MX2007011329A - Combinaciones de polimero de interpolimeros de etileno/alfa-olefina con compatibilidad mejorada. - Google Patents
Combinaciones de polimero de interpolimeros de etileno/alfa-olefina con compatibilidad mejorada.Info
- Publication number
- MX2007011329A MX2007011329A MX2007011329A MX2007011329A MX2007011329A MX 2007011329 A MX2007011329 A MX 2007011329A MX 2007011329 A MX2007011329 A MX 2007011329A MX 2007011329 A MX2007011329 A MX 2007011329A MX 2007011329 A MX2007011329 A MX 2007011329A
- Authority
- MX
- Mexico
- Prior art keywords
- ethylene
- polymer blends
- interpolymer
- olefin
- alpha
- Prior art date
Links
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title abstract 4
- 239000005977 Ethylene Substances 0.000 title abstract 4
- 229920002959 polymer blend Polymers 0.000 title abstract 4
- 239000004711 α-olefin Substances 0.000 title 1
- 229920000098 polyolefin Polymers 0.000 abstract 2
- 229920001400 block copolymer Polymers 0.000 abstract 1
- 229920001519 homopolymer Polymers 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
- C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
- C08F297/083—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins the monomers being ethylene or propylene
- C08F297/086—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins the monomers being ethylene or propylene the block polymer contains at least three blocks
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/14—Monomers containing five or more carbon atoms
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F295/00—Macromolecular compounds obtained by polymerisation using successively different catalyst types without deactivating the intermediate polymer
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
- C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
- C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
- C08F297/083—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins the monomers being ethylene or propylene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/646—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/005—Modified block copolymers
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- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
- C08F2410/01—Additive used together with the catalyst, excluding compounds containing Al or B
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- C—CHEMISTRY; METALLURGY
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
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- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
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- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
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- C—CHEMISTRY; METALLURGY
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
- C08L23/0815—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Ethene-propene or ethene-propene-diene copolymers
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Graft Or Block Polymers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Sealing Material Composition (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Abstract
Se describen en la presente combinaciones polimericas que comprenden por lo menos un interpolimero de etileno/(-olefina y dos poliolefinas diferentes que pueden ser homopolimeros. Los interpolimeros de etileno/(-olefina son copolimeros de bloque que comprende por lo menos un bloque duro y por lo menos un bloque blando. En algunas modalidades, el interpolimero de etileno/(-olefina puede funcionar como un compatibilizante entre las dos poliolefinas que, de otro modo, pueden no ser compatibles. Asimismo, se describen metodos para preparar las combinaciones polimericas y articulos moldeados a partir de las combinaciones polimericas.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/US2005/008917 WO2005090427A2 (en) | 2004-03-17 | 2005-03-17 | Catalyst composition comprising shuttling agent for ethylene multi-block copolymer formation |
US71782505P | 2005-09-16 | 2005-09-16 | |
PCT/US2006/009402 WO2006101924A2 (en) | 2005-03-17 | 2006-03-15 | Polymer blends from interpolymer of ethylene/alpha-olefin with improved compatibility |
Publications (1)
Publication Number | Publication Date |
---|---|
MX2007011329A true MX2007011329A (es) | 2007-10-02 |
Family
ID=36602585
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2007011329A MX2007011329A (es) | 2005-03-17 | 2006-03-15 | Combinaciones de polimero de interpolimeros de etileno/alfa-olefina con compatibilidad mejorada. |
Country Status (12)
Country | Link |
---|---|
EP (1) | EP1858942B1 (es) |
JP (2) | JP5231984B2 (es) |
KR (1) | KR101319124B1 (es) |
CN (1) | CN101365733B (es) |
AR (1) | AR053694A1 (es) |
AU (1) | AU2006227663A1 (es) |
BR (1) | BRPI0609852B1 (es) |
CA (1) | CA2601241A1 (es) |
MX (1) | MX2007011329A (es) |
RU (1) | RU2408622C2 (es) |
TW (1) | TWI377214B (es) |
WO (1) | WO2006101924A2 (es) |
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US8273826B2 (en) * | 2006-03-15 | 2012-09-25 | Dow Global Technologies Llc | Impact modification of thermoplastics with ethylene/α-olefin interpolymers |
TW200643084A (en) * | 2005-03-17 | 2006-12-16 | Dow Global Technologies Inc | Impact modification of thermoplastics with ethylene/α-olefin interpolymers |
AU2006237514B2 (en) * | 2005-03-17 | 2011-10-27 | Dow Global Technologies Llc | Cap liners, closures and gaskets from multi-block polymers |
US7906587B2 (en) * | 2005-09-16 | 2011-03-15 | Dow Global Technologies Llc | Polymer blends from interpolymer of ethylene/α olefin with improved compatibility |
CN101802086B (zh) * | 2007-07-13 | 2013-10-02 | 陶氏环球技术有限责任公司 | 具有受控的嵌段序列分布和至少一个低结晶度硬嵌段的催化的烯烃嵌段共聚物 |
CN101835838B (zh) | 2007-10-22 | 2014-03-12 | 陶氏环球技术公司 | 聚合物组合物以及用于模塑制品的方法 |
JP6317055B2 (ja) * | 2008-10-03 | 2018-05-09 | ダウ グローバル テクノロジーズ エルエルシー | エチレン/α−オレフィンインターポリマーを含むポリマーブレンド |
WO2010135244A2 (en) | 2009-05-19 | 2010-11-25 | Polyone Corporation | Thermoplastic elastomers exhibiting superior food contact compliance |
JP5806218B2 (ja) * | 2009-10-02 | 2015-11-10 | ダウ グローバル テクノロジーズ エルエルシー | ブロック複合材及び耐衝撃性改質組成物 |
CN104159966B (zh) | 2012-03-07 | 2016-08-24 | 陶氏环球技术有限责任公司 | 用于膜和织物的基于聚烯烃的配制物 |
KR101286918B1 (ko) | 2012-07-20 | 2013-07-19 | 이영기 | 폼타이어용 조성물 |
WO2014101154A1 (en) * | 2012-12-31 | 2014-07-03 | Dow Global Technologies Llc | Thermoplastic vulcanizate with crosslinked olefin block copolymer |
EP3039071B1 (en) * | 2013-08-28 | 2019-04-10 | SABIC Global Technologies B.V. | Soft touch compositions and articles thereof |
WO2016064479A1 (en) * | 2014-10-24 | 2016-04-28 | Exxonmobil Chemical Patents Inc. | Thermoplastic vulcanizate compositions |
RU2599574C1 (ru) * | 2015-09-17 | 2016-10-10 | Публичное Акционерное Общество "Нижнекамскнефтехим" | Полиэтиленовая композиция для наружного слоя покрытий стальных труб |
KR101987782B1 (ko) * | 2015-12-07 | 2019-06-11 | 주식회사 엘지화학 | 폴리프로필렌계 복합재 |
WO2018057078A1 (en) | 2016-09-21 | 2018-03-29 | Exxonmobil Chemical Patents Inc. | Compositions of olefin block copolymers and propylene-based elastomers |
US10227483B2 (en) | 2016-09-21 | 2019-03-12 | Exxonmobil Chemical Patents Inc. | Compositions of olefin block copolymers and propylene-based elastomers |
US10435527B2 (en) * | 2017-09-26 | 2019-10-08 | Chevron Phillips Chemical Company Lp | Dual component LLDPE copolymers with improved impact and tear resistance |
US11566122B2 (en) | 2017-11-01 | 2023-01-31 | Avient Corporation | Damping thermoplastic olefin elastomers |
EP3788104A1 (en) | 2018-05-03 | 2021-03-10 | Dow Global Technologies LLC | Propylene-based polymer compositions with excellent flexibility and hot air weldability |
CN111989363A (zh) * | 2018-05-09 | 2020-11-24 | Nok株式会社 | 橡胶组合物 |
TWI733232B (zh) | 2018-10-31 | 2021-07-11 | 奧地利商柏列利斯股份公司 | 升級的再生聚乙烯聚丙烯摻合物,c2c8塑性體作為用於改良摻合物之增容劑之用途及用於提供聚乙烯-聚丙烯組成物的製程 |
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BRPI0508148B1 (pt) * | 2004-03-17 | 2015-09-01 | Dow Global Technologies Inc | Interpolímero de etileno em multibloco, derivado reticulado e composição |
JP4879882B2 (ja) * | 2004-03-17 | 2012-02-22 | ダウ グローバル テクノロジーズ エルエルシー | より高次のオレフィンマルチブロックコポリマーを形成するためのシャトリング剤を含む触媒組成物 |
WO2005090425A1 (en) * | 2004-03-17 | 2005-09-29 | Dow Global Technologies Inc. | Catalyst composition comprising shuttling agent for ethylene copolymer formation |
JP2007084806A (ja) * | 2005-08-22 | 2007-04-05 | Mitsui Chemicals Inc | プロピレン系樹脂組成物 |
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2006
- 2006-03-15 EP EP06738464.4A patent/EP1858942B1/en active Active
- 2006-03-15 WO PCT/US2006/009402 patent/WO2006101924A2/en active Application Filing
- 2006-03-15 CN CN2006800084087A patent/CN101365733B/zh active Active
- 2006-03-15 AU AU2006227663A patent/AU2006227663A1/en not_active Abandoned
- 2006-03-15 CA CA002601241A patent/CA2601241A1/en not_active Abandoned
- 2006-03-15 RU RU2007134342/05A patent/RU2408622C2/ru not_active IP Right Cessation
- 2006-03-15 KR KR1020077021220A patent/KR101319124B1/ko active Active
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- 2006-03-15 AR ARP060101003A patent/AR053694A1/es active IP Right Grant
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Also Published As
Publication number | Publication date |
---|---|
JP2013014771A (ja) | 2013-01-24 |
EP1858942A2 (en) | 2007-11-28 |
TW200640956A (en) | 2006-12-01 |
WO2006101924A2 (en) | 2006-09-28 |
JP5231984B2 (ja) | 2013-07-10 |
RU2007134342A (ru) | 2009-03-20 |
TWI377214B (en) | 2012-11-21 |
JP2008545810A (ja) | 2008-12-18 |
BRPI0609852A2 (pt) | 2010-05-04 |
KR20070122199A (ko) | 2007-12-28 |
JP5859401B2 (ja) | 2016-02-10 |
RU2408622C2 (ru) | 2011-01-10 |
CN101365733A (zh) | 2009-02-11 |
EP1858942B1 (en) | 2016-04-13 |
CA2601241A1 (en) | 2006-09-28 |
AU2006227663A1 (en) | 2006-09-28 |
KR101319124B1 (ko) | 2013-10-23 |
CN101365733B (zh) | 2012-06-20 |
BRPI0609852B1 (pt) | 2017-12-26 |
WO2006101924A3 (en) | 2007-07-12 |
AR053694A1 (es) | 2007-05-16 |
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