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MX165983B - Metodo y aparato para la conversion de metano en hidrocarburos superiores - Google Patents

Metodo y aparato para la conversion de metano en hidrocarburos superiores

Info

Publication number
MX165983B
MX165983B MX010932A MX1093288A MX165983B MX 165983 B MX165983 B MX 165983B MX 010932 A MX010932 A MX 010932A MX 1093288 A MX1093288 A MX 1093288A MX 165983 B MX165983 B MX 165983B
Authority
MX
Mexico
Prior art keywords
gas mixture
bed
reaction
methane
conversion
Prior art date
Application number
MX010932A
Other languages
English (en)
Inventor
David W Leyshon
Arobert A Bader
Original Assignee
Atlantic Richfield Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Atlantic Richfield Co filed Critical Atlantic Richfield Co
Publication of MX165983B publication Critical patent/MX165983B/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/76—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen
    • C07C2/82—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen oxidative coupling
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/76—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen
    • C07C2/82—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen oxidative coupling
    • C07C2/84—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen oxidative coupling catalytic
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00026—Controlling or regulating the heat exchange system
    • B01J2208/00035—Controlling or regulating the heat exchange system involving measured parameters
    • B01J2208/00044—Temperature measurement
    • B01J2208/00061—Temperature measurement of the reactants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00026—Controlling or regulating the heat exchange system
    • B01J2208/00035—Controlling or regulating the heat exchange system involving measured parameters
    • B01J2208/0007—Pressure measurement
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00106—Controlling the temperature by indirect heat exchange
    • B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
    • B01J2208/00194—Tubes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00389—Controlling the temperature using electric heating or cooling elements
    • B01J2208/00407—Controlling the temperature using electric heating or cooling elements outside the reactor bed
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00477—Controlling the temperature by thermal insulation means
    • B01J2208/00495—Controlling the temperature by thermal insulation means using insulating materials or refractories
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00504—Controlling the temperature by means of a burner
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/0053—Controlling multiple zones along the direction of flow, e.g. pre-heating and after-cooling
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S585/00—Chemistry of hydrocarbon compounds
    • Y10S585/909—Heat considerations
    • Y10S585/91—Exploiting or conserving heat of quenching, reaction, or regeneration

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)

Abstract

La presente invención se refiere a un método para convertir metano en productos de hidrocarburo superiores, en donde una mezcla de gas que consiste de metano y un oxidante gaseoso se pone en contacto con un agente de contacto sólido a las condiciones de reacción, caracterizado porque: i) se hace pasar la mezcla de gas a una temperatura por lo menos de 100 grados C, menor que la temperatura de reacción hacia un lecho delgado del reactor adiabático que contiene el agente de contacto sólido, ii) se calienta la mezcla de gas a la temperatura de reacción en el lecho, mediante el flujo conductivo de calor generado por la reacción axialmente a través del lecho en contra-corriente con respecto al flujo de la mezcla de gas, y iii) se separa una mezcla de gas de reacción que contiene los hidrocarburos superiores desde el lecho.
MX010932A 1987-03-30 1988-03-29 Metodo y aparato para la conversion de metano en hidrocarburos superiores MX165983B (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US3149687A 1987-03-30 1987-03-30
US07/158,128 US4876409A (en) 1987-03-30 1988-03-04 Thin bed cofeed reactors for methane conversion

Publications (1)

Publication Number Publication Date
MX165983B true MX165983B (es) 1992-12-15

Family

ID=26707318

Family Applications (1)

Application Number Title Priority Date Filing Date
MX010932A MX165983B (es) 1987-03-30 1988-03-29 Metodo y aparato para la conversion de metano en hidrocarburos superiores

Country Status (13)

Country Link
US (1) US4876409A (es)
EP (1) EP0285337B1 (es)
JP (1) JP2699174B2 (es)
KR (1) KR970000936B1 (es)
CN (1) CN1014514B (es)
AU (1) AU605264B2 (es)
BR (1) BR8801430A (es)
CA (1) CA1294632C (es)
DE (1) DE3872558T2 (es)
DK (1) DK167675B1 (es)
ES (1) ES2041789T3 (es)
MX (1) MX165983B (es)
NO (1) NO173699C (es)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4973777A (en) * 1985-11-08 1990-11-27 Institut Francais Du Petrole Process for thermally converting methane into hydrocarbons with higher molecular weights, reactor for implementing the process and process for realizing the reactor
EP1347826B1 (en) * 2000-12-05 2010-01-20 Texaco Development Corporation Compact fuel processor for producing a hydrogen rich gas
US6793699B2 (en) * 2001-09-05 2004-09-21 Dennis D. Coleman Continuous tracer generation apparatus
US7223602B2 (en) * 2001-09-05 2007-05-29 Coleman Dennis D Continuous tracer generation method
US8277525B2 (en) * 2003-02-07 2012-10-02 Dalton Robert C High energy transport gas and method to transport same
US8925543B2 (en) * 2009-01-13 2015-01-06 Aerojet Rocketdyne Of De, Inc. Catalyzed hot gas heating system for pipes
CN102086146B (zh) * 2010-12-15 2012-10-17 西南化工研究设计院 一种采用绝热反应体系的草酸酯加氢制取乙二醇的工艺
WO2014078226A1 (en) * 2012-11-15 2014-05-22 Phillips 66 Company Process scheme for catalytic production of renewable hydrogen from oxygenate feedstocks
CN108136370A (zh) 2015-07-15 2018-06-08 沙特基础工业全球技术公司 用于甲烷氧化偶联的银促进催化剂
WO2018146591A1 (en) 2017-02-09 2018-08-16 Sabic Global Technologies B.V. Oxidative coupling of methane at near ambient feed temperature
WO2018175533A1 (en) 2017-03-22 2018-09-27 Sabic Global Technologies, B.V. Mixed oxides catalysts for oxidative coupling of methane
WO2018208907A1 (en) 2017-05-10 2018-11-15 Ecocatalytic Inc. Methods and systems for oxidative dehydrogenation of hydrocarbons to olefins
US10557391B1 (en) * 2017-05-18 2020-02-11 Advanced Cooling Technologies, Inc. Incineration system and process
WO2019083561A1 (en) 2017-10-24 2019-05-02 Sabic Global Technologies, B.V. METHOD FOR CONVERTING A NATURAL GAS SUPPLY CHARGE WITH INERT CONTENT TO CHEMICAL INTERMEDIATES
US11666879B2 (en) * 2018-04-18 2023-06-06 Sabic Global Technologies B.V. Small channel short fixed bed adiabatic reactor for oxidative coupling of methane
US10941088B1 (en) 2018-05-02 2021-03-09 Sabic Global Technologies B.V. Method and reactor for oxidative coupling of methane
CN110041156A (zh) * 2019-05-30 2019-07-23 中国科学院山西煤炭化学研究所 一种甲烷直接转化制乙烯的集成工艺
GB2603959A (en) * 2021-02-23 2022-08-24 Zelp Ltd Methane Oxidation Device

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR711394A (fr) * 1930-03-19 1931-09-08 Ig Farbenindustrie Ag Procédé pour transformer le méthane ou d'autres hydrocarbures aliphatiques en hydrocarbures à poids moléculaire plus élevé
US3223746A (en) * 1962-12-28 1965-12-14 Socony Mobil Oil Co Inc High temperature heat exchange
US4754095A (en) * 1984-04-16 1988-06-28 Atlantic Richfield Company Chemical conversion process
US4754094A (en) * 1984-04-16 1988-06-28 Atlantic Richfield Company Fixed bed reactor system
US4654458A (en) * 1985-09-26 1987-03-31 Amoco Corporation Conversion of a lower alkane
FR2589859B1 (fr) * 1985-11-08 1988-02-05 Inst Francais Du Petrole Procede de conversion thermique du methane en hydrocarbures de poids moleculaires plus eleves

Also Published As

Publication number Publication date
US4876409A (en) 1989-10-24
EP0285337A1 (en) 1988-10-05
KR880011308A (ko) 1988-10-27
AU1378388A (en) 1988-09-29
CN1014514B (zh) 1991-10-30
BR8801430A (pt) 1988-11-01
DK173488A (da) 1988-10-01
ES2041789T3 (es) 1993-12-01
DK173488D0 (da) 1988-03-29
NO881369D0 (no) 1988-03-28
DE3872558D1 (de) 1992-08-13
NO881369L (no) 1988-10-03
CN88101761A (zh) 1988-11-16
DK167675B1 (da) 1993-12-06
NO173699C (no) 1994-01-26
JP2699174B2 (ja) 1998-01-19
DE3872558T2 (de) 1992-12-10
JPS63277638A (ja) 1988-11-15
AU605264B2 (en) 1991-01-10
NO173699B (no) 1993-10-11
EP0285337B1 (en) 1992-07-08
CA1294632C (en) 1992-01-21
KR970000936B1 (ko) 1997-01-21

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