LU87333A1 - PROCESS FOR DYEING KERATINIC FIBERS WITH AN INDOLE DERIVATIVE ASSOCIATED WITH A NITRITE AND COMPOSITION FOR USE - Google Patents
PROCESS FOR DYEING KERATINIC FIBERS WITH AN INDOLE DERIVATIVE ASSOCIATED WITH A NITRITE AND COMPOSITION FOR USE Download PDFInfo
- Publication number
- LU87333A1 LU87333A1 LU87333A LU87333A LU87333A1 LU 87333 A1 LU87333 A1 LU 87333A1 LU 87333 A LU87333 A LU 87333A LU 87333 A LU87333 A LU 87333A LU 87333 A1 LU87333 A1 LU 87333A1
- Authority
- LU
- Luxembourg
- Prior art keywords
- composition
- nitrite
- hydroxy
- dyeing
- indole
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims description 103
- 238000004043 dyeing Methods 0.000 title claims description 29
- 238000000034 method Methods 0.000 title claims description 29
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 title claims description 25
- 239000000835 fiber Substances 0.000 title claims description 18
- SIKJAQJRHWYJAI-UHFFFAOYSA-N Indole Chemical class C1=CC=C2NC=CC2=C1 SIKJAQJRHWYJAI-UHFFFAOYSA-N 0.000 title claims description 5
- 210000004209 hair Anatomy 0.000 claims description 46
- 150000002475 indoles Chemical class 0.000 claims description 24
- 239000000975 dye Substances 0.000 claims description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 16
- 102000011782 Keratins Human genes 0.000 claims description 15
- 108010076876 Keratins Proteins 0.000 claims description 15
- 239000002609 medium Substances 0.000 claims description 13
- 230000002378 acidificating effect Effects 0.000 claims description 10
- 229940054051 antipsychotic indole derivative Drugs 0.000 claims description 10
- -1 ammonium metals Chemical class 0.000 claims description 8
- 230000003647 oxidation Effects 0.000 claims description 7
- 238000007254 oxidation reaction Methods 0.000 claims description 7
- 230000007935 neutral effect Effects 0.000 claims description 5
- 150000002826 nitrites Chemical class 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 4
- 239000012736 aqueous medium Substances 0.000 claims description 3
- OYWUQIAXQPURRE-UHFFFAOYSA-N (1,2-dimethylindol-6-yl) acetate Chemical compound CC(=O)OC1=CC=C2C=C(C)N(C)C2=C1 OYWUQIAXQPURRE-UHFFFAOYSA-N 0.000 claims description 2
- OSNDKMMOJAUTDW-UHFFFAOYSA-N 1,2-dimethylindol-6-ol Chemical compound C1=C(O)C=C2N(C)C(C)=CC2=C1 OSNDKMMOJAUTDW-UHFFFAOYSA-N 0.000 claims description 2
- OOOVRUXKQGYTPJ-UHFFFAOYSA-N 1-methylindol-6-ol Chemical compound C1=C(O)C=C2N(C)C=CC2=C1 OOOVRUXKQGYTPJ-UHFFFAOYSA-N 0.000 claims description 2
- XAWPKHNOFIWWNZ-UHFFFAOYSA-N 1h-indol-6-ol Chemical compound OC1=CC=C2C=CNC2=C1 XAWPKHNOFIWWNZ-UHFFFAOYSA-N 0.000 claims description 2
- AQPAAQVLJBZFCV-UHFFFAOYSA-N 1h-indol-6-yl acetate Chemical compound CC(=O)OC1=CC=C2C=CNC2=C1 AQPAAQVLJBZFCV-UHFFFAOYSA-N 0.000 claims description 2
- ORVPXPKEZLTMNW-UHFFFAOYSA-N 1h-indol-7-ol Chemical compound OC1=CC=CC2=C1NC=C2 ORVPXPKEZLTMNW-UHFFFAOYSA-N 0.000 claims description 2
- OWVWIOHXPDECMB-UHFFFAOYSA-N 2,3-dimethyl-1h-indol-6-ol Chemical compound OC1=CC=C2C(C)=C(C)NC2=C1 OWVWIOHXPDECMB-UHFFFAOYSA-N 0.000 claims description 2
- JKIGVFLHAJUPCP-UHFFFAOYSA-N 2-methyl-1h-indol-6-ol Chemical compound C1=C(O)C=C2NC(C)=CC2=C1 JKIGVFLHAJUPCP-UHFFFAOYSA-N 0.000 claims description 2
- AXSWRCGZBWBXQD-UHFFFAOYSA-N 3-methyl-1h-indol-6-ol Chemical compound OC1=CC=C2C(C)=CNC2=C1 AXSWRCGZBWBXQD-UHFFFAOYSA-N 0.000 claims description 2
- NLMQHXUGJIAKTH-UHFFFAOYSA-N 4-hydroxyindole Chemical compound OC1=CC=CC2=C1C=CN2 NLMQHXUGJIAKTH-UHFFFAOYSA-N 0.000 claims description 2
- SGNZYJXNUURYCH-UHFFFAOYSA-N 5,6-dihydroxyindole Chemical compound C1=C(O)C(O)=CC2=C1NC=C2 SGNZYJXNUURYCH-UHFFFAOYSA-N 0.000 claims description 2
- BIMHWDJKNOMNLD-UHFFFAOYSA-N 5-Hydroxyindole-2-carboxylic acid Chemical compound OC1=CC=C2NC(C(=O)O)=CC2=C1 BIMHWDJKNOMNLD-UHFFFAOYSA-N 0.000 claims description 2
- LMIQERWZRIFWNZ-UHFFFAOYSA-N 5-hydroxyindole Chemical compound OC1=CC=C2NC=CC2=C1 LMIQERWZRIFWNZ-UHFFFAOYSA-N 0.000 claims description 2
- HJUFFOMJRAXIRF-UHFFFAOYSA-N 6-hydroxy-1h-indole-2-carboxylic acid Chemical compound C1=C(O)C=C2NC(C(=O)O)=CC2=C1 HJUFFOMJRAXIRF-UHFFFAOYSA-N 0.000 claims description 2
- NYORHELBFKLYBG-UHFFFAOYSA-N 6-hydroxy-1h-indole-3-carboxylic acid Chemical compound OC1=CC=C2C(C(=O)O)=CNC2=C1 NYORHELBFKLYBG-UHFFFAOYSA-N 0.000 claims description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 2
- 239000003513 alkali Substances 0.000 claims description 2
- CAMXVZOXBADHNJ-UHFFFAOYSA-N ammonium nitrite Chemical class [NH4+].[O-]N=O CAMXVZOXBADHNJ-UHFFFAOYSA-N 0.000 claims description 2
- 150000001768 cations Chemical class 0.000 claims description 2
- ULTUXSUIBQEMNH-UHFFFAOYSA-N dimethyl 6-acetyloxy-1-methylindole-2,3-dicarboxylate Chemical compound C1=C(OC(C)=O)C=C2N(C)C(C(=O)OC)=C(C(=O)OC)C2=C1 ULTUXSUIBQEMNH-UHFFFAOYSA-N 0.000 claims description 2
- 239000000982 direct dye Substances 0.000 claims description 2
- FVMVBNSCNRLYIJ-UHFFFAOYSA-N ethyl 6-hydroxy-1h-indole-2-carboxylate Chemical compound C1=C(O)C=C2NC(C(=O)OCC)=CC2=C1 FVMVBNSCNRLYIJ-UHFFFAOYSA-N 0.000 claims description 2
- IYOILHQLYJPODQ-UHFFFAOYSA-N ethyl 6-hydroxy-1h-indole-3-carboxylate Chemical compound OC1=CC=C2C(C(=O)OCC)=CNC2=C1 IYOILHQLYJPODQ-UHFFFAOYSA-N 0.000 claims description 2
- TUJKJAMUKRIRHC-UHFFFAOYSA-N hydroxyl Chemical compound [OH] TUJKJAMUKRIRHC-UHFFFAOYSA-N 0.000 claims description 2
- PZOUSPYUWWUPPK-UHFFFAOYSA-N indole Natural products CC1=CC=CC2=C1C=CN2 PZOUSPYUWWUPPK-UHFFFAOYSA-N 0.000 claims description 2
- RKJUIXBNRJVNHR-UHFFFAOYSA-N indolenine Natural products C1=CC=C2CC=NC2=C1 RKJUIXBNRJVNHR-UHFFFAOYSA-N 0.000 claims description 2
- OYZMJHNFWMBBQC-UHFFFAOYSA-N methyl 6-hydroxy-1h-indole-3-carboxylate Chemical compound OC1=CC=C2C(C(=O)OC)=CNC2=C1 OYZMJHNFWMBBQC-UHFFFAOYSA-N 0.000 claims description 2
- QXAUTQFAWKKNLM-UHFFFAOYSA-N methyl indole-3-carboxylate Natural products C1=CC=C2C(C(=O)OC)=CNC2=C1 QXAUTQFAWKKNLM-UHFFFAOYSA-N 0.000 claims description 2
- 239000003960 organic solvent Substances 0.000 claims description 2
- ORTFAQDWJHRMNX-UHFFFAOYSA-M oxidooxomethyl Chemical compound [O-][C]=O ORTFAQDWJHRMNX-UHFFFAOYSA-M 0.000 claims description 2
- 229910052700 potassium Inorganic materials 0.000 claims description 2
- 239000011591 potassium Substances 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims description 2
- 230000009466 transformation Effects 0.000 claims description 2
- 239000013598 vector Substances 0.000 claims description 2
- 229910052751 metal Inorganic materials 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- TYLFICUVJRBFNX-UHFFFAOYSA-N methyl 6-hydroxy-1-methylindole-3-carboxylate Chemical compound OC1=CC=C2C(C(=O)OC)=CN(C)C2=C1 TYLFICUVJRBFNX-UHFFFAOYSA-N 0.000 claims 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 18
- 235000019441 ethanol Nutrition 0.000 description 11
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 10
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 9
- 230000002269 spontaneous effect Effects 0.000 description 8
- 238000001035 drying Methods 0.000 description 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 6
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Substances [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 6
- 235000010288 sodium nitrite Nutrition 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 5
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 241000158728 Meliaceae Species 0.000 description 3
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 3
- 239000002671 adjuvant Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000002562 thickening agent Substances 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- JHFAEUICJHBVHB-UHFFFAOYSA-N 1h-indol-2-ol Chemical compound C1=CC=C2NC(O)=CC2=C1 JHFAEUICJHBVHB-UHFFFAOYSA-N 0.000 description 1
- CUDYYMUUJHLCGZ-UHFFFAOYSA-N 2-(2-methoxypropoxy)propan-1-ol Chemical class COC(C)COC(C)CO CUDYYMUUJHLCGZ-UHFFFAOYSA-N 0.000 description 1
- SVONRAPFKPVNKG-UHFFFAOYSA-N 2-ethoxyethyl acetate Chemical compound CCOCCOC(C)=O SVONRAPFKPVNKG-UHFFFAOYSA-N 0.000 description 1
- LPEKGGXMPWTOCB-UHFFFAOYSA-N 8beta-(2,3-epoxy-2-methylbutyryloxy)-14-acetoxytithifolin Natural products COC(=O)C(C)O LPEKGGXMPWTOCB-UHFFFAOYSA-N 0.000 description 1
- 244000215068 Acacia senegal Species 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical class [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical class CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 229920002305 Schizophyllan Polymers 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 229920013806 TRITON CG-110 Polymers 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 description 1
- 239000002535 acidifier Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 235000011162 ammonium carbonates Nutrition 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 229960003116 amyl nitrite Drugs 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000002610 basifying agent Substances 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 229920001222 biopolymer Polymers 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- ODQWQRRAPPTVAG-GZTJUZNOSA-N doxepin Chemical compound C1OC2=CC=CC=C2C(=C/CCN(C)C)/C2=CC=CC=C21 ODQWQRRAPPTVAG-GZTJUZNOSA-N 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 125000003754 ethoxycarbonyl group Chemical group C(=O)(OCC)* 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 229930182470 glycoside Natural products 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 description 1
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 1
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 1
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- JJVFSXOKZAJCNR-UHFFFAOYSA-N methyl 6-acetyloxy-1-methylindole-3-carboxylate Chemical compound CC(=O)OC1=CC=C2C(C(=O)OC)=CN(C)C2=C1 JJVFSXOKZAJCNR-UHFFFAOYSA-N 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 229940057867 methyl lactate Drugs 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 239000006083 mineral thickener Substances 0.000 description 1
- CSDTZUBPSYWZDX-UHFFFAOYSA-N n-pentyl nitrite Chemical compound CCCCCON=O CSDTZUBPSYWZDX-UHFFFAOYSA-N 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N n-propyl alcohol Natural products CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/4906—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom
- A61K8/4913—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom having five membered rings, e.g. pyrrolidone carboxylic acid
- A61K8/492—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom having five membered rings, e.g. pyrrolidone carboxylic acid having condensed rings, e.g. indol
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/10—Preparations for permanently dyeing the hair
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Cosmetics (AREA)
- Coloring (AREA)
Description
Procédé de teinture des fibres kératiniques avec un derive d‘indole associé à un nitrite et composition de mise en oeuvre.Process for dyeing keratin fibers with an indole derivative associated with a nitrite and composition for use.
L'invention est relative à un nouveau procédé de teinture mettant en oeuvre les dérivés monohydroxylés d'indole associés à un nitrite et aux compositions mises en oeuvre dans ce procédé.The invention relates to a new dyeing process using the monohydroxylated derivatives of indole associated with a nitrite and to the compositions used in this process.
Les dérivés monohydroxylés d'indole sont bien connus dans l'état de la technique et ont déjà été préconisés pour la teinture des fibres kératiniques et en particulier des cheveux.Monohydroxylated indole derivatives are well known in the state of the art and have already been recommended for the dyeing of keratin fibers and in particular of the hair.
De telles utilisations sont décrites en particulier dans les brevets US-A-4.013.404, DE-A-3.031.709 et FR-A-2.252.841.Such uses are described in particular in patents US-A-4,013,404, DE-A-3,031,709 and FR-A-2,252,841.
Ces procédés mettent généralement en oeuvre, lorsque les colorants sont utilisés comme colorants d'oxydation, du peroxyde d'hydrogène ou des perseis, présentant l'inconvénient bien connu d'être dégradant pour le cheveu.These methods generally use, when the dyes are used as oxidation dyes, hydrogen peroxide or perseis, having the well-known drawback of being degrading for the hair.
La demanderesse a découvert, de façon surprenante, qu'il était possible d'effectuer une teinture à l'aide de dérivés monohydroxylés d'indole, sans utiliser de peroxyde d'hydrogène ni de persei, en imprégnant, dans un premier temps, les fibres kêratiniques, et en particulier les cheveux, par le dérivé d'indole monohydroxylé et, dans un deuxième temps, par une composition acide, l'une au moins des compositions contenant un nitrite.The Applicant has discovered, surprisingly, that it was possible to carry out a dyeing using monohydroxylated derivatives of indole, without using hydrogen peroxide or persei, by impregnating, at first, the keratin fibers, and in particular the hair, by the monohydroxylated indole derivative and, secondly, by an acid composition, at least one of the compositions containing a nitrite.
Les teintures ainsi obtenues sont particulièrement intéressantes puisqu'elles permettent de teindre les cheveux dans les tons naturels, chauds, à reflets cuivrés, présentant une bonne résistance aux agents extérieurs, tels que la lumière, les intempéries et le lavage.The dyes thus obtained are particularly advantageous since they make it possible to dye the hair in natural, warm tones, with coppery reflections, having good resistance to external agents, such as light, bad weather and washing.
L'invention a donc pour objet un nouveau procédé de teinture des fibres kêratiniques mettant en oeuvre des dérivés monohydroxylés d'indole et un nitrite.The subject of the invention is therefore a new process for dyeing keratin fibers using monohydroxylated indole derivatives and a nitrite.
Un autre objet de l'invention est constitué par les compositions et le dispositif à plusieurs compartiments utilisés dans le cadre de ce procédé.Another object of the invention consists of the compositions and the device with several compartments used in the context of this process.
D'autres objets de l'invention apparaîtront à la lecture de la description et des exemples qui suivent.Other objects of the invention will appear on reading the description and the examples which follow.
Le procédé de teinture des fibres kêratiniques, en particulier des cheveux, conforme à l'invention, est essentiellement caractérisé par le fait que l'on applique sur ces fibres au moins une composition (A) contenant dans un milieu approprié pour la teinture, au moins un dérivé d'indole répondant à la formule :The process for dyeing keratin fibers, in particular the hair, according to the invention, is essentially characterized in that at least one composition (A) is applied to these fibers containing, in a medium suitable for dyeing, minus an indole derivative corresponding to the formula:
(I) dans laquelle :(I) in which:
Ri désigne un atome d'hydrogène ou un radical alkyle en C1-C4; R2 et R3/ identiques ou différents/ désignent un atome d'hydrogène, un radical alkyle inférieur en CI-C4, un radical carboxyle, un radical alcoxycarbonyle ; ZO représente un groupement hydroxyle ou hydroxyle protégé; l'application de la composition (A) étant suivie par l'application d'une composition aqueuse acide (B), la composition (A) ou la composition (B) contenant au moins un nitrite.Ri denotes a hydrogen atom or a C1-C4 alkyl radical; R2 and R3 / identical or different / denote a hydrogen atom, a lower C1-C4 alkyl radical, a carboxyl radical, an alkoxycarbonyl radical; ZO represents a protected hydroxyl or hydroxyl group; the application of the composition (A) being followed by the application of an acidic aqueous composition (B), the composition (A) or the composition (B) containing at least one nitrite.
Dans la formule (I) précitée, Z désigne lorsque ZO représente un radical hydroxyle protégé, de préférence, un radical acyle en C2-Cg.In the above formula (I), Z denotes when ZO represents a protected hydroxyl radical, preferably a C2-Cg acyl radical.
Conformément à l'invention, les composés particulièrement préférés de formule (I), sont des composés dans lesquels le radical alkyle désigne methyle, éthyle; le radical alcoxycarbonyle désigne méthoxy ou éthoxycarbonyle; le radical acyle désigne de préférence acétyle.In accordance with the invention, the particularly preferred compounds of formula (I) are compounds in which the alkyl radical denotes methyl, ethyl; the alkoxycarbonyl radical denotes methoxy or ethoxycarbonyl; the acyl radical preferably denotes acetyl.
Parmi ces composés, on peut plus particulièrement citer le 6-hydroxyindole, le 6-hydroxy 3-carbométhoxyindole, le 6-hydroxy 1-méthyl 3-carbo-methoxyindole, le 6-acétoxy 1—mêthyl 3-carbométhcxy indole, le 6-acétoxy 1-méthyl 2,3-dicarbométhoxyindole, le 6-acétoxy 1,2-dimêthylindole, le 6-hydroxy 1,2-diméthylindole, le 6-hydroxy 2-mêthylindole, le 6-hydroxy 2-carboxyindole, le 6-hydroxy 2,3-diméthyl indole, le 6-hydroxy 3-carboxyindole, le 6-hydroxy 3-carbéthoxyindole, le 6-hydroxy 2-carbéthoxyindole, le 6-acetoxyindole, le 6-hydroxy 3-méthylindole, le 5-hydroxyindole, le 7-hydroxyindole, le 4-hydroxyindole, le 6—hydroxy 1— methylindole, le 5—hydroxy 2-carboxyindole.Among these compounds, mention may more particularly be made of 6-hydroxyindole, 6-hydroxy 3-carbomethoxyindole, 6-hydroxy 1-methyl 3-carbo-methoxyindole, 6-acetoxy 1-methyl 3-carbomethoxy indole, 6- acetoxy 1-methyl 2,3-dicarbomethoxyindole, 6-acetoxy 1,2-dimethylindole, 6-hydroxy 1,2-dimethylindole, 6-hydroxy 2-methylindole, 6-hydroxy 2-carboxyindole, 6-hydroxy 2,3-dimethyl indole, 6-hydroxy 3-carboxyindole, 6-hydroxy 3-carbethoxyindole, 6-hydroxy 2-carbethoxyindole, 6-acetoxyindole, 6-hydroxy 3-methylindole, 5-hydroxyindole, 7-hydroxyindole, 4-hydroxyindole, 6-hydroxy 1-methylindole, 5-hydroxy 2-carboxyindole.
Les nitrites tout particulièrement utilisables, conformément à l'invention, sont : - des nitrites de métaux alcalins, alcalino-terreux ou d'ammonium et tout autre cation cosmetiquement acceptable lorsqu'il est utilisé pour la teinture des cheveux humains vivants; - des dérivés organiques de nitrite, tels que par exemple le nitrite d'amyle; ou encore - des vecteurs de nitrite, c'est-à-dire des composés qui, par transformation, génèrent un nitrite.The nitrites which can be very particularly used, in accordance with the invention, are: - nitrites of alkali metals, alkaline earth metals or of ammonium and any other cosmetically acceptable cation when it is used for dyeing living human hair; - organic nitrite derivatives, such as for example amyl nitrite; or - nitrite vectors, that is, compounds which, by transformation, generate nitrite.
Les nitrites particulièrement préférés sont les nitrites de sodium, de potassium ou d'ammonium.Particularly preferred nitrites are sodium, potassium or ammonium nitrites.
Les dérivés d'indole sont utilisés dans la composition (A) dans des quantités suffisantes pour teindre les fibres kératiniques après association avec le nitrite, selon la nuance désirée. Cette concentration est comprise entre 0,01 et 0,3 mole/litre.The indole derivatives are used in composition (A) in amounts sufficient to dye the keratin fibers after association with the nitrite, according to the desired shade. This concentration is between 0.01 and 0.3 mole / liter.
L'anion nitrite exprimé sous forme de -NO2“ est présent dans des quantités suffisantes pour développer avec les dérivés d'indole répondant à la formule (I), appliqués dans la première étape, une coloration. Sa concentration est de préférence comprise entre 0,02 et 1 mole/litre.The nitrite anion expressed in the form of -NO2 “is present in sufficient quantities to develop with the indole derivatives corresponding to formula (I), applied in the first step, a coloration. Its concentration is preferably between 0.02 and 1 mole / liter.
Le pH de la composition (A) est de préférence compris entre 2 et 10.The pH of the composition (A) is preferably between 2 and 10.
Le pH de la composition (B) est acide et permet de réguler la coloration.The pH of the composition (B) is acidic and makes it possible to regulate the coloring.
En effet, en milieu acide, le nitrite est suffisamment oxydant pour réagir avec 1'hydroxyindole ou son dérivé protégé.Indeed, in an acid medium, the nitrite is sufficiently oxidizing to react with the hydroxyindole or its protected derivative.
Le pH de la composition (B) est compris de preference entre 2 et 6 et en particulier il est ajusté à environ 3 pour des durées de contact faibles et pour des nuances les plus foncées.The pH of composition (B) is preferably between 2 and 6 and in particular it is adjusted to around 3 for short contact times and for the darkest shades.
Une forme de réalisation particulièrement préférée de l'invention consiste à appliquer, dans un premier temps, la composition (A) contenant le dérivé d'indole de formule (I) et, dans un second temps, la composition (B) contenant en milieu aqueux et acide, un nitrite.A particularly preferred embodiment of the invention consists in applying, firstly, the composition (A) containing the indole derivative of formula (I) and, secondly, the composition (B) containing in medium aqueous and acidic, a nitrite.
Une autre forme de réalisation de l'invention peut consister à appliquer, dans un premier temps, une composition (A1) contenant, dans un milieu approprié pour la teinture, le dérivé d'indole de formule (I) en milieu neutre ou alcalin et un nitrite. Dans ce cas, on teint les cheveux, en appliquant, dans un deuxième temps, une composition comprenant un milieu aqueux approprié pour la teinture ajusté à un pH acide et de préférence compris entre 2 et 6.Another embodiment of the invention may consist in applying, firstly, a composition (A1) containing, in a medium suitable for dyeing, the indole derivative of formula (I) in a neutral or alkaline medium and a nitrite. In this case, the hair is dyed, by applying, in a second step, a composition comprising an aqueous medium suitable for dyeing adjusted to an acidic pH and preferably between 2 and 6.
Un autre objet de l'invention est constitué par une telle composition (A') contenant simultanément les dérivés d'indole répondant à la formule (I), définis ci-dessus et les anions nitrite. Les proportions en dérivés d'indole de formule (I) et en nitrite, ainsi que la nature des nitrites, sont celles indiquées ci-dessus.Another subject of the invention consists of such a composition (A ') simultaneously containing the indole derivatives corresponding to formula (I), defined above and the nitrite anions. The proportions of indole derivatives of formula (I) and of nitrite, as well as the nature of the nitrites, are those indicated above.
Les compositions (A) ou (B) ainsi que la composition (A') contenant les dérivés d'indole de formule (I) et le nitrite, peuvent contenir des adjuvants habituellement utilisés en teinture des fibres kêratiniques et plus particulièrement en plus de l'eau, un solvant qui, dans le cas où la composition est appliquée sur les cheveux, est cosmétiquement acceptable.The compositions (A) or (B) as well as the composition (A ′) containing the indole derivatives of formula (I) and the nitrite, may contain adjuvants usually used in dyeing keratin fibers and more particularly in addition to the water, a solvent which, in the case where the composition is applied to the hair, is cosmetically acceptable.
Les solvants sont choisis parmi les solvants organiques, tels que les alcools inférieurs en 0^-05, l'alcool éthylique, l'alcool propylique ou isopropylique, l'alcool tertiobutylique, l'éthylène glycol, le propylèneglycol, les éthers monométhylique, monoêthylique ou raonobutylique de 1'ethyleneglycol, l'acétate du monoêthyléther de 1'éthylèneglycol, les monomethylethers du propylèneglycol et du dijsropylene glycol, le lactate de méthyle.The solvents are chosen from organic solvents, such as lower alcohols in 0 ^ -05, ethyl alcohol, propyl or isopropyl alcohol, tert-butyl alcohol, ethylene glycol, propylene glycol, monomethyl, monoethyl ethers or ethylene glycol ronobutyl, ethylene glycol monoethyl ether acetate, propylene glycol and dipropylene glycol monomethyl ethers, methyl lactate.
Les solvants particulièrement préférés sont l'alcool éthylique et le propylèneglycol.Particularly preferred solvents are ethyl alcohol and propylene glycol.
Les solvants sont utilisés plus particulièrement dans des concentrations comprises entre 10 et 50% pour les alcools inférieurs lorsque la concentration en dérivés d'indole de formule (I) dépasse 1% en poids par rapport au poids total de la composition.The solvents are used more particularly in concentrations of between 10 and 50% for lower alcohols when the concentration of indole derivatives of formula (I) exceeds 1% by weight relative to the total weight of the composition.
Les compositions utilisables dans le procédé conforme a l'invention peuvent également contenir d'autres adjuvants qui sont cosmétiquement acceptables lorsque les compositions sont destinées à teindre les cheveux humains. Ces adjuvants sont, entre autres, des agents tensio-actifs anioniques, cationiques, non ioniques, amphotères ou leurs mélanges, présents de préférence dans des proportions comprises entre 0,1 et 50%; des agents épaississants, des parfums, des agents séquestrants, des agents filmogènes, des agents de traitement, des agents dispersants, des agents de conditionnement, des agents conservateurs, des agents opacifiants, des agents de gonflement des fibres kératiniques.The compositions which can be used in the process according to the invention may also contain other adjuvants which are cosmetically acceptable when the compositions are intended for dyeing human hair. These adjuvants are, inter alia, anionic, cationic, nonionic, amphoteric surfactants or their mixtures, preferably present in proportions of between 0.1 and 50%; thickening agents, perfumes, sequestering agents, film-forming agents, treatment agents, dispersing agents, conditioning agents, preserving agents, opacifying agents, keratin fiber swelling agents.
Les épaississants peuvent être choisis parmi 1'alginate de sodium, la gomme arabique, la gomme de guar, les biopolymères comme la gomme de xanthane, les sclêroglucanes, les dérivés de cellulose tels que la méthylcellulose, 1'hydroxyêthylcellulose, 1'hydroxy- propylméthylcellulose, le sel de sodium de la carboxyméthyIcellulose et les polymères d'acide acrylique éventuellement réticulés.The thickeners can be chosen from sodium alginate, gum arabic, guar gum, biopolymers such as xanthan gum, scleroglucans, cellulose derivatives such as methylcellulose, hydroxyethylcellulose, hydroxypropylmethylcellulose , the sodium salt of carboxymethylcellulose and optionally crosslinked acrylic acid polymers.
On peut également utiliser des épaississants minéraux tels que la bentonite.One can also use mineral thickeners such as bentonite.
Ces épaississants utilisés seuls ou en mélange, sont présents de préférence dans des proportions comprises entre 0,1 et 5% en poids par rapport au poids total de la composition et avantageusement entre 0,5 et 3% en poids.These thickeners, used alone or as a mixture, are preferably present in proportions of between 0.1 and 5% by weight relative to the total weight of the composition and advantageously between 0.5 and 3% by weight.
Les agents d'acidification utilisables sont plus particulièrement choisis parmi l'acide lactique, l'acide acétique, l'acide tartrique, l'acide phosphorique, l'acide chlorhydrique ou l'acide citrique.The acidifying agents which can be used are more particularly chosen from lactic acid, acetic acid, tartaric acid, phosphoric acid, hydrochloric acid or citric acid.
Les agents alcalinisants sont particulièrement choisis parmi les amines, telles que les alcanolamines, les alkylamines ou alors les hydroxydes ou les carbonates alcalins ou d'ammonium.The basifying agents are particularly chosen from amines, such as alkanolamines, alkylamines or then alkali or ammonium hydroxides or carbonates.
Les compositions (A), (A') et/ou (B) utilisables dans le procédé conforme à l'invention, peuvent également contenir d'autres colorants habituellement utilisés pour la teinture des fibres kératiniques et en particulier le 5,6-dihydroxyindole ou ses dérivés, décrits plus particulièrement dans le brevet FR-A-2.595.245.The compositions (A), (A ') and / or (B) which can be used in the process according to the invention, may also contain other dyes usually used for dyeing keratin fibers and in particular 5,6-dihydroxyindole or its derivatives, described more particularly in patent FR-A-2,595,245.
Les compositions peuvent également contenir des colorants directs, en particulier les derives nitres benzéniques, des colorants d'oxydation, tels que des précurseurs de colorants d'oxydation du type para ou ortho, des coupleurs ou des colorants d'oxydation dits "rapides", c'est-à-dire des molécules à structure benzénique, précurseurs de colorants susceptibles de générer les composés colorés par simple oxydation a l'air pendant le temps de pose sur la chevelure, généralement inférieur à 1 heure et en absence d'un autre agent oxydant.The compositions may also contain direct dyes, in particular benzene nitro derivatives, oxidation dyes, such as oxidation dye precursors of the para or ortho type, couplers or oxidation dyes known as "fast", that is to say molecules with a benzene structure, precursors of dyes capable of generating the colored compounds by simple oxidation in the air during the exposure time on the hair, generally less than 1 hour and in the absence of another oxidizing agent.
Les compositions peuvent être formulées sous des formes diverses cosmétiquement acceptables/ lorsqu'elles sont appliquées sur les cheveux, telles que liquides plus ou moins épaissis ou gélifiés, crème, émulsion, mousse ou autres formes appropriées pour réaliser la teinture.The compositions can be formulated in various cosmetically acceptable forms / when they are applied to the hair, such as more or less thickened or gelled liquids, cream, emulsion, foam or other forms suitable for making the dye.
En vue de la mise en oeuvre du procédé conforme à l'invention, on peut conditionner les différentes compositions dans un dispositif à plusieurs compartiments, encore appelé "kit" ou nécessaire de teinture, comportant tous les composants destinés à être appliqués dans une même teinture sur les fibres kératiniques, et en particulier les cheveux, en applications successives avec ou sans prémélange.With a view to implementing the process according to the invention, the various compositions can be packaged in a device with several compartments, also called a "kit" or dye kit, comprising all the components intended to be applied in the same dye. on keratin fibers, and in particular the hair, in successive applications with or without premix.
De tels dispositifs sont connus en eux-mêmes et peuvent comporter un premier compartiment contenant la composition (A) renfermant le dérivé d'indole de formule (I) dans un milieu approprié pour la teinture, un deuxième compartiment, la composition (B) contenant dans un milieu approprié pour la teinture à un pH acide, un nitrite tel que défini ci-dessus.Such devices are known in themselves and may comprise a first compartment containing the composition (A) containing the indole derivative of formula (I) in a medium suitable for dyeing, a second compartment, the composition (B) containing in a medium suitable for dyeing at an acidic pH, a nitrite as defined above.
Une autre forme de réalisation de 1 'invention consiste à prévoir un dispositif à plusieurs compartiments ou kits, comportant dans un premier compartiment, la composition (A1) contenant dans un milieu approprié pour la teinture et présentant un pH neutre ou alcalin, le dérivé d'indole de formule (I) et les anions nitrite, et dans un second compartiment, une solution aqueuse présentant un pH acide compris de préférence entre 2 et 6.Another embodiment of the invention consists in providing a device with several compartments or kits, comprising in a first compartment, the composition (A1) containing in a medium suitable for dyeing and having a neutral or alkaline pH, the derivative d indole of formula (I) and the nitrite anions, and in a second compartment, an aqueous solution having an acid pH preferably between 2 and 6.
Le procédé conforme à l'invention ainsi que les compositions définies ci-dessus, peuvent être mis en oeuvre pour teindre les cheveux naturels ou déjà teints, permanentes ou non, ou défrisés, ou des cheveux fortement ou légèrement décolorés, éventuellement permanentés.The process according to the invention, as well as the compositions defined above, can be used to dye natural or already dyed hair, permanent or not, or straightened, or strongly or slightly discolored hair, possibly permed.
Dans ce cas, on applique la composition (A) à une température qui est celle de la tête, c'est-à-dire comprise entre 25 et 35ÖC, pendant 5 à 30 minutes, et on fait suivre, avec ou sans rinçage intermédiaire, cette application par l'application de la composition (B) contenant le nitrite, qui est maintenue au contact des cheveux pendant 5 à 30 minutes. La température de la teinture est également celle de la tête et elle est comprise entre 25 et 35°C.In this case, the composition (A) is applied at a temperature which is that of the head, that is to say between 25 and 35 ° C., for 5 to 30 minutes, and followed, with or without intermediate rinsing. , this application by applying the composition (B) containing the nitrite, which is maintained in contact with the hair for 5 to 30 minutes. The temperature of the dye is also that of the head and is between 25 and 35 ° C.
Dans la forme de réalisation mettant en oeuvre les dérivés d'indole de formule (I) et le nitrite dans une même composition en milieu neutre ou alcalin, on maintient la première composition (A') au contact des cheveux pendant 5 à 30 minutes et après rinçage éventuel, on applique la composition aqueuse acide.In the embodiment using the indole derivatives of formula (I) and the nitrite in the same composition in neutral or alkaline medium, the first composition (A ′) is maintained in contact with the hair for 5 to 30 minutes and after optional rinsing, the acidic aqueous composition is applied.
Ces compositions peuvent également être utilisées pour la teinture des fourrures ou de la laine.These compositions can also be used for dyeing furs or wool.
Les exemples suivants sont destinés à illustrer l'invention sans pour autant présenter un caractère limitatif.The following examples are intended to illustrate the invention without, however, being limiting in nature.
EXEMPLE 1 COMPOSITION (A) : - 4-hydroxyindoie 0,8 g - Monobutylêther de l'éthylène glycol 8,0 gEXAMPLE 1 COMPOSITION (A): - 4-hydroxyindoie 0.8 g - Monobutyl ether of ethylene glycol 8.0 g
- Alkyléther de glycoside vendu à la concentration de 60% MA- Glycoside alkyl ether sold at a concentration of 60% MA
sous la dénomination de TRITON CG 110under the name of TRITON CG 110
par la Société SEPPIC 2,4 g MAby SEPPIC 2.4 g MA
- pH spontané = 4,7 " Eau qsp 100,0 g COMPOSITION (B) : - Nitrite de sodium 2,0 g - Acide chlorhydrique qs pH=3,8 “ Eau qsp 100,0 g- spontaneous pH = 4.7 "Water qs 100.0 g COMPOSITION (B): - Sodium nitrite 2.0 g - Hydrochloric acid qs pH = 3.8" Water qs 100.0 g
La composition (A) est appliquée pendant 15 minutes sur des cheveux gris à 90% de blancs. Après rinçage, on applique pendant 10 minutes la composition (B). On rince et on sèche les cheveux. Ils sont alors colorés dans une nuance blond doré.Composition (A) is applied for 15 minutes to gray hair containing 90% white hairs. After rinsing, composition (B) is applied for 10 minutes. Rinse and dry the hair. They are then colored in a golden blonde shade.
EXEMPLE 2 COMPOSITION (A) : - 6-hydroxyindoIe 1,5 g - Ethanol 12,0 g - pH spontané = 6 “ Eau qsp 100,0 g COMPOSITION (B) : - Nitrite de sodium 2,0 g - Acide chlorhydrique qs pH=3,8 “ Eau qsp 100,0 gEXAMPLE 2 COMPOSITION (A): - 6-hydroxyindoIe 1.5 g - Ethanol 12.0 g - spontaneous pH = 6 “Water qs 100.0 g COMPOSITION (B): - Sodium nitrite 2.0 g - Hydrochloric acid qs pH = 3.8 “Water qs 100.0 g
La composition (A) est appliquée pendant 15 minutes sur des cheveux gris à 90% de blancs. Après rinçage, on applique pendant 10 minutes la composition (B) avant de rincer à nouveau. Après séchage, on obtient des cheveux teints dans une nuance blond acajou cuivré.Composition (A) is applied for 15 minutes to gray hair containing 90% white hairs. After rinsing, the composition (B) is applied for 10 minutes before rinsing again. After drying, the hair is dyed in a coppery mahogany blonde shade.
EXEMPLE 3EXAMPLE 3
On prépare les compositions suivantes : COMPOSITION (A) : - 4-hydroxyindole 2,5 g - Ethanol .30,0 g - Eau qsp 100,0 g - pH spontané = 6 COMPOSITION (B) : - Nitrite de sodium 2,5 g - Acide chlorhydrique qs pH=3 - Eau qsp 100,0 gThe following compositions are prepared: COMPOSITION (A): - 4-hydroxyindole 2.5 g - Ethanol .30.0 g - Water qs 100.0 g - spontaneous pH = 6 COMPOSITION (B): - Sodium nitrite 2.5 g - Hydrochloric acid qs pH = 3 - Water qs 100.0 g
La composition est appliquée pendant 15 minutes sur des cheveux gris à 90% de blancs. Après rinçage, on applique pendant 10 minutes la composition (B) avant de rincer à nouveau. Après séchage, on obtient des cheveux teints dans une nuance orangé foncé.The composition is applied for 15 minutes to gray hair containing 90% white hairs. After rinsing, the composition (B) is applied for 10 minutes before rinsing again. After drying, hair dyed in a dark orange shade is obtained.
EXEMPLE 4EXAMPLE 4
On prépare les compositions suivantes : COMPOSITION (A) : - 5-hydroxyindole 2,5 g - Ethanol .20,0 g “ E^u qsp 100,0 g - pH spontané = 5,75 COMPOSITION (B) : - Nitrite de sodium 2,5 g - Acide chlorhydrique qs pH=3 ” Eau qsp 100,0 gThe following compositions are prepared: COMPOSITION (A): - 5-hydroxyindole 2.5 g - Ethanol .20.0 g “E ^ u qs 100.0 g - spontaneous pH = 5.75 COMPOSITION (B): - Nitrite sodium 2.5 g - hydrochloric acid qs pH = 3 ”Water qs 100.0 g
On applique la composition (A) pendant 15 minutes sur des cheveux gris à 90% de blancs. Après rinçage, on applique pendant 9 minutes la composition (B) avant de rincer à nouveau. Après séchage, on obtient des cheveux teints dans une nuance violet lumineux très intense.Composition (A) is applied for 15 minutes to gray hair containing 90% white hairs. After rinsing, the composition (B) is applied for 9 minutes before rinsing again. After drying, dyed hair is obtained in a very intense luminous purple shade.
EXEMPLE 5EXAMPLE 5
On prépare les compositions suivantes : COMPOSITION (A) : - 5-hydroxy 2-carboxyindole 2,5 g - Ethanol .40,0 g “ Eau qsp 100,0 g - pH spontané = 2,85 COMPOSITION (E) : - Nitrite de sodium 2,5 g - Acide chlorhydrique qs pH=3 “ Eau qsp 100,0 gThe following compositions are prepared: COMPOSITION (A): - 5-hydroxy 2-carboxyindole 2.5 g - Ethanol .40.0 g “Water qs 100.0 g - spontaneous pH = 2.85 COMPOSITION (E): - Nitrite sodium 2.5 g - hydrochloric acid qs pH = 3 “Water qs 100.0 g
La composition (A) est appliquée pendant 15 minutes sur des cheveux gris à 90% de blancs. Après rinçage, on applique pendant 8 minutes la composition (B) avant de rincer à nouveau. Après séchage, on obtient des cheveux teints dans une nuance rouge vif.Composition (A) is applied for 15 minutes to gray hair containing 90% white hairs. After rinsing, the composition (B) is applied for 8 minutes before rinsing again. After drying, hair dyed in a bright red shade is obtained.
EXEMPLE 6EXAMPLE 6
On prépare les compositions suivantes : COMPOSITION (A) : - 6-hydroxyindole 2,5 g - Ethanol . io,0 g “ Eau qsp 100,0 g - pH spontané = 5,7 COMPOSITION (B) : - Nitrite de sodium 2,5 g - Acide chlorhydrique qs pH=3 - Eau qsp 100,0 gThe following compositions are prepared: COMPOSITION (A): - 6-hydroxyindole 2.5 g - Ethanol. io, 0 g “Water qs 100.0 g - spontaneous pH = 5.7 COMPOSITION (B): - Sodium nitrite 2.5 g - Hydrochloric acid qs pH = 3 - Water qs 100.0 g
La composition (A) est appliquée pendant 15 minutes sur des cheveux gris à 90% de blancs. Après rinçage, on applique pendant 9 minutes la composition (E) avant de rincer à nouveau. Après séchage, on obtient des cheveux teints dans une nuance acajou cuivré.Composition (A) is applied for 15 minutes to gray hair containing 90% white hairs. After rinsing, the composition (E) is applied for 9 minutes before rinsing again. After drying, the hair is dyed in a coppery mahogany shade.
EXEMPLE 7EXAMPLE 7
On prépare les compositions suivantes : COMPOSITION (A) : - 6-hydroxy 1-mêthyl indole 2,5 g - Ethanol .20,0 g “ Eau qsp 100,0 g - pH spontané = 5,8 COMPOSITION (B) : - Nitrite de sodium 2,5 g - Acide chlorhydrique qs pH=3 - Eaa qsp 100,0 gThe following compositions are prepared: COMPOSITION (A): - 6-hydroxy 1-methyl indole 2.5 g - Ethanol .20.0 g “Water qs 100.0 g - spontaneous pH = 5.8 COMPOSITION (B): - Sodium nitrite 2.5 g - Hydrochloric acid qs pH = 3 - Eaa qs 100.0 g
On applique la composition (A) sur des cheveux gris à 90% de blancs pendant 15 minutes. Après rinçage, on applique pendant 10 minutes la composition (B) avant de rincer à nouveau. Après séchage, on obtient des cheveux teints dans une nuance acajou cuivré.Composition (A) is applied to gray hair containing 90% white hair for 15 minutes. After rinsing, the composition (B) is applied for 10 minutes before rinsing again. After drying, the hair is dyed in a coppery mahogany shade.
EXEMPLE 8EXAMPLE 8
On prépare les compositions suivantes : COMPOSITION (A) : - 7-hydroxyindole 2,5 g - Ethanol 20,0 g “ Eau qsp 100,0 g - pH spontané = 5,75 COMPOSITION (E) : - Nitrite de sodium 2,5 g - Acide chlorhydrique qs pH=3 “ Eau qsp 100,0 gThe following compositions are prepared: COMPOSITION (A): - 7-hydroxyindole 2.5 g - Ethanol 20.0 g “Water qs 100.0 g - spontaneous pH = 5.75 COMPOSITION (E): - Sodium nitrite 2, 5 g - Hydrochloric acid qs pH = 3 “Water qs 100.0 g
On applique la composition (A) pendant 15 minutes sur des cheveux gris à 90% de blancs. Après rinçage, on applique pendant 9 minutes la composition (B) avant de rincer à nouveau. Après séchage, on obtient des cheveux teints dans une nuance jaune orangé.Composition (A) is applied for 15 minutes to gray hair containing 90% white hairs. After rinsing, the composition (B) is applied for 9 minutes before rinsing again. After drying, hair dyed in an orange-yellow shade is obtained.
Claims (20)
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| LU87333A LU87333A1 (en) | 1988-09-08 | 1988-09-08 | PROCESS FOR DYEING KERATINIC FIBERS WITH AN INDOLE DERIVATIVE ASSOCIATED WITH A NITRITE AND COMPOSITION FOR USE |
| EP89402311A EP0360638A1 (en) | 1988-09-08 | 1989-08-21 | Process for dyeing keratinous fibres with an indole derivative associated with a nitrite, and composition therefor |
| JP1230561A JPH02104779A (en) | 1988-09-08 | 1989-09-07 | Dyeing method for keratinous fibers |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| LU87333A LU87333A1 (en) | 1988-09-08 | 1988-09-08 | PROCESS FOR DYEING KERATINIC FIBERS WITH AN INDOLE DERIVATIVE ASSOCIATED WITH A NITRITE AND COMPOSITION FOR USE |
| LU87333 | 1988-09-08 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| LU87333A1 true LU87333A1 (en) | 1990-04-06 |
Family
ID=19731087
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| LU87333A LU87333A1 (en) | 1988-09-08 | 1988-09-08 | PROCESS FOR DYEING KERATINIC FIBERS WITH AN INDOLE DERIVATIVE ASSOCIATED WITH A NITRITE AND COMPOSITION FOR USE |
Country Status (3)
| Country | Link |
|---|---|
| EP (1) | EP0360638A1 (en) |
| JP (1) | JPH02104779A (en) |
| LU (1) | LU87333A1 (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2654335A1 (en) * | 1989-11-10 | 1991-05-17 | Oreal | TINCTORIAL COMPOSITIONS FOR KERATIN FIBERS CONTAINING OXIDATION COLORING PRECURSORS AND 4-HYDROXYINDOLE DERIVED COUPLERS, AND METHOD OF DYING USING SAME. |
| FR2659228B1 (en) * | 1990-03-08 | 1994-10-14 | Oreal | PROCESS FOR DYEING KERATINIC FIBERS WITH 6 OR 7-MONOHYDROXY-INDOLES WITH ACID PH AND COMPOSITIONS USED THEREOF. |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4776857A (en) * | 1986-11-21 | 1988-10-11 | Repligen Corporation | Use of hydroxylated indoles as dye precursors |
-
1988
- 1988-09-08 LU LU87333A patent/LU87333A1/en unknown
-
1989
- 1989-08-21 EP EP89402311A patent/EP0360638A1/en not_active Ceased
- 1989-09-07 JP JP1230561A patent/JPH02104779A/en active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| EP0360638A1 (en) | 1990-03-28 |
| JPH02104779A (en) | 1990-04-17 |
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