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KR970059229A - 블렌드 고체 고분자 전해질 조성물 - Google Patents

블렌드 고체 고분자 전해질 조성물 Download PDF

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Publication number
KR970059229A
KR970059229A KR1019960002104A KR19960002104A KR970059229A KR 970059229 A KR970059229 A KR 970059229A KR 1019960002104 A KR1019960002104 A KR 1019960002104A KR 19960002104 A KR19960002104 A KR 19960002104A KR 970059229 A KR970059229 A KR 970059229A
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South Korea
Prior art keywords
weight
polymer electrolyte
solid polymer
blend solid
present
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KR1019960002104A
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English (en)
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KR0173087B1 (ko
Inventor
박정기
김동원
Original Assignee
윤덕용
한국과학기술원
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Priority to KR1019960002104A priority Critical patent/KR0173087B1/ko
Publication of KR970059229A publication Critical patent/KR970059229A/ko
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L71/00Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
    • C08L71/02Polyalkylene oxides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/16Halogen-containing compounds
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/1016Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018Polymeric electrolyte materials
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00Electrolytes
    • H01M2300/0017Non-aqueous electrolytes
    • H01M2300/0065Solid electrolytes
    • H01M2300/0082Organic polymers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Sustainable Energy (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Materials Engineering (AREA)
  • Conductive Materials (AREA)
  • Secondary Cells (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Primary Cells (AREA)

Abstract

본 발명은 블렌드 고체 고분자 전해질에 관한 것이다. 본 발명의 블렌드 고체 고분자 전해질은 폴리올리고옥시에틸옥시세바코일 약 10~60중량%, 폴리에틸렌옥사이드 약 10~60중량%, 리튬염 약 15~25중량%, 바람직하게는 약 16~64중량%, 약 16~64 중량% 및 약 19~20중량%로 조성된다. 본 발명의 블렌드 고체 고분자 전해질들은 기계적 물성 및 이온 전도 특성이 모두 우수하고, 유기 용매를 전혀 포함하고 있지 않아 전해액 누출 및 전극의 부식 문제가 없으며, 상용성이 뛰어나고, 특히 제조공정이 간단하고 가격이 저렴하여 인-라인 프로세스를 이용한 고분자 전해질 필름 제조시 공정성이 크게 향상되어 리튬 고분자 이차전지를 비롯한 여러 전기화학장치에 유용하게 사용될 수 있다.

Description

블렌드 고체 고분자 전해질 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 본 발명에 따른 블렌드 고체 고분자 전해질의 온도에 따른 이온 전도도를 나타낸 그래프이다.

Claims (3)

  1. 폴리에틸렌옥사이드 10~70중량%:하기 일반식으로 표시되는 반복단위를 갖는 폴리올리고옥시에틸렌옥시세바코일 10~70 중량%;
    [상기식에서, n은 20 내지 30의 수(number)이다]; 및, 리튬염 15~25중량 %를 함유하는 블렌드 고체 고분자 전해질 조성물.
  2. 폴리에틸렌옥사이드 10~70 중량%; 하기 일반식으로 표시되는 반복단위를 갖는 폴리올리고옥시에틸렌옥시세바코일 10~70 중량%;
    [상기 식에서, n은 20 내지 30의 수이다]; 및, 리튬염 15~225중량%를 유기용매에 용해시켜 고점성의 균일 용액을 제조하는 단계; 상기 고점성의 균일 용액을 캐스팅하여 필름을 얻는 단계; 및, 상기 필름을 건조시켜 수분 및 용매를 완전히 제거하는 단계를 포함하는 블렌드 고체 고분자 전해질의 제조방법.
  3. 하기 일반식으로 표시되는 반복단위를 갖는 폴리올리고옥시에틸렌옥시세바코일;
    상기 식에서, n은 20 내지 30의 수이다.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019960002104A 1996-01-30 1996-01-30 블렌드 고체 고분자 전해질 조성물 KR0173087B1 (ko)

Priority Applications (1)

Application Number Priority Date Filing Date Title
KR1019960002104A KR0173087B1 (ko) 1996-01-30 1996-01-30 블렌드 고체 고분자 전해질 조성물

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1019960002104A KR0173087B1 (ko) 1996-01-30 1996-01-30 블렌드 고체 고분자 전해질 조성물

Publications (2)

Publication Number Publication Date
KR970059229A true KR970059229A (ko) 1997-08-12
KR0173087B1 KR0173087B1 (ko) 1999-03-30

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Application Number Title Priority Date Filing Date
KR1019960002104A KR0173087B1 (ko) 1996-01-30 1996-01-30 블렌드 고체 고분자 전해질 조성물

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Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100349627B1 (ko) * 2000-05-17 2002-08-23 한국과학기술원 가교화된 폴리에틸렌옥사이드를 이용한 고분자 전해질조성물 및 제조방법

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