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KR920701348A - 플루오로카본 탄성체 및 비닐리덴 불화물로 구성된 압출 가공 조제를 함유하는 중합체 조성물 - Google Patents

플루오로카본 탄성체 및 비닐리덴 불화물로 구성된 압출 가공 조제를 함유하는 중합체 조성물

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KR920701348A
KR920701348A KR1019910700377A KR910700377A KR920701348A KR 920701348 A KR920701348 A KR 920701348A KR 1019910700377 A KR1019910700377 A KR 1019910700377A KR 910700377 A KR910700377 A KR 910700377A KR 920701348 A KR920701348 A KR 920701348A
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vinylidene fluoride
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KR950006266B1 (ko
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리챠드 채프만 쥬니어 조오지
에드윈 프리스터 도난
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제임즈 제이 플린
이 아이 듀우판 디 네모아 앤드 캄파니
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C08L27/18—Homopolymers or copolymers or tetrafluoroethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
    • C08L23/0815—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C08L27/16—Homopolymers or copolymers or vinylidene fluoride

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)

Abstract

내용 없음

Description

플루오로카본 탄성체 및 비닐리덴 불화물로 구성된 압출 가공 조제를 함유하는 중합체 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (30)

  1. (a)난이하게-용융-가공성 탄화수소 중합체의 주 부분; 및 (b)(1)가공성을 개선하기 위한, 적어도 효과적인 양의 탄성 플루오로카본 공중합체 및 (2)가공성을 개선하기 위한, 적어도 효과적인 양의 결정성 비닐리덴 불화물 중합체의 부 부분으로 구성되고 개선된 가공성을 갖는 중합체 블렌드 조성물.
  2. 제1항에 있어서, 중합체(a)가 R이 H 또는 알킬인 일반식 RCH=CH2의 하나이상의 모노올레핀의 단독중합체 또는 공중합체인 조성물.
  3. 제2항에 있어서, 알킬이 C1-8알킬인 조성물.
  4. 제1항에 있어서, 중합체(a)가 고밀도 폴리에틸렌인 조성물.
  5. 제1항에 있어서, 중합체(a)가 저 밀도 폴리에틸렌인 조성물.
  6. 제1항에 있어서, 중합체(a)가 선형 저 밀도 폴리에틸렌 공중합체인 조성물.
  7. 제1항에 있어서, 중합체(a)가 에틸렌, 프로필렌 및 비-공역 디엔의 중합체 반복단위로 구성된 공중합체인 조성물.
  8. 제1항 또는 제2항에 있어서, (b)(1)의 양이 (a)의 중량을 기준으로, 단지 0.5중량%인 조성물.
  9. 제1항 또는 제2항에 있어서, (b)(1)의 양이 (a)의 중량을 기준으로, 0.002-0.08중량%인 조성물.
  10. 제1항 또는 제2항에 있어서, (b)(2)의 양이 (a)의 중량을 기준으로, 0.002-0.08중량%인 조성물.
  11. 제1항 또는 제2항에 있어서, 성분(b)(1)에 있어서, 불소 대다수의 몰비가 적어도 1:1.5인 조성물.
  12. 제1항 또는 제2항에 있어서, 성분(b)(1)이 비닐리덴불화물, 헥사플루오로프로필렌, 클로로트리플루오로에틸렌, 테트라플루오로에틸렌 및 퍼플루오로알킬 퍼플루오로비닐에테르로 부터 선택된 단량체의 플루오로카본 공중합체인 조성물.
  13. 제1항 또는 제2항에 있어서, 성분(b)(1)이 헥사플루오로프로필렌, 클로로트리플루오로에틸렌, 1-히드로펜타 플루오로프로필렌 및 2-히드로펜타플루오로프로필렌으로 부터 선택된 단량체 및 비닐리덴 불화물의 공중합체인 조성물.
  14. 제1항 또는 제2항에 있어서, 성분(b)(1)이 비닐리덴불화물, 테트라플루오로에틸렌, 및 헥사플루오로 프로필렌 또는 1-또는 2-히드로펜타플루오로프로필렌의 삼원공중합체인 조성물.
  15. 제1항 또는 제2항에 있어서, 성분(b)(1)이 테트라플루오로 에틸렌 및 프로필렌, 및 임의로 비닐리덴불화물의 공중합체인 조성물.
  16. 제1항 또는 제2항에 있어서, 성분(b)(1)대 성분(b)(2)의 중량비가 10:90 내지 90:10 범위내인 조성물.
  17. 제1항 또는 제2항에 있어서, 성분(b)(1)대 성분(b)(2)의 중량비가 20:80 내지 80:20 범위내인 조성물.
  18. 제1항 또는 제2항에 있어서, (b)(2)가 비닐리덴 불화물 및 헥사플루오로프로필렌의 공중합체인 조성물.
  19. 제1항에 있어서, (a)가 선형 저 밀도 폴리에틸렌 중합체이고, (b)(1)이 적어도 10,000의 분자량을 갖고 45-90:5-15:0-35의 몰비로 비닐리덴 불화물, 헥사플루오로프로필렌 및 테트라플루오로에틸렌의 공중합된 단위로 구성되고, (b)(2)가 비닐리덴 불화물의 단독 중합체이며, (b)(1):(b)(2)의 중량비가 10:90 내지 90:10인 조성물.
  20. 제1항에 있어서, (a)가 선형 저 밀도 폴리에틸렌 중합체이고, (b)(1)이 적어도 10,000의 분자량을 갖고 45-90:5-50:0-35의 몰비로 비닐리덴 불화물, 헥사플루오로프로필렌 및 테트라플루오로에틸렌의 공중합된 단위로 구성되고, (b)(2)가 비닐리덴 불화물 및 헥사플루오로프로필렌의 결정성 공중합체이며, (b)(1):(b)(2)의 중량비가 10:90 내지 90:10인 조성물.
  21. (a)10-90 중량부의 탄성 플루오로카본 공중합체 및 (b)90-10 중량부의 결정성 비닐리덴 불화물 중합체로 구성된 가공조제의, 총 100부로 가공성을 개선하기 위해, 효과적인 양을 그안에 혼합한 난이하게 용융-가공성 탄화수소 중합체를 용융압출시키는 것으로 구성되는 압출법.
  22. 제21항에 있어서, 난이-용융-가공성 중합체가 R이 H 또는 알킬인 일반식 RCH-CH2의 하나이상의 모노올레핀의 단독중합체 또는 공중합체인 방법.
  23. 제21항 또는 제22항에 있어서, 성분(a)에 있어서 불소 대 수소의 몰비가 적어도 1:1.5인 방법.
  24. 제21항 또는 제22항에 있어서, 성분(a)가 비닐리덴 불화물, 헥사플루오로프로필렌, 클로로트리플루오로에틸렌, 테트라플루오로 에틸렌 및 퍼플루오로알킬 퍼플루오로비닐 에테르로 부터 선택된 단량체의 플루오로카본 공중합체인 방법.
  25. 제21항 또는 제22항에 있어서, 성분(a)가 헥사 플루오로프로필렌, 클로로트리플루오로 에틸렌, 1-히드로펜타 플루오로프로필렌 및 2-히드로펜타플루오로프로필렌으로 부터 선택된 단량체 및 비닐리덴 불화물의 공중합체인 방법.
  26. 제21항에 있어서, 성분(a)가 비닐리덴 불화물, 테트라프루오로 에틸렌, 및 헥사플루오로프로필렌 또는 1-또는 2-히드로펜타플루오로프로필렌의 삼원공중합체인 방법.
  27. 제21항 또는 제22항에 있어서, 성분(a)가 테트라 플루오로 에틸렌 및 프로필렌, 및 임의로 비닐리덴 불화물의 공중합체인 방법.
  28. 제21항 또는 제22항에 있어서, (b)가 비닐리덴 불화물 및 헥사플루오로프로필렌의 공중합체인 조성물.
  29. 제21항에 있어서, 난이-용융 가공성 중합체가 선형 저밀도 폴리에틸렌 중합체이고, (a)가 적어도 10,000의 분자량을 갖고, 45-90:5-50:0-35의 몰비로 비닐리덴 불화물, 헥사플루오로 프로필렌 및 테트라플루오로 에틸렌의 공중합된 단위로 구성되고, (b)가 비닐리덴 불화물의 단독 중합체이며, (a):(b)의 중합비가 10:90 내지 90:10인 방법.
  30. 제21항에 있어서, 난이-용융 가공성 중합체가 선형 저밀도 폴리에틸렌 중합체이고, (a)가 적어도 10,000의 분자량을 갖고, 45-90:5-50:0-35의 몰비로 비닐리덴 불화물, 헥사플루 오로프로필렌 및 테트라플루오로 에틸렌의 공중합된 단위로 구성되고, (b)가 비닐리덴 불화물 및 헥사플루오로프로필렌의 결정성 공중합체이며, (a):(b)의 중합비가 10:90 내지 90:10인 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019910700377A 1989-10-06 1990-09-20 플루오로카본 탄성체 및 비닐리덴 불화물로 구성된 압출 가공 조제를 함유하는 중합체 조성물 Expired - Fee Related KR950006266B1 (ko)

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US41800689A 1989-10-06 1989-10-06
US418,006 1989-10-06
US418006 1989-10-06
PCT/US1990/005247 WO1991005009A1 (en) 1989-10-06 1990-09-20 A polymer composition containing an extrusion processing aid comprising a fluorocarbon elastomer and vinylidene fluoride

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JPS59193940A (ja) * 1983-04-18 1984-11-02 Mitsubishi Petrochem Co Ltd 結晶性オレフイン重合体樹脂組成物
JPS6264847A (ja) * 1985-09-18 1987-03-23 Mitsubishi Petrochem Co Ltd 射出成形用ポリエチレン組成物
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US4837074A (en) * 1987-08-06 1989-06-06 The Dow Chemical Company Thermoformed polyolefin articles having improved gloss
JPS6474247A (en) * 1987-09-16 1989-03-20 Tosoh Corp Polyolefin resin composition
US4855360A (en) * 1988-04-15 1989-08-08 Minnesota Mining And Manufacturing Company Extrudable thermoplastic hydrocarbon polymer composition
US4904735A (en) * 1988-07-08 1990-02-27 E. I. Du Pont De Nemours And Company Processing aid for polymers

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KR950006266B1 (ko) 1995-06-13
DE69028915D1 (de) 1996-11-21
WO1991005009A1 (en) 1991-04-18
CA2027099C (en) 2001-02-27
BR9006939A (pt) 1991-12-17
CA2027099A1 (en) 1991-04-07
JPH03505346A (ja) 1991-11-21
AU6419390A (en) 1991-04-28
DE69028915T2 (de) 1997-05-15
ATE144271T1 (de) 1996-11-15
EP0447512B1 (en) 1996-10-16
EP0447512A1 (en) 1991-09-25
AU622050B2 (en) 1992-03-26
EP0447512A4 (en) 1992-10-07

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