KR950006870B1 - 유기질섬유를 함침시키는 방법 - Google Patents
유기질섬유를 함침시키는 방법 Download PDFInfo
- Publication number
- KR950006870B1 KR950006870B1 KR1019930001092A KR930001092A KR950006870B1 KR 950006870 B1 KR950006870 B1 KR 950006870B1 KR 1019930001092 A KR1019930001092 A KR 1019930001092A KR 930001092 A KR930001092 A KR 930001092A KR 950006870 B1 KR950006870 B1 KR 950006870B1
- Authority
- KR
- South Korea
- Prior art keywords
- radical
- organosilicon compound
- units
- case
- general formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/38—Polysiloxanes modified by chemical after-treatment
- C08G77/382—Polysiloxanes modified by chemical after-treatment containing atoms other than carbon, hydrogen, oxygen or silicon
- C08G77/392—Polysiloxanes modified by chemical after-treatment containing atoms other than carbon, hydrogen, oxygen or silicon containing sulfur
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Silicon Polymers (AREA)
- Reinforced Plastic Materials (AREA)
- Paper (AREA)
Abstract
Description
Claims (10)
- 다음 일반식(Ⅰ)의 단위로 구성된 오르가노실리콘화합물로 유기질섬유를 함침시키는 방법.위식에서, R은 각각의 경우 같거나 다르며 1가 유기래디컬이고, R1은 각각의 경우 같거나 다르며 수소원자 또는 1가 유기래디컬이고, R2는 각각의 경우 같거나 다르며 -QSO3Mv래디컬이며[Q는 2가 탄화수소래디컬, m은 카티온, V는 M의 전하의 정역치(reciprocal value)임], a는 0, 1, 2 또는 3, b는 0, 1, 2 또는 3, C는 0, 1, 2 또는 3이다. 단, 그 오르가노실리콘화합물은 분자당 적어도 하나의 R2은 래디컬을 가지며 a, b 및 c 합이 3 또는 3 미만이다.
- 제1항에 있어서, 사용한 일반식(Ⅰ)의 단위로 구성된 오르가노실리콘화합물은 다음 일반식(Ⅱ)의 오르가노폴리실록산 및 다음 일반식(Ⅲ)의 오르가노폴리실록산과, 일반식(Ⅱ) 또는 (Ⅲ)의 오르가노폴리실록산으로 구성되는 그룹(group)에서 선택한 오르가노실리콘화합물임을 특징으로 하는 상기 방법.위식에서 R은 각각의 경우 같거나 다르며 1가 유기래디컬이고, R4는 각각의 경우 같거나 다르며 수소원자 또는 1가 유기래디컬이고, R2는 각각의 경우 같거나 다르며 -QSO3Mv래디컬(Q는 2가 탄화수소래디컬, M은 카티온, V는 M전하의 정역치임)이고, m은 20~500의 정수 n은 20∼1000의 정수, 0는 1-40의 정수, p는 0 또는 1이고, [R2SiO]단위전체 또는 일부는[RSiO3/2]-, [R(R1O)SiO]-, [(R1O)2SiO]-, [(R1O)SiO3/2]- 및/또는 [SiO4/2] 단위에 의해 치환되거나 [RR2SiO]단위 전체 또는 일부 각각은 [(R1O)R2SiO]- 및/또는 [R2SiO3/2]단위에 의해 치환된다(여기서 R1및 R27는 위에서 정의한 것과 같음).
- 제1항 또는 제2항에 있어서, Q는 n-프로필렌래디컬임을 특징으로 하는 상기방법.
- 제1항 또는 제2항에 있어서, M은 소듐이온, NHEt3 +, NH3(C2H4OH)+, [NH3(CH2)2SiMeO]+와 [NH3(CH2)2NH2(CH2)3SiMeO]2+로 구성되는 그룹에서 선택된 적어도 하나의 단위를 구성하는 (폴리)실록산 (Me는 메틸래디컬, Et는 에틸래디컬임)임을 특징으로 하는 상기방법.
- 제1항 또는 제2항에 있어서, 사용한 오르가노실리콘화합물은 다음일반식(Ⅴ)의 단위로 구성된 오르가노실리콘화합물을 설파이프와 물의 전재하에서 반응시켜 제조한 오르가노실리콘화합물임을 특징으로 하는 상기방법.위식에서 R4는 각각의 경우 같거나 다르며 1가 유기래디컬이고, R5는 각각의 경우 같거나 다르며 수소원자 또는 1가 유기래디컬이고, R6은 각각의 경우 같거나 다르며 -Q′X 래디컬(Q는 2가 탄화수소래디컬, X는 할로겐원임)이고, d는 0, 1, 2 또는 3, e는 0, 1, 2, 또는 3, f는 0, 2 또는 3이다. 단, 그 오르가노실리콘화합물은 분자당 적어도 하나의 R6래디컬을 가지며, d, e 및 f의 합은 4 또는 4미만이다.
- 제1항 또는 제2항에 있어서, 그 오르가노실리콘화합물은 수용성분산액의 형태로 사용함을 특징으로 하는 상기방법.
- 제6항에 있어서, 그 수용성분산액은 적어도 하나의 설포네이트기를 포함하며, 그 수용성분산액에 대하여 5-60wt%의 일반식(Ⅰ)의 단위로 구성되는 오르가노실리콘화합물을 구성함을 특징으로 하는 상기방법.
- 제1항에 있어서, 그 유기질섬유는 울(wool), 면(cotton), 폴리에스테르, 폴리아미드, 폴리아크릴로니트릴 및 이들의 혼합물임을 특징으로 하는 상기방법.
- 제1항 또는 제2항에 있어서, 적어도 하나의 설포네이트기를 포함하며, 일반식(Ⅰ)의 단위로 구성되는 오르가노실리콘화합물을 함침되는 유기질섬유 총중량에 대하여 0.1~5wt%로 처리함을 특징으로 하는 상기방법.
- 제1항 또는 제2항에 있어서, 적어도 하나의 설포네이트기를 포함하며 일반식(Ⅰ)의 단위로 구성되는 오르가노실리콘화합물은 함침되는 유기질섬유총중량에 대하여 0.3~1.5wt%로 처리함을 특징으로 하는 상기방법.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4203567A DE4203567A1 (de) | 1992-02-07 | 1992-02-07 | Verfahren zum impraegnieren von organischen fasern |
DEP4203567.8 | 1992-02-07 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR930018093A KR930018093A (ko) | 1993-09-21 |
KR950006870B1 true KR950006870B1 (ko) | 1995-06-23 |
Family
ID=6451191
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019930001092A Expired - Fee Related KR950006870B1 (ko) | 1992-02-07 | 1993-01-28 | 유기질섬유를 함침시키는 방법 |
Country Status (9)
Country | Link |
---|---|
EP (1) | EP0554863B1 (ko) |
JP (1) | JPH05279964A (ko) |
KR (1) | KR950006870B1 (ko) |
AT (1) | ATE115204T1 (ko) |
CA (1) | CA2088738A1 (ko) |
DE (2) | DE4203567A1 (ko) |
ES (1) | ES2065190T3 (ko) |
MX (1) | MX9300649A (ko) |
TW (1) | TW232038B (ko) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5354815A (en) * | 1992-06-05 | 1994-10-11 | Comfort Technologies | Polymers having enhanced hydrophilicity and thermal regulated properties and process of producing the same |
US5408012A (en) * | 1993-05-27 | 1995-04-18 | Comfort Technologies, Inc. | Polymers having enhanced durable hydrophilicity and durable rewetting properties and process of producing the same |
DE19710461A1 (de) * | 1997-03-13 | 1998-09-17 | Wacker Chemie Gmbh | Farbstoffreste aufweisende Organopolysiloxane |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1206160B (de) * | 1960-09-30 | 1965-12-02 | Wacker Chemie Gmbh | Verfahren zum Sulfonieren von Organopoly-siloxanen oder Organoalkoxysilanen |
DE1419462A1 (de) * | 1962-02-10 | 1968-10-10 | Goldschmidt Ag Th | Hydrophobierungsemulsion |
US3328449A (en) * | 1963-12-05 | 1967-06-27 | Dow Corning | Sulfopropylated, organofunctional silanes and siloxanes |
JPS58204028A (ja) * | 1982-05-21 | 1983-11-28 | Shin Etsu Chem Co Ltd | オルガノシランまたはオルガノシロキサンの乳化重合方法 |
GB8706093D0 (en) * | 1987-03-14 | 1987-04-15 | Dow Corning Ltd | Organosilicon sulphosuccinates |
JPH02160031A (ja) * | 1988-12-15 | 1990-06-20 | Shin Etsu Chem Co Ltd | アニオン型シリコーン界面活性物質及びその製造方法 |
DE3940536A1 (de) * | 1989-12-07 | 1991-06-13 | Wacker Chemie Gmbh | Sulfosuccinatgruppen enthaltende organopolysiloxane |
DE4004946A1 (de) * | 1990-02-16 | 1991-08-22 | Wacker Chemie Gmbh | Feinteilige organopolysiloxanemulsionen |
-
1992
- 1992-02-07 DE DE4203567A patent/DE4203567A1/de not_active Withdrawn
- 1992-12-17 TW TW081110113A patent/TW232038B/zh active
-
1993
- 1993-01-28 KR KR1019930001092A patent/KR950006870B1/ko not_active Expired - Fee Related
- 1993-02-03 CA CA002088738A patent/CA2088738A1/en not_active Abandoned
- 1993-02-04 JP JP5017347A patent/JPH05279964A/ja active Pending
- 1993-02-04 AT AT93101725T patent/ATE115204T1/de not_active IP Right Cessation
- 1993-02-04 DE DE59300032T patent/DE59300032D1/de not_active Expired - Fee Related
- 1993-02-04 ES ES93101725T patent/ES2065190T3/es not_active Expired - Lifetime
- 1993-02-04 EP EP93101725A patent/EP0554863B1/de not_active Expired - Lifetime
- 1993-02-04 MX MX9300649A patent/MX9300649A/es unknown
Also Published As
Publication number | Publication date |
---|---|
EP0554863B1 (de) | 1994-12-07 |
EP0554863A1 (de) | 1993-08-11 |
ES2065190T3 (es) | 1995-02-01 |
KR930018093A (ko) | 1993-09-21 |
CA2088738A1 (en) | 1993-08-08 |
JPH05279964A (ja) | 1993-10-26 |
MX9300649A (es) | 1993-09-01 |
TW232038B (ko) | 1994-10-11 |
DE4203567A1 (de) | 1993-08-12 |
ATE115204T1 (de) | 1994-12-15 |
DE59300032D1 (de) | 1995-01-19 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
KR910007455B1 (ko) | 광학적으로 투명하고, 열적 및 기계적으로 안정한 수성, 미립자 실리콘 유제, 이의 제조방법 및 용도 | |
EP1063344B1 (en) | Nitrogen atom-containing polysiloxanes, their preparation, and fiber and fabric finishing agent compositions | |
CA1322433C (en) | Fiber treatment agent composition | |
CA1244604A (en) | Method for treating materials with organopolysiloxane compounds | |
EP0510631B1 (en) | Siloxane modified polyester for fibre treatment | |
EP1401920B1 (en) | Modified polyorganosiloxanes, aqueous emulsions thereof, their production and their use | |
US7329707B2 (en) | Partially quaternised, amino-functional organopolysiloxanes and their use in aqueous systems | |
US6472468B1 (en) | Fluorinated polysiloxane, making method, and fiber or fabric treating agent composition | |
EP2027328B1 (en) | Treating textiles with silicone polyether-amide block copolymers | |
US4625010A (en) | Organopolysiloxanes having Si-bonded hydrogen and SiC-bonded epoxy groups and a process for preparing the same | |
EP1373411A1 (en) | Organopolysiloxane composition, method of making emulsion-forming organopolysiloxane composition and metod of treating textile fiber or fabric | |
US4152273A (en) | Soil releasable hydrophilic surface finish for textile fabrics | |
US5258451A (en) | Method for the preparation of an aqueous emulsion of organopolysiloxane | |
KR870000475B1 (ko) | 유기섬유(organic fibers)제 직물(Textile Materials)을 함침(impregnating)시키는 방법 | |
US4666745A (en) | Organopolysiloxanes having Si-bonded hydrogen and SiC-bonded epoxy groups and a process for preparing the same | |
KR20040034598A (ko) | 발수성 텍스타일 마무리제 및 제조방법 | |
US5300237A (en) | Fiber treatment agent | |
US6072017A (en) | Monoacrylate-polyether treated fiber | |
KR950006870B1 (ko) | 유기질섬유를 함침시키는 방법 | |
KR950003854B1 (ko) | 유기섬유의 함침방법 | |
KR890000243B1 (ko) | 고급알킬 개질된 에폭시실리콘 터폴리머 함유 수성 유제조성물 | |
KR890001790B1 (ko) | 유기섬유의 함침방법(impregnating method) | |
US6001422A (en) | Method for finishing treatment of a fabric material | |
EP1753906A1 (en) | Textile treatments using fluoropolymer-branched silicone polyethers | |
GB2075040A (en) | Organopolysiloxane Compositions |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A201 | Request for examination | ||
PA0109 | Patent application |
St.27 status event code: A-0-1-A10-A12-nap-PA0109 |
|
PA0201 | Request for examination |
St.27 status event code: A-1-2-D10-D11-exm-PA0201 |
|
R17-X000 | Change to representative recorded |
St.27 status event code: A-3-3-R10-R17-oth-X000 |
|
PG1501 | Laying open of application |
St.27 status event code: A-1-1-Q10-Q12-nap-PG1501 |
|
E902 | Notification of reason for refusal | ||
PE0902 | Notice of grounds for rejection |
St.27 status event code: A-1-2-D10-D21-exm-PE0902 |
|
P11-X000 | Amendment of application requested |
St.27 status event code: A-2-2-P10-P11-nap-X000 |
|
P13-X000 | Application amended |
St.27 status event code: A-2-2-P10-P13-nap-X000 |
|
G160 | Decision to publish patent application | ||
PG1605 | Publication of application before grant of patent |
St.27 status event code: A-2-2-Q10-Q13-nap-PG1605 |
|
E701 | Decision to grant or registration of patent right | ||
PE0701 | Decision of registration |
St.27 status event code: A-1-2-D10-D22-exm-PE0701 |
|
GRNT | Written decision to grant | ||
PR0701 | Registration of establishment |
St.27 status event code: A-2-4-F10-F11-exm-PR0701 |
|
PR1002 | Payment of registration fee |
St.27 status event code: A-2-2-U10-U11-oth-PR1002 Fee payment year number: 1 |
|
FPAY | Annual fee payment |
Payment date: 19980608 Year of fee payment: 4 |
|
PR1001 | Payment of annual fee |
St.27 status event code: A-4-4-U10-U11-oth-PR1001 Fee payment year number: 4 |
|
R18-X000 | Changes to party contact information recorded |
St.27 status event code: A-5-5-R10-R18-oth-X000 |
|
LAPS | Lapse due to unpaid annual fee | ||
PC1903 | Unpaid annual fee |
St.27 status event code: A-4-4-U10-U13-oth-PC1903 Not in force date: 19990624 Payment event data comment text: Termination Category : DEFAULT_OF_REGISTRATION_FEE |
|
PC1903 | Unpaid annual fee |
St.27 status event code: N-4-6-H10-H13-oth-PC1903 Ip right cessation event data comment text: Termination Category : DEFAULT_OF_REGISTRATION_FEE Not in force date: 19990624 |
|
R17-X000 | Change to representative recorded |
St.27 status event code: A-5-5-R10-R17-oth-X000 |
|
PN2301 | Change of applicant |
St.27 status event code: A-5-5-R10-R13-asn-PN2301 St.27 status event code: A-5-5-R10-R11-asn-PN2301 |
|
P22-X000 | Classification modified |
St.27 status event code: A-4-4-P10-P22-nap-X000 |
|
R18-X000 | Changes to party contact information recorded |
St.27 status event code: A-5-5-R10-R18-oth-X000 |