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MX2016007388A - Producto abs con retardancia a la flama mejorada. - Google Patents

Producto abs con retardancia a la flama mejorada.

Info

Publication number
MX2016007388A
MX2016007388A MX2016007388A MX2016007388A MX2016007388A MX 2016007388 A MX2016007388 A MX 2016007388A MX 2016007388 A MX2016007388 A MX 2016007388A MX 2016007388 A MX2016007388 A MX 2016007388A MX 2016007388 A MX2016007388 A MX 2016007388A
Authority
MX
Mexico
Prior art keywords
weight
graft
monomer
acrylonitrile
flame retardance
Prior art date
Application number
MX2016007388A
Other languages
English (en)
Other versions
MX384007B (es
Inventor
Niessner Norbert
Ahn Sangjun
Walker Roland
Pepers Michel
Barth Johannes
Michels Gisbert
Hwang Younghwa
Verstraeten Rudy
Patcas Florian
J Banaszak Brian
Original Assignee
Ineos Styrolution Group Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ineos Styrolution Group Gmbh filed Critical Ineos Styrolution Group Gmbh
Publication of MX2016007388A publication Critical patent/MX2016007388A/es
Publication of MX384007B publication Critical patent/MX384007B/es

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F279/00Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
    • C08F279/02Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
    • C08F279/04Vinyl aromatic monomers and nitriles as the only monomers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02Homopolymers or copolymers of hydrocarbons
    • C08L25/04Homopolymers or copolymers of styrene
    • C08L25/08Copolymers of styrene
    • C08L25/12Copolymers of styrene with unsaturated nitriles
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L55/00Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
    • C08L55/02ABS [Acrylonitrile-Butadiene-Styrene] polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L69/00Compositions of polycarbonates; Compositions of derivatives of polycarbonates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L69/00Compositions of polycarbonates; Compositions of derivatives of polycarbonates
    • C08L69/005Polyester-carbonates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C08L77/02Polyamides derived from omega-amino carboxylic acids or from lactams thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C08L77/06Polyamides derived from polyamines and polycarboxylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/17Viscosity
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2800/00Copolymer characterised by the proportions of the comonomers expressed
    • C08F2800/20Copolymer characterised by the proportions of the comonomers expressed as weight or mass percentages
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2325/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
    • C08J2325/02Homopolymers or copolymers of hydrocarbons
    • C08J2325/04Homopolymers or copolymers of styrene
    • C08J2325/08Copolymers of styrene
    • C08J2325/12Copolymers of styrene with unsaturated nitriles
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/10Transparent films; Clear coatings; Transparent materials
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/30Applications used for thermoforming
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/04Thermoplastic elastomer

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Graft Or Block Polymers (AREA)

Abstract

La invención se relaciona con composiciones de moldeo ABS termoplásticas que comprenden componentes A) y B): A) de 5 a 80% en peso de un polímero de injerto A) que tiene una distribución de tamaño de partícula bimodal hecha de, en base a A), a1) de 40 a 90% en peso de una base de injerto elastomérica particulada a1), obtenible por medio de polimerización de, basada en a1), a11) de 75.5 a 89.5% en peso de al menos un dieno conjugado, a12) de 10.5 a 24.5% en peso de al menos un monómero vinilaromático y a2) de 10 a 60% en peso de un injerto a2) hecho de, basado en a2), a21) de 65 a 95% en peso de al menos un monómero vinilaromático, a22) de 5 a 35% en peso de acrilonitrilo, y a23) de 0 a 30% en peso de al menos otro monómero monoetilenicalmente insaturado, B) de 20 a 95% en peso de un polímero termoplástico B) que tiene un número de viscosidad VN (determinado de acuerdo a DIN 53726 a 25 °C, 0.5% en peso en dimetilformamida) de 50 a 120 ml/g, hecho de, basado en B), b1) de 69 a 81% en peso de al menos un monómero vinilaromático, b2) de 19 a 31% en peso de acrilonitrilo, y b3) de 0 a 30% en peso de al menos otro monómero monotilénicamente insaturado. La invención además se relaciona con un proceso para la preparación del copolímero de injerto A y del copolímero de injerto obtenible por dicho proceso.
MX2016007388A 2013-12-11 2014-04-16 Producto abs con retardancia a la flama mejorada. MX384007B (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP13196751 2013-12-11
PCT/EP2014/057826 WO2015086164A1 (en) 2013-12-11 2014-04-16 Abs product with improved fire retardancy

Publications (2)

Publication Number Publication Date
MX2016007388A true MX2016007388A (es) 2016-11-14
MX384007B MX384007B (es) 2025-03-14

Family

ID=49884914

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2016007388A MX384007B (es) 2013-12-11 2014-04-16 Producto abs con retardancia a la flama mejorada.

Country Status (6)

Country Link
US (1) US10059791B2 (es)
EP (1) EP3080201B1 (es)
KR (1) KR102128531B1 (es)
ES (1) ES2703340T3 (es)
MX (1) MX384007B (es)
WO (1) WO2015086164A1 (es)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106232648B (zh) 2014-04-30 2019-06-07 英力士苯领集团股份公司 具有最佳残余单体含量的热塑性成型化合物
ES2763440T3 (es) * 2015-03-25 2020-05-28 Ineos Styrolution Group Gmbh Procedimiento para preparar composiciones poliméricas termoplásticas con grado optimizado de reticulación
AU2017100888B4 (en) * 2016-06-30 2018-03-22 Ptt Global Chemical Public Company Limited Polycarbonate composition with improved mechanical properties
KR102511427B1 (ko) * 2019-07-24 2023-03-20 주식회사 엘지화학 아크릴계 공중합체 응집제 및 이를 이용한 그라프트 공중합체의 제조방법
KR102719853B1 (ko) * 2019-07-24 2024-10-22 주식회사 엘지화학 열가소성 수지 및 이의 제조방법
CN115768830A (zh) * 2020-05-29 2023-03-07 英力士苯领集团股份公司 低密度abs复合物

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA667626A (en) 1958-07-24 1963-07-30 W. Vanderhoff John Self-extinguishing vinyl aromatic polymer compositions and method of making the same
US3014954A (en) 1959-06-16 1961-12-26 Monsanto Chemicals Polyphosphorus esters and method of preparing same
FR1580834A (es) 1968-01-04 1969-09-12
CH578138A5 (es) 1973-02-28 1976-07-30 Jylland Gummivarefabriken As
DE2407776A1 (de) 1974-02-19 1975-09-04 Licentia Gmbh Schaltung zur regelung der betriebsspannung fuer die transistor-zeilenendstufe eines fernsehempfaengers
DE2715932A1 (de) 1977-04-09 1978-10-19 Bayer Ag Schnellkristallisierende poly(aethylen/alkylen)-terephthalate
DE19728629A1 (de) * 1997-07-04 1999-01-07 Basf Ag Thermoplastische Formmassen mit geringer Eigenfarbe
EP1752478A1 (en) * 2005-08-08 2007-02-14 Basf Aktiengesellschaft A process for the production of a graft copolymer having a bimodal particle distribution.
EP1783170A1 (en) * 2005-10-24 2007-05-09 Basf Aktiengesellschaft Thermoplastic molding composition comprising finely divided inert materials
PL2054472T3 (pl) 2006-08-18 2015-11-30 Styrolution Europe Gmbh Termoplastyczne tłoczywa na bazie akrylonitrylu, styrenu i butadienu, oraz środek aglomerujący zawierający akrylan etylu i metakryloamid
US20120034478A1 (en) 2010-08-09 2012-02-09 Basf Se Thermoplastic moulding composition with improved adhesion of electroplated metal layer
WO2012019982A1 (en) * 2010-08-09 2012-02-16 Basf Se Thermoplastic moulding compositions with improved adhesion of electroplated metal layer
EP2652035B1 (en) * 2010-12-16 2024-03-27 INEOS Styrolution Europe GmbH Thermoplastic moulding compositions for metal plated articles with improved resistance against repeated impact
MX382688B (es) * 2013-04-18 2025-03-13 Styrolution Group Gmbh Materiales de moldeo termoplástico a base de acrilonitrilo, butadieno y estireno.

Also Published As

Publication number Publication date
KR102128531B1 (ko) 2020-07-01
US20160304652A1 (en) 2016-10-20
KR20160098349A (ko) 2016-08-18
ES2703340T3 (es) 2019-03-08
EP3080201B1 (en) 2018-11-28
MX384007B (es) 2025-03-14
US10059791B2 (en) 2018-08-28
EP3080201A1 (en) 2016-10-19
WO2015086164A1 (en) 2015-06-18

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