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KR940000409A - 알켄산 유도체 제조방법 - Google Patents

알켄산 유도체 제조방법 Download PDF

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Publication number
KR940000409A
KR940000409A KR1019930011631A KR930011631A KR940000409A KR 940000409 A KR940000409 A KR 940000409A KR 1019930011631 A KR1019930011631 A KR 1019930011631A KR 930011631 A KR930011631 A KR 930011631A KR 940000409 A KR940000409 A KR 940000409A
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KR
South Korea
Prior art keywords
dielectric constant
alkanol
reaction
less
reaction medium
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KR1019930011631A
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English (en)
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KR100295155B1 (ko
Inventor
드랜트 아이트
바베 야게르 빌렘
Original Assignee
알베르투스 빌헬무스·요아네스 쩨스트라텐
셀 인터나쵸 나아레 레사아치 마아츠 샤피 비이부이
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Application filed by 알베르투스 빌헬무스·요아네스 쩨스트라텐, 셀 인터나쵸 나아레 레사아치 마아츠 샤피 비이부이 filed Critical 알베르투스 빌헬무스·요아네스 쩨스트라텐
Publication of KR940000409A publication Critical patent/KR940000409A/ko
Application granted granted Critical
Publication of KR100295155B1 publication Critical patent/KR100295155B1/ko

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • C07C67/38—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by addition to an unsaturated carbon-to-carbon bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/44—Palladium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/24—Phosphines

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

본 발명은 조절된 극성의 반응 매질내에서 반응이 수행되는, 팔라듐 화합물, 멀티덴테이트 포스핀 리간드, 및 임의로 프로톤산으로 구성되는 촉매 시스템의 존재하에, 액체 상태의 히드록실 기-함유 화합물 및 일산화탄소와 지방족 컨쥬게이트 디엔을 반응시킴으로써 알켄산 유도체를 제조하는 방법에 관한것이다.

Description

알켄산 유도체 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (11)

  1. 조절된 극성의 반응 매질내에서 반응이 수행되는, 팔라듐 화합물, 멀티덴테이트 포스핀 리간드, 및 임의로 프로톤산으로 구성되는 촉매시스템의 존재하에, 액테 상태의 히드록실기-함유 화합물 및 일산화탄소화 지방족 컨쥬게이트 디엔을 반응시킴으로써 알켄산 유도체를 제조하는 방법.
  2. 제1항에 있어서, 반응 매질의 이론치 유전상수 εcalc(순수한 액체 기질 및 용매의 25℃에서의 유전상수의 부피 평균으로서 계산됨)이 8이하의 값인 방법.
  3. 제2항에 있어서, 반응 매질의 이론치 유전상수가 4.5-7.5의 범위내의 εcalc값에서 유지되는 방법.
  4. 제1-3항중 임의 하나 이상의 항에 있어서, 히드록실 기- 함유 화합물이 20 이하의 25℃에서의 유전상수를 가지는 알칸올인 방법.
  5. 제4항에 있어서, 20 이하의 25℃에서의 유전상수 ε를 가지는 알칸올이 터트-부탄올인 방법.
  6. 제1-3항중 임의 하나 이상의 항에 있어서, 농도가 반응 경과중에 액체 반응 매질의 20부피% 이하로 유지되는, 히드록실 기- 함유 화합물이 20이상의 25℃에서의 유전상수를 가지는 알칸올인 방법.
  7. 제6항에 있어서, 농도가 반응 경과중에 액체 반응 매질의 12부피% 이하로 유지되는, 히드록실 기-함유 화합물이 30 이상의 25℃에서의 유전상수 ε를 가지는 알칸올인 방법.
  8. 제6또는 7항에 있어서, 알칸올의 부가의 양이, 알칸올의 소비와 실질적으로 상응하는 속도로 반응 경과중에 연속적으로 또는 간헐적으로 첨가되는 방법.
  9. 제1-8항중 임의 하나 이상의 항에 있어서, 6이하의 25℃에서의 유전상수 ε를 가지는 용매를 사용하는 방법.
  10. 제9항에 있어서, 용매가 에테르인 방법.
  11. 제1-10항중 임의 하나 이상의 항에 있어서, 유기 질소-함유 염기가 5부피% 이하의 농도로 존재하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019930011631A 1992-06-29 1993-06-24 알켄산유도체제조방법 KR100295155B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP92201941 1992-06-29
EP92201941.9 1992-06-29

Publications (2)

Publication Number Publication Date
KR940000409A true KR940000409A (ko) 1994-01-03
KR100295155B1 KR100295155B1 (ko) 2001-11-05

Family

ID=8210733

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019930011631A KR100295155B1 (ko) 1992-06-29 1993-06-24 알켄산유도체제조방법

Country Status (6)

Country Link
US (1) US5350876A (ko)
JP (1) JP3384501B2 (ko)
KR (1) KR100295155B1 (ko)
CN (1) CN1036916C (ko)
CA (1) CA2099192A1 (ko)
DE (1) DE69314388T2 (ko)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5719313A (en) * 1995-03-16 1998-02-17 Shell Oil Company Carbonylation catalyst system and a process for the carbonylation of acetylenically unsaturated compounds
AU6750798A (en) * 1997-04-07 1998-10-30 Dsm N.V. Carbonylation catalyst system
GB0403592D0 (en) * 2004-02-18 2004-03-24 Lucite Int Uk Ltd A catalyst system
GB0516556D0 (en) * 2005-08-12 2005-09-21 Lucite Int Uk Ltd Improved catalyst system
WO2007057640A1 (en) * 2005-11-17 2007-05-24 Lucite International Uk Limited Carbonylation of ethylenically unsaturated compounds
GB0607494D0 (en) * 2006-04-13 2006-05-24 Lucite Int Uk Ltd Metal complexes
CA2671409C (en) 2006-12-02 2016-07-26 Lucite International Uk Limited Novel carbonylation ligands and their use in the carbonylation of ethylenically unsaturated compounds
GB0625518D0 (en) * 2006-12-21 2007-01-31 Lucite Int Uk Ltd Carbonylation of conjugated dienes
GB0812297D0 (en) * 2008-07-04 2008-08-13 Lucite Int Uk Ltd Novel carbonylation ligand sand thier use of in the carbonylation of ethylenically unsaturated compounds
GB201000078D0 (en) 2010-01-05 2010-02-17 Lucite Int Uk Ltd Process for the carbonylation of ethylenically unsaturated compounds, novel carbonylation ligands and catalyst systems incorporatng such ligands
WO2014079691A1 (en) * 2012-11-23 2014-05-30 Firmenich Sa Hydrocarbonylation or methoxycarbonylation of 1,3-diene derivatives with palladium complex

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1110405A (en) * 1964-12-23 1968-04-18 Ici Ltd The production of esters
JPS50645A (ko) * 1973-05-07 1975-01-07
US4124617A (en) * 1977-06-28 1978-11-07 Texaco Development Corporation Process for preparing unsaturated aliphatic esters from aliphatic dienes
US4172087A (en) * 1978-02-13 1979-10-23 Texaco Development Corporation Process for preparing unsaturated aliphatic esters from aliphatic dienes
FR2498594A1 (fr) * 1981-01-23 1982-07-30 Rhone Poulenc Ind Procede de preparation de monoesters d'acides carboxyliques b,g-insatures
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KR880007418A (ko) * 1986-12-10 1988-08-27 오노 알버어스 공역 디엔의 선택적 카르보닐화 방법 및 이를 위한 유기 질소-함유 열기를 갖지 않는 촉매 시스템
KR880007426A (ko) * 1986-12-24 1988-08-27 오노 알버어스 팔라듐 촉매를 사용한 올레핀형 불포화 화합물의 카르보닐화 방법
GB8707405D0 (en) * 1987-03-27 1987-04-29 Shell Int Research Preparation of diester of adipic acid
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GB9002521D0 (en) * 1990-02-05 1990-04-04 Shell Int Research Carbonylation catalyst system
US5026901A (en) * 1990-03-29 1991-06-25 E. I. Du Pont De Nemours And Company Palladium catalyzed carboalkoxylation of butadiene

Also Published As

Publication number Publication date
JP3384501B2 (ja) 2003-03-10
KR100295155B1 (ko) 2001-11-05
JPH0665148A (ja) 1994-03-08
CN1082024A (zh) 1994-02-16
CA2099192A1 (en) 1993-12-30
US5350876A (en) 1994-09-27
DE69314388T2 (de) 1998-02-26
CN1036916C (zh) 1998-01-07
DE69314388D1 (de) 1997-11-13

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