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LV10023B - Geometrical isomer of 1-substituted-1-triazolylstyrenes, and their production and use as fungicide, herbicide and/or plant growth regulant - Google Patents

Geometrical isomer of 1-substituted-1-triazolylstyrenes, and their production and use as fungicide, herbicide and/or plant growth regulant Download PDF

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Publication number
LV10023B
LV10023B LVP-92-391A LV920391A LV10023B LV 10023 B LV10023 B LV 10023B LV 920391 A LV920391 A LV 920391A LV 10023 B LV10023 B LV 10023B
Authority
LV
Latvia
Prior art keywords
isomer
compound
formula
cont
triazole
Prior art date
Application number
LVP-92-391A
Other languages
English (en)
Other versions
LV10023A (lv
Inventor
Yuji Funaki
Hirofumi Oshita
Shigeo Yamamoto
Shizuya Tanaka
Toshiro Kato
Original Assignee
Sumitomo Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP3287679A external-priority patent/JPS55124771A/ja
Priority claimed from JP4165979A external-priority patent/JPS55147265A/ja
Priority claimed from JP10054779A external-priority patent/JPS5625105A/ja
Priority claimed from JP11657679A external-priority patent/JPS5640671A/ja
Priority claimed from JP12236679A external-priority patent/JPS5645462A/ja
Priority claimed from JP12348579A external-priority patent/JPS5646869A/ja
Priority claimed from JP12457179A external-priority patent/JPS5646870A/ja
Priority claimed from JP1056880A external-priority patent/JPS56108773A/ja
Application filed by Sumitomo Chemical Co filed Critical Sumitomo Chemical Co
Publication of LV10023A publication Critical patent/LV10023A/lv
Publication of LV10023B publication Critical patent/LV10023B/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/12—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647—Triazoles; Hydrogenated triazoles
    • A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D249/00—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
    • C07D249/02—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms not condensed with other rings
    • C07D249/08—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles

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  • Organic Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Plant Pathology (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Claims (6)

  1. LV 10023 IZGUDROJUMA FORMULA / I. Ģeometriskais izomērs, kura formula irs
    0RT I 1 CII - R2 kur Rj ir ūdeņraža atoms, Cj-0^ alkil-, C^-C^ alkeuil- vai 2-pro-pinil- grupa, R2 ^i“^6 alkil-, ciklopropil- vai' I-metilciklo-propil- grupa, R^, kura var būt tā pati vai atšķirīga, ir halogēna atoms, alkil-, halogēn- aizvietota Cj-C^ alkil-, Cj- alkoksi-, fenoksi-, fenil-, ciāno- vai nitro- grupa, un n ir vesels skaitlis no 0 līdz 3» un kas iegūts reducējot vienu no diviem triazola savienojuma ģeometriskajiem izomēriem, kura formula ir:
    R 2 2 kur Rg, Rj un n ir ka definēts augstāk, kuram olefīna protons parādās PMR spektra (deiterohloroformā) stiprākā magnētiskajā laukā, vai ēterif ieejot iegūto reducēšanas produktu, vai tā sāļus. 2. (Ģeometriskais izomērs vai tā sāļi saskaņā ar patenta formulas I.punktu, kur Rj ir ūdeņraža atoms un R^ ir terc-butil-grupa. 3. deometriskais izomērs vai tā sāļi saskaņā ar patenta formulas 2.punktu, kur a ir I un ir hlora atoms 4- stāvoklī. 4. deometriskais izomērs vai tā sāļi saskaņā ar patenta formulas 2.punktu, kur a ir 2 un R^ ir hlora atoms 2- un 4- stāvoklī. 5. deometriskais izomērs saskaņā ar patenta formulas I.punk-tu, kur Rjir ūdeņraža atoms, R2 ir I-metilciklopropil- grupa, Rj ir halogēna atoms un n ir 0, I vai 2.
  2. 6. Viens no diviem triazola savienojuma ģeometriskajiem izo-mēriem, kura formula ir: R, kur R2, Rj un n ir kā definēts patenta formulas I.punktā, kuram olefīna protons parādās PMR spektra (deiterohloroformā) stiprākā magnētiskajā laukā.
  3. 7. Viens no diviem triazola savienojuma ģeometriskajiem izo-mēriem, kura formula ir: 0
    R II c 2 3 LV 10023 kur Rg ir I-metilciklopropil- grupa, in un n ir kā definēts patenta formulas I.punktā, kuram olefīna protons parādās PMR spektra (deiterohloroformā) vājākajā magnētiskajā laukā.
  4. 8. Iegūšanas paņēmiens, viena no diviem triazola savienojuma ģeometriskajiem izomērīem, kura formula ir 0 jr\ I (Ļ Vch » c - c , r2 <Vn ļļ II kur Rg, Rj un n ir kā definēts patenta formulas I.punktā, kuram olefīna protons parādās PMR spektra (deiterohlorofomā) stiprākajā magnētiskajā laukā, kas atšķiras ar to, ka minēto izomēru iegūst izomerizējot otru ģeometrisko izoz-mē-ru, kuram olefīna protons parādās PMR spektra (deiterohlorofor-mā) vājākajā magnētiskajā laukā, apstarojot ar stariem.
  5. 9. Iegūšanas paņēmiens, viena no diviem triazola savienojuma ģeometriskajiem izomēriera, kura formula ir:
    C - R, N -ļļ I!—n kur Rg, Rj un n ir kā definēts patenta formulas I.punktā, kuram olefīna protons parādās PMR spektra (deiterohloroformā) stiprākajā magnētiskajā laukā, kas a t š ķ i r a s ar to, ka minēto izomēru iegūst izomerizējot aku ģeometrisko izomēru maisījumu, to apstarojot ar stariem. 10. deometriskā izomēra iegūšanas paņēmiens, kura formula.
    - 4 kur Rj un n ir kā definēts patenta formulas I. punktā, kas atšķiras ar to, ka minēto izomēru iegūst reducējot vienu no dieviem triazola savienojuma ģeometriskajiem izomēriem, kura for™ mula irj - 4
    R 2 kur R^, Rj un n ir kā definēts patenta formulas I.punktā, kuram olefīna protons parādās PMR spektra (deiterohloroformā) stiprākajā magnētiskajā laukā. •II. Ģeometriskā izomēra iegūšanas paņēmiens, kura formula ir: ORj
    kur Rj ir Cj-C^ alkil-, C^-O^ alkenil- vai 2-propinil- grupa, un R^, R^ un n ir kā definēts patenta formulas I.punktā, kas atšķirasarto, ka minēto izomēru iegūst pakļaujot ķīmiskai iedarbībai ģeometrisko izomēru, kura formula ir: OE
    ! VCH * C - CH - R, (H 5>n N HI!-1 kur un n ir kā definēts patenta formulas I.punktā, un kas iegūts reducējot vienu no diviem triazola savienojuma ģeometriskajiem izomāriem, kura formula ir: 5 LV 10023 Ο
    kur Ej un n ir ka definēts patenta formulas I. punktā, kuram olefīna protons parādās PMR spektra (deiterohloroformā) stiprākajā magnētiskajā laukā, vai tā alkoholātu ar reagēt-spējigu Cj-G^ alkil-, C^-O^ alkenil- vai 2-propinil atvasinājumu bāzes klātienē, vai arī sāļus.
  6. 12. Fungicīdi, herbicīdi un/vai lauksaimniecības un dārzkopības augu augšanas regulatori, kas raksturīgi ar to, ka satur kā aktīvo komponenti ģeometrisko izomēru ar formulu, n-GH <Vn 0RT I 1 = C-CH - R I Ņ II -N kur Rj, Rp, Rj un n ir kā definēts patenta formulas I.punktā, karš iegūts reducējot vienu no triazola savienojuma ģeometriskajiem izomēriem, kura formula iri 0
    ^TVgH = G - C - R, I /IK » 1 u_N kur R£» Rj un n ir ka definēts patenta formulas I.punktā, kuram olefīna protons parādās FM8 spektra (deiterohloroformā) stiprākajā magnētiskajā laukā, vai sekojoši ēterificējot iegūto reducēšanas produktu, vai sāļus.
LVP-92-391A 1979-03-20 1992-12-22 Geometrical isomer of 1-substituted-1-triazolylstyrenes, and their production and use as fungicide, herbicide and/or plant growth regulant LV10023B (en)

Applications Claiming Priority (8)

Application Number Priority Date Filing Date Title
JP3287679A JPS55124771A (en) 1979-03-20 1979-03-20 Triazole-based geometrical isomerism compound or its salt, its preparation, and fungicide for agriculture and gardening comprising it as active ingredient
JP4165979A JPS55147265A (en) 1979-04-05 1979-04-05 Triazole geometrical isomer compound and its preparation
JP10054779A JPS5625105A (en) 1979-08-06 1979-08-06 Plant growth regulator and herbicide containing geometrical isomer of triazole compound or its salt as effective component
JP11657679A JPS5640671A (en) 1979-09-10 1979-09-10 Triazole compound or its salt, its preparation and agricultural and horticultural germicide, herbicide and plant growth regulator containing the same as active constituent
JP12236679A JPS5645462A (en) 1979-09-21 1979-09-21 Triazole compound and its preparation
JP12348579A JPS5646869A (en) 1979-09-25 1979-09-25 Geometrical isomer of triazole compound or its salt, its preparation, and agricultural and horticultural fungicide, plant growth regulating agent, and herbicide containing the same as effective component
JP12457179A JPS5646870A (en) 1979-09-26 1979-09-26 Geometrical isomer of triazole compound and its preparation
JP1056880A JPS56108773A (en) 1980-01-30 1980-01-30 Triazole compound and its salt, their preparation, and fungicide, herbicide, and plant growth regulating agent containing said compound as effective component

Publications (2)

Publication Number Publication Date
LV10023A LV10023A (lv) 1994-05-10
LV10023B true LV10023B (en) 1995-02-20

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LVP-92-391A LV10023B (en) 1979-03-20 1992-12-22 Geometrical isomer of 1-substituted-1-triazolylstyrenes, and their production and use as fungicide, herbicide and/or plant growth regulant

Country Status (19)

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US (2) US4554007A (lv)
AR (1) AR226305A1 (lv)
AU (1) AU536825B2 (lv)
BR (1) BR8001617A (lv)
CA (1) CA1154449A (lv)
CH (1) CH644851A5 (lv)
DE (1) DE3010560A1 (lv)
DK (1) DK157811C (lv)
FR (1) FR2460939B1 (lv)
GB (1) GB2046260B (lv)
HU (1) HU186281B (lv)
IL (1) IL59671A (lv)
IT (1) IT1143014B (lv)
LV (1) LV10023B (lv)
MY (1) MY8700898A (lv)
NL (1) NL192791C (lv)
NZ (1) NZ193168A (lv)
PL (1) PL123010B1 (lv)
YU (1) YU42969B (lv)

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Also Published As

Publication number Publication date
YU42969B (en) 1989-02-28
DE3010560C2 (lv) 1990-09-20
FR2460939B1 (fr) 1985-06-28
NL8001658A (nl) 1980-09-23
US4554007A (en) 1985-11-19
PL222822A1 (lv) 1981-02-13
GB2046260A (en) 1980-11-12
NL192791C (nl) 1998-02-03
BR8001617A (pt) 1980-11-18
NZ193168A (en) 1983-04-12
IL59671A (en) 1984-02-29
YU76680A (en) 1983-10-31
FR2460939A1 (fr) 1981-01-30
AR226305A1 (es) 1982-06-30
NL192791B (nl) 1997-10-01
MY8700898A (en) 1987-12-31
DK118580A (da) 1980-09-21
PL123010B1 (en) 1982-09-30
DK157811B (da) 1990-02-19
IT1143014B (it) 1986-10-22
AU5657180A (en) 1980-09-25
DK157811C (da) 1990-08-13
IT8048189A0 (it) 1980-03-18
US4749716A (en) 1988-06-07
CH644851A5 (de) 1984-08-31
IL59671A0 (en) 1980-06-30
CA1154449A (en) 1983-09-27
AU536825B2 (en) 1984-05-24
LV10023A (lv) 1994-05-10
HU186281B (en) 1985-07-29
DE3010560A1 (de) 1980-10-02
GB2046260B (en) 1983-12-21

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