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KR950703049A - DETERGENT COMPOSITIONS - Google Patents

DETERGENT COMPOSITIONS Download PDF

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Publication number
KR950703049A
KR950703049A KR1019950700420A KR19950700420A KR950703049A KR 950703049 A KR950703049 A KR 950703049A KR 1019950700420 A KR1019950700420 A KR 1019950700420A KR 19950700420 A KR19950700420 A KR 19950700420A KR 950703049 A KR950703049 A KR 950703049A
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KR
South Korea
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weight
detergent
detergent composition
salt
alkyl
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Withdrawn
Application number
KR1019950700420A
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Korean (ko)
Inventor
마르셀 바이유리 제라르
알란 제이. 모스 마이클
알렉산더 소리 그래함
셈 에르솔마츠 세미
Original Assignee
자코버스 코넬리스 라써
더 프록터 앤드 갬블 캄파니(The Procter & Gamble Company)
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Application filed by 자코버스 코넬리스 라써, 더 프록터 앤드 갬블 캄파니(The Procter & Gamble Company) filed Critical 자코버스 코넬리스 라써
Publication of KR950703049A publication Critical patent/KR950703049A/en
Withdrawn legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/08—Silicates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/33—Amino carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246—Silicates, e.g. diatomaceous earth
    • C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
    • C11D3/1273—Crystalline layered silicates of type NaMeSixO2x+1YH2O

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

Granular detergent compositions comprising ethylenediamine-N,N'-disuccinic acid or salts thereof and a crystalline layered sodium silicate of formula LMSixO2xH.yH2O wherein L is an alkali metal, and M is sodium or hydrogen, x is a number from 1.9 to 4 and y is a number from 0 to 20 are provided. The compositions also preferably comprise surfactant and additional non-phosphate detergent builder compounds.

Description

세제 조성물(DETERGENT COMPOSITIONS)DETERGENT COMPOSITIONS

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (15)

(a) 일반식 LMSix2×H. yH2O(여기서, L은 알칼리 금속이고 M은 나트륨 또는 수소이며, X는 1.9 내지 4이고 y는 0 내지 20이다)의 결정성 적층된 규산염 빌더 물질 1 내지 80중량%; (d) 에틸렌디아민-N,N′-디석신산, 또는 알칼리 금속, 알칼리 토금속, 암모늄염 또는 치환된 암모늄염, 또는 이들의 혼합물 0.05 내지 10중량%; (c) 음이온성 계면활성제, 비이온성 계면활성제, 쯔비터이온성 계면활성제, 양쪽성 계면활성제, 양이온성 계면활성제 및 이들의 혼합물중에서 선택된 세제 계면활성제 0 내지 30중량%; 및 (d) 추가적 비인산염 세제 빌더 화합물 0 내지 50중량%를 포함하는 세제 조성물.(a) Formula LMSix 2 × H. 1-80% by weight of a crystalline laminated silicate builder material of yH 2 O, wherein L is an alkali metal, M is sodium or hydrogen, X is 1.9 to 4 and y is 0 to 20; (d) 0.05-10% by weight of ethylenediamine-N, N'-disuccinic acid, or an alkali metal, alkaline earth metal, ammonium salt or substituted ammonium salt, or mixtures thereof; (c) 0-30% by weight detergent detergent selected from anionic surfactants, nonionic surfactants, zwitterionic surfactants, amphoteric surfactants, cationic surfactants, and mixtures thereof; And (d) 0-50% by weight of additional non-phosphate detergent builder compound. 제1항에 있어서, 에틸렌디아민-N,N′-디석신산 성분이 이의 [S,S] 이성체 형태인 세제 조성물.The detergent composition of claim 1, wherein the ethylenediamine-N, N′-disuccinic acid component is in its [S, S] isomeric form. 제1항 또는 제2항에 있어서, 에틸렌디아민-N,N′-디석신산 성분이 마그네슘 착물 형태인 세제 조성물.3. The detergent composition of claim 1, wherein the ethylenediamine-N, N′-disuccinic acid component is in the form of a magnesium complex. 제1항 내지 제3항중 어느 한 항에 있어서, 결정성 적층된 규산염 물질이 S-Na2Si2O5(Na SKS-6)인 세제 조성물.The detergent composition according to claim 1, wherein the crystalline laminated silicate material is S-Na 2 Si 2 O 5 (Na SKS-6). 제1항 내지 제4항 중이 어느 한 항에 있어서, 음이온성 계면활성제가 C12-C20알킬 설페이트염과 분자당 평균 1 내지 7개의 에톡시 그룹을 함유하는 수용성 C11-C19알킬 에톡시설페이트염과의 혼합물(여기서, 알킬설페이트염 대 알킬 에톡시설페이트염의 중량비는 2 : 1 내지 19 : 1의 범위이다)을 포함하는 세제 조성물.The water-soluble C 11 -C 19 alkyl ethoxy according to any one of claims 1 to 4, wherein the anionic surfactant contains a C 12 -C 20 alkyl sulfate salt and an average of 1 to 7 ethoxy groups per molecule. A detergent composition comprising a mixture with a sulfate salt, wherein the weight ratio of alkylsulfate salt to alkyl ethoxysulfate salt is in the range from 2: 1 to 19: 1. 제5항에 있어서, 알킬 설페이트염이 C14-C15알킬 설페이트염이고, 알킬 에톡시설페이트염이 분자당 평균 3개의 에톡시 그룹을 함유하는 C12-C15알킬 에톡시설페이트염이며 이의 중량비가 3.5 : 1 내지 10 : 1 범위인 세제 조성물.6. The alkyl sulfate salt of claim 5 wherein the alkyl sulfate salt is a C 14 -C 15 alkyl sulfate salt, the alkyl ethoxysulfate salt is a C 12 -C 15 alkyl ethoxysulfate salt containing an average of three ethoxy groups per molecule and the weight ratio thereof Detergent composition having a range of 3.5: 1 to 10: 1. 제1항 내지 제6항 중의 어느 한 항에 있어서, 비이온성 계면활성제가 하기 일반식의 폴리하이드록시 지방산 아미드인 세제 조성물.The detergent composition according to any one of claims 1 to 6, wherein the nonionic surfactant is a polyhydroxy fatty acid amide of the following general formula. 상기 식에서, R1은 H, C1-C4하이드로카빌, 2-하이드록시에틸, 2-하이드록시 프로필 또는 이들의 혼합물이고, R2는 C5-C31하이드로카빌이며, Z는 선형 탄화수소 쇄에 3개 이상의 하이드록시 그룹이 직접 결합되어 있는 폴리하이드록시하이드로카빌 또는 이의 알콕실화 유도체이다.Wherein R 1 is H, C 1 -C 4 hydrocarbyl, 2-hydroxyethyl, 2-hydroxy propyl or mixtures thereof, R 2 is C 5 -C 31 hydrocarbyl, Z is a linear hydrocarbon chain Polyhydroxyhydrocarbyl or alkoxylated derivatives thereof, to which at least three hydroxy groups are directly bonded. 제1항 내지 제7항 중 어느 한 항에 있어서, 비이온성 계면활성제가 알콜 1몰당 평균 3 내지 8몰의 에틸렌옥사이드를 함유하는 C9-C151급 알콜 에톡실레이트인 조성물.8. The composition of claim 1, wherein the nonionic surfactant is a C 9 -C 15 primary alcohol ethoxylate containing an average of 3 to 8 moles of ethylene oxide per mole of alcohol. 9 . 제8항에 있어서, 1급 알콜 에톡실레이트가 알콜 1몰당 평균 3 내지 5몰의 에틸렌 옥사이드를 함유하는 C12-C151급 알콜인 조성물.The composition of claim 8 wherein the primary alcohol ethoxylate is a C 12 -C 15 primary alcohol containing on average 3 to 5 moles of ethylene oxide per mole of alcohol. 제1항 내지 제9항 중 어느 한 항에 있어서 추가적 비인산염 빌더 화합물이 나트륨 알루미노실리케이트 제올라이트, 알칼리 금속 탄산염 및 중탄산염, 카복실레이트 및 폴리카복실레이트, 및 말레산 무수물/아크릴산 공중합체 중에서 선택되는 세제 조성물.The detergent of claim 1, wherein the additional nonphosphate builder compound is selected from sodium aluminosilicate zeolites, alkali metal carbonates and bicarbonates, carboxylates and polycarboxylates, and maleic anhydride / acrylic acid copolymers. Composition. 제1항 내지 제10항 중 어느 한항에 있어서, 결정성 적층된 규산염 빌더 물질 7 내지 20중량% 및 추가적 비인산염 빌더 화합물 10 내지 40중량%를 포함하는 세제 조성물.The detergent composition of claim 1, comprising from 7 to 20% by weight of the crystalline laminated silicate builder material and from 10 to 40% by weight of the additional non-phosphate builder compound. 제1항 내지 제11항 중 어느 한 항에 있어서, 무기 퍼하이드레이트 표백제 3 내지 40중량% 및 고체 퍼옥시산 표백제 전구체 1 내지 20중량%가 도입된 세제 조성물.The detergent composition according to any one of claims 1 to 11, wherein 3 to 40% by weight of inorganic perhydrate bleach and 1 to 20% by weight of solid peroxy acid bleach precursor are introduced. 제12항에 있어서, 무기 퍼하이드레이트염이 조성물의 5 내지 30중량%의 존재하는 과탄산나트륨이고, 고체 퍼옥시산 표백제 전구체가 조성물의 1 내지 10중량%도 존재하는 TAED인 세제 조성물.13. The detergent composition of claim 12, wherein the inorganic perhydrate salt is 5-30% by weight of sodium percarbonate present and the solid peroxy acid bleach precursor is TAED, which also contains 1-10% by weight of the composition. 제1항 내지 제13항 중 어느 한 항에 있어서, 유기 퍼옥시산 1 내지 10중량% 도입된 세제 조성물.The detergent composition according to any one of claims 1 to 13, wherein 1 to 10% by weight of organic peroxy acid is introduced. 제1항 내지 제14항 중 어느 한 항에 있어서, 세제 효소, 오염 현탁제 및 재침착 방지제, 광학적 증백제, 비누거품 억제제, 향료 및 이들의 혼합물중에서 선택된 추가적 세제 성분을 포함하는 세제 조성물.The detergent composition according to claim 1 comprising an additional detergent component selected from detergent enzymes, contaminant suspending and anti-deposition agents, optical brighteners, suds suppressors, flavorings and mixtures thereof. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019950700420A 1992-08-01 1993-07-21 DETERGENT COMPOSITIONS Withdrawn KR950703049A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GB9216409.4 1992-08-01
GB929216409A GB9216409D0 (en) 1992-08-01 1992-08-01 Detergent compositions
PCT/US1993/006876 WO1994003572A1 (en) 1992-08-01 1993-07-21 Detergent compositions

Publications (1)

Publication Number Publication Date
KR950703049A true KR950703049A (en) 1995-08-23

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KR1019950700420A Withdrawn KR950703049A (en) 1992-08-01 1993-07-21 DETERGENT COMPOSITIONS

Country Status (16)

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EP (1) EP0652933B1 (en)
JP (1) JP3474188B2 (en)
KR (1) KR950703049A (en)
CN (1) CN1035067C (en)
AT (1) ATE184642T1 (en)
AU (1) AU671294B2 (en)
CA (1) CA2141610C (en)
DE (1) DE69326471T2 (en)
DK (1) DK0652933T3 (en)
ES (1) ES2135484T3 (en)
GB (1) GB9216409D0 (en)
GR (1) GR3031211T3 (en)
MA (1) MA22949A1 (en)
MX (1) MX9304664A (en)
TR (1) TR28606A (en)
WO (1) WO1994003572A1 (en)

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US5550285A (en) * 1994-07-11 1996-08-27 Albemarle Corp Method for producing calcium salts of [S,S]-ethylenediamine-N,N'-disuccinic acid
WO1996006908A1 (en) * 1994-08-26 1996-03-07 The Procter & Gamble Company Ethylenediamine disuccinate as detergent builder
IL116638A0 (en) * 1995-01-12 1996-05-14 Procter & Gamble Method and compositions for laundering fabrics
GB9507659D0 (en) 1995-04-13 1995-05-31 Ass Octel Alkylation process
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WO1997008288A1 (en) * 1995-08-30 1997-03-06 The Dow Chemical Company Succinic acid derivative degradable chelants, uses and compositions thereof
US5733858A (en) * 1995-08-30 1998-03-31 The Dow Chemical Company Succinic acid derivative degradable chelants, uses and compositions thererof
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AUPN538295A0 (en) * 1995-09-13 1995-10-05 Australian National University, The Magnesiosilicate cation exchange compounds
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PL2746376T3 (en) * 2012-12-21 2018-04-30 The Procter & Gamble Company Dishwashing composition
US20150252310A1 (en) 2014-03-07 2015-09-10 Ecolab Usa Inc. Alkyl amides for enhanced food soil removal and asphalt dissolution
CN104560461A (en) * 2015-02-24 2015-04-29 烟台顺隆化工科技有限公司 Washing agent for mercury-polluted building wastes
KR101977161B1 (en) * 2019-03-18 2019-05-10 에이앤에이치 인터내셔널 코스메틱스 Cosmetic composition for improving skin texture and moisturizing skin contating natural vegetable wax as effective element, and manufacturing method thereof

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Also Published As

Publication number Publication date
DK0652933T3 (en) 1999-12-20
GR3031211T3 (en) 1999-12-31
AU4779693A (en) 1994-03-03
GB9216409D0 (en) 1992-09-16
ATE184642T1 (en) 1999-10-15
EP0652933A4 (en) 1996-09-18
TR28606A (en) 1996-11-04
MA22949A1 (en) 1994-04-01
EP0652933B1 (en) 1999-09-15
CA2141610C (en) 1999-04-13
AU671294B2 (en) 1996-08-22
ES2135484T3 (en) 1999-11-01
WO1994003572A1 (en) 1994-02-17
MX9304664A (en) 1994-03-31
JPH07509526A (en) 1995-10-19
DE69326471T2 (en) 2000-05-04
CN1084556A (en) 1994-03-30
CN1035067C (en) 1997-06-04
JP3474188B2 (en) 2003-12-08
EP0652933A1 (en) 1995-05-17
CA2141610A1 (en) 1994-02-17
DE69326471D1 (en) 1999-10-21

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Patent event date: 19950202

Patent event code: PA01051R01D

Comment text: International Patent Application

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