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KR960000845A - Novel fluorine-substituted absic acid derivatives and preparation method thereof - Google Patents

Novel fluorine-substituted absic acid derivatives and preparation method thereof Download PDF

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Publication number
KR960000845A
KR960000845A KR1019940015476A KR19940015476A KR960000845A KR 960000845 A KR960000845 A KR 960000845A KR 1019940015476 A KR1019940015476 A KR 1019940015476A KR 19940015476 A KR19940015476 A KR 19940015476A KR 960000845 A KR960000845 A KR 960000845A
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South Korea
Prior art keywords
substituted
absic acid
fluorine
acid derivatives
absic
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KR1019940015476A
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Korean (ko)
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KR0123414B1 (en
Inventor
김범태
민용기
박노균
김태준
조광연
Original Assignee
강박광
재단법인 한국화학연구소
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Priority to KR1019940015476A priority Critical patent/KR0123414B1/en
Publication of KR960000845A publication Critical patent/KR960000845A/en
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Publication of KR0123414B1 publication Critical patent/KR0123414B1/en

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C59/00—Compounds having carboxyl groups bound to acyclic carbon atoms and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
    • C07C59/40—Unsaturated compounds
    • C07C59/76—Unsaturated compounds containing keto groups
    • C07C59/88—Unsaturated compounds containing keto groups containing halogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
    • C07C57/52—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms containing halogen
    • C07C57/56—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms containing halogen containing rings other than six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C59/00—Compounds having carboxyl groups bound to acyclic carbon atoms and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
    • C07C59/40—Unsaturated compounds
    • C07C59/42—Unsaturated compounds containing hydroxy or O-metal groups
    • C07C59/56—Unsaturated compounds containing hydroxy or O-metal groups containing halogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/62—Halogen-containing esters
    • C07C69/65—Halogen-containing esters of unsaturated acids

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

본 발명은 신규한 불소치환 아브시스산 유도체에 관한 것이다. 좀 더 구체적으로, 본 발명은 하기 일반식(Ⅰ) 및 (Ⅱ)로 표시되는 신규한 불소치환 아브시스산 유도체와 그의 제조방법 및 식물생장조절제로서의 용도에 관한 것이다.The present invention relates to a novel fluorine-substituted absic acid derivative. More specifically, the present invention relates to novel fluorine-substituted absic acid derivatives represented by the following general formulas (I) and (II), methods for their preparation and use as plant growth regulators.

상기식에서, X는 H2또는 O이고; Y는 H 또는 OH이며; 및, R은 H 또는 탄소수 1 내지 2개의 알킬기이다.Wherein X is H 2 or O; Y is H or OH; And R is H or an alkyl group having 1 to 2 carbon atoms.

본 발명에 의해 제조된 불소치환된 아브시스산 유도체는 천연의 아브시스산 보다 안정하면서도 생리활성면에서도 강력한 아브시스산 활성을 나타내어, 그 자체로서 제초활성을 갖는 농약 및 왜화제 등의 식물생장조절제의 활성성분으로 이용될 수 있으며, 유효성분을 합성하는 중간체로서도 유용할 것으로 밝혀졌다.The fluorine-substituted absic acid derivatives prepared by the present invention are more stable than natural absic acid and exhibit strong abscitic activity in terms of physiological activity, and thus have plant growth regulators such as pesticides and dwarfs having herbicidal activity. It can be used as an active ingredient of, has been found to be useful as an intermediate for synthesizing the active ingredient.

Description

신규한 불소치환 아브시스산 유도체 및 그의 제조방법Novel fluorine-substituted absic acid derivatives and preparation method thereof

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음As this is a public information case, the full text was not included.

Claims (4)

하기 일반식(Ⅰ)로 표시되는 불소치환된 아브시스산 유도체.상기식에서, X는 H2또는 O이고; Y는 H 또는 OH이며; 및, R은 H 또는 탄소수 1 내지 2개의 알킬기이다.A fluorine-substituted absic acid derivative represented by the following general formula (I). Wherein X is H 2 or O; Y is H or OH; And R is H or an alkyl group having 1 to 2 carbon atoms. 하기 구조식으로 표시되는 광학활성을 지닌 불소치환 아브시스산 유도체.A fluorine-substituted absic acid derivative having an optical activity represented by the following structural formula. 하기 구조식으로 표시되는 광학활성을 지닌 불소치환 아브시스산 유도체.A fluorine-substituted absic acid derivative having an optical activity represented by the following structural formula. 하기 일반식(Ⅰ)로 표시되는 불소치환된 아브시스산 유도체를 유효성분으로 함유하는 식물생장조절제.상기식에서, X, Y 및 R은 제1항에 기재한 바와 같다.A plant growth regulator containing a fluorine-substituted absic acid derivative represented by the following general formula (I) as an active ingredient. Wherein X, Y and R are as described in claim 1. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019940015476A 1994-06-30 1994-06-30 Novel abscisic acid derivatives with fluorine KR0123414B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
KR1019940015476A KR0123414B1 (en) 1994-06-30 1994-06-30 Novel abscisic acid derivatives with fluorine

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1019940015476A KR0123414B1 (en) 1994-06-30 1994-06-30 Novel abscisic acid derivatives with fluorine

Publications (2)

Publication Number Publication Date
KR960000845A true KR960000845A (en) 1996-01-25
KR0123414B1 KR0123414B1 (en) 1997-11-12

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KR1019940015476A KR0123414B1 (en) 1994-06-30 1994-06-30 Novel abscisic acid derivatives with fluorine

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KR0123414B1 (en) 1997-11-12

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