KR930002265B1 - Deodorant Composition - Google Patents

Abstract

No content.

Description

Deodorant Composition

1 is a chart showing the deodorization rate of ammonia and the rate of inhibition of ammonia production with respect to the mixing ratio of flavonoids and panesol,

2 is a chart showing the hydrogen sulfide deodorization rate and hydrogen sulfide generation inhibition rate with respect to the mixture ratio of flavonoids and panesol,

FIG. 3 is a graph showing methyl mercaptan deodorization rate and methyl mercaptan production inhibition rate with respect to the mixing ratio of flavonoids and panesol.

The present invention relates to a deodorant composition, and more particularly, to a deodorant composition having excellent effect of preventing odor occurrence and removing odor generated by containing flavonoids and panezol which are plant extracts in a known deodorant composition.

Generally, deodorant is classified into human deodorant and environmental deodorant. Human deodorant refers to a product that removes or prevents all odors generated from the human body such as foot smell, odor, sweat smell, and the like. It refers to a product that removes or prevents all odors except odors. It can be used in various forms such as aerosol type, pump type, roll-on type, stick type, powder type, granule type, liquid type and gel type. have.

Deodorants can be classified into four main principles to eliminate odors:

(1) Physical deodorization method: A method of removing odor by ventilation or diffusion, or by adsorbing odor using porous materials such as activated carbon, zeolite, silica gel, and the like.

(2) Sensory deodorization method: A method of blocking odor by aromatic substances (fragrances).

(3) Chemical deodorization method: A method in which a deodorant is chemically reacted with a malodorous component to be odorless by neutralization reaction, addition reaction, and condensation reaction.

(4) Biological deodorization method: Method of fundamentally preventing the cause of odor, such as sterilizing bacteria or bacteria causing odor occurrence or preventing corruption.

The physical deodorization method of (1) of the above deodorization method is one of widely used deodorization method, which may be effective in a narrow space such as a refrigerator, but is ineffective in a large space, and the sensory deodorization method of (2) is used in general households. It is a method commonly used to block odor by fragrance of deodorant itself, but it is difficult to maintain balance between fragrance and odor by this deodorization method. It is not preferable to use. In addition, the chemical deodorization method of (3) can be effectively used for odor components, but there are inconveniences that require careful handling depending on the drug used, and the biological deodorization method of (4) has a very expected effect after the odor is generated. All four deodorants have not been able to provide a perfect deodorant, so deodorants have been selected and applied according to the purpose or place of use.

In order to overcome this limited usability, various studies on the main components of the deodorant have been conducted. Among them, the representative results of the study are to apply the plant extract as the deodorant. The application of plant extracts as a deodorant is generally preferred because of its low toxicity to humans and livestock. However, although it is rare to have both deodorant and odor generating inhibitory at the same time, the effect is so weak that it can exert both effects simultaneously. Deodorant could not be provided.

In Japanese Patent Laid-Open No. 86-8055, it is stated that deodorizing various odors such as ammonia, amines, and mercaptans by using flavonoids extracted from plants alone can be expected. It did not provide excellent sterilizing and antimicrobial activity against the decaying bacteria and bacteria, which could not provide a product that satisfies both the deodorizing effect and the odor generating effect at the same time.

Therefore, deodorant composition which has excellent deodorizing ability against odor already generated by using plant extract which is less toxic to human body and livestock and sterilizes and sterilizes decaying bacteria and bacteria which is the root cause of odor generation. This has been expected.

Accordingly, the present invention has been repeatedly studied to solve the problems of the prior art deodorant products prepared by combining them with each other synergistically when the flavonoid (Flavonoid) and farnesol (Farnesol) is added to the known deodorant composition at the same time The present invention was completed by finding that the deodorizing power of the odor and the ability to suppress odor production were excellent.

An object of the present invention is to provide a deodorant composition which is remarkably excellent in deodorizing power and odor production inhibition by simultaneously adding the plant extracts flavonoids and panazole in the known deodorant composition.

Hereinafter, the present invention will be described in detail.

The present invention relates to a deodorant composition characterized by simultaneously containing a flavonoid and panazole in a known deodorant composition.

Deodorant prepared by simultaneously adding flavonoids and panesol as in the present invention, sterilizes the decaying bacteria and bacteria due to the strong antimicrobial activity of plant essential oils panesol suppresses the generation of odors, the flavonoids are added to the odor components already generated It is an excellent deodorant composition that not only removes malodorous components by reaction, polymerization and neutralization but also adds flavonoids and panesol simultaneously.

If the amount of the main components of the deodorant, that is, the total amount of flavonoids and panesol is less than 1% by weight of the total composition, there is a disadvantage in that the effect of inhibiting the production of unpleasant odors (ammonia, hydrogen sulfide, methyl mercaptan) is insufficient, If the percentage exceeds the odor of the main component (flavonoids + panesol) itself acts as an unpleasant odor of the product, there is a disadvantage that the product usability is not good, so the content of the preferred main component is 1% to 30% by weight of the total content of the deodorant.

Panerazole (3,7,11-trimethyldodeca-2,6,10-trienol), which is a natural plant essential oil used in the present invention, is represented by the following structural formula (I).

Flavonoids, which are plant extracts used in the present invention, are derivatives of flavones having a skeleton represented by the following structural formula (II) and the flavonoids are mainly composed of the derivatives shown in Table 1.

TABLE 1

* Flavonoid derivatives

R: rhamnoside

RG: rhamnoglucoside

The flavonoids and panesol used in the present invention may be dispersed in alcohol or purified water and used in liquid form or mixed with powder form and added to the deodorant in the form of powder to make various products. Various types of products are also included within the scope of the present invention.

Hereinafter, the present invention will be described in more detail with reference to Examples.

[Examples 1 to 9 and Comparative Examples 1 to 3]

Examples 1 to 9 and Comparative Examples 1 to 3 relate to the composition ratio of each component of the deodorant composition for testing the deodorizing effect and the odor generating inhibitory effect of various odors, which is composed of ethanol, propylene glycol, purified water, perfume, etc. The deodorant composition was referred to as Comparative Example 1, and the deodorant composition of Comparative Example 1 contained only 10% by weight of flavonoids, and Comparative Example 2, containing only 10% by weight of panesol, was referred to as Comparative Example 3 and the weight ratio of the composition of Comparative Example 1 9: 1, 8: 2, 7: 3, 6: 4, 5: 5, 4: 6, 3: 7, 2: 8, 1: 9 Add the plant extract flavonoids and panazole to add a common deodorant The deodorant composition prepared according to the preparation method was called Examples 1 to 9, and the composition ratio of each component is shown in Table 2.

Odor production inhibition experiment and the deodorant effect test method performed in the present invention is as follows.

[Smell generation experiment]

Put 20 g of decaying fish and eggs in a sealed glass box and measure the concentrations of ammonia, hydrogen sulfide, and methyl mercaptan in the glass box. 2 g of each of the deodorant compositions of Examples 1 to 9 and Comparative Examples 1 to 3 were put into a glass box, and after 1 hour, the concentrations of ammonia, hydrogen sulfide, and methyl mercaptan were measured to administer the composition of Comparative Example 1. The concentrations of ammonia, hydrogen sulfide, and methyl mercaptan in the glass box were converted to 100, respectively, and the relative odor production inhibition of the deodorants was measured, and the results are shown in Tables 3 to 5 and FIGS. 1 to 3.

[Deodorant deodorant effect experiment]

In a sealed glass box, a standard preparation of ammonia, hydrogen sulfide, and methyl mercaptan, respectively, is made to be 200 ppm, which is a control against deodorant addition. 2 g of each of the deodorant compositions of Examples 1 to 9 and Comparative Examples 1 to 3 were put into each sealed glass box, and after 1 hour, the concentrations of ammonia, hydrogen sulfide and methyl mercaptan were measured by gas detection method. The calculated results are shown in Tables 6 to 8 and FIGS. 1 to 3.

TABLE 2

TABLE 3

* Ammonia production inhibitory effect

TABLE 4

* Hydrogen sulfide production inhibitory effect.

TABLE 5

* Methyl mercaptan production inhibitory effect.

TABLE 6

* Ammonia deodorant effect.

TABLE 7

* Hydrogen sulfide deodorant effect.

TABLE 8

* Methyl mercaptan deodorant effect

Examples 1 to 9 and Comparative Examples 1 to 3 used in the present invention from the results of Table 3 to Table 8 and FIGS. 1 to 3 showing the odor generating inhibition and deodorizing effects for each of ammonia, hydrogen sulfide and methyl mercaptan It was confirmed that the deodorant composition containing both flavonoids and panazoles was more excellent in synergic odor removal and odor generation than in the case of using flavonoids or panazoles alone.

[Examples 10 to 12 and Comparative Examples 4 to 5]

Examples 10 to 12 and Comparative Examples 4 to 5 relate to the odor generating inhibitory effect and the deodorizing effect on the total content of the main component (panezol + furanoid) in the total composition of the deodorant. Examples 10 to 12 and Comparative Examples 4 to 5 were prepared in the same manner as in Example 5 except for the composition ratios shown in Table 9.

The inhibitory effect of the production of ammonia, hydrogen sulfide and methyl mercaptan was calculated in the same manner as in the examples and the comparative examples, and the inhibition rate of unpleasant production was calculated. The usability was determined according to the criteria of the following judgment. Indicated.

TABLE 9

TABLE 10

[Judgement of Usability Symptoms]

[++]: The smell of the main ingredient itself can not be recognized at all.

[+]: The smell of the main ingredient itself can be recognized.

[±]: strong smell of the main ingredient itself.

[-]: The smell of the main ingredient itself acts as an unpleasant odor.

From Table 10 showing the results of Examples 10 to 12 and Comparative Examples 4 to 5, the main component (flavonoid + panazole) is less than 0.1% by weight of the total composition of the deodorant, but the usability is excellent, but production of ammonia, hydrogen sulfide and methyl mercaptan When the inhibition rate is extremely low, the function as a deodorant cannot be fulfilled, and if the main component exceeds 30% by weight of the total composition of the deodorant, the unpleasant generation inhibition rate is excellent, but the main component itself acts as a deodorant, and thus the usability is extremely poor. Therefore, the main component (flavonoid + panazole) can be used as a deodorant composition exhibiting excellent deodorizing function when contained in 1 to 30% by weight of the total composition of the deodorant.

Therefore, the deodorant composition of the present invention, as shown in the results of the Examples 1 to 12 and Comparative Examples 1 to 5, when used simultaneously mixed with the flavonoids and panesol, hypoallergenic plant extract, regardless of the mixing ratio It is possible to fundamentally suppress the development of unpleasant odor by inhibiting the growth of bacteria, and also, as a deodorant composition having excellent synergistic effect when mixed and used simultaneously with the flavonoids or panesol, respectively, even for the unpleasant odors that have already occurred. It was possible to provide a deodorant composition having excellent usability when the main component (flavonoid + panazole) was 1 to 30% by weight of the total deodorant composition regardless of the mixing ratio.

Claims (2)

A deodorant composition characterized by simultaneously containing a panelazole represented by the following structural formula (I) and a flavonoid represented by the structural formula (II). Wherein R ₁ is —OH or —H, R ₂ is —OH or —OCH ₃ , R ₃ is —OH or —OR or ORG, R ₄ is free of functional groups, or is —H or —OH , R is rhamnoside and RG is rhamnoglucoside. The deodorant composition according to claim 1, wherein the panezol and flavonoid content is 1 to 30% by weight of the total composition of the deodorant.