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KR930017911A - L-형태의 1:1 금속 메티오닌 복합체 - Google Patents

L-형태의 1:1 금속 메티오닌 복합체 Download PDF

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Publication number
KR930017911A
KR930017911A KR1019920009096A KR920009096A KR930017911A KR 930017911 A KR930017911 A KR 930017911A KR 1019920009096 A KR1019920009096 A KR 1019920009096A KR 920009096 A KR920009096 A KR 920009096A KR 930017911 A KR930017911 A KR 930017911A
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South Korea
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transition metal
complex salt
salt according
metal complex
group
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KR1019920009096A
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KR950013575B1 (ko
Inventor
디. 앤더슨 마이클
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디. 앤더슨 마이클
진프로 코포레이션
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
    • C07F3/06—Zinc compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
    • C07C323/50—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton
    • C07C323/51—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton
    • C07C323/57—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton the carbon skeleton being further substituted by nitrogen atoms, not being part of nitro or nitroso groups
    • C07C323/58—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton the carbon skeleton being further substituted by nitrogen atoms, not being part of nitro or nitroso groups with amino groups bound to the carbon skeleton
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23K—FODDER
    • A23K20/00—Accessory food factors for animal feeding-stuffs
    • A23K20/10—Organic substances
    • A23K20/142—Amino acids; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23K—FODDER
    • A23K20/00—Accessory food factors for animal feeding-stuffs
    • A23K20/20—Inorganic substances, e.g. oligoelements
    • A23K20/30—Oligoelements

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Zoology (AREA)
  • Animal Husbandry (AREA)
  • Food Science & Technology (AREA)
  • Proteomics, Peptides & Aminoacids (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Fodder In General (AREA)
  • Manufacture And Refinement Of Metals (AREA)

Abstract

본 발명은 실질적으로 순수한 1:1L-형태 전이 금속 메티오닌 복합체 염에 관한 것으로, 바람직한 전이 금속은 아연, 크롬, 망간 및 철이다. 염은 순수한 L-형태 메티오닌과의 반응에 의해 형성된다. 그 결과로서, 보충을 위한 용량은 염의 라세미 혼합물에서 사용되는 양의 절반이 될 수 있다.

Description

L-형태의 1:1금속 메티오닌 복합체
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. 하기 식의 실질적으로 순수한 1:1L-형태 전이 금속 메티오닌 복합체 염:
    〔CH3SCH2CH2CH(NH2)COO M〕WX
    상기식에서, M은 아연, 크롬, 망간 및 철로 이루어지는 군으로부터 선택되는 금속이고, X는 음이온이며, w는 X의 음이온 전하와 평형을 유지하는 정수이다.
  2. 제1항에 있어서, M이 아연인 것을 특징으로 하는 1:1 L-형태 전이 금속 복합체 염.
  3. 제1항에 있어서, M이 망간인 것을 특징으로 하는 1:1 L-형태 전이 금속 복합체 염.
  4. 제1항에 있어서, M이 철인 것을 특징으로 하는 1:1 L-형태 전이 금속 복합체 염.
  5. 제1항에 있어서, M이 크롬인 것을 특징으로 하는 1:1 L-형태 전이 금속 복합체 염.
  6. 제1항에 있어서, X가 유기 음이온인 것을 특징으로 하는 1:1 L-형태 전이 금속 복합체 염.
  7. 제1항에 있어서, X가 아세트산, 프로피온산 및 벤조산으로 이루어지는 군으로부터 선택되는 유기 1 염기산 음이온인 것을 특징으로 하는 1:1 L-형태 전이 금속 복합체 염.
  8. 제1항에 있어서, X가 무기 음이온인 것을 특징으로 하는 1:1 L-형태 전이 금속 복합체 염.
  9. 제1항에 있어서, X가 할로겐화물, 황산염 및 인산염으로 이루어지는 군으로부터 선택되는 무기 음이온인 것을 특징으로 하는 1:1 L-형태 전이 금속 복합체 염.
  10. (a) 순수한 L-형태의 메티오닌을 얻는 단계; (b) 상기 순수한 L-형태의 메티오닌을 아연, 망간 및 철의 수용성 금속 염들로 이루어지는 군으로부터 선택되는 수용성 금속염과 반응시키는 단계; (c) 상기 반응을 7 또는 그 이하의 pH에서 수행하는 단계; 그리고 (d) 상기 1:1 L-형태의 전이 금속 메티오닌 복합체 염을 실질적으로 순수한 고체 형태로 분리하는 단계로 이루어지는, 하기 식의 실질적으로 순수한 1:1 L-형태 전이 금속 복합체 염의 제조방법.
    〔CH3SCH2CH2CH(NH2)COO M〕WX
    상기식에서, M은 아연, 크롬, 망간 및 철로 이루어지는 군으로부터 선택되는 금속이고, X는 음이온이며, w는 X의 음이온 전하와 평형을 유지하기 위한 정수이다.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019920009096A 1992-02-21 1992-05-28 L-형태의 1:1 금속 메티오닌 복합체 KR950013575B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US07/839,913 US5278329A (en) 1992-02-21 1992-02-21 L-form 1:1 metal methionine complexes
US07/839,913 1992-02-21

Publications (2)

Publication Number Publication Date
KR930017911A true KR930017911A (ko) 1993-09-20
KR950013575B1 KR950013575B1 (ko) 1995-11-09

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US (1) US5278329A (ko)
EP (1) EP0556498B1 (ko)
JP (1) JP2521215B2 (ko)
KR (1) KR950013575B1 (ko)
AT (1) ATE127786T1 (ko)
AU (1) AU650138B2 (ko)
CA (1) CA2068784C (ko)
DE (1) DE69204821T2 (ko)
DK (1) DK0556498T3 (ko)
ES (1) ES2081052T3 (ko)
GR (1) GR3018385T3 (ko)

Families Citing this family (39)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5631031A (en) * 1994-06-13 1997-05-20 Meade; Thomas L. Water-insoluble amino acid salt
US5430164A (en) * 1994-10-18 1995-07-04 Zinpro Corporation Enhanced solubilization of zinc and manganese methionine complex salts by addition of ferric ion
US5583243A (en) * 1995-05-19 1996-12-10 Zinpro Corporation Salts of alpha-hydroxy aliphatic carboxylic acids and uses thereof
US5670344A (en) * 1996-02-02 1997-09-23 The Procter & Gamble Company Preventing undesired color formation in iron fortified chocolate-flavored beverages by including edible acids or their salts
US5698724A (en) * 1996-04-30 1997-12-16 Zinpro Corporation Amino acid metal complexes using hydrolyzed protein as the amino acid source and methods re same
US5707670A (en) * 1996-08-29 1998-01-13 The Procter & Gamble Company Use of bilayer forming emulsifiers in nutritional compositions comprising divalent mineral salts to minimize off-tastes and interactions with other dietary components
DE19707380A1 (de) * 1997-02-25 1998-08-27 Degussa Verfahren zur Herstellung eines rieselfähigen Tierfuttermittelsupplements auf Methioninsalzbasis und das so erhältliche Granulat
US5885610A (en) * 1997-03-04 1999-03-23 Zinpro Corporation By-pass rumen product
ES2141016B1 (es) * 1997-08-07 2000-10-16 Orea Laurentino Lopez "complejos metalicos polinucleares para paliar estados carenciales de micronutrientes en seres vivos".
US6767741B1 (en) 1999-08-27 2004-07-27 Invitrogen Corporation Metal binding compounds and their use in cell culture medium compositions
JP4680339B2 (ja) * 1999-11-26 2011-05-11 日清丸紅飼料株式会社 コクシジウム症の予防および／または治療用飼料
US6166071A (en) * 2000-03-13 2000-12-26 Albion International, Inc. Zinc amino acid chelates having ligands comprised of glycine and a sulfur-containing amino acids
US6352714B1 (en) 2000-07-11 2002-03-05 Der, Inc. Method of producing a metal nutrient for an animal feed
US7696219B2 (en) * 2000-09-27 2010-04-13 Everett Laboratories, Inc. Method and composition for supplementation of nutritional deficiences in renal patients
US6995166B1 (en) * 2000-09-27 2006-02-07 Everett Laboratories, Inc. Method and composition for supplementation of nutritional deficiencies in renal patients
US20040137036A1 (en) * 2001-05-09 2004-07-15 Yoshitane Kojima Zinc-containing foods
US6541051B2 (en) 2001-05-30 2003-04-01 Zinpro Corporation Preparation of metal complexes of amino acids obtained by hydrolysis of soy protein
US6660293B2 (en) * 2001-06-29 2003-12-09 Everett Laboratories, Inc. Compositions and methods for prophylactic and therapeutic supplementation of nutrition in subjects
US7560123B2 (en) * 2004-08-12 2009-07-14 Everett Laboratories, Inc. Compositions and methods for nutrition supplementation
US7247328B2 (en) * 2002-05-31 2007-07-24 Zinpro Corporation Chromium (III) alpha amino acid complexes
US7129375B2 (en) 2002-10-16 2006-10-31 Zinpro Corporation Metal complexes of α amino dicarboxylic acids
US6814983B2 (en) * 2002-12-10 2004-11-09 Everett Laboratories, Inc. Compositions and methods for nutrition supplementation
US8617617B2 (en) * 2002-12-10 2013-12-31 Everett Laboratories, Inc. Methods and kits for co-administration of nutritional supplements
US7022351B2 (en) * 2003-01-14 2006-04-04 Zinpro Corporation Composition for supplementing animals with solutions of essential metal amino acid complexes
US6911550B2 (en) 2003-02-21 2005-06-28 Zinpro Corporation Derivatives of seleno-amino acids with improved bioavailability and method for their preparation
KR100481326B1 (ko) * 2004-06-22 2005-04-07 주식회사 동암비티 유기태 킬레이트의 제조방법
US20080063730A9 (en) * 2004-07-29 2008-03-13 Giordano John A Methods for prophylactic and therapeutic nutritional supplementation
US8101587B2 (en) 2004-08-12 2012-01-24 Everett Laboratories, Inc. Kits for nutrition supplementation
KR101164711B1 (ko) * 2009-02-27 2012-07-11 씨제이제일제당 (주) 미네랄 첨가와 산처리를 이용하여 메치오닌의 용해도를 증가시키는 방법
CN101941931A (zh) * 2010-09-07 2011-01-12 湖北神舟化工有限公司 一种制备蛋氨酸金属螯合物的方法
US8741375B2 (en) 2011-06-07 2014-06-03 Zinpro Corporation Mixed amino acid metal salt complexes
US8183227B1 (en) 2011-07-07 2012-05-22 Chemo S. A. France Compositions, kits and methods for nutrition supplementation
KR101546389B1 (ko) 2011-09-08 2015-08-21 헤리티지 테크놀러지스, 엘엘씨 미량 영양소 보충제
US8168611B1 (en) 2011-09-29 2012-05-01 Chemo S.A. France Compositions, kits and methods for nutrition supplementation
US8968807B1 (en) 2013-09-24 2015-03-03 Zinpro Corporation Use of ethylene diamine metal complexes to deliver highly absorbable metals for animal nutrition
US9669056B2 (en) 2014-05-16 2017-06-06 Micronutrients Usa Llc Micronutrient supplement made from copper metal
CN110117241A (zh) * 2019-06-12 2019-08-13 禄丰天宝磷化工有限公司 一种清洁环保的α-氨基酸络合金属盐的生产方法及其装置
CN110143899A (zh) * 2019-06-12 2019-08-20 禄丰天宝磷化工有限公司 一种清洁环保的蛋氨酸络合金属盐的生产方法和装置
CN115260068A (zh) * 2022-07-20 2022-11-01 天宝动物营养科技股份有限公司 以羟基蛋氨酸为片基的二价金属共盐化合物及其制备方法与应用

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3463858A (en) * 1965-05-06 1969-08-26 Dean R Anderson Organic zinc feed additive and method of making same
US3647834A (en) * 1969-08-11 1972-03-07 Mead Johnson & Co Zinc mercaptide n-acetylcysteine carboxylate salts
US4039681A (en) * 1973-08-20 1977-08-02 Zinpro Corporation Zinc methionine complex for acne treatment
US3941818A (en) * 1973-08-20 1976-03-02 Zinpro Corporation 1:1 Zinc methionine complexes
US4021569A (en) * 1973-08-20 1977-05-03 Zinpro Corporation Method of nutritional supplementation for zinc and methionine by ingesting 1:1 zinc methionine complexes
US3925433A (en) * 1973-09-10 1975-12-09 Zinpro Corp 1:1 And 2:1 chromium, alpha amino acid complex salts
US3950372A (en) * 1974-07-03 1976-04-13 Zinpro Corporation 1:1 Manganese alpha amino acid complexes
US4067984A (en) * 1975-11-05 1978-01-10 Smith Kline & French Laboratories Limited Pyridylbutylamino ethylene compounds
US4067994A (en) * 1976-03-26 1978-01-10 Zinpro Corporation Iron methionine complex salts
US4216143A (en) * 1977-10-20 1980-08-05 Ashmead H H Soluble non-ferrous metal proteinates
US4172072A (en) * 1977-10-20 1979-10-23 Ashmead H H Buffered enzymatically produced metal proteinates
DE3230292C2 (de) * 1982-08-14 1986-12-18 Lohmann Tierernährung GmbH, 2190 Cuxhaven Teilchenförmiges Futterzusatzmittel für Wiederkäuer und Verfahren zu seiner Herstellung
US4670269A (en) * 1985-06-26 1987-06-02 Zinpro Corporation Cobalt complexes and their use as nutritional supplements
US4678854A (en) * 1986-11-25 1987-07-07 Zinpro Corporation Cobalt complexes and their use as nutritional supplements
US4764633A (en) * 1987-08-31 1988-08-16 Zinpro Corporation Ferric ion catalyzed complexation of zinc and/or manganese with alpha amino acids
US5061815A (en) * 1988-07-06 1991-10-29 Zinpro Corporation Metal lysine complexes and method for producing metal lysine complexes
US4956188A (en) * 1988-10-20 1990-09-11 Zinpro Corporation Copper complexes with alpha hydroxy organic acids and their use as nutritional supplements
US4900561A (en) * 1989-01-03 1990-02-13 Zinpro Corporation Copper complexes of alpha-amino acids that contain terminal amino groups, and their use as nutritional supplements
US4948594A (en) * 1989-01-03 1990-08-14 Zinpro Corporation Copper complexes of alpha-amino acids that contain terminal amino groups, and their use as nutritional supplements

Also Published As

Publication number Publication date
EP0556498A2 (en) 1993-08-25
GR3018385T3 (en) 1996-03-31
ES2081052T3 (es) 1996-02-16
DE69204821T2 (de) 1996-05-23
EP0556498B1 (en) 1995-09-13
DE69204821D1 (de) 1995-10-19
KR950013575B1 (ko) 1995-11-09
US5278329A (en) 1994-01-11
JP2521215B2 (ja) 1996-08-07
CA2068784A1 (en) 1993-08-22
DK0556498T3 (da) 1996-02-05
CA2068784C (en) 1996-08-20
JPH06287173A (ja) 1994-10-11
ATE127786T1 (de) 1995-09-15
AU1715392A (en) 1993-08-26
AU650138B2 (en) 1994-06-09
EP0556498A3 (en) 1993-09-08

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