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KR930012941A - Process for preparing conductive polymer composition - Google Patents

Process for preparing conductive polymer composition Download PDF

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Publication number
KR930012941A
KR930012941A KR1019910022232A KR910022232A KR930012941A KR 930012941 A KR930012941 A KR 930012941A KR 1019910022232 A KR1019910022232 A KR 1019910022232A KR 910022232 A KR910022232 A KR 910022232A KR 930012941 A KR930012941 A KR 930012941A
Authority
KR
South Korea
Prior art keywords
carbon black
polymer
ethylene
vinylidene fluoride
polymer composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
KR1019910022232A
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Korean (ko)
Inventor
이정창
임화준
이병천
정원훈
Original Assignee
박원근
금성전선 주식회사
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 박원근, 금성전선 주식회사 filed Critical 박원근
Priority to KR1019910022232A priority Critical patent/KR930012941A/en
Publication of KR930012941A publication Critical patent/KR930012941A/en
Ceased legal-status Critical Current

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  • Processes Of Treating Macromolecular Substances (AREA)

Abstract

본 발명은 양의 온도계수를 가지는 전도성 중합체 조성물에 있어서 보다 균일한 양의 온도계수 특성을 가질수 있는 전도성 중합체 조성물의 제조방법에 관한 것으로서, 먼저 에틸렌/아크릴산 공중합체 또는 에틸렌/에틸 아크릴레이트 공중합체 또는 에틸렌/비닐 아세테이트 또는 불화 비니리덴-헥사 플루오로 프로필렌 고무상 중합체 또는 불화 비닐리덴-헥사 플루오로 프로필렌-텐트라 플루오로 에틸렌 고무상 중합체등의 비결정성 고분자 공중합체 100중량부에 카본 블랙 30 내지 80중량부를 밴버리식 혼합기에서 혼합하여 카본 블랙 마스터 배치를 만드는 단계와, 상기의 카본 블랙 마스터 배치에 최종적으로 원하는 카본 블랙양이 되도록 폴리에티렌 또는 불화 비닐리덴등의 결정성 고분자를 넣어 혼합하여 최종적으로 양의 온도계수 특성을 지니는 전도성 고분자 중합체 조성물을 만드는 단계로 이루어진다.The present invention relates to a method for preparing a conductive polymer composition which may have a more uniform amount of temperature coefficient properties in a conductive polymer composition having a positive temperature coefficient, and firstly, an ethylene / acrylic acid copolymer or an ethylene / ethyl acrylate copolymer or Carbon black 30 to 80 in 100 parts by weight of an amorphous polymer copolymer such as ethylene / vinyl acetate or vinylidene fluoride-hexafluoropropylene rubbery polymer or vinylidene fluoride-hexafluoropropylene-tentrafluoroethylene rubbery polymer Mixing the parts by weight in a banbury mixer to form a carbon black masterbatch, and finally adding a crystalline polymer such as polystyrene or vinylidene fluoride to the carbon black masterbatch so as to finally have a desired amount of carbon black. With positive temperature coefficient characteristics Conducting a step to make the polymer composition.

Description

전선절연 수지 조성물Wire Insulation Resin Composition

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음As this is a public information case, the full text was not included.

도면은 양의 온도계수(PTC)특성을 가지는 전도성 고분자 재료의 온도, 저항 관계를 나타내는 그래프이다.The figure is a graph which shows the temperature and resistance relationship of the conductive polymer material which has a positive temperature coefficient (PTC) characteristic.

Claims (1)

폴리에틸렌(PE) 또는 비닐리덴(PVdF)등의 결정성 고분자에 전도성 충진제(카본블랙)을 넣어 양의 온도계수 특성을 가지는 전도성 중합체 조성물을 제조하는데 있어서, 먼저 에틸렌/아크릴산 공중합체 또는 에틸렌/에틸 아크릴레이트 공중합체 또는 에틸렌/비닐 아세테이트 또는 불화 비닐리덴-헥사 플루오로 프로필렌 고무상 중합체 또는 불화 비닐리덴-헥사 플루오로 프로필렌-테트라 플루오로 에틸렌 고무상 중합체등의 비결정성 고분자 공중합체 100중량부에 카본 블랙 30 내지 80중량를 밴버리식 혼합기에서 혼합하여 카본 블랙 마스터 배치를 만드는 단계와, 상기의 마스터 배치에 최종적으로 원하는 카본 블랙양이 되도록 폴리에틸렌 또는 불화 비닐리덴등의 결정성 고분자를 넣어 혼합하여, 최종적으로 양의 온도계수 특성을 지니는 전도성 고분자 중합체 조성물을 만드는 단계로 이루어지는 전도성 중합체 조성물의 제조방법.In preparing a conductive polymer composition having positive temperature coefficient characteristics by adding a conductive filler (carbon black) to a crystalline polymer such as polyethylene (PE) or vinylidene (PVdF), firstly, an ethylene / acrylic acid copolymer or ethylene / ethyl acryl Carbon black to 100 parts by weight of an amorphous polymer such as a late copolymer or ethylene / vinyl acetate or vinylidene fluoride-hexafluoropropylene rubbery polymer or vinylidene fluoride-hexafluoropropylene-tetrafluoroethylene rubbery polymer Mixing 30 to 80 weights in a Banbury mixer to form a carbon black master batch, and adding a crystalline polymer such as polyethylene or vinylidene fluoride to the master batch so as to finally have a desired amount of carbon black, and finally mixing Of conductive polymers with temperature coefficient of A method of making a conductive polymer composition, comprising the step of making a coalescing composition. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019910022232A 1991-12-05 1991-12-05 Process for preparing conductive polymer composition Ceased KR930012941A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
KR1019910022232A KR930012941A (en) 1991-12-05 1991-12-05 Process for preparing conductive polymer composition

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1019910022232A KR930012941A (en) 1991-12-05 1991-12-05 Process for preparing conductive polymer composition

Publications (1)

Publication Number Publication Date
KR930012941A true KR930012941A (en) 1993-07-21

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KR1019910022232A Ceased KR930012941A (en) 1991-12-05 1991-12-05 Process for preparing conductive polymer composition

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KR (1) KR930012941A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001064785A1 (en) * 2000-03-02 2001-09-07 Ko, Chang-Mo Ptc conductive polymer compositions, method of controlling the same and electrical device containing the same
KR100340379B1 (en) * 1999-09-09 2002-06-12 유성종 method for producting a conductive polymer composite
KR100485132B1 (en) * 2002-02-15 2005-04-25 전병민 a manufacture method of carbon coating fiber
KR101480009B1 (en) * 2013-05-16 2015-01-07 고려대학교 산학협력단 Semi-conductive compound for ultra-high voltage power cables and ultra-high voltage power cables using thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100340379B1 (en) * 1999-09-09 2002-06-12 유성종 method for producting a conductive polymer composite
WO2001064785A1 (en) * 2000-03-02 2001-09-07 Ko, Chang-Mo Ptc conductive polymer compositions, method of controlling the same and electrical device containing the same
KR100485132B1 (en) * 2002-02-15 2005-04-25 전병민 a manufacture method of carbon coating fiber
KR101480009B1 (en) * 2013-05-16 2015-01-07 고려대학교 산학협력단 Semi-conductive compound for ultra-high voltage power cables and ultra-high voltage power cables using thereof

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Legal Events

Date Code Title Description
A201 Request for examination
PA0109 Patent application

Patent event code: PA01091R01D

Comment text: Patent Application

Patent event date: 19911205

PA0201 Request for examination

Patent event code: PA02012R01D

Patent event date: 19911205

Comment text: Request for Examination of Application

PG1501 Laying open of application
E902 Notification of reason for refusal
PE0902 Notice of grounds for rejection

Comment text: Notification of reason for refusal

Patent event date: 19950620

Patent event code: PE09021S01D

E601 Decision to refuse application
PE0601 Decision on rejection of patent

Patent event date: 19951130

Comment text: Decision to Refuse Application

Patent event code: PE06012S01D

Patent event date: 19950620

Comment text: Notification of reason for refusal

Patent event code: PE06011S01I