MX2008015756A - Formulaciones desemulsificantes y deshidratantes para crudos pesados a base de copolimeros en bloques bifuncionalizados con aminas. - Google Patents
Formulaciones desemulsificantes y deshidratantes para crudos pesados a base de copolimeros en bloques bifuncionalizados con aminas.Info
- Publication number
- MX2008015756A MX2008015756A MX2008015756A MX2008015756A MX2008015756A MX 2008015756 A MX2008015756 A MX 2008015756A MX 2008015756 A MX2008015756 A MX 2008015756A MX 2008015756 A MX2008015756 A MX 2008015756A MX 2008015756 A MX2008015756 A MX 2008015756A
- Authority
- MX
- Mexico
- Prior art keywords
- formulations
- demulsifying
- dehydrating
- block copolymers
- heavy crude
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title abstract 4
- 238000009472 formulation Methods 0.000 title abstract 3
- 150000001412 amines Chemical class 0.000 title abstract 2
- 229920001400 block copolymer Polymers 0.000 title abstract 2
- 239000010779 crude oil Substances 0.000 title abstract 2
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 abstract 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract 3
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 abstract 2
- 238000009835 boiling Methods 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 239000008096 xylene Substances 0.000 abstract 1
- 150000003738 xylenes Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G33/00—Dewatering or demulsification of hydrocarbon oils
- C10G33/04—Dewatering or demulsification of hydrocarbon oils with chemical means
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2618—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing nitrogen
- C08G65/2621—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing nitrogen containing amine groups
- C08G65/2624—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing nitrogen containing amine groups containing aliphatic amine groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2618—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing nitrogen
- C08G65/2621—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing nitrogen containing amine groups
- C08G65/2627—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing nitrogen containing amine groups containing aromatic or arylaliphatic amine groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2618—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing nitrogen
- C08G65/2621—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing nitrogen containing amine groups
- C08G65/263—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing nitrogen containing amine groups containing heterocyclic amine groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/32—Polymers modified by chemical after-treatment
- C08G65/329—Polymers modified by chemical after-treatment with organic compounds
- C08G65/333—Polymers modified by chemical after-treatment with organic compounds containing nitrogen
- C08G65/33303—Polymers modified by chemical after-treatment with organic compounds containing nitrogen containing amino group
- C08G65/33306—Polymers modified by chemical after-treatment with organic compounds containing nitrogen containing amino group acyclic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/32—Polymers modified by chemical after-treatment
- C08G65/329—Polymers modified by chemical after-treatment with organic compounds
- C08G65/333—Polymers modified by chemical after-treatment with organic compounds containing nitrogen
- C08G65/33303—Polymers modified by chemical after-treatment with organic compounds containing nitrogen containing amino group
- C08G65/33317—Polymers modified by chemical after-treatment with organic compounds containing nitrogen containing amino group heterocyclic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
- C08L71/02—Polyalkylene oxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2650/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G2650/28—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule characterised by the polymer type
- C08G2650/50—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule characterised by the polymer type containing nitrogen, e.g. polyetheramines or Jeffamines(r)
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2650/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G2650/28—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule characterised by the polymer type
- C08G2650/58—Ethylene oxide or propylene oxide copolymers, e.g. pluronics
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Polyethers (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
La presente invención se relaciona con formulaciones desemulsificantes y deshidratantes de crudos pesados a base de copolímeros en bloques de baja polidispersidad bifuncionalizados con aminas. Estas formulaciones pueden contener disolventes cuyo punto de ebullición esté comprendido ente 35 y 200 ºC, preferentemente: diclorometano, cloroformo, tolueno, xilenos, turbosina, nafta o mezcla de ellos.
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
MX2008015756A MX2008015756A (es) | 2008-12-10 | 2008-12-10 | Formulaciones desemulsificantes y deshidratantes para crudos pesados a base de copolimeros en bloques bifuncionalizados con aminas. |
DE200910057556 DE102009057556A1 (de) | 2008-12-10 | 2009-12-09 | Demulgier- und Dehydratisierungs-Formulierungen für schwere Rohöle auf der Basis von mit Aminen bifunktionalisierten Blockcopolymeren |
US12/635,050 US8815960B2 (en) | 2008-12-10 | 2009-12-10 | Demulsifying and dehydrating formulations for heavy crude oils based on block copolymers bifunctionalized with amines |
US14/338,941 US9518231B2 (en) | 2008-12-10 | 2014-07-23 | Demulsifying and dehydrating formulations for heavy crude oils based on block copolymers bifunctionalized with amines |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
MX2008015756A MX2008015756A (es) | 2008-12-10 | 2008-12-10 | Formulaciones desemulsificantes y deshidratantes para crudos pesados a base de copolimeros en bloques bifuncionalizados con aminas. |
Publications (1)
Publication Number | Publication Date |
---|---|
MX2008015756A true MX2008015756A (es) | 2010-06-10 |
Family
ID=42229887
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2008015756A MX2008015756A (es) | 2008-12-10 | 2008-12-10 | Formulaciones desemulsificantes y deshidratantes para crudos pesados a base de copolimeros en bloques bifuncionalizados con aminas. |
Country Status (3)
Country | Link |
---|---|
US (2) | US8815960B2 (es) |
DE (1) | DE102009057556A1 (es) |
MX (1) | MX2008015756A (es) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9745521B2 (en) | 2013-02-28 | 2017-08-29 | Instituto Mexicano Del Petroleo | Dehydrating and desalting compositions of crude oils, using triblock copolymers α,ω-bifunctionalized with amines |
US9752084B2 (en) | 2013-02-26 | 2017-09-05 | Instituto Mexicano Del Petroleo | Block copolymers, synthesis and application as dehydrating and desalting of heavy crudes |
US10125226B2 (en) | 2013-06-05 | 2018-11-13 | Instituto Mexicano Del Petroleo | Scale-up process of bifunctionalized triblock copolymers with secondary and tertiary amines, with application in dewatering and desalting of heavy crude oils |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
MX2008015756A (es) * | 2008-12-10 | 2010-06-10 | Mexicano Inst Petrol | Formulaciones desemulsificantes y deshidratantes para crudos pesados a base de copolimeros en bloques bifuncionalizados con aminas. |
CN102127465B (zh) * | 2011-01-28 | 2013-09-18 | 辽宁华孚石油高科技股份有限公司 | 稠油的低温脱水工艺 |
MX340805B (es) | 2011-04-18 | 2016-06-24 | Inst Mexicano Del Petróleo | Formulaciones sinergicas de copolimeros funcionalizados y liquidos ionicos para el deshidratado y desalado de aceites crudos medianos, pesados y extrapesados. |
CN102286536B (zh) * | 2011-07-14 | 2014-04-02 | 同济大学 | 一种胞壁结合型生物破乳剂的提取方法 |
FR2987841A1 (fr) * | 2012-03-08 | 2013-09-13 | Univ Bordeaux 1 | Utilisation d'un copolymere a blocs de type hydrophile-hydrophobe en tant qu'agent desemulsifiant et composition desemulsifiante a base d'un tel copolymere |
EP2653463B1 (en) * | 2012-04-20 | 2014-06-25 | Rohm and Haas Company | Dibenzylamine hydrophobe |
WO2019173453A1 (en) | 2018-03-06 | 2019-09-12 | Si Group, Inc. | Paraffin inhibitor composition for use at low temperatures |
MX2019005132A (es) | 2019-05-02 | 2020-11-03 | Mexicano Inst Petrol | Bipolimeros tribloques poe-pop-poe, con terminaciones anfotericas, como agentes desemulsionantes de aceites crudos pesados. |
CN112607826B (zh) * | 2021-03-02 | 2021-05-07 | 烟台垚磊信息技术有限公司 | 一种含油乳化废水处理装置 |
WO2022225842A1 (en) | 2021-04-21 | 2022-10-27 | Ecolab Usa Inc. | Asphaltene and paraffin dispersant compositions and uses thereof |
MX2023009450A (es) * | 2023-08-11 | 2025-03-07 | Inst Mexicano Del Petroleo | Terpolimeros acrilicos aleatorios de masa molecular controlada empleados en la desestabilizacion de emulsiones simples (w/o) y/o complejas (o/w/o) en aceites crudos. |
Family Cites Families (22)
Publication number | Priority date | Publication date | Assignee | Title |
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US2425845A (en) | 1945-04-21 | 1947-08-19 | Carbide & Carbon Chem Corp | Mixtures of polyoxyalkylene diols and methods of making such mixtures |
US3334038A (en) | 1964-06-01 | 1967-08-01 | Petrolite Corp | Phase separation process |
US3782472A (en) * | 1967-03-20 | 1974-01-01 | Petrolite Corp | Steam injection of oil formations |
US3699051A (en) * | 1970-08-27 | 1972-10-17 | Nalco Chemical Co | Compositions and processes for breaking petroleum emulsions |
US3835060A (en) | 1972-08-21 | 1974-09-10 | Texaco Inc | Demulsification compositions containing alkyl ether sulfates |
US4439345A (en) * | 1981-06-11 | 1984-03-27 | Marathon Oil Company | Demulsification of a crude oil middle phase emulsion |
US4384977A (en) * | 1981-06-11 | 1983-05-24 | Marathon Oil Company | Polyalkyloxyamines as demulsifying agents |
JPS5847015A (ja) * | 1981-09-14 | 1983-03-18 | Mitsui Tekisako Chem Kk | エポキシ樹脂用硬化剤 |
US4382852A (en) * | 1981-12-02 | 1983-05-10 | Texaco Canada Resources, Inc. | Demulsification of bitumen emulsions using cationic polymers |
US4747851A (en) * | 1987-01-02 | 1988-05-31 | Texaco Inc. | Novel polyoxyalkylene diamine compound and ori-inhibited motor fuel composition |
US4944770A (en) * | 1988-09-02 | 1990-07-31 | Texaco, Inc. | Motor fuel additive and ori-inhibited motor fuel composition |
DD298812A5 (de) * | 1990-06-20 | 1992-03-12 | ������@������������k�� | Demulgator |
DE4136661A1 (de) | 1991-11-07 | 1993-05-13 | Basf Ag | Erdoelemulsionsspalter |
EP0584708B1 (de) * | 1992-08-22 | 1998-05-13 | Clariant GmbH | Polyfunktionelle Demulgatoren für Rohöle |
US5609794A (en) | 1994-08-05 | 1997-03-11 | Exxon Chemical Patents, Inc. | Demulsifier for water-in-oil emulsions, and method of use |
US6294093B1 (en) | 1998-09-04 | 2001-09-25 | Nalco/Exxon Energy Chemicals, L.P. | Aqueous dispersion of an oil soluble demulsifier for breaking crude oil emulsions |
US20040266973A1 (en) | 2003-06-24 | 2004-12-30 | Strickland J. Byron | Alkoxylated alkylphenol-arylaldehyde polymer |
GB0511649D0 (en) * | 2005-06-06 | 2005-07-13 | Bp Plc | Method |
CA2648590C (en) | 2006-04-07 | 2015-06-23 | Akzo Nobel N.V. | Environmentally-friendly oil/water demulsifiers |
MX2008015756A (es) * | 2008-12-10 | 2010-06-10 | Mexicano Inst Petrol | Formulaciones desemulsificantes y deshidratantes para crudos pesados a base de copolimeros en bloques bifuncionalizados con aminas. |
MX340805B (es) * | 2011-04-18 | 2016-06-24 | Inst Mexicano Del Petróleo | Formulaciones sinergicas de copolimeros funcionalizados y liquidos ionicos para el deshidratado y desalado de aceites crudos medianos, pesados y extrapesados. |
MX368308B (es) * | 2013-06-05 | 2019-09-26 | Mexicano Inst Petrol | Proceso de escalamiento de copolimeros tribloque bifuncionalizados con aminas secundarias y terciarias, con aplicacion en la deshidratacion y desalado de aceites crudos pesados. |
-
2008
- 2008-12-10 MX MX2008015756A patent/MX2008015756A/es active IP Right Grant
-
2009
- 2009-12-09 DE DE200910057556 patent/DE102009057556A1/de not_active Withdrawn
- 2009-12-10 US US12/635,050 patent/US8815960B2/en active Active
-
2014
- 2014-07-23 US US14/338,941 patent/US9518231B2/en not_active Expired - Fee Related
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9752084B2 (en) | 2013-02-26 | 2017-09-05 | Instituto Mexicano Del Petroleo | Block copolymers, synthesis and application as dehydrating and desalting of heavy crudes |
US10167388B2 (en) | 2013-02-26 | 2019-01-01 | Instituto Mexicano Del Petroleo | Block copolymers, synthesis and application as dehydrating and desalting of heavy crudes |
US9745521B2 (en) | 2013-02-28 | 2017-08-29 | Instituto Mexicano Del Petroleo | Dehydrating and desalting compositions of crude oils, using triblock copolymers α,ω-bifunctionalized with amines |
US10047302B2 (en) | 2013-02-28 | 2018-08-14 | Instituto Mexicano Del Petroleo | Dehydrating and desalting compositions of crude oils, using triblock copolymers α, Ω-bifunctionalized with amines |
US10125226B2 (en) | 2013-06-05 | 2018-11-13 | Instituto Mexicano Del Petroleo | Scale-up process of bifunctionalized triblock copolymers with secondary and tertiary amines, with application in dewatering and desalting of heavy crude oils |
Also Published As
Publication number | Publication date |
---|---|
US8815960B2 (en) | 2014-08-26 |
US20140336285A1 (en) | 2014-11-13 |
US9518231B2 (en) | 2016-12-13 |
DE102009057556A1 (de) | 2010-09-16 |
US20100140141A1 (en) | 2010-06-10 |
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Legal Events
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FG | Grant or registration |