MX172661B - Proceso mejorado para producir polibuteno y producto resultante - Google Patents
Proceso mejorado para producir polibuteno y producto resultanteInfo
- Publication number
- MX172661B MX172661B MX018399A MX1839989A MX172661B MX 172661 B MX172661 B MX 172661B MX 018399 A MX018399 A MX 018399A MX 1839989 A MX1839989 A MX 1839989A MX 172661 B MX172661 B MX 172661B
- Authority
- MX
- Mexico
- Prior art keywords
- feed stream
- mixture
- polybutene
- reaction zone
- stream mixture
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/08—Butenes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Polymerization Catalysts (AREA)
- Lubricants (AREA)
Abstract
La presente invención se refiere a un proceso para preparar polibuteno de bajo peso molecular que tiene un Mn dentro de la escala de aproximadamente 700 a aproximadamente 3000 y una distribución de peso molecular de menos de aproximadamente 2.0 a partir de una mezcla de corriente de alimentación de hidrocarburo de 4 átomos de carbono que contiene por lo menos aproximadamente 6 por ciento en peso de isobutileno, en una zona de reacción agitada mantenida a temperatura de aproximadamente -50 a +30 grados C, que comprende: a) inyectar el HC1 en una cantidad de aproximadamente 25 a 300 partes en peso por un millón de partes en peso de la mezcla de la corriente de alimentación hacia la mezcla de la corriente de alimentación, b) introducir simultáneamente la mezcla de la corriente de alimetnación tratada y el catalizador de cloruro de organoaluminio como corrientes separadas hacia la zona de reacción; c) poner en contacto la mezcla de la corriente de alimentación tratada introducida y el catalizador introducido en la zona de reacción durante un período de tiempo bajo condiciones suficientes para formar una mezcla de reacción de polimerización que contiene el polibuteno; d) retirar la mezcla de reacción de polimerización desde la zona de reacción; y e) recuperar el producto de polibuteno de la mezcla de reacción de polimerización retirada.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/276,135 US4935576A (en) | 1988-11-25 | 1988-11-25 | Polybutene process |
Publications (2)
Publication Number | Publication Date |
---|---|
MX18399A MX18399A (es) | 1993-06-01 |
MX172661B true MX172661B (es) | 1994-01-06 |
Family
ID=23055330
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX018399A MX172661B (es) | 1988-11-25 | 1989-11-17 | Proceso mejorado para producir polibuteno y producto resultante |
Country Status (8)
Country | Link |
---|---|
US (1) | US4935576A (es) |
EP (1) | EP0370805B1 (es) |
JP (1) | JP3020969B2 (es) |
KR (1) | KR0140225B1 (es) |
BR (1) | BR8905962A (es) |
CA (1) | CA2002270C (es) |
DE (1) | DE68928398T2 (es) |
MX (1) | MX172661B (es) |
Families Citing this family (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BR9106284A (pt) * | 1990-03-26 | 1993-04-13 | Exxon Chemical Patents Inc | Processo para preparar olibuteno de baixo peso molecular,e,polibuteno |
TW291486B (es) * | 1992-12-17 | 1996-11-21 | Exxon Chemical Patents Inc | |
US5652202A (en) * | 1995-08-15 | 1997-07-29 | Exxon Chemical Patents Inc. | Lubricating oil compositions |
US5558802A (en) * | 1995-09-14 | 1996-09-24 | Exxon Chemical Patents Inc | Multigrade crankcase lubricants with low temperature pumpability and low volatility |
AU5813398A (en) | 1997-01-08 | 1998-08-03 | Hercules Incorporated | Metal oxide solid acids as catalysts for the preparation of hydrocarbon resins |
US6770605B1 (en) * | 2000-09-11 | 2004-08-03 | The Lubrizol Corporation | Modified polyisobutylene succinimide dispersants having improved seal, sludge, and deposit performance |
KR100486044B1 (ko) | 2000-11-13 | 2005-04-29 | 대림산업 주식회사 | 폴리부텐의 제조방법 |
CA2360611C (en) * | 2001-10-30 | 2010-08-17 | Bayer Inc. | Transition metal-free initiator for the preparation of isobutylene-based polymers |
JP5227490B2 (ja) * | 2004-08-25 | 2013-07-03 | Jx日鉱日石エネルギー株式会社 | オレフィン重合体の製造方法 |
JP5199538B2 (ja) * | 2005-11-09 | 2013-05-15 | 出光興産株式会社 | α−オレフィンオリゴマーの製造方法 |
US20110297341A1 (en) * | 2010-06-07 | 2011-12-08 | Dilkus Christopher P | Creping Release Agents |
KR20150005206A (ko) * | 2013-07-05 | 2015-01-14 | 대림산업 주식회사 | 폴리부텐 제조 시 발생되는 폐수의 처리 장치 및 방법 |
CN114874373B (zh) * | 2021-02-05 | 2023-07-21 | 中国石油化工股份有限公司 | 液体丁基橡胶及其制备方法 |
CN114874371B (zh) * | 2021-02-05 | 2023-07-21 | 中国石油化工股份有限公司 | 一种制备液体丁基橡胶的方法及其制备得到的液体丁基橡胶 |
CN114874372B (zh) * | 2021-02-05 | 2023-07-21 | 中国石油化工股份有限公司 | 一种液体丁基橡胶以及制备液体丁基橡胶的方法 |
Family Cites Families (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2957930A (en) * | 1956-08-27 | 1960-10-25 | Cosden Petroleum Corp | Process for the production of polyisobutylene |
US3119884A (en) * | 1958-03-27 | 1964-01-28 | Cosden Oil & Chem Co | Reactor and method for polymerizing olefins |
US3200170A (en) * | 1962-02-21 | 1965-08-10 | Standard Oil Co | Aluminum chloride catalyzed polymerization process |
US3200169A (en) * | 1962-02-21 | 1965-08-10 | Standard Oil Co | Aluminum chloride catalyzed polymerization process |
US3349065A (en) * | 1964-05-01 | 1967-10-24 | Exxon Research Engineering Co | Butyl rubber catalyst system utilizing air2x with an hx promoter |
DE1720779A1 (de) * | 1968-01-31 | 1971-07-22 | Bayer Ag | Polyolefine |
US3639661A (en) * | 1969-01-21 | 1972-02-01 | Ceskoslovenska Akademie Ved | Polymerization of isobutylene |
US3501551A (en) * | 1969-03-19 | 1970-03-17 | Standard Oil Co | Process for producing normal butene polymers |
BE731006A (fr) * | 1969-04-03 | 1969-09-15 | Hydrocarbures aromatiques alkyles au moyen de polymeres du n-butene et procede pour les preparer | |
GB1449840A (en) * | 1973-10-08 | 1976-09-15 | British Petroleum Co | Alkylation process |
JPS50136385A (es) * | 1974-04-19 | 1975-10-29 | ||
US3991129A (en) * | 1974-09-23 | 1976-11-09 | Cosden Technology, Inc. | Production of polybutene with static mixer |
GB1534306A (en) * | 1975-02-12 | 1978-11-29 | Ban I | Magnetic recording/reproducing apparatus |
US3985822A (en) * | 1976-03-05 | 1976-10-12 | Cosden Technology, Inc. | Process for the production of poly-n-butenes |
CA1108799A (en) * | 1977-08-01 | 1981-09-08 | James M. Watson | Polymerization process |
IT1098336B (it) * | 1978-06-16 | 1985-09-07 | Snam Progetti | Processo per la preparazione di resine idrocarburiche |
EP0101205B1 (en) * | 1982-08-13 | 1987-01-07 | Exxon Research And Engineering Company | Process for preparing polyisobutylene |
US4465887A (en) * | 1983-06-27 | 1984-08-14 | Standard Oil Company (Indiana) | Process for producing butylene polymers having molecular weights in the range of from about 400 to 5000 molecular weight |
US4558170A (en) * | 1983-06-29 | 1985-12-10 | Exxon Research & Engineering Co. | Polyisobutylene process |
-
1988
- 1988-11-25 US US07/276,135 patent/US4935576A/en not_active Expired - Lifetime
-
1989
- 1989-11-06 CA CA002002270A patent/CA2002270C/en not_active Expired - Lifetime
- 1989-11-17 MX MX018399A patent/MX172661B/es unknown
- 1989-11-22 EP EP89312155A patent/EP0370805B1/en not_active Expired - Lifetime
- 1989-11-22 JP JP1302275A patent/JP3020969B2/ja not_active Expired - Fee Related
- 1989-11-22 DE DE68928398T patent/DE68928398T2/de not_active Expired - Fee Related
- 1989-11-24 KR KR89017101A patent/KR0140225B1/ko not_active IP Right Cessation
- 1989-11-27 BR BR898905962A patent/BR8905962A/pt not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
US4935576A (en) | 1990-06-19 |
JP3020969B2 (ja) | 2000-03-15 |
EP0370805A3 (en) | 1991-07-31 |
BR8905962A (pt) | 1990-06-19 |
KR900007888A (ko) | 1990-06-02 |
DE68928398T2 (de) | 1998-02-19 |
MX18399A (es) | 1993-06-01 |
JPH02225505A (ja) | 1990-09-07 |
CA2002270A1 (en) | 1991-05-06 |
KR0140225B1 (en) | 1998-07-01 |
CA2002270C (en) | 1994-07-26 |
DE68928398D1 (de) | 1997-11-27 |
EP0370805A2 (en) | 1990-05-30 |
EP0370805B1 (en) | 1997-10-22 |
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