[go: up one dir, main page]

KR950700397A - Granular detergent compositions - Google Patents

Granular detergent compositions

Info

Publication number
KR950700397A
KR950700397A KR1019940703165A KR19940703165A KR950700397A KR 950700397 A KR950700397 A KR 950700397A KR 1019940703165 A KR1019940703165 A KR 1019940703165A KR 19940703165 A KR19940703165 A KR 19940703165A KR 950700397 A KR950700397 A KR 950700397A
Authority
KR
South Korea
Prior art keywords
salt
weight
granular detergent
detergent composition
alkyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
KR1019940703165A
Other languages
Korean (ko)
Other versions
KR100253863B1 (en
Inventor
수즌 맥비드 피오나
포우웰 수잰
Original Assignee
린다 디. 로러
더 프록터 앤드 갬블 캄파니
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 린다 디. 로러, 더 프록터 앤드 갬블 캄파니 filed Critical 린다 디. 로러
Publication of KR950700397A publication Critical patent/KR950700397A/en
Application granted granted Critical
Publication of KR100253863B1 publication Critical patent/KR100253863B1/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38Cationic compounds
    • C11D1/65Mixtures of anionic with cationic compounds
    • C11D1/652Mixtures of anionic compounds with carboxylic amides or alkylol amides
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/37Mixtures of compounds all of which are anionic
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/06Powder; Flakes; Free-flowing mixtures; Sheets
    • C11D17/065High-density particulate detergent compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/28Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29Sulfates of polyoxyalkylene ethers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38Cationic compounds
    • C11D1/52Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
    • C11D1/525Carboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain two or more hydroxy groups per alkyl group, e.g. R3 being a reducing sugar rest

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

하나 이상의 계면활성제 함유 미립자 성분이 증강제 시스템과 함께, 1mol당 평균 1 내지 7개의 에톡시 그룹을 함유하는 수용성 C11-C18알킬 에톡시설페이트 염과의 균질 혼합물로 존재하는 하나 이상의 1급 음이온성 또는 비이온성 계면활성제로 필수적으로 이루어진 계면활성제 시스템을 포함하는 다수의 미립자 성분을 포함하고 밀도가 550g/l보다 큰 과립형 세제 조성물이 제공된다. 알킬 에톡시설페이트염에 대한 1급 음이온성 또는 비이온성 계면활성제 또는 이들의 혼합물 중량비는 19:1 내지 2:1이며, 단 알킬 에톡시 설페이트 염의 양은 성분의 0.25 내지 10중량%이다. 이러한 계면활성제 시스템을 함유하는 개개의 미립자 성분 및 조성물에 있어서 개선된 용해율 특성이 관찰된다.One or more primary anionic, wherein the one or more surfactant-containing particulate components are present in a homogeneous mixture with the water-soluble C 11 -C 18 alkyl ethoxysulfate salt containing an average of 1 to 7 ethoxy groups per mole, together with the enhancer system. Or a granular detergent composition comprising a plurality of particulate components comprising a surfactant system consisting essentially of a nonionic surfactant and having a density greater than 550 g / l. The weight ratio of primary anionic or nonionic surfactants or mixtures thereof to alkyl ethoxysulfate salts is from 19: 1 to 2: 1, provided that the amount of alkyl ethoxysulfate salt is from 0.25 to 10% by weight of the components. Improved dissolution rate characteristics are observed for the individual particulate components and compositions containing such surfactant systems.

Description

과립형 세제 조성물(Granular detergent compositions)Granular detergent compositions

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (22)

하나 이상의 미립자 성분이 C14-C20알킬 설페이트 염(1), 지방족 C12-C20알칸 설포네이트 염(2), C12-C10알킬 메틸 에스테르 설포네이트염(3), 일반식 R6---Z 의 폴리하이드록시 지방산 아미드(4)(여기서, R5는 H, C1-C4하이드로카빌, 2-하이드록시에틸, 2-하이드록시프로필 또는 이들의 혼합물이고, R6은 C11-C31하이드로카빌이며, Z는 3개 이상의 하이드록시 그룹이 직접 결합된 선형 탄화수소 쇄를 갖는 폴리하이드록시하이드로 카빌 또는 이의 알킬옥시화 유도체이다) 및 이들의 임의의 혼합물 중에서 선택된 1급 음이온성 또는 비이온성 계면활성제(i)과 1mol당 평균 1 내지 7개의 에톡시 그룹을 함유하는 수용성 C11-C18알킬에톡시설페이트 염(ⅱ)로 필수적으로 이루어진 계면활성제 시스템 성분(a)(이때, 1급 음이온성 또는 비이온성 계면활성제 또는 이들의 혼합물, 및 수용성 C11-C18알킬 에톡시설페이트 염은 균질 혼합물로서 존재하며, 알킬 에톡시설페이트 염에 대한 1급 음이온성 또는 비이온성 계면활성제 또는 이들의 혼합물의 중량비는 2:1 내지 19:1이고, 단 알킬 에톡시설페이트염의 양은 성분의 0.25 내지 10중량%이다) 5 내지 60중량%와 유기 및/또는 무기 증강제 염 또는 이러한 염들의 혼합물 성분(b) 15 내지 95중량%를 포함하는, 다수의 독립된 미립자 성분으로 이루어지며 밀도가 550g/l 이상인 과립형 세제 조성물.The at least one particulate component is a C 14 -C 20 alkyl sulfate salt (1), aliphatic C 12 -C 20 alkane sulfonate salt (2), C 12 -C 10 alkyl methyl ester sulfonate salt (3), general formula R 6 - - Polyhydroxy fatty acid amide (4) of -Z, wherein R 5 is H, C 1 -C 4 hydrocarbyl, 2-hydroxyethyl, 2-hydroxypropyl or mixtures thereof, and R 6 is C 11- C 31 hydrocarbyl, Z is a polyhydroxyhydrocarbyl or alkyloxylated derivatives thereof having a linear hydrocarbon chain directly bonded to three or more hydroxy groups) and any mixtures thereof Surfactant system component (a) consisting essentially of a soluble surfactant (i) and a water-soluble C 11 -C 18 alkylethoxysulfate salt (ii) containing an average of 1 to 7 ethoxy groups per mole, wherein anionic or nonionic surfactants, or mixtures thereof, and a water-soluble C 11 -C 18 alkyl ethoxy sulfate salt is present as a homogeneous mixture, a primary for the alkyl ethoxy sulfate salt anionic or nonionic The weight ratio of the agent or mixture thereof is from 2: 1 to 19: 1, provided that the amount of alkyl ethoxysulfate salt is from 0.25 to 10% by weight of the component) and from 5 to 60% by weight of organic and / or inorganic enhancer salts or such salts. A granular detergent composition comprising a plurality of independent particulate components, comprising from 15 to 95% by weight of mixture component (b) and having a density of at least 550 g / l. 제 1 항에 있어서, 알킬 에톡시설페이트 염이 성분의 0.5내지 5중량%의 양으로 존재하는 과립형 세제 조성물.The granular detergent composition of claim 1, wherein the alkyl ethoxysulfate salt is present in an amount of from 0.5 to 5% by weight of the component. 제 1 항에 또는 제 2 항에 있어서, 계면활성제(1)이 C16-C20알킬 설페이트 염을 포함하는 과립형 세제 조성물.The granular detergent composition according to claim 1 or 2, wherein the surfactant (1) comprises a C 16 -C 20 alkyl sulfate salt. 제 1 항 또는 제 2 항에 있어서, 계면활성제(1)이 실질적으로 측쇄화된 C14-C15알킬 설페이트 염을 포함하는 과립형 세제 조성물.3. Granular detergent composition according to claim 1 or 2, wherein the surfactant (1) comprises a substantially branched C 14 -C 15 alkyl sulfate salt. 제 1 항 내지 제 4 항 중의 어느 한 항에 있어서, 계면활성제(4)가 하기 일반식의 폴리하이드록시 지방산 아미드인 과립형 세제 조성물.The granular detergent composition according to any one of claims 1 to 4, wherein the surfactant (4) is a polyhydroxy fatty acid amide of the following general formula. R6---CH2(CHOH)4CH2OHR 6- - -CH 2 (CHOH) 4 CH 2 OH 상기식에서, R6은 C11-C19직쇄 알킬 또는 알케닐 그룹이고, R5는 메틸이다.Wherein R 6 is a C 11 -C 19 straight alkyl or alkenyl group and R 5 is methyl. 하나 이상의 미립자 성분이 C14-C20알킬 설페이트 염(i)과 1mol당 평균 1 내지 7개의 에톡시 그룹을 함유하는 수용성 C11-C18알킬 에톡시설페이트 염(ⅱ)로 필수적으로 이루어진 계면활성제 시스템 성분(a)(이때, 알킬 에톡시설페이트 염에 대한 알킬 설페이트 염의 중량비는 2:1 내지 19:1이고, 단 알킬 에톡실레이트 염의 양은 성분의 0.25 내지 10중량%이다) 5 내지 60중량%와 유기 및/또는 무기 증강제 염또는 이러한 염들의 혼합물 성분(b) 15 내지 95중량%를 포함하는, 다수의 독립적인 미립자 성분으로 이루어지며 음이온성 계면활성제의 총량이 조성물의 5 내지 10중량%이고 밀도가 550g/l 이상인 과립형 세제조성물.Surfactant consisting essentially of at least one particulate component of C 14 -C 20 alkyl sulfate salt (i) and water-soluble C 11 -C 18 alkyl ethoxysulfate salt (ii) containing an average of 1 to 7 ethoxy groups per mole System component (a), wherein the weight ratio of alkyl sulfate salt to alkyl ethoxysulfate salt is from 2: 1 to 19: 1, provided that the amount of alkyl ethoxylate salt is from 0.25 to 10% by weight of the component) from 5 to 60% by weight And from 15 to 95% by weight of organic and / or inorganic enhancer salts or mixtures of these salts, comprising a plurality of independent particulate components, the total amount of the anionic surfactant being from 5 to 10% by weight of the composition Granular detergent composition having a density of at least 550 g / l. 제 6 항에 있어서, 알킬 에톡시설페이트 염이 성분의 0.5 내지 5중량%의 양으로 존재하는 과립형 세제 조성물.7. Granular detergent composition according to claim 6, wherein the alkyl ethoxysulfate salt is present in an amount of 0.5 to 5% by weight of the component. 제 6 항 또는 제 7 항에 있어서, 알킬 설페이트염이 C16-C20알킬 설페이트 염을 포함하는 과립형 세제 조성물.8. Granular detergent composition according to claim 6 or 7, wherein the alkyl sulfate salt comprises a C 16 -C 20 alkyl sulfate salt. 제 6 항 또는 제 7 항에 있어서, 알킬 설페이트 염이 실질적으로 측쇄화된 C14-C15알킬 설페이트 염을 포함하는 과립형 세제 조성물.8. Granular detergent composition according to claim 6 or 7, wherein the alkyl sulfate salt comprises a substantially branched C 14 -C 15 alkyl sulfate salt. 제 1 항 내지 제 9 항중 어느 한 항에 있어서, 하나 이상의 미립자 성분이 분무 건조된 과립인 과립형 세제 조성물.10. The granular detergent composition of claim 1, wherein the one or more particulate components are spray dried granules. 11. 제10항에 있어서, 하나 이상의 분무 건조된 과립이 계면활성제 시스템 (a) 5내지 30중량%, 유기및/또는 무기 증강제 염 (b) 25 내지 95중량%, (a)와 (b)이외의 세제 성분 0 내지 45중량% 및 물을 포함하는 과립형 세제 조성물.The method of claim 10, wherein the one or more spray dried granules comprises from 5 to 30 weight percent of surfactant system (a), from 25 to 95 weight percent of organic and / or inorganic enhancer salt (b), other than (a) and (b). A granular detergent composition comprising 0 to 45 wt% of detergent components and water. 제 1 항 내지 제11항 중의 어느 한 항에 있어서, 하나 이상의 미립자 성분이 미립자 응집체인 과립형 세제 조성물.The granular detergent composition according to any one of claims 1 to 11, wherein the at least one particulate component is a particulate aggregate. 제12항에 있어서, 하나 이상의 미립자 응집체 성분이 계면활성제 시스템 (a) 15 내지 60중량%, 유기 및/또는 무기 증강제 염 (b) 20 내지 85중량%, (a)와 (b)이외의 세제 성분 0 내지 45중량% 및 물을 포함하는 과립형 세제 조성물.13. The detergent of claim 12, wherein the at least one particulate aggregate component comprises from 15 to 60 weight percent of surfactant system (a), from 20 to 85 weight percent of organic and / or inorganic enhancer salt (b), and from (a) and (b). Granular detergent composition comprising 0 to 45% by weight of the component and water. 제 1 항 내지 제13항 중의 어느 한 항에 있어서, 추가의 비이온성 계면활성제를 세제 조성물의 2 내지 9중량%로 포함하는 과립형 세제 조성물.14. Granular detergent composition according to any one of claims 1 to 13, wherein the non-ionic surfactant comprises from 2 to 9% by weight of the detergent composition. 제14항에 있어서, 추가의 비이온성 계면활성제가 1mol당 평균 3 내지 11개의 에톡시 그룹을 함유하는 C12-C20에톡시화 알콜인 과립형 세제 조성물.15. The granular detergent composition of claim 14, wherein the additional nonionic surfactant is a C 12 -C 20 ethoxylated alcohol containing an average of 3 to 11 ethoxy groups per mole. 제14항 또는 제15항에 있어서, 추가의 비이온성 계면활성제가 1mol당 평균 3 내지 7개, 가장 바람직하게는 평균 3개의 에톡시 그룹을 함유하는 C12-C15에톡시화 알콜인 과립형 세제 조성물.The granular detergent according to claim 14 or 15, wherein the additional nonionic surfactant is a C 12 -C 15 ethoxylated alcohol containing an average of 3 to 7 and most preferably an average of 3 ethoxy groups per mol. Composition. 제 1 항 내지 제16항중 어느 한 항에 있어서, 알킬 에톡시설페이트 염이 1mol당 바람직하게는 평균 1 내지 5개, 가장 바람직하게는 평균 1 내지 3개의 에톡시 그룹과 축합된 C12-C15알킬 설페이트를 포함하는 과립형 세제 조성물.The C 12 -C 15 according to any one of claims 1 to 16, wherein the alkyl ethoxysulfate salt is condensed with preferably 1 to 5, most preferably 1 to 3 ethoxy groups, per mole. Granular detergent composition comprising an alkyl sulfate. 제 1 항 내지 제17항중의 어느 한 항에 있어서, 유기 및/또는 무기 증강제 염이 비인산염 증강제 염의 혼합물을 포함하는 과립형 세제 조성물.The granular detergent composition of claim 1, wherein the organic and / or inorganic enhancer salt comprises a mixture of non-phosphate enhancer salts. 제18항에 있어서, 증강제 염의 혼합물이 A형, X형 또는 HS형의 결정성 나트륨 알루미노규산염 제올라이트; 알칼리 금속 탄산염 및 중탄산염; 알칼리 금속 폴리카복실레이트; 알칼리 금속 또는 알칼리 토금속 알킬렌 아미노 포릴메틸렌 포스포네이트; 및 폴리카복실산이 2개 이하의 탄소원자에 의해 서로 분리된 2개 이상의 카복실 라디칼을 포함하는 단독중합체성 또는 공중합체성 폴리카복실산의 알칼리 금속염 중에서 선택되는 과립형 세제 조성물.19. The composition of claim 18, wherein the mixture of enhancer salts comprises crystalline sodium aluminosilicate zeolites of Form A, Form X or Form HS; Alkali metal carbonates and bicarbonates; Alkali metal polycarboxylates; Alkali metal or alkaline earth metal alkylene amino formethylene phosphonates; And an alkali metal salt of a homopolymeric or copolymeric polycarboxylic acid wherein the polycarboxylic acid comprises at least two carboxyl radicals separated from each other by up to two carbon atoms. 제 1 항 내지 제19항중 어느 한 항에 있어서, 하나 이상의 미립자 성분이 조성물에 15중량% 이상, 바람직하게는 20 내지 45중량%의 양으로 존재하는 분무 거조된 과립인 과립형 세제 조성물.20. The granular detergent composition according to claim 1, wherein the at least one particulate component is a spray dried granule present in the composition in an amount of at least 15% by weight, preferably 20 to 45% by weight. 제 1 항 내지 제20항에 있어서, 하나 이상의 미립자 성분이 조성물에 1 내지 50중량%, 보다 바람직하게는 10 내지 40중량%의 양으로 존재하는 미립자 응집체인 과립형 세제 조성물.21. The granular detergent composition of claim 1, wherein the at least one particulate component is a particulate aggregate present in the composition in an amount of 1-50% by weight, more preferably 10-40% by weight. 제 1 항 내지 제21항중 어느 한 항에 있어서, 산소 표백제, 표백제 활성제, 광활성화 표백제, 시트레이트, 비결정성 규산염, 기타 증강제 염, 세제 효소, 오염물 현탁 및 재부착 방지제, 형광증백제, 거품억제제 및 이들의 혼합물 중에서 선택된 추가의 미립자 성분을 포함하는 과립형 세제 조성물.22. Oxygen bleach, bleach activator, photoactivated bleach, citrate, amorphous silicate, other enhancer salts, detergent enzymes, contaminant suspension and reattachment inhibitors, fluorescent brighteners, antifoams And a further particulate component selected from mixtures thereof. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019940703165A 1992-03-10 1993-03-05 Granular detergent compositions Expired - Fee Related KR100253863B1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GB9205189.5 1992-03-10
GB929205189A GB9205189D0 (en) 1992-03-10 1992-03-10 Granular detergent compositions
PCT/US1993/001897 WO1993018124A1 (en) 1992-03-10 1993-03-05 Granular detergent compositions

Publications (2)

Publication Number Publication Date
KR950700397A true KR950700397A (en) 1995-01-16
KR100253863B1 KR100253863B1 (en) 2000-04-15

Family

ID=10711832

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019940703165A Expired - Fee Related KR100253863B1 (en) 1992-03-10 1993-03-05 Granular detergent compositions

Country Status (16)

Country Link
EP (1) EP0630399B1 (en)
JP (1) JP3561803B2 (en)
KR (1) KR100253863B1 (en)
CN (1) CN1054396C (en)
AT (1) ATE208808T1 (en)
AU (1) AU670578B2 (en)
CA (1) CA2131171C (en)
DE (1) DE69331136D1 (en)
EG (1) EG20451A (en)
FI (1) FI944163L (en)
GB (1) GB9205189D0 (en)
IN (1) IN185983B (en)
MA (1) MA22820A1 (en)
MX (1) MX9301335A (en)
NO (1) NO308112B1 (en)
WO (1) WO1993018124A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101411559B1 (en) * 2011-05-13 2014-06-24 주식회사 엘지생활건강 Sheet for laundry

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19519139A1 (en) * 1995-05-30 1996-12-05 Henkel Kgaa Granular detergent or cleaning agent with high bulk density
GB9711359D0 (en) 1997-05-30 1997-07-30 Unilever Plc Detergent powder composition
GB9711350D0 (en) * 1997-05-30 1997-07-30 Unilever Plc Granular detergent compositions and their production
DE69817811T2 (en) 1997-05-30 2004-04-01 Unilever N.V. GIANT GRANULAR DETERGENT COMPOSITIONS
GB9711356D0 (en) 1997-05-30 1997-07-30 Unilever Plc Particulate detergent composition
US9546274B2 (en) 2009-05-26 2017-01-17 The Armor All/Stp Products Company Automotive protectant compositions with improved vertical cling
CN103221525A (en) 2010-11-16 2013-07-24 陶氏环球技术有限责任公司 Hard surface cleaners comprising low VOC, low odor alkanolamines
ES2421162T3 (en) 2011-04-04 2013-08-29 Unilever Nv Fabric washing procedure
US8865638B2 (en) 2013-03-15 2014-10-21 Church & Dwight Co., Inc. Unit dose laundry compositions
US9273270B2 (en) 2014-02-20 2016-03-01 Church & Dwight Co., Inc. Unit dose cleaning products for delivering a peroxide-containing bleaching agent
GB201406268D0 (en) * 2014-04-08 2014-05-21 Pq Silicas Uk Ltd Particulate zeolite composition

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5150912A (en) * 1974-10-31 1976-05-06 Kao Corp Senjozaisoseibutsu
US4019999A (en) * 1975-07-23 1977-04-26 The Procter & Gamble Co. Spray-dried granular detergent containing aluminosilicate, silicate, and pyrophosphate
JPS52154810A (en) * 1976-06-18 1977-12-22 Lion Corp Granulated detergent composition
US4487710A (en) * 1982-03-01 1984-12-11 The Procter & Gamble Company Granular detergents containing anionic surfactant and ethoxylated surfactant solubility aid
ES8607378A1 (en) * 1984-08-06 1986-05-16 Kao Corp Powder detergent of high density
JPH0637639B2 (en) * 1988-10-12 1994-05-18 ライオン株式会社 High bulk density granular detergent composition
GB9012612D0 (en) * 1990-06-06 1990-07-25 Unilever Plc Detergents compositions

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101411559B1 (en) * 2011-05-13 2014-06-24 주식회사 엘지생활건강 Sheet for laundry

Also Published As

Publication number Publication date
WO1993018124A1 (en) 1993-09-16
KR100253863B1 (en) 2000-04-15
NO308112B1 (en) 2000-07-24
EP0630399A1 (en) 1994-12-28
FI944163A7 (en) 1994-09-09
JP3561803B2 (en) 2004-09-02
JPH07504696A (en) 1995-05-25
EP0630399A4 (en) 1996-04-03
MX9301335A (en) 1993-12-01
NO943315D0 (en) 1994-09-08
ATE208808T1 (en) 2001-11-15
AU3786393A (en) 1993-10-05
DE69331136D1 (en) 2001-12-20
GB9205189D0 (en) 1992-04-22
IN185983B (en) 2001-05-26
EG20451A (en) 1999-04-29
AU670578B2 (en) 1996-07-25
EP0630399B1 (en) 2001-11-14
CA2131171C (en) 1998-08-18
NO943315L (en) 1994-11-09
FI944163A0 (en) 1994-09-09
FI944163L (en) 1994-09-09
CN1054396C (en) 2000-07-12
CN1077491A (en) 1993-10-20
CA2131171A1 (en) 1993-09-16
MA22820A1 (en) 1993-10-01

Similar Documents

Publication Publication Date Title
US5466802A (en) Detergent compositions which provide dye transfer inhibition benefits
US4265777A (en) Detergent compositions containing an aluminosilicate detergency builder and an unsaturated fatty acid soap
CA1200172A (en) Detergent compositions
CA1143242A (en) Stable liquid detergent compositions
EP0591445B1 (en) Liquid detergent with stabilized enzyme
KR950700397A (en) Granular detergent compositions
KR880011370A (en) Liquid, phosphate-free single-phase degreasing composition for aluminum surfaces.
IE63070B1 (en) Liquid detergent containing solid peroxygen bleach
SE446460B (en) FIXED, PARTICULAR DETERGENT COMPOSITION
CA2412252C (en) Post-added .alpha.-sulfofatty acid ester compositions and methods of making and using the same
KR890000650A (en) Liquid detergent composition
JPH03197597A (en) Liquid detergent composition containing enzyme and enzyme stabilizing system
JPS5925895A (en) Stable liquid detergent composition
US5783548A (en) Stable liquid detergent compositions inhibiting dye transfer
EP0189225A2 (en) Built liquid detergent containing anionic, ethoxylated nonionic and amide surfactants
CN1127988A (en) Low foaming liquid detergent composition
US4436653A (en) Stable liquid detergent compositions
EP0530959B1 (en) Fabric softening compositions based on pentaerythritol compound and dispersant for such a compound
GB2188645A (en) Liquid detergents containing anionic surfactant
KR950703039A (en) DETERGENT BLEACH COMPOSITIONS CONTAINING LAYERED SILICATE BUILDER AND PERCARBONATE STABILIZED BY EDDS Stabilized by Ethylenediamine-N, N'-Disuccinic Acid, Laminated Silicate Enhancer and Percarbonate
CZ335395A3 (en) Granulated detergent
JPH08503509A (en) Stable liquid detergent composition that suppresses dye migration
US4931215A (en) Detergent compositions containing a combination of a co-builder and a builder
US5182044A (en) Zeolite containing liquid detergent composition
CA1210299A (en) Liquid detergent compositions having high reserve alkalinity

Legal Events

Date Code Title Description
PA0105 International application

St.27 status event code: A-0-1-A10-A15-nap-PA0105

R17-X000 Change to representative recorded

St.27 status event code: A-3-3-R10-R17-oth-X000

PG1501 Laying open of application

St.27 status event code: A-1-1-Q10-Q12-nap-PG1501

A201 Request for examination
P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

PA0201 Request for examination

St.27 status event code: A-1-2-D10-D11-exm-PA0201

R18-X000 Changes to party contact information recorded

St.27 status event code: A-3-3-R10-R18-oth-X000

R17-X000 Change to representative recorded

St.27 status event code: A-3-3-R10-R17-oth-X000

PN2301 Change of applicant

St.27 status event code: A-3-3-R10-R13-asn-PN2301

St.27 status event code: A-3-3-R10-R11-asn-PN2301

R18-X000 Changes to party contact information recorded

St.27 status event code: A-3-3-R10-R18-oth-X000

E701 Decision to grant or registration of patent right
PE0701 Decision of registration

St.27 status event code: A-1-2-D10-D22-exm-PE0701

GRNT Written decision to grant
PR0701 Registration of establishment

St.27 status event code: A-2-4-F10-F11-exm-PR0701

PR1002 Payment of registration fee

St.27 status event code: A-2-2-U10-U12-oth-PR1002

Fee payment year number: 1

PG1601 Publication of registration

St.27 status event code: A-4-4-Q10-Q13-nap-PG1601

LAPS Lapse due to unpaid annual fee
PC1903 Unpaid annual fee

St.27 status event code: A-4-4-U10-U13-oth-PC1903

Not in force date: 20030128

Payment event data comment text: Termination Category : DEFAULT_OF_REGISTRATION_FEE

PC1903 Unpaid annual fee

St.27 status event code: N-4-6-H10-H13-oth-PC1903

Ip right cessation event data comment text: Termination Category : DEFAULT_OF_REGISTRATION_FEE

Not in force date: 20030128

R18-X000 Changes to party contact information recorded

St.27 status event code: A-5-5-R10-R18-oth-X000