymers
ES2797898T3 (es) * 2015-09-10 2020-12-04 Basell Poliolefine Italia Srl Catalizador para la polimerización de olefinas
ES2704727T3 (es) 2015-11-17 2019-03-19 Borealis Ag Composición de TPO de flujo elevado con excelente balance de propiedades mecánicas para interiores de automóviles
US10494517B1 (en) 2016-12-05 2019-12-03 Basell Poliolefine Italia S.R.L. Heterophasic propylene copolymers
RU2734534C1 (ru) * 2017-07-19 2020-10-20 Базелл Полиолефин Италия С.Р.Л. Сополимеры пропилена
WO2019241063A1 (en) * 2018-06-11 2019-12-19 W.R. Grace & Co.-Conn. Propylene-ethylene copolymer compositions suitable for hot fill packaging of foodstuffs
EP3814421B1 (en) * 2018-06-29 2023-12-20 Borealis AG C2c3 random copolymer composition
CN112469745B (zh) * 2018-08-22 2023-11-24 巴塞尔聚烯烃意大利有限公司 无规丙烯-乙烯共聚物
TW202104290A (zh) * 2019-05-29 2021-02-01 奧地利商柏列利斯股份公司 C2c3隨機共聚物
KR20240076546A (ko) 2022-11-22 2024-05-30 한화토탈에너지스 주식회사 공중합성이 개선된 프로필렌계 공중합체의 제조방법
KR20250041439A (ko) 2023-09-18 2025-03-25 한화토탈에너지스 주식회사 폴리프로필렌 제조용 고체촉매 및 블록공중합체 제조방법

Family Cites Families (38)

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JPS5490382A (en) * 1977-12-28 1979-07-18 Mitsubishi Petrochem Co Ltd Preparation of olefin polymer
IT1096661B (it) 1978-06-13 1985-08-26 Montedison Spa Procedimento per la preparazione di prodotti in forma sferoidale solidi a temperatura ambiente
IT1098272B (it) 1978-08-22 1985-09-07 Montedison Spa Componenti,di catalizzatori e catalizzatori per la polimerizzazione delle alfa-olefine
JPS5582103A (en) 1978-12-15 1980-06-20 Mitsubishi Petrochem Co Ltd Production of alpha-olefin polymer
JPH06104693B2 (ja) 1986-01-06 1994-12-21 東邦チタニウム株式会社 オレフイン類重合用触媒
EP0268685B2 (en) 1986-05-06 1996-08-07 Toho Titanium Co. Ltd. Catalyst for polymerizing olefins
JP2514015B2 (ja) 1987-01-07 1996-07-10 東邦チタニウム株式会社 オレフイン類重合用固体触媒成分
IT1221653B (it) 1987-11-27 1990-07-12 Ausimonti Spa Copolimeri cristallini del propilene
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BR112012031137B1 (pt) * 2010-06-10 2020-05-26 Ineos Technologies Usa Llc Processo de polimerização de olefinas
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WO2015169653A1 (en) 2014-05-06 2015-11-12 Basell Poliolefine Italia S.R.L. Random propylene-ethylene copolymers

Also Published As

Publication number Publication date
US9676883B2 (en) 2017-06-13
BR112016024633B1 (pt) 2022-05-03
RU2016145451A3 (es) 2018-06-07
EP3140328B1 (en) 2020-11-18
KR20160143857A (ko) 2016-12-14
EP3140328A1 (en) 2017-03-15
CN106232643B (zh) 2019-02-26
BR112016024633A2 (pt) 2017-08-15
CN106232643A (zh) 2016-12-14
US20170073444A1 (en) 2017-03-16
RU2662152C2 (ru) 2018-07-24
WO2015169831A1 (en) 2015-11-12
RU2016145451A (ru) 2018-06-07
MX388983B (es) 2025-03-20
JP6307178B2 (ja) 2018-04-04
JP2017514000A (ja) 2017-06-01
KR101764561B1 (ko) 2017-08-02

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