KR960022717A - 폴리에스테르 기판에 열가소성 탄성중합체 배합물을 점착시키는 방법 - Google Patents
폴리에스테르 기판에 열가소성 탄성중합체 배합물을 점착시키는 방법 Download PDFInfo
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- KR960022717A KR960022717A KR1019950055131A KR19950055131A KR960022717A KR 960022717 A KR960022717 A KR 960022717A KR 1019950055131 A KR1019950055131 A KR 1019950055131A KR 19950055131 A KR19950055131 A KR 19950055131A KR 960022717 A KR960022717 A KR 960022717A
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- 239000000758 substrate Substances 0.000 title claims abstract 18
- 239000000203 mixture Substances 0.000 title claims abstract 16
- 229920002725 thermoplastic elastomer Polymers 0.000 title claims abstract 15
- 229920000728 polyester Polymers 0.000 title claims abstract 10
- 238000000034 method Methods 0.000 claims abstract 13
- 229920000098 polyolefin Polymers 0.000 claims abstract 10
- 229920001971 elastomer Polymers 0.000 claims abstract 9
- 239000012948 isocyanate Substances 0.000 claims abstract 7
- 239000000806 elastomer Substances 0.000 claims abstract 5
- 239000000654 additive Substances 0.000 claims abstract 4
- 239000006185 dispersion Substances 0.000 claims abstract 4
- 239000003822 epoxy resin Substances 0.000 claims abstract 4
- 229920000647 polyepoxide Polymers 0.000 claims abstract 4
- 229920002397 thermoplastic olefin Polymers 0.000 claims abstract 4
- 239000000839 emulsion Substances 0.000 claims abstract 2
- 229920001577 copolymer Polymers 0.000 claims 5
- 239000000178 monomer Substances 0.000 claims 4
- 239000005060 rubber Substances 0.000 claims 4
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims 2
- 230000000996 additive effect Effects 0.000 claims 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims 2
- 150000001735 carboxylic acids Chemical class 0.000 claims 2
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical group O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 claims 2
- 229920001519 homopolymer Polymers 0.000 claims 2
- 150000005673 monoalkenes Chemical class 0.000 claims 2
- IMSODMZESSGVBE-UHFFFAOYSA-N 2-Oxazoline Chemical compound C1CN=CO1 IMSODMZESSGVBE-UHFFFAOYSA-N 0.000 claims 1
- 229920002943 EPDM rubber Polymers 0.000 claims 1
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 claims 1
- 239000004593 Epoxy Substances 0.000 claims 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims 1
- 229920000459 Nitrile rubber Polymers 0.000 claims 1
- 239000005062 Polybutadiene Substances 0.000 claims 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims 1
- 150000008064 anhydrides Chemical class 0.000 claims 1
- PVEOYINWKBTPIZ-UHFFFAOYSA-N but-3-enoic acid Chemical class OC(=O)CC=C PVEOYINWKBTPIZ-UHFFFAOYSA-N 0.000 claims 1
- 229920005549 butyl rubber Polymers 0.000 claims 1
- 239000007795 chemical reaction product Substances 0.000 claims 1
- 150000001991 dicarboxylic acids Chemical class 0.000 claims 1
- 125000003700 epoxy group Chemical group 0.000 claims 1
- 239000004744 fabric Substances 0.000 claims 1
- 239000000835 fiber Substances 0.000 claims 1
- 229920005555 halobutyl Polymers 0.000 claims 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 1
- 238000000465 moulding Methods 0.000 claims 1
- 229920003052 natural elastomer Polymers 0.000 claims 1
- 229920001194 natural rubber Polymers 0.000 claims 1
- 229920001084 poly(chloroprene) Polymers 0.000 claims 1
- 229920000768 polyamine Polymers 0.000 claims 1
- 229920002857 polybutadiene Polymers 0.000 claims 1
- 229920001195 polyisoprene Polymers 0.000 claims 1
- 239000000047 product Substances 0.000 claims 1
- 229920003048 styrene butadiene rubber Polymers 0.000 claims 1
- 229920003051 synthetic elastomer Polymers 0.000 claims 1
- 239000005061 synthetic rubber Substances 0.000 claims 1
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
- C08J5/06—Reinforcing macromolecular compounds with loose or coherent fibrous material using pretreated fibrous materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Ethene-propene or ethene-propene-diene copolymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2321/00—Characterised by the use of unspecified rubbers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/04—Thermoplastic elastomer
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31786—Of polyester [e.g., alkyd, etc.]
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- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Laminated Bodies (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Artificial Filaments (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
Abstract
본 발명은 - 수성 분산액내 블럭된 디-이소시아네이트로 폴리에스테르 기판을 처리시키는 단계, 또는 순차적으로 또는 동시에 수성 분산액/유액내 에폭시 수지 및 블럭된 디-이소시아네이트로 상기 기판을 처리시키는 단계, - 상기 처리시킨 기판에 열가소성 탄성중합체 배합물을 도포시키고 열 및 압력을 가하여 상기 기판의 표면에 상기 열가소성 탄성중합체 배합물을 점착시키는 단계로 구성되고, 폴리에스테르 기판에 (a) 하나 이상의 열가소성 폴리올레핀, (b) 하나 이상의 경화되지 않은, 부분적으로 또는 전체적으로 경화된 탄성중합체 또는 이들의 배합물 (c) 관능화된 폴리올레핀 및 (d) 임의의 첨가제로 구성되는 열가소성 탄성중합체 배합물을 점착시키는 방법에 관한다. 본 발명은 또 상기 방법으로 얻을 수 있는 조형제품에 관한다.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (14)
- - 수성 분산액내 블럭된 디-이소시아네이트로 폴리에스테르 기판을 처리시키는 단계, 또는 순차적으로 또는 동시에 수성 분산액/유액내 에폭시 수지 및 블럭된 디-이소시아네이트로 상기 기판을 처리시키는 단계, - 상기 처리시킨 기판에 열가소성 탄성중합체 배합물을 도포시키고 열 및 압력을 가하여 상기 기판의 표면에 상기 열가소성 탄성중합체 배합물을 점착시키는 단계로 구성되며, 폴리에스테르 기판에 (a) 하나 이상의 열가소성 폴리올레핀, (b) 하나 이상의 경화되지 않은, 부분적으로 또는 전체적으로 경화된 탄성중합체 또는 이들의 배합물 (c) 관능화된 폴리올레핀 및 (d) 임의의 첨가제로 구성되는 열가소성 탄성중합체 배합물을 점착시키는 방법.
- 제1항에 있어서, (a), (b) 및 임의로 (d)의 배합물을 도포하기 전에 폴리에스테르 기판에 관능화된 폴리올레핀 (c)를 도포하는 방법.
- 제1항 또는 제2항에 있어서, 열가소성 탄성중합체 배합물이 폴리올레핀(a)+탄성 중합체(b)+관능화된 폴리올레핀(c)+첨가제 (d)의 총량을 기준으로하여 (a)+(b)+(c)의 양이 35중량% 이상일 것을 조건으로 -약 10~87중량%의 하나 이상의 열가소성 폴리올레핀(a), - 약 10~70중량%의 하나 이상의 탄성중합체(b), - 약 3-80중량%의 관능화된 폴리올레핀(c), 및 - 약 65중량% 이하의 첨가제(d)로 구성되는 방법.
- 제1항 내지 제3항 중 어느 한 항에 있어서, 열가소성 탄성중합체 배합물이 - C2-7모노올레핀 단량체의 단독중합체 또는 공중합체 또는 이들의 (메트) 아크릴레이트 및/또는 비닐아세테이트와의 공중합체에서 선택되는 하나 이상의 열가소성 폴리올레핀, 및 -EPDM 고무, EPM 고무, 부틸고무, 할로겐화된 부틸고무, 이소모노올레핀 및 파라- 알킬스티렌의 공중합체 또는 이의 할로겐화된 유도체, 천연 또는 합성고무, 폴리이소프렌 폴리부타디엔 고무, 스티렌-부티디엔-공중합체 고무, 니트릴 고무, 폴리클로로프렌 고무 및 이들의 혼합물로 이루어지는 그룹에서 선택되는 하나 이상의 탄성중합체로 구성되는 방법.
- 제1항 내지 제4항 중 어느 한 항에 있어서, 관능화된 폴리올레핀이 C3~C20을 함유하는 불포화된 카복실산, C4~C10을 함유하는 디카복실산 또는 이들의 유도체 또는 존재할 경우 이들의 무수물, C6이상을 함유하는 불포화된 카복실산의 에폭시그룹-함유-에스테르, C5이상을 함유하는 불포화된 카복실산의 하이드록시 그룹 함유-에스테르, 옥사졸린, 폴리아민으로 추가로 관능화된 불포화된 상기의 카복실산 또는 불포화된 디카복실산 단량체, 및 이들의 혼합물에서 선택된 단량체가 그래프트된 C2~C7모노올레핀 단량체의 단독중합체 또는 공중합체 또는 이들의 (메트) 아크릴레이트 및/또는 비닐 아세테이트와의 공중합체에서 선택되는 방법.
- 제1항 내지 제5항 중 어느 한 항에 있어서, 그래프트 단량체의 함량이 관능화된 폴리올레핀(c)의 양을 기준으로하여 약 0.3~10중량%인 방법.
- 제1항 내지 제6항 중 어느 한 항에 있어서, 열가소성 탄성중합체 배합물내 관능화된 폴리올레핀(c)의 양이 열가소성 탄성중합체 배합물의 양을 기준으로하여 약 5~75중량%인 방법.
- 제1항에 있어서, 기판이 임의로 에폭시-활성화된 폴리에스테르에서 선택되는 방법.
- 제1항 내지 제8항 중 어느 한 항에 있어서, 블럭된 디-이소시아네이트가 카프로락탐 블럭된 메틸렌-비스-(4-페닐이소시아네이트 또는 4,4'-메틸렌-비스-(페닐카바닐레이트)에서 선택되는 방법.
- 제9항에 있어서, 기판상의 블럭된 디-이소시아네이트 또는 블럭된 디-이소시아네이트 및 에폭시 수지의 양이 기판표면 1m2당 약 5~500g인 방법.
- 제1항 내지 제10항 중 어느 한 항에 있어서, 에폭시 수지가 글리세롤-폴리-글리시딜에테르 또는 비스 페놀 A 및 에피클로로하이드린의 반응 생성물에서 선택되는 방법.
- 제1항 내지 제11항 중 어느 한 항에 있어서, 열가소성 탄성중합체 배합물을 약 170~280℃의 온도 및 약 001MPa(1bar)~20MPa(200bar)의 압력에서 기판의 서리된 표면에 점착시키는 방법.
- 기판, 및 상기 기판의 표면 또는 표면의 일부에 점착하는 열가소성 탄성중합체로 구성되고, 제1항 내지 제12항 중 어느 한 항의 방법으로 얻을 수 있는 조형제품.
- 제13항에 있어서, 기판이 폴리에스테르 섬유, 폴리에스테르 코드 및 폴리에스테르 직물에서 선택되는 조형제품.※ 참고사항 :최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP94120649.2 | 1994-12-24 | ||
| EP19940120649 EP0718347A1 (en) | 1994-12-24 | 1994-12-24 | Method to adhere thermoplastic elastomer blends to polyester substrates |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR960022717A true KR960022717A (ko) | 1996-07-18 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019950055131A Withdrawn KR960022717A (ko) | 1994-12-24 | 1995-12-23 | 폴리에스테르 기판에 열가소성 탄성중합체 배합물을 점착시키는 방법 |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US5609962A (ko) |
| EP (1) | EP0718347A1 (ko) |
| JP (1) | JPH08269404A (ko) |
| KR (1) | KR960022717A (ko) |
Families Citing this family (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5952065A (en) | 1994-08-31 | 1999-09-14 | Nike, Inc. | Cushioning device with improved flexible barrier membrane |
| TW345540B (en) | 1994-08-31 | 1998-11-21 | Nike Inc | Laminated resilient flexible barrier membranes (1) |
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-
1994
- 1994-12-24 EP EP19940120649 patent/EP0718347A1/en not_active Withdrawn
-
1995
- 1995-12-18 US US08/573,709 patent/US5609962A/en not_active Expired - Lifetime
- 1995-12-23 KR KR1019950055131A patent/KR960022717A/ko not_active Withdrawn
- 1995-12-25 JP JP35105095A patent/JPH08269404A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| JPH08269404A (ja) | 1996-10-15 |
| EP0718347A1 (en) | 1996-06-26 |
| US5609962A (en) | 1997-03-11 |
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Patent event code: PA01091R01D Comment text: Patent Application Patent event date: 19951223 |
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| PC1203 | Withdrawal of no request for examination | ||
| WITN | Application deemed withdrawn, e.g. because no request for examination was filed or no examination fee was paid |