KR980001997A - 폴리올조성물 - Google Patents
폴리올조성물 Download PDFInfo
- Publication number
- KR980001997A KR980001997A KR1019960023391A KR19960023391A KR980001997A KR 980001997 A KR980001997 A KR 980001997A KR 1019960023391 A KR1019960023391 A KR 1019960023391A KR 19960023391 A KR19960023391 A KR 19960023391A KR 980001997 A KR980001997 A KR 980001997A
- Authority
- KR
- South Korea
- Prior art keywords
- phosphite
- hydroquinone
- carbon atoms
- hydrogen
- bromine
- Prior art date
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- 229920005862 polyol Polymers 0.000 title claims abstract 10
- 150000003077 polyols Chemical class 0.000 title claims abstract 8
- 239000000203 mixture Substances 0.000 title claims abstract 6
- -1 hydroquinone compound Chemical class 0.000 claims abstract 9
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N 1,4-Benzenediol Natural products OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 claims abstract 7
- 239000003381 stabilizer Substances 0.000 claims abstract 4
- 125000000217 alkyl group Chemical group 0.000 claims 5
- 125000004432 carbon atom Chemical group C* 0.000 claims 5
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims 4
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims 4
- 229910052794 bromium Inorganic materials 0.000 claims 4
- 229910052801 chlorine Inorganic materials 0.000 claims 4
- 239000000460 chlorine Substances 0.000 claims 4
- 125000001188 haloalkyl group Chemical group 0.000 claims 4
- 229910052736 halogen Inorganic materials 0.000 claims 4
- 150000002367 halogens Chemical class 0.000 claims 4
- 229910052739 hydrogen Inorganic materials 0.000 claims 4
- 239000001257 hydrogen Substances 0.000 claims 4
- 125000003118 aryl group Chemical group 0.000 claims 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 2
- 150000002431 hydrogen Chemical class 0.000 claims 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 2
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 claims 2
- 150000005208 1,4-dihydroxybenzenes Chemical class 0.000 claims 1
- RIUKNBHCAWXEFE-UHFFFAOYSA-N 2,5-di(nonyl)benzene-1,4-diol Chemical compound CCCCCCCCCC1=CC(O)=C(CCCCCCCCC)C=C1O RIUKNBHCAWXEFE-UHFFFAOYSA-N 0.000 claims 1
- JZODKRWQWUWGCD-UHFFFAOYSA-N 2,5-di-tert-butylbenzene-1,4-diol Chemical compound CC(C)(C)C1=CC(O)=C(C(C)(C)C)C=C1O JZODKRWQWUWGCD-UHFFFAOYSA-N 0.000 claims 1
- QVLXDGDLLZYJAM-UHFFFAOYSA-N 2,5-dioctylbenzene-1,4-diol Chemical compound CCCCCCCCC1=CC(O)=C(CCCCCCCC)C=C1O QVLXDGDLLZYJAM-UHFFFAOYSA-N 0.000 claims 1
- XRCRJFOGPCJKPF-UHFFFAOYSA-N 2-butylbenzene-1,4-diol Chemical compound CCCCC1=CC(O)=CC=C1O XRCRJFOGPCJKPF-UHFFFAOYSA-N 0.000 claims 1
- ZZXILYOBAFPJNS-UHFFFAOYSA-N 2-octylbenzene-1,4-diol Chemical compound CCCCCCCCC1=CC(O)=CC=C1O ZZXILYOBAFPJNS-UHFFFAOYSA-N 0.000 claims 1
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 claims 1
- 125000002877 alkyl aryl group Chemical group 0.000 claims 1
- 235000010290 biphenyl Nutrition 0.000 claims 1
- 239000004305 biphenyl Substances 0.000 claims 1
- 125000006267 biphenyl group Chemical group 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- GLOQRSIADGSLRX-UHFFFAOYSA-N decyl diphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OCCCCCCCCCC)OC1=CC=CC=C1 GLOQRSIADGSLRX-UHFFFAOYSA-N 0.000 claims 1
- NMAKPIATXQEXBT-UHFFFAOYSA-N didecyl phenyl phosphite Chemical compound CCCCCCCCCCOP(OCCCCCCCCCC)OC1=CC=CC=C1 NMAKPIATXQEXBT-UHFFFAOYSA-N 0.000 claims 1
- ZJIPHXXDPROMEF-UHFFFAOYSA-N dihydroxyphosphanyl dihydrogen phosphite Chemical compound OP(O)OP(O)O ZJIPHXXDPROMEF-UHFFFAOYSA-N 0.000 claims 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- 125000001624 naphthyl group Chemical group 0.000 claims 1
- AZQWKYJCGOJGHM-UHFFFAOYSA-N para-benzoquinone Natural products O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 claims 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 claims 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims 1
- BWPNIANVWARHPR-UHFFFAOYSA-N tridecyl dihydrogen phosphite Chemical compound CCCCCCCCCCCCCOP(O)O BWPNIANVWARHPR-UHFFFAOYSA-N 0.000 claims 1
- BDZBKCUKTQZUTL-UHFFFAOYSA-N triethyl phosphite Chemical compound CCOP(OCC)OCC BDZBKCUKTQZUTL-UHFFFAOYSA-N 0.000 claims 1
- CYTQBVOFDCPGCX-UHFFFAOYSA-N trimethyl phosphite Chemical compound COP(OC)OC CYTQBVOFDCPGCX-UHFFFAOYSA-N 0.000 claims 1
- HQUQLFOMPYWACS-UHFFFAOYSA-N tris(2-chloroethyl) phosphate Chemical compound ClCCOP(=O)(OCCCl)OCCCl HQUQLFOMPYWACS-UHFFFAOYSA-N 0.000 claims 1
- WGKLOLBTFWFKOD-UHFFFAOYSA-N tris(2-nonylphenyl) phosphite Chemical compound CCCCCCCCCC1=CC=CC=C1OP(OC=1C(=CC=CC=1)CCCCCCCCC)OC1=CC=CC=C1CCCCCCCCC WGKLOLBTFWFKOD-UHFFFAOYSA-N 0.000 claims 1
- QQBLOZGVRHAYGT-UHFFFAOYSA-N tris-decyl phosphite Chemical compound CCCCCCCCCCOP(OCCCCCCCCCC)OCCCCCCCCCC QQBLOZGVRHAYGT-UHFFFAOYSA-N 0.000 claims 1
- 239000004721 Polyphenylene oxide Substances 0.000 abstract 1
- 229920005830 Polyurethane Foam Polymers 0.000 abstract 1
- 239000007857 degradation product Substances 0.000 abstract 1
- 238000010525 oxidative degradation reaction Methods 0.000 abstract 1
- 229920001281 polyalkylene Polymers 0.000 abstract 1
- 229920000570 polyether Polymers 0.000 abstract 1
- 239000011496 polyurethane foam Substances 0.000 abstract 1
- 238000004383 yellowing Methods 0.000 abstract 1
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- Compositions Of Macromolecular Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
본 발명은 황변현상을 일으키지않는 폴리우레탄 폼을 제조하는데 사용되는 폴리올 조성물에 관한 것이다. 즉 폴리알킬렌 폴리에테르 폴리올중에 있는 산화적분해산물을 제거하여 폴리올을 안정화시키기 위하여 안정화제로 히드로퀴논계 화합물 및 1종 이상의 아인산 에스테르계 화합물을 폴리올 안정화제로 사용한 폴리올 조성물에 관한 것이다.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (4)
- 폴리올 100중량부에 대해 하기 일반식(Ⅰ)의 히드로퀴논계 화합물 0.001~2.0중량부 및 하기 일반식(Ⅱ,Ⅲ,Ⅳ 및 Ⅴ)에서 선택된 1종 이상의 아인산 에스테르계 화합물 0.001~2.0중량부를 함유함을 특징으로 하는 안정화제가 함유된 폴리올 조성물.상기 식에서, R1은 수소, 메틸 또는 에틸이고, R2, R3, R4및 R5는 각각 수소 또는 탄소수 1~9의 알킬기이다.상기 식에서, R1, R2및 R3는 각각 수소 또는 탄소수 1~20의 알킬, 아릴, 할로알킬기(할로겐은 염소 또는 브롬)이다.(단, R1,R2및 R3중 1개가 수소이면 나머지 2개는 반드시 탄소 1~20개의 알킬 아릴, 할로알킬기(할로겐은 염소 또는 브롬)이다.)상기 식에서 Ar은 나프틸, 디페닐 또는 페닐이고, R4는 탄소수 4~20의 알킬기이다.상기 식에서, R5내지 R9는 각각 탄소수 1~20의 알킬기, 아릴, 할로알킬기(할로겐은 염소 또는 브롬)이다.상기 식에서, R10, R11은 각각 탄소수 1~20의 알킬기, 아릴, 할로알킬기(할로겐은 염소 또는 브롬)이다.
- 제1항에 있어서, 일반식(1)의 히드로퀴논 유도체 0.01~0.3중량부 및 일반식(Ⅱ, Ⅲ, Ⅳ 및 Ⅴ)에서 선택된 1종 이상의 아인산 에스테르 화합물 0.01~0.3중량부를 함유함을 특징으로 하는 안정화제가 함유된 폴리올 조성물.
- 제1항에 있어서, 일반식(1)의 히드로퀴논계 화합물은, 히드로퀴논, 2,5-디터셜리-부틸 히드로퀴논, 2,5-디터셜리-아밀히드로퀴논, 2,5-디옥틸 히드로퀴논, 모노터셜리-부틸히드로퀴논, 2,5-디노닐히드로퀴논, 모노터셜리-아밀히드퀴논, 옥틸히드로퀴논, 부틸히드로퀴논 등임을 특징으로 하는 안정화제가 함유된 폴리올 조성물.
- 제1항에 있어서, 일반식(Ⅱ) 내지 (Ⅴ)로 표시되는 아인산에스테르계 화합물은 트리스(2,4-디터셜리-부틸페닐)포스파이트, 트리스(2-클로로에틸)포스파리트, 트리페닐포스파이트, 디데실 페닐 포스파이트, 데실 디페닐 포스파이트, 트리데실 하이드로젠 포스파이트, 페닐 다이소데실 포스파이트, 트리데실 포스파이트, 트리에틸포스파이트, 트리메틸포스파이트, 디(이소데실)펜타 에리트리틸 디포스파이트, 트리스(노닐페닐)포스파이트 등에서 선택된 1종 이상임을 특징으로 하는 안정화제가 함유된 폴리올 조성물.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1019960023391A KR980001997A (ko) | 1996-06-25 | 1996-06-25 | 폴리올조성물 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1019960023391A KR980001997A (ko) | 1996-06-25 | 1996-06-25 | 폴리올조성물 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR980001997A true KR980001997A (ko) | 1998-03-30 |
Family
ID=66288320
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019960023391A KR980001997A (ko) | 1996-06-25 | 1996-06-25 | 폴리올조성물 |
Country Status (1)
| Country | Link |
|---|---|
| KR (1) | KR980001997A (ko) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US968002A (en) * | 1908-12-05 | 1910-08-23 | Chalmers Detroit Motor Company | Induction-conduit for explosion-engines. |
| JPS56112931A (en) * | 1980-02-12 | 1981-09-05 | Sanyo Chem Ind Ltd | Polyol composition |
| JPS61130320A (ja) * | 1984-11-29 | 1986-06-18 | Daihachi Kagaku Kogyosho:Kk | 難燃性ポリウレタンフオ−ム組成物 |
| JPH0480256A (ja) * | 1990-07-23 | 1992-03-13 | Kurabo Ind Ltd | ポリウレタンフォームの製法 |
| KR940005646A (ko) * | 1992-06-04 | 1994-03-22 | 벡커, 바인 | 가수분해 안정성 3가 인 화합물의 제조방법 및 열가소성 수지용 안정화제로서 이의 용도 |
-
1996
- 1996-06-25 KR KR1019960023391A patent/KR980001997A/ko not_active Application Discontinuation
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US968002A (en) * | 1908-12-05 | 1910-08-23 | Chalmers Detroit Motor Company | Induction-conduit for explosion-engines. |
| JPS56112931A (en) * | 1980-02-12 | 1981-09-05 | Sanyo Chem Ind Ltd | Polyol composition |
| JPS61130320A (ja) * | 1984-11-29 | 1986-06-18 | Daihachi Kagaku Kogyosho:Kk | 難燃性ポリウレタンフオ−ム組成物 |
| JPH0480256A (ja) * | 1990-07-23 | 1992-03-13 | Kurabo Ind Ltd | ポリウレタンフォームの製法 |
| KR940005646A (ko) * | 1992-06-04 | 1994-03-22 | 벡커, 바인 | 가수분해 안정성 3가 인 화합물의 제조방법 및 열가소성 수지용 안정화제로서 이의 용도 |
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