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KR950018077A - Anaerobic Curable Composition (II) - Google Patents

Anaerobic Curable Composition (II) Download PDF

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Publication number
KR950018077A
KR950018077A KR1019930029702A KR930029702A KR950018077A KR 950018077 A KR950018077 A KR 950018077A KR 1019930029702 A KR1019930029702 A KR 1019930029702A KR 930029702 A KR930029702 A KR 930029702A KR 950018077 A KR950018077 A KR 950018077A
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KR
South Korea
Prior art keywords
weight
composition
compound
butyl
peroxide
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Application number
KR1019930029702A
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Korean (ko)
Inventor
김덕일
배근택
곽필규
Original Assignee
안시환
주식회사 에스 케이 씨
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Priority to KR1019930029702A priority Critical patent/KR950018077A/en
Publication of KR950018077A publication Critical patent/KR950018077A/en

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Abstract

본 발명은 인접한 두 금속 표면간의 접착 충진에 사용되는 혐기성 경화형 접착 조성물에 관한 것이다. 본 발명의 조성물은 (I) 적어도 하나이상의 비닐 작용기를 가진 중합가능한 단량체; (2) 상기 성분 (1)의 중량을 기준으로, 0.01 내지 10중량%의 유기디설파이드 화합물과 0.1 내지 10중량%의 유기 퍼옥사이드 화합물을 하는 중합 개제 시스템; 및 (3) 상기 성분(1)의 중량을 기준으로 0.1 내지 10중량%의 촉진제를 포함한다. 본 발명의 조성물은 활성도가 낮은 피착재상에서도 접착 속도가 매우 높다는 잇점이 있다.The present invention relates to an anaerobic curable adhesive composition used for adhesive filling between two adjacent metal surfaces. The composition of the present invention comprises (I) a polymerizable monomer having at least one vinyl functional group; (2) a polymerization initiation system comprising from 0.01 to 10% by weight of an organic disulfide compound and from 0.1 to 10% by weight of an organic peroxide compound, based on the weight of component (1); And (3) 0.1 to 10% by weight of accelerator, based on the weight of component (1). The composition of the present invention has the advantage that the adhesion rate is very high even on a low-active adherend.

Description

혐기성 경화형 조성물(Ⅱ)Anaerobic Curable Composition (II)

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (6)

(1) 적어도 하나이상의 비닐 작용기를 가진 중합가능한 단량체; (2) 상기 성분(1)의 중량을 기준으로, 0.01 내지 10중량%의 유기디설파이드 화합물과 0.1 내지 10중량%의 유기 퍼옥사이드 화합물을 포함하는 중합 개시제 시스템; 및 (3) 상기 성분(1)의 중량을 기준으로 0.01 내지 10중량%의 촉진제를 포함하는 혐기성 경화형 조성물.(1) polymerizable monomers having at least one vinyl functional group; (2) a polymerization initiator system comprising 0.01 to 10% by weight of an organic disulfide compound and 0.1 to 10% by weight of an organic peroxide compound, based on the weight of component (1); And (3) 0.01 to 10% by weight of accelerator, based on the weight of component (1). 제1항에 있어서, 상기 중합가능한 단량체가 일관능성 또는 다관능성 아크릴레이트 또는 메타크릴레이트 단량체인 것을 특징으로 하는 조성물.The composition of claim 1 wherein the polymerizable monomer is a monofunctional or polyfunctional acrylate or methacrylate monomer. 제1항에 있어서, 상기 디설파이드 화합물이 하기 구조식의 대칭 또는 비대칭 지방족 또는 방향족 디설파이드 화합물인 것을 특징으로 하는 조성물.The composition of claim 1, wherein the disulfide compound is a symmetric or asymmetric aliphatic or aromatic disulfide compound of the following structural formula. R1- S - S - R2 R 1 -S-S-R 2 상기식에서, R1및 R2는 각각 수소, 탄소수 1 내지 18의 알킬 또는 아릴기, 또는 극성 치환기를 가진 알킬 또는 아릴기를 나타낸다.In the above formula, R 1 and R 2 each represent hydrogen, an alkyl or aryl group having 1 to 18 carbon atoms, or an alkyl or aryl group having a polar substituent. 제3항에 있어서, R1및 R2가 각각 수소, 메틸, 에틸, 프로필, 이소프로필, n-부틸, i-부틸, t-부틸, 펜틸, 헥실, 헵틸, 옥틸, 데카닐, 도데카닐, 옥타데카닐, 페닐, 모노-또는 디-치환된 페닐, 벤질 또는 큐밀인 것을 특징으로 하는 조성물.4. A compound according to claim 3, wherein R 1 and R 2 are each hydrogen, methyl, ethyl, propyl, isopropyl, n-butyl, i-butyl, t-butyl, pentyl, hexyl, heptyl, octyl, decanyl, dodecanyl, Octadecanyl, phenyl, mono- or di-substituted phenyl, benzyl or cumyl. 제1항에 있어서, 상기 유기 퍼옥사이드 화합물이 디메틸벤젠 하이드록퍼옥사이드, 메틸에틸 케톤 하이드로퍼옥사이드, t-부틸하이드로퍼옥사이드, 디큐민 퍼옥사이드 또는 디-t-부틸 퍼옥사이드인 것을 특징으로 하는 조성물.The composition according to claim 1, wherein the organic peroxide compound is dimethylbenzene hydroxide peroxide, methylethyl ketone hydroperoxide, t-butylhydroperoxide, dicumin peroxide or di-t-butyl peroxide. . 제1항에 있어서, 상기 촉진제가 3차 아민 또는 설피미드 유도체인 것을 특징으로 하는 조성물.The composition of claim 1 wherein the promoter is a tertiary amine or sulfimide derivative. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019930029702A 1993-12-24 1993-12-24 Anaerobic Curable Composition (II) KR950018077A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
KR1019930029702A KR950018077A (en) 1993-12-24 1993-12-24 Anaerobic Curable Composition (II)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1019930029702A KR950018077A (en) 1993-12-24 1993-12-24 Anaerobic Curable Composition (II)

Publications (1)

Publication Number Publication Date
KR950018077A true KR950018077A (en) 1995-07-22

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KR1019930029702A KR950018077A (en) 1993-12-24 1993-12-24 Anaerobic Curable Composition (II)

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KR (1) KR950018077A (en)

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