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KR920018083A - 올레핀 중합용 촉매 및 성분 - Google Patents

올레핀 중합용 촉매 및 성분 Download PDF

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Publication number
KR920018083A
KR920018083A KR1019920005084A KR920005084A KR920018083A KR 920018083 A KR920018083 A KR 920018083A KR 1019920005084 A KR1019920005084 A KR 1019920005084A KR 920005084 A KR920005084 A KR 920005084A KR 920018083 A KR920018083 A KR 920018083A
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South Korea
Prior art keywords
catalyst component
compound
olefin polymerization
weight
porosity
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KR1019920005084A
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KR100204131B1 (ko
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모리니 기암피에로
알비자티 엔리코
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원본미기재
히몬트 인코포레이티드
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/904—Monomer polymerized in presence of transition metal containing catalyst at least part of which is supported on a polymer, e.g. prepolymerized catalysts

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

내용 없음

Description

올레핀 중합용 촉매 및 성분
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (6)

  1. Mg이할로겐화물 또는 Mg-C 결합을 포함하지 않으며 이할로겐화물로 변환될 수 있는 Mg화합물상에 지지된 0.5cc/g 이상의 다공률을 갖는 다공성 중합체 지지체와 4가 티타늄 할리드 또는 할로겐 알코올레이트 및 전자 공여 화합물을 반응시켜 수득되는 올레핀 중합용 촉매에 있어서, Ti화합물과 반응하기전 및 Ti화합물과 반응후의 최종 촉매성분 중에 존재하는 다공성 중합체 지지체 상에 지지된 Mg의 양이 촉매성분의 중량으로 6~12중량%인 것을 특징으로 하는 올레핀 중합용 촉매성분.
  2. 제1항에 있어서, Ti 화합물은 TiCl4이고 전자 공여 화합물은 하기의 일반식을 갖는 디에테르류로부터 선택되는 올레핀 중합용 촉매 성분.
    〔식중 R, R1및 R2는 동일 또는 상이하며 C1~C18직쇄 또는 측쇄 알킬, C3~C18시클로알킬, C6~C18아릴, C7~C18알킬아릴 또는 아릴알킬기이고, R1또는 R2는 수소일수도 있다〕
  3. 제2항에 있어서, R은 메틸이고, R1및 R2는 동일 또는 상이하며, 에틸, 프로필, 이소프로필, 부틸, 이소부틸, t-부틸, 네오펜틸, 이소펜틸, 페닐, 벤질 또는 시클로헥실인 올레핀 중합용 촉매 성분.
  4. 제2항에 있어서, Ti ; Mg 중량비가 0.25 미만이고 Ti : 전자 공여 화합물 몰비가 0.3 :1~3 :1인 올레핀 중합용 촉매 성분.
  5. 제3항에 있어서, Ti : Mg 중량비가 0.25미만이고, Ti : 디에테르 몰비가 0.3 : 1~3 : 1인 올레핀 중합용 촉매 성분.
  6. 제1항에 있어서, 다공성 중합체 지지체는 1~3m/g의 다공률 및 70% 이상의 동공 반지름이 100Å 이상인 올레핀 중합용 촉매 성분.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019920005084A 1991-03-27 1992-03-27 올레핀 중합용 촉매 및 성분 Expired - Fee Related KR100204131B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ITMI91A000813 1991-03-27
ITMI910813A IT1245249B (it) 1991-03-27 1991-03-27 Componenti e catalizzatori per la polimerizzazione di olefine

Publications (2)

Publication Number Publication Date
KR920018083A true KR920018083A (ko) 1992-10-21
KR100204131B1 KR100204131B1 (ko) 1999-06-15

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Family Applications (1)

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KR1019920005084A Expired - Fee Related KR100204131B1 (ko) 1991-03-27 1992-03-27 올레핀 중합용 촉매 및 성분

Country Status (23)

Country Link
US (1) US5244855A (ko)
EP (1) EP0506073B1 (ko)
JP (1) JP3308589B2 (ko)
KR (1) KR100204131B1 (ko)
CN (1) CN1035383C (ko)
AT (1) ATE137772T1 (ko)
AU (1) AU645896B2 (ko)
BR (1) BR9201078A (ko)
CA (1) CA2064125A1 (ko)
CS (1) CS91992A3 (ko)
DE (1) DE69210454T2 (ko)
FI (1) FI108442B (ko)
HU (1) HUT62611A (ko)
IL (1) IL101246A (ko)
IT (1) IT1245249B (ko)
MX (1) MX9201352A (ko)
MY (1) MY106929A (ko)
NO (1) NO179329C (ko)
PT (1) PT100311B (ko)
RU (1) RU2073688C1 (ko)
TW (1) TW203063B (ko)
YU (1) YU27892A (ko)
ZA (1) ZA921926B (ko)

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Publication number Priority date Publication date Assignee Title
IT1262934B (it) * 1992-01-31 1996-07-22 Montecatini Tecnologie Srl Componenti e catalizzatori per la polimerizzazione di olefine
IT1262935B (it) * 1992-01-31 1996-07-22 Montecatini Tecnologie Srl Componenti e catalizzatori per la polimerizzazione di olefine
IT1274253B (it) * 1995-02-21 1997-07-15 Himont Inc Processo per la preparazione di componenti catalitici solidi per la polimerizzazione di olefine
US5661095A (en) * 1995-06-06 1997-08-26 Quantum Chemical Corporation Olefin polymerization catalyst component supported on a copolymer of an olefin and an unsaturated silane
US5849655A (en) * 1996-12-20 1998-12-15 Fina Technology, Inc. Polyolefin catalyst for polymerization of propylene and a method of making and using thereof
ES2213898T3 (es) * 1997-03-29 2004-09-01 Basell Poliolefine Italia S.P.A. Aductos de dicloruro de magnesio/alcohol, procedimiento para su preparacion y componentes catalizadores obtenidos a partir de estos.
CN1067691C (zh) * 1997-05-13 2001-06-27 中国石油化工总公司 一种负载型聚丙烯催化剂
US6383273B1 (en) 1999-08-12 2002-05-07 Apyron Technologies, Incorporated Compositions containing a biocidal compound or an adsorbent and/or catalyst compound and methods of making and using therefor
ES2243601T3 (es) * 2001-02-15 2005-12-01 Saudi Basic Industries Corporation Composicion de catalizador soportado para la polimerizacion de olefinas, procedimiento para su preparacion y polimerizacion usando la misma.
EP1233029B1 (en) * 2001-02-15 2003-11-12 Saudi Basic Industries Corporation Supported catalyst composition for polymerization of olefins; method for preparing the same and process for polymerization using the same
US7005487B2 (en) * 2002-07-02 2006-02-28 Basell Poliolefine Italia S.R.L. Catalyst system for the polymerization of olefins
CN1958621B (zh) * 2005-10-31 2010-12-22 中国石油化工股份有限公司 用于烯烃聚合的固体催化剂组分及其催化剂和催化剂应用
JP5480148B2 (ja) * 2007-10-16 2014-04-23 中国石化揚子石油化工有限公司 マグネシウム化合物担持非メタロセン触媒およびその製造
KR101207294B1 (ko) * 2007-10-16 2012-12-03 시노펙 양지 페트로케미컬 컴퍼니 엘티디. 담지된 비-메탈로센 촉매 및 이의 제조방법
CN101412767B (zh) * 2007-10-16 2011-09-21 中国石化扬子石油化工有限公司 一种负载型非茂金属催化剂及其制备方法
CN101412769B (zh) * 2007-10-16 2014-05-07 中国石化扬子石油化工有限公司 一种负载型非茂金属催化剂及其制备方法
CN101412766B (zh) * 2007-10-16 2011-10-19 中国石化扬子石油化工有限公司 一种镁化合物负载型非茂金属催化剂及其制备方法
CN103626895B (zh) * 2012-08-23 2016-03-30 中国石油化工股份有限公司 用于烯烃聚合反应的催化剂组分及其催化剂制备方法
CN103626894B (zh) * 2012-08-23 2016-03-30 中国石油化工股份有限公司 用于烯烃聚合反应的催化剂组分及其催化剂制备方法
CN103626893B (zh) * 2012-08-23 2016-03-30 中国石油化工股份有限公司 用于烯烃聚合反应的催化剂组分及其催化剂制备方法
WO2022094508A1 (en) * 2020-10-30 2022-05-05 Exxonmobil Chemical Patents Inc. Polypropylene produced using modified styrenic internal electron donors

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2082153A5 (fr) * 1970-03-05 1971-12-10 Solvay Catalyseurs et procede perfectionnes pour la polymerisation et la copolymerisation des olefines
IT1098011B (it) * 1978-08-08 1985-08-31 Euteco Spa Catalizzatori supportati per la omo- o co-polimerizzazione di affa-olefine
US4263168A (en) * 1979-01-10 1981-04-21 Imperial Chemical Industries Limited Olefine polymerization catalyst
IT1217744B (it) * 1988-05-31 1990-03-30 Himont Inc Componenti e catalizzatori per la polimerizzazione di olefine
US5139985A (en) * 1988-05-31 1992-08-18 Himont Incorporated Components and catalyst for the polymerization olefins
IT1230134B (it) * 1989-04-28 1991-10-14 Himont Inc Componenti e catalizzatori per la polimerizzazione di olefine.
IT1237812B (it) * 1989-12-22 1993-06-17 Himont Inc Componenti e catalizzatori per la polimerizzazione di olefine
IT1238387B (it) * 1990-01-10 1993-07-16 Himont Inc Componenti e catalizzatori per la polimerizzazione di olefine

Also Published As

Publication number Publication date
FI921348A0 (fi) 1992-03-27
CN1035383C (zh) 1997-07-09
FI108442B (fi) 2002-01-31
HUT62611A (en) 1993-05-28
YU27892A (sh) 1994-06-24
ITMI910813A1 (it) 1992-09-27
CA2064125A1 (en) 1992-09-28
US5244855A (en) 1993-09-14
AU1319792A (en) 1992-10-01
ITMI910813A0 (it) 1991-03-27
CS91992A3 (en) 1992-10-14
AU645896B2 (en) 1994-01-27
HU9200943D0 (en) 1992-06-29
EP0506073A3 (en) 1992-12-02
ZA921926B (en) 1992-11-25
EP0506073A2 (en) 1992-09-30
BR9201078A (pt) 1992-11-24
TW203063B (ko) 1993-04-01
DE69210454T2 (de) 1996-10-10
PT100311B (pt) 1999-06-30
IL101246A (en) 1994-12-29
RU2073688C1 (ru) 1997-02-20
NO179329C (no) 1996-09-18
PT100311A (pt) 1993-06-30
NO921185D0 (no) 1992-03-26
IT1245249B (it) 1994-09-13
NO921185L (no) 1992-09-28
KR100204131B1 (ko) 1999-06-15
JPH0625338A (ja) 1994-02-01
NO179329B (no) 1996-06-10
FI921348L (fi) 1992-09-28
EP0506073B1 (en) 1996-05-08
CN1066274A (zh) 1992-11-18
ATE137772T1 (de) 1996-05-15
DE69210454D1 (de) 1996-06-13
MX9201352A (es) 1992-10-01
MY106929A (en) 1995-08-30
JP3308589B2 (ja) 2002-07-29

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