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KR930016432A - 시클로알킬리덴 비스페놀 포스파이트 및 그의 제조방법 - Google Patents

시클로알킬리덴 비스페놀 포스파이트 및 그의 제조방법 Download PDF

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Publication number
KR930016432A
KR930016432A KR1019930000853A KR930000853A KR930016432A KR 930016432 A KR930016432 A KR 930016432A KR 1019930000853 A KR1019930000853 A KR 1019930000853A KR 930000853 A KR930000853 A KR 930000853A KR 930016432 A KR930016432 A KR 930016432A
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South Korea
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compound
hydrogen
composition
formula
alkyl
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KR1019930000853A
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English (en)
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네스바드바 피터
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베르너 발데크
시바 가이기 아게
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Publication of KR930016432A publication Critical patent/KR930016432A/ko

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
    • C07F9/6574—Esters of oxyacids of phosphorus
    • C07F9/65748—Esters of oxyacids of phosphorus the cyclic phosphorus atom belonging to more than one ring system
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
    • C07F9/6574—Esters of oxyacids of phosphorus
    • C07F9/65746—Esters of oxyacids of phosphorus the molecule containing more than one cyclic phosphorus atom
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/52—Phosphorus bound to oxygen only
    • C08K5/527—Cyclic esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/06—Polyethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/12—Polypropene

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Anti-Oxidant Or Stabilizer Compositions (AREA)

Abstract

본 발명은, 열, 산화 또는 광유발로 인한 분해로부터 유기 물질을 보호하기 위한 안정화제로서 유용한 하기 일반식(Ⅰ)의 신규 화합물을 제공한다.
상기 식에서, n은 0.1 또는 2이고 R 및 R1은 독립적으로 C1-C4알킬 또는 함께 결합되어 형성된 2,3-디히드로펜타메틸렌 라디칼이며, R2및 R3는 독립적으로 수소, C1-C4알킬 또는 C5-C6시클로알킬 그리고 R4, R5, R6및 R7는, n이 1인 경우, 독립적으로 수소, 또는 C1-C4알킬이며, n이 0 및 2인 경우 수소이다.

Description

시클로알킬리덴 비스페놀 포스파이트 및 그의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (18)

  1. 하기 일반식(Ⅰ)의 화합물,
    상기 식에서, n은 0,1 또는 2이고 R 및 R1은 독립적으로 C1-C4알킬 또는 함께 결합되어 형성된 2,3-디히드로펜타메틸렌 라디칼이며, R2및 R3는 독립적으로 수소 또는 C5-C4알킬 또는 C1-C6시클로알킬 그리고, R4, R5및 R7는 n이 1인 경우, 독립적으로 수소, 또는 C1-C4알킬이며, n이 0 및 2인 경우 수소이다.
  2. 제1항에 있어서 n이 1 또는 2인 화합물.
  3. 제1항에 있어서 R2및 R3가 독립적으로 수소 C1-C4알킬 또는 시클로헥실인 화합물.
  4. 제1항에 있어서 n이 1인 화합물.
  5. 제1항에 있어서 n이 1이며 R4가 수소이고, R5, R6및 R7이 독립적으로 수소 또는 메틸인 화합물.
  6. 제1항에 있어서 R2및 R3가 독립적으로 수소, 메탈, 부틸 또는 시클로헥실인 화합물.
  7. 제1항에 있어서, R2및 R3가 독립적으로 수소, 메틸 또는 3차 부틸인 화합물.
  8. 제1항에 있어서, R5, R6및 R7이 수소이며 R4가 수소 또는 3차부틸인 화합물.
  9. 제1항에 있어서, R4, R5, R6및 R7이 수소인 화합물.
  10. 제1항에 있어서, R 및 R1이 독립적으로 메틸은 부틸이거나, 함께 결합되어 형성된 2,3-디히드로펜타메틸렌 라디칼인 화합물.
  11. 산화, 열 및 광-유발 분해에 민감한 유기 물질(a) 및 제1항에 따른 일반식(Ⅰ)의 화합물 1개 이상(b)을 포함하는 조성물.
  12. 제11항에 있어서, 성분(a)가 천연, 반-합성 또는 합성 중합체인 조성물.
  13. 제11항에 있어서, 성분(a)가 열가소성 중합체인 조성물.
  14. 제11항에 있어서, 성분(a)가 폴리올레핀 또는 폴리비닐 클로라이드인 조성물.
  15. 제11항에 있어서, 성분(a)가 폴리에틸렌 또는 포릴프로필렌인 조성물.
  16. 제11항에 있어서, 성분(a) 및 (b)이외에도 산화 방지제, 광안정화제 또는 공정 안정화제를 포함하는 조성물.
  17. 안정화제로서 일반식(Ⅰ)화합물 1개 이상을 유기 물질에 혼입 또는 도포하여 산화, 열 및 광유발 분해로부터 유기 물질을 보호하는 방법.
  18. 하기 일반(Ⅱ)의 화합물을 하기 일반식(Ⅲa)의 시클릭 클로로포스파이트와 반응시켜 일반식(Ⅰ)의 화합물을 제조하는 방법.
    상기 식에서, 치환체 R, R1, R2, R3, R4, R5, R6, R7과 n은 제1항에서 정의한 바와 같다.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019930000853A 1992-01-21 1993-01-21 시클로알킬리덴 비스페놀 포스파이트 및 그의 제조방법 KR930016432A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CH92-0/149 1992-01-21
CH14992 1992-01-21

Publications (1)

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KR930016432A true KR930016432A (ko) 1993-08-26

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Country Link
US (1) US5280057A (ko)
EP (1) EP0553059B1 (ko)
JP (1) JPH0625271A (ko)
KR (1) KR930016432A (ko)
CN (1) CN1075968A (ko)
AT (1) ATE143966T1 (ko)
AU (1) AU656255B2 (ko)
BR (1) BR9300218A (ko)
CA (1) CA2087582A1 (ko)
CZ (1) CZ5093A3 (ko)
DE (1) DE59304064D1 (ko)
ES (1) ES2095025T3 (ko)
MX (1) MX9207621A (ko)
SK (1) SK1393A3 (ko)
TW (1) TW260688B (ko)
ZA (1) ZA93380B (ko)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6140432A (en) * 1995-07-13 2000-10-31 Exxon Chemical Patents Inc. Polymerization catalyst systems, their production and use
US6124230A (en) * 1995-07-13 2000-09-26 Exxon Chemical Patents, Inc. Polymerization catalyst systems, their production and use
TW338046B (en) * 1995-06-29 1998-08-11 Ciba Sc Holding Ag Process for the preparation of stabilized olefin polymers
US5594053A (en) * 1996-01-22 1997-01-14 General Electric Company Aromatic cyclic bisphosphite esters and polymeric compositions thereof
US8142864B2 (en) * 2007-01-25 2012-03-27 Konica Minolta Opto, Inc. Cellulose ester pellets, cellulose ester film, manufacturing method of cellulose ester film, polarizing plate, and liquid crystal display
US8466096B2 (en) * 2007-04-26 2013-06-18 Afton Chemical Corporation 1,3,2-dioxaphosphorinane, 2-sulfide derivatives for use as anti-wear additives in lubricant compositions

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US2883365A (en) * 1955-03-01 1959-04-21 Goodrich Co B F Sulfur vulcanizable rubber and 1,1-bis(4-hydroxy phenyl) cycloalkane
US2894004A (en) * 1956-08-13 1959-07-07 Dow Chemical Co Bisphenols
US3039993A (en) * 1960-05-10 1962-06-19 Weston Chemical Corp Polyethylene stabilizers
DE1237312B (de) * 1961-06-27 1967-03-23 Pure Chem Ltd Formmassen aus Polymerisaten von Olefinen
FR1384809A (fr) * 1963-11-28 1965-01-08 Kuhlmann Ets Nouveaux esters phosphoreux, procédé pour leur fabrication et applications desdits esters
US3467733A (en) * 1965-11-26 1969-09-16 Hooker Chemical Corp Cyclic esters of phosphorus and a process for the preparation thereof
US3441633A (en) * 1965-12-03 1969-04-29 Weston Chemical Corp Cyclic phosphites
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US3856728A (en) * 1971-04-26 1974-12-24 Argus Chem Acrylonitrile-butadiene-styrene polymers having improved resistance to discoloration
US4206111A (en) * 1977-05-06 1980-06-03 Borg-Warner Corporation Stabilized polyolefins
GB2042562B (en) * 1979-02-05 1983-05-11 Sandoz Ltd Stabilising polymers
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JPS5692934A (en) * 1979-12-26 1981-07-28 Adeka Argus Chem Co Ltd Synthetic resin composition
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ATE143966T1 (de) 1996-10-15
CN1075968A (zh) 1993-09-08
AU656255B2 (en) 1995-01-27
SK1393A3 (en) 1993-09-09
DE59304064D1 (de) 1996-11-14
US5280057A (en) 1994-01-18
ZA93380B (en) 1993-07-21
TW260688B (ko) 1995-10-21
EP0553059B1 (de) 1996-10-09
ES2095025T3 (es) 1997-02-01
EP0553059A1 (de) 1993-07-28
CA2087582A1 (en) 1993-07-22
AU3184193A (en) 1993-07-22
MX9207621A (es) 1993-07-01
BR9300218A (pt) 1993-07-27
JPH0625271A (ja) 1994-02-01
CZ5093A3 (en) 1993-10-13

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