MX2015007532A - Proceso para la preparacion de 4-amino-5-fluor-3-cloro-6-(sustitui do) picolinatos. - Google Patents
Proceso para la preparacion de 4-amino-5-fluor-3-cloro-6-(sustitui do) picolinatos.Info
- Publication number
- MX2015007532A MX2015007532A MX2015007532A MX2015007532A MX2015007532A MX 2015007532 A MX2015007532 A MX 2015007532A MX 2015007532 A MX2015007532 A MX 2015007532A MX 2015007532 A MX2015007532 A MX 2015007532A MX 2015007532 A MX2015007532 A MX 2015007532A
- Authority
- MX
- Mexico
- Prior art keywords
- picolinates
- fluoro
- chloro
- amino
- preparation
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 2
- -1 4-Amino-5-fluoro-3-chloro-6-(substituted)picolinates Chemical class 0.000 abstract 3
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 abstract 2
- DTQVDTLACAAQTR-UHFFFAOYSA-N Trifluoroacetic acid Chemical compound OC(=O)C(F)(F)F DTQVDTLACAAQTR-UHFFFAOYSA-N 0.000 abstract 2
- 230000008878 coupling Effects 0.000 abstract 1
- 238000010168 coupling process Methods 0.000 abstract 1
- 238000005859 coupling reaction Methods 0.000 abstract 1
- 239000012025 fluorinating agent Substances 0.000 abstract 1
- 238000003682 fluorination reaction Methods 0.000 abstract 1
- 239000004009 herbicide Substances 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- WDWDWGRYHDPSDS-UHFFFAOYSA-N methanimine Chemical class N=C WDWDWGRYHDPSDS-UHFFFAOYSA-N 0.000 abstract 1
- BHAAPTBBJKJZER-UHFFFAOYSA-N p-anisidine Chemical compound COC1=CC=C(N)C=C1 BHAAPTBBJKJZER-UHFFFAOYSA-N 0.000 abstract 1
- SIOXPEMLGUPBBT-UHFFFAOYSA-N picolinic acid Chemical class OC(=O)C1=CC=CC=N1 SIOXPEMLGUPBBT-UHFFFAOYSA-N 0.000 abstract 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
- C07D213/79—Acids; Esters
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C251/00—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton
- C07C251/02—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton containing imino groups
- C07C251/04—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton containing imino groups having carbon atoms of imino groups bound to hydrogen atoms or to acyclic carbon atoms
- C07C251/10—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton containing imino groups having carbon atoms of imino groups bound to hydrogen atoms or to acyclic carbon atoms to carbon atoms of an unsaturated carbon skeleton
- C07C251/12—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton containing imino groups having carbon atoms of imino groups bound to hydrogen atoms or to acyclic carbon atoms to carbon atoms of an unsaturated carbon skeleton being acyclic
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
- C07D213/79—Acids; Esters
- C07D213/803—Processes of preparation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Pyridine Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
4-Amino-5-flúor-3-cloro-6-(sustituido) picolinato son preparados a partir de ácido trifluoroacético,p-5 metoxianilina, un C1-C4 alquil propiolato y una amina de metileno sustituida mediante una serie de pasos.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201261736841P | 2012-12-13 | 2012-12-13 | |
PCT/US2013/074575 WO2014093580A1 (en) | 2012-12-13 | 2013-12-12 | Process for the preparation of 4-amino-5-fluoro-3-chloro-6-(substituted)picolinates |
Publications (1)
Publication Number | Publication Date |
---|---|
MX2015007532A true MX2015007532A (es) | 2015-10-14 |
Family
ID=50931648
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2015007532A MX2015007532A (es) | 2012-12-13 | 2013-12-12 | Proceso para la preparacion de 4-amino-5-fluor-3-cloro-6-(sustitui do) picolinatos. |
Country Status (16)
Country | Link |
---|---|
US (3) | US9260392B2 (es) |
EP (1) | EP2931047B1 (es) |
JP (1) | JP6239003B2 (es) |
KR (1) | KR20150095785A (es) |
CN (2) | CN105007734B (es) |
AR (1) | AR093978A1 (es) |
AU (1) | AU2013359247B2 (es) |
BR (1) | BR102013032022A2 (es) |
CA (1) | CA2894676A1 (es) |
IL (1) | IL239224B (es) |
MX (1) | MX2015007532A (es) |
NZ (1) | NZ708700A (es) |
PL (1) | PL2931047T3 (es) |
RU (1) | RU2015128095A (es) |
WO (1) | WO2014093580A1 (es) |
ZA (1) | ZA201504165B (es) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BR102014028164A2 (pt) * | 2013-11-12 | 2015-09-08 | Dow Agrosciences Llc | processo para fluoração de compostos |
TW201609652A (zh) | 2013-11-12 | 2016-03-16 | 陶氏農業科學公司 | 用於氟化化合物之過程(三) |
TW201609651A (zh) | 2013-11-12 | 2016-03-16 | 陶氏農業科學公司 | 用於氟化化合物之過程(一) |
TWI726900B (zh) | 2015-08-04 | 2021-05-11 | 美商陶氏農業科學公司 | 用於氟化化合物之過程 |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ZA714760B (en) * | 1970-08-04 | 1972-05-31 | Ici Ltd | Pyridylamine derivatives and pesticidal compositions comprising them |
AR037228A1 (es) | 2001-07-30 | 2004-11-03 | Dow Agrosciences Llc | Compuestos del acido 6-(aril o heteroaril)-4-aminopicolinico, composicion herbicida que los comprende y metodo para controlar vegetacion no deseada |
UA82358C2 (uk) * | 2003-04-02 | 2008-04-10 | Дау Агросайенсиз Ллс | 6-алкіл або алкеніл-4-амінопіколінати гербіцидна композиція, спосіб боротьби з небажаною рослинністю |
TWI396682B (zh) * | 2006-01-13 | 2013-05-21 | Dow Agrosciences Llc | 6-(經多重取代之芳基)-4-胺基吡啶甲酸酯及其作為除草劑之用途 |
PL2327694T3 (pl) * | 2007-10-02 | 2013-12-31 | Dow Agrosciences Llc | Podstawione kwasy 4-aminopikolinowe i ich zastosowanie jako herbicydów |
US8252938B2 (en) * | 2009-06-08 | 2012-08-28 | Dow Agrosciences, Llc. | Process for the preparation of 6-(aryl)-4-aminopicolinates |
CN101798282A (zh) * | 2010-03-30 | 2010-08-11 | 中国科学院上海有机化学研究所 | 多取代的含氟吡啶 |
BR112013018859A2 (pt) * | 2011-01-25 | 2016-07-12 | Dow Agrosciences Llc | "ácidos e ésteres 6-amino-2-substituídos-5-vinilsililpirimidina-4-carboxílicos e ácidos e ésteres 4-amino-6-substituídos-3-vinilsililpiridina-picolínicos como herbicidas" |
TWI537252B (zh) * | 2011-01-25 | 2016-06-11 | 陶氏農業科學公司 | 用於製備4-胺基-5-氟-3-鹵素-6-(經取代之)吡啶甲酸酯的方法(一) |
TWI529163B (zh) * | 2011-01-25 | 2016-04-11 | 陶氏農業科學公司 | 用於製備4-胺基-5-氟-3-鹵素-6-(經取代之)吡啶甲酸酯的方法 |
-
2013
- 2013-12-12 US US14/104,127 patent/US9260392B2/en not_active Expired - Fee Related
- 2013-12-12 WO PCT/US2013/074575 patent/WO2014093580A1/en active Application Filing
- 2013-12-12 CN CN201380064597.XA patent/CN105007734B/zh not_active Expired - Fee Related
- 2013-12-12 PL PL13863202T patent/PL2931047T3/pl unknown
- 2013-12-12 RU RU2015128095A patent/RU2015128095A/ru not_active Application Discontinuation
- 2013-12-12 CA CA2894676A patent/CA2894676A1/en not_active Abandoned
- 2013-12-12 KR KR1020157018308A patent/KR20150095785A/ko not_active Withdrawn
- 2013-12-12 NZ NZ708700A patent/NZ708700A/en not_active IP Right Cessation
- 2013-12-12 MX MX2015007532A patent/MX2015007532A/es unknown
- 2013-12-12 CN CN201710073216.4A patent/CN106977453A/zh active Pending
- 2013-12-12 JP JP2015547525A patent/JP6239003B2/ja not_active Expired - Fee Related
- 2013-12-12 AU AU2013359247A patent/AU2013359247B2/en not_active Ceased
- 2013-12-12 EP EP13863202.1A patent/EP2931047B1/en not_active Not-in-force
- 2013-12-12 BR BRBR102013032022-6A patent/BR102013032022A2/pt not_active Application Discontinuation
- 2013-12-13 AR ARP130104695A patent/AR093978A1/es unknown
-
2015
- 2015-06-04 IL IL239224A patent/IL239224B/en not_active IP Right Cessation
- 2015-06-09 ZA ZA2015/04165A patent/ZA201504165B/en unknown
-
2016
- 2016-02-10 US US15/040,577 patent/US9518019B2/en not_active Expired - Fee Related
- 2016-08-23 US US15/243,996 patent/US20160355468A1/en not_active Abandoned
Also Published As
Publication number | Publication date |
---|---|
WO2014093580A1 (en) | 2014-06-19 |
KR20150095785A (ko) | 2015-08-21 |
US9260392B2 (en) | 2016-02-16 |
BR102013032022A2 (pt) | 2014-10-21 |
US20160159742A1 (en) | 2016-06-09 |
EP2931047B1 (en) | 2017-08-16 |
CN105007734B (zh) | 2017-03-15 |
AU2013359247B2 (en) | 2016-02-18 |
JP2016504318A (ja) | 2016-02-12 |
RU2015128095A (ru) | 2017-01-18 |
AU2013359247A1 (en) | 2014-06-19 |
IL239224A0 (en) | 2015-07-30 |
CN106977453A (zh) | 2017-07-25 |
EP2931047A1 (en) | 2015-10-21 |
NZ708700A (en) | 2016-10-28 |
US20160355468A1 (en) | 2016-12-08 |
IL239224B (en) | 2018-01-31 |
US9518019B2 (en) | 2016-12-13 |
EP2931047A4 (en) | 2016-06-08 |
CA2894676A1 (en) | 2014-06-19 |
ZA201504165B (en) | 2016-11-30 |
PL2931047T3 (pl) | 2018-01-31 |
JP6239003B2 (ja) | 2017-11-29 |
CN105007734A (zh) | 2015-10-28 |
AR093978A1 (es) | 2015-07-01 |
US20140171650A1 (en) | 2014-06-19 |
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