KR960702348A - 불포화 카르복실산 에스테르 제조용 촉매 및 그의 사용 방법 (Catalyst and Process for Using for the Preparation of Unsaturated Carboxylic Acid Esters) - Google Patents
불포화 카르복실산 에스테르 제조용 촉매 및 그의 사용 방법 (Catalyst and Process for Using for the Preparation of Unsaturated Carboxylic Acid Esters)Info
- Publication number
- KR960702348A KR960702348A KR1019950705255A KR19950705255A KR960702348A KR 960702348 A KR960702348 A KR 960702348A KR 1019950705255 A KR1019950705255 A KR 1019950705255A KR 19950705255 A KR19950705255 A KR 19950705255A KR 960702348 A KR960702348 A KR 960702348A
- Authority
- KR
- South Korea
- Prior art keywords
- catalyst
- preparation
- carboxylic acid
- acid esters
- unsaturated carboxylic
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
- C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
- C07C67/055—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/48—Silver or gold
- B01J23/52—Gold
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
- B01J23/8926—Copper and noble metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0207—Pretreatment of the support
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/067,445 US5347046A (en) | 1993-05-25 | 1993-05-25 | Catalyst and process for using same for the preparation of unsaturated carboxylic acid esters |
PCT/US1994/005382 WO1994027720A1 (en) | 1993-05-25 | 1994-05-11 | Catalyst and process for using same for the preparation of unsaturated carboxylic acid esters |
Publications (1)
Publication Number | Publication Date |
---|---|
KR960702348A true KR960702348A (ko) | 1996-04-27 |
Family
ID=22076033
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019950705255A KR960702348A (ko) | 1993-05-25 | 1995-11-24 | 불포화 카르복실산 에스테르 제조용 촉매 및 그의 사용 방법 (Catalyst and Process for Using for the Preparation of Unsaturated Carboxylic Acid Esters) |
Country Status (10)
Country | Link |
---|---|
US (1) | US5347046A (ko) |
EP (1) | EP0708684A1 (ko) |
JP (1) | JP3698322B2 (ko) |
KR (1) | KR960702348A (ko) |
CN (1) | CN1123527A (ko) |
AU (1) | AU6912994A (ko) |
BR (1) | BR9406696A (ko) |
CA (1) | CA2161952A1 (ko) |
TW (1) | TW254934B (ko) |
WO (1) | WO1994027720A1 (ko) |
Families Citing this family (51)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4323980C1 (de) * | 1993-07-16 | 1995-03-30 | Hoechst Ag | Palladium und Kalium sowie Cadmium, Barium oder Gold enthaltender Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung zur Herstellung von Vinylacetat |
CA2135021A1 (en) * | 1993-11-19 | 1995-05-20 | David J. Gulliver | Process for the preparation of catalysts for use in the production of vinyl acetate |
IL112414A (en) * | 1994-01-25 | 1998-08-16 | Anglo American Res Lab Pty Ltd | Method of preparing a catalyst by impregnating a porous support with a solution |
US5665668A (en) * | 1994-01-25 | 1997-09-09 | Grigorova; Bojidara | Method of making a catalyst |
DE19501891C1 (de) * | 1995-01-23 | 1996-09-26 | Degussa | Verfahren zur Herstellung eines Trägerkatalysators und seine Verwendung für die Produktion von Vinylacetat |
US5688993A (en) * | 1995-12-22 | 1997-11-18 | E. I. Du Pont De Nemours And Company | Method for modifying catalyst performance during the gas phase synthesis of vinyl acetate |
DE19623226A1 (de) * | 1996-06-11 | 1997-12-18 | Basf Ag | Katalysatorsysteme vom Typ der Ziegler-Natta-Katalysatoren |
US5731457A (en) * | 1997-06-03 | 1998-03-24 | Hoechst Celanese Corporation | Vinyl acetate process utilizing a palladium-gold-copper catalyst |
US5968869A (en) * | 1997-06-03 | 1999-10-19 | Celanese International Corporation | Vinyl acetate catalyst comprising palladium and gold deposited on a copper containing carrier |
DE19734975A1 (de) * | 1997-08-13 | 1999-03-11 | Hoechst Ag | Schalenkatalysator, Verfahren zu dessen Herstellung sowie Verwendung, insbesondere zur Gasphasenoxidation von Ethylen und Essigsäure zu Vinylacetat |
US5948724A (en) * | 1997-10-28 | 1999-09-07 | Celanese International Corporation | Vinyl acetate catalyst comprising metallic palladium and gold and cupric acetate |
US6072078A (en) * | 1997-12-12 | 2000-06-06 | Celanese International Corporation | Vinyl acetate production using a catalyst comprising palladium, gold, copper and any of certain fourth metals |
GB9810928D0 (en) * | 1998-05-22 | 1998-07-22 | Bp Chem Int Ltd | Catalyst and process |
US6015769A (en) * | 1998-06-02 | 2000-01-18 | Celanese International Corporation | Vinyl acetate catalyst comprising metallic palladium, gold and copper supported on a carrier and prepared with potassium aurate |
US6017847A (en) * | 1998-06-02 | 2000-01-25 | Celanese International Corporation | Vinyl acetate catalyst prepared with potassium aurate and comprising metallic palladium and gold on a carrier precoated with copper |
JP2000070718A (ja) * | 1998-06-17 | 2000-03-07 | Nippon Shokubai Co Ltd | ベンジルエステルの製造方法 |
US6303537B1 (en) * | 1999-11-17 | 2001-10-16 | Celanese International Corporation | Vinyl acetate catalyst comprising metallic palladium and gold and prepared utilizing sonication |
CN1090997C (zh) * | 2000-04-30 | 2002-09-18 | 中国石油化工集团公司 | 一种选择加氢除炔多金属催化剂 |
US20040242918A1 (en) * | 2000-06-27 | 2004-12-02 | Showa Denko K.K | Support and catalyst for use in producing lower aliphatic carboxylic acid ester, process for producing the catalyst and process for producing lower aliphatic carboxylic acid ester using the catalyst |
US6534438B1 (en) * | 2000-07-26 | 2003-03-18 | Bp Chemicals Limited | Catalyst composition |
DE10048844A1 (de) * | 2000-10-02 | 2002-04-11 | Basf Ag | Verfahren zur Herstellung von Platinmetall-Katalysatoren |
US6576665B2 (en) | 2001-04-03 | 2003-06-10 | Braintree Laboratories, Inc. | Encapsulated calcium acetate caplet and a method for inhibiting gastrointestinal phosphorous absorption |
TWI255736B (en) * | 2002-02-05 | 2006-06-01 | Basf Ag | A catalyst composition for the oxychlorination of ethylene and its use |
DE10208254A1 (de) * | 2002-02-26 | 2003-09-04 | Bayer Ag | Katalysator |
US6620965B1 (en) | 2002-03-08 | 2003-09-16 | Catalytic Distillation Technologies | Process for vinyl acetate |
JP5001543B2 (ja) * | 2004-11-17 | 2012-08-15 | 三菱レイヨン株式会社 | パラジウム含有担持触媒の製造方法 |
US8563032B2 (en) * | 2005-12-05 | 2013-10-22 | Roxane Laboratories, Inc. | Formulation and manufacturing process for calcium acetate capsules |
CN101511473B (zh) * | 2006-08-30 | 2012-07-18 | 昭和电工株式会社 | 用于生产乙酸链烯基酯的催化剂的制备方法 |
US7825204B2 (en) | 2006-12-19 | 2010-11-02 | Lyondell Chemical Technology, L.P. | Inorganic oxide extrudates |
JP2008173629A (ja) * | 2006-12-20 | 2008-07-31 | Showa Denko Kk | アシルオキシ化反応用触媒およびその製造方法 |
EP2177267B1 (en) * | 2007-08-13 | 2013-07-31 | Asahi Kasei Chemicals Corporation | Catalyst for carboxylic acid ester production, method for producing the same, and method for producing carboxylic acid ester |
JP4803767B2 (ja) * | 2007-10-26 | 2011-10-26 | 旭化成ケミカルズ株式会社 | 複合粒子担持物、該複合粒子担持物の製造方法、及び該複合粒子担持物を化学合成用の触媒として用いた化合物の製造方法 |
JP2009220099A (ja) * | 2008-02-20 | 2009-10-01 | Showa Denko Kk | 低級脂肪族カルボン酸製造用触媒の製造方法 |
US8173830B2 (en) * | 2009-05-07 | 2012-05-08 | Celanese International Corporation | Vinyl ester production from acetylene and carboxylic acid utilizing homogeneous catalyst |
US20100310441A1 (en) * | 2009-06-05 | 2010-12-09 | Basf Corporation | Catalytic Article for Removal of Volatile Organic Compounds in Low Temperature Applications |
GB201110850D0 (en) | 2011-03-04 | 2011-08-10 | Johnson Matthey Plc | Catalyst and mehtod of preparation |
DE102012008715A1 (de) * | 2012-05-03 | 2013-11-07 | Clariant Produkte (Deutschland) Gmbh | Herstellung von Schalenkatalysatoren in einer Beschichtungsvorrichtung |
DE102012008714A1 (de) * | 2012-05-03 | 2013-11-07 | Clariant Produkte (Deutschland) Gmbh | Vorimprägnierung von Schalenkatalysatoren mit einem Acetat |
GB201210891D0 (en) * | 2012-06-19 | 2012-08-01 | Johnson Matthey Plc | Catalyst composition |
TWI510293B (zh) * | 2012-09-19 | 2015-12-01 | Clariant Int Ltd | 用於製造烯基羧酸酯之銅促進殼催化劑,及用於製造該銅促進殼催化劑之方法。 |
CN106582871B (zh) * | 2015-10-19 | 2020-07-03 | 中国石油化工股份有限公司 | 醋酸烯丙酯生产所用的催化剂 |
US10596552B2 (en) * | 2017-06-21 | 2020-03-24 | China Petroleum & Chemical Corporation | Catalyst for preparing cumene and use thereof |
WO2018235705A1 (ja) * | 2017-06-23 | 2018-12-27 | エヌ・イーケムキャット株式会社 | 酢酸ビニル合成用パラジウム-金担持触媒の製造方法 |
CN112672823A (zh) * | 2018-09-17 | 2021-04-16 | 沙特基础工业全球技术公司 | 用于由合成气产生醇和醚的催化剂 |
KR102563207B1 (ko) | 2018-10-31 | 2023-08-02 | 에스케이이노베이션 주식회사 | 코발트계 단원자 탈수소화 촉매 및 이를 이용하여 파라핀으로부터 대응되는 올레핀을 제조하는 방법 |
CN112642480B (zh) * | 2019-10-10 | 2022-12-09 | 中国石油化工股份有限公司 | 乙烯法醋酸乙烯催化剂 |
KR20210061711A (ko) * | 2019-11-20 | 2021-05-28 | 에스케이이노베이션 주식회사 | 탈수소화 성형 촉매 및 이를 이용하여 파라핀을 올레핀으로 전환시키는 방법 |
CN110773163B (zh) * | 2019-12-02 | 2023-07-07 | 上海华谊(集团)公司 | 甲基丙烯醛选择加氢制甲基烯丙醇的催化剂及其制备方法 |
EP3928864B1 (en) | 2020-06-25 | 2024-11-06 | SK Innovation Co., Ltd. | Method for producing cobalt-based single-atom dehydrogenation catalysts having improved thermal stability and method for producing olefins from corresponding paraffins |
US12064750B2 (en) | 2020-09-17 | 2024-08-20 | Sk Innovation Co., Ltd. | Cobalt-based single-atom dehydrogenation catalysts having high selectivity and regenerability and method for producing corresponding olefins from paraffins using the same |
US20230398523A1 (en) * | 2020-11-27 | 2023-12-14 | Resonac Corporation | Method for manufacturing catalyst for manufacture of vinyl acetate and method for manufacturing vinyl acetate |
Family Cites Families (34)
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US3190912A (en) * | 1962-05-02 | 1965-06-22 | Nat Distillers Chem Corp | Process for preparing esters |
BE638489A (ko) * | 1962-10-11 | |||
US3277159A (en) * | 1963-06-18 | 1966-10-04 | Union Oil Company Of America | Process for the production of unsaturated esters and acetals from olefins |
GB1067850A (en) * | 1963-12-13 | 1967-05-03 | Ici Ltd | Improvements in and relating to the production of vinyl acetate |
US3346624A (en) * | 1964-05-11 | 1967-10-10 | Union Oil Co | Process for the catalytic oxidation of olefins with a group viii noble metal catalyst and oxygen to aldehydes, acetals and unsaturated esters |
US3531531A (en) * | 1965-06-23 | 1970-09-29 | Du Pont | Process for producing acetaldehyde from ethylene |
DE1252662B (ko) * | 1965-06-25 | |||
US3373189A (en) * | 1965-07-09 | 1968-03-12 | Nat Distillers Chem Corp | Vapor phase process for producing vinyl acetate from ethylene |
US3607916A (en) * | 1965-12-17 | 1971-09-21 | Asahi Chemical Ind | Process for producing vinyl acetate |
NL6608559A (ko) * | 1966-06-21 | 1967-12-22 | ||
CH495319A (de) * | 1966-12-17 | 1970-08-31 | Bayer Ag | Verfahren zur Herstellung organischer Ester |
DE1618589A1 (de) * | 1967-04-01 | 1971-02-25 | Knapsack Ag | Verfahren zur Herstellung von Carbonsaeuren |
US4057575A (en) * | 1967-09-25 | 1977-11-08 | Union Oil Company Of California | Process for the preparation of unsaturated esters |
US3579569A (en) * | 1967-10-06 | 1971-05-18 | Grace W R & Co | Preparation of vinyl acetate |
US3471532A (en) * | 1967-10-09 | 1969-10-07 | Union Oil Co | Oxidation of olefins |
US3650986A (en) * | 1967-12-23 | 1972-03-21 | Knapsack Ag | Carrier catalyst for the manufacture of unsaturated esters of carboxylic acids |
CH534005A (de) * | 1968-02-01 | 1973-02-28 | Bayer Ag | Verfahren zur Herstellung eines Palladium und Gold enthaltenden Katalysators |
DE1668114C3 (de) * | 1968-03-15 | 1974-12-19 | Bayer Ag, 5090 Leverkusen | Verfahren zur Herstellung von Vinylacetat |
US3557192A (en) * | 1968-03-18 | 1971-01-19 | Grace W R & Co | Process for preparing unsaturated esters |
GB1283737A (en) * | 1968-09-04 | 1972-08-02 | Nat Distillers Chem Corp | Method of catalyst preparation |
FR1596449A (ko) * | 1968-10-12 | 1970-06-15 | ||
US3622620A (en) * | 1969-10-27 | 1971-11-23 | Denki Kagaku Kogyo Kk | Method of making vinyl acetate |
US3939199A (en) * | 1971-01-06 | 1976-02-17 | Hoechst Aktiengesellschaft | Oxacylation of olefins in the gaseous phase |
US3758551A (en) * | 1971-11-10 | 1973-09-11 | Nat Distillers Chem Corp | Process for the preparation of acrylate and methacrylate esters |
US3970697A (en) * | 1974-07-01 | 1976-07-20 | National Distillers And Chemical Corporation | Oxidation of ethylene to acetic acid |
JPS5136413A (en) * | 1974-09-10 | 1976-03-27 | Kuraray Co | Fuhowaesuteru no seizoho |
US4133962A (en) * | 1975-02-14 | 1979-01-09 | Hoechst Aktiengesellschaft | Process for the preparation of carboxylic acid alkenyl esters |
GB1571910A (en) * | 1975-12-18 | 1980-07-23 | Nat Distillers Chem Corp | Vinyl acetate process and catalyst therefor |
DE2601154A1 (de) * | 1976-01-14 | 1977-07-21 | Bayer Ag | Neuer katalysator, seine herstellung und verwendung |
US4048096A (en) * | 1976-04-12 | 1977-09-13 | E. I. Du Pont De Nemours And Company | Surface impregnated catalyst |
DE2811211A1 (de) * | 1978-03-15 | 1979-09-27 | Hoechst Ag | Traeger-katalysator fuer die herstellung von ungesaettigten estern aus olefinen (c tief 3 -c tief 10 ), carbonsaeuren und sauerstoff in der gasphase |
FR2523149A1 (fr) * | 1982-03-15 | 1983-09-16 | Catalyse Soc Prod Francais | Nouveau catalyseur supporte palladium-or, sa preparation et son utilisation dans les reactions d'hydrogenation selective d'hydrocarbures diolefiniques et/ou acetyleniques |
DE3803900A1 (de) * | 1988-02-09 | 1989-08-17 | Hoechst Ag | Verfahren zur herstellung von vinylacetat |
US5194417A (en) * | 1991-12-05 | 1993-03-16 | Quantum Chemical Corporation | Pretreatment of palladium-gold catalysts useful in vinyl acetate synthesis |
-
1993
- 1993-05-25 US US08/067,445 patent/US5347046A/en not_active Expired - Lifetime
-
1994
- 1994-05-11 CN CN94192124A patent/CN1123527A/zh active Pending
- 1994-05-11 CA CA002161952A patent/CA2161952A1/en not_active Abandoned
- 1994-05-11 BR BR9406696A patent/BR9406696A/pt not_active Application Discontinuation
- 1994-05-11 WO PCT/US1994/005382 patent/WO1994027720A1/en not_active Application Discontinuation
- 1994-05-11 AU AU69129/94A patent/AU6912994A/en not_active Abandoned
- 1994-05-11 EP EP94917387A patent/EP0708684A1/en not_active Withdrawn
- 1994-05-11 JP JP50072295A patent/JP3698322B2/ja not_active Expired - Lifetime
- 1994-05-12 TW TW083104285A patent/TW254934B/zh active
-
1995
- 1995-11-24 KR KR1019950705255A patent/KR960702348A/ko not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
US5347046A (en) | 1994-09-13 |
CN1123527A (zh) | 1996-05-29 |
JPH08510685A (ja) | 1996-11-12 |
CA2161952A1 (en) | 1994-12-08 |
JP3698322B2 (ja) | 2005-09-21 |
WO1994027720A1 (en) | 1994-12-08 |
AU6912994A (en) | 1994-12-20 |
TW254934B (ko) | 1995-08-21 |
BR9406696A (pt) | 1996-03-19 |
EP0708684A1 (en) | 1996-05-01 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PA0105 | International application |
Patent event date: 19951124 Patent event code: PA01051R01D Comment text: International Patent Application |
|
PG1501 | Laying open of application | ||
PC1203 | Withdrawal of no request for examination | ||
WITN | Application deemed withdrawn, e.g. because no request for examination was filed or no examination fee was paid |