KR920009855A - 비닐화합물의 중합방지제 및 중합 방지법 - Google Patents
비닐화합물의 중합방지제 및 중합 방지법 Download PDFInfo
- Publication number
- KR920009855A KR920009855A KR1019910019840A KR910019840A KR920009855A KR 920009855 A KR920009855 A KR 920009855A KR 1019910019840 A KR1019910019840 A KR 1019910019840A KR 910019840 A KR910019840 A KR 910019840A KR 920009855 A KR920009855 A KR 920009855A
- Authority
- KR
- South Korea
- Prior art keywords
- polymerization
- vinyl compound
- polymerization inhibitor
- group
- manganese
- Prior art date
Links
- 238000006116 polymerization reaction Methods 0.000 title claims 17
- 239000003112 inhibitor Substances 0.000 title claims 9
- 238000000034 method Methods 0.000 title claims 7
- 230000002265 prevention Effects 0.000 title claims 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 title claims 2
- -1 vinyl compound Chemical class 0.000 claims 10
- 229920002554 vinyl polymer Polymers 0.000 claims 10
- 150000001555 benzenes Chemical class 0.000 claims 3
- 150000002696 manganese Chemical class 0.000 claims 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 2
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims 2
- 239000004480 active ingredient Substances 0.000 claims 2
- DKVNPHBNOWQYFE-UHFFFAOYSA-N carbamodithioic acid Chemical compound NC(S)=S DKVNPHBNOWQYFE-UHFFFAOYSA-N 0.000 claims 2
- 150000001879 copper Chemical class 0.000 claims 2
- 229910052748 manganese Inorganic materials 0.000 claims 2
- 239000011572 manganese Substances 0.000 claims 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 claims 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- 125000004432 carbon atom Chemical group C* 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- KGGZTXSNARMULX-UHFFFAOYSA-L copper;dicarbamodithioate Chemical compound [Cu+2].NC([S-])=S.NC([S-])=S KGGZTXSNARMULX-UHFFFAOYSA-L 0.000 claims 1
- 150000002148 esters Chemical class 0.000 claims 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 1
- 150000002430 hydrocarbons Chemical group 0.000 claims 1
- 125000005397 methacrylic acid ester group Chemical group 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- 229910052757 nitrogen Inorganic materials 0.000 claims 1
- 125000004433 nitrogen atom Chemical group N* 0.000 claims 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
- C07C7/20—Use of additives, e.g. for stabilisation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
- C07C51/50—Use of additives, e.g. for stabilisation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/48—Separation; Purification; Stabilisation; Use of additives
- C07C67/62—Use of additives, e.g. for stabilisation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Analytical Chemistry (AREA)
- Water Supply & Treatment (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polymerisation Methods In General (AREA)
Abstract
Description
Claims (9)
- 메틸기, 에틸기, 선형 또는 분지형 프로필기, 선형 또는 분지형 부틸기 및 페닐기로 이루어진 군에서 선택되는 동종 또는 이종의 탄화수소기 2개가 결합된 질소원자를 갖는 디티오카르바민산 망간중의 1종 이상을 유효성분으로 함유하는 것을 특징으로 하는 비닐화합물의 중합 방지제.
- 하기 일반식(I)으로 대표되는 티우람(티오카바모일)유도체를 유효성분으로 함유하는 것을 특징으로 하는 비닐화합물의 중합방지제.(위 식에서 R1, R2, R3및 R4는 각각 탄소수 1 내지 8의 알킬기와 페닐기 중의 어느 하나임).
- 상기 청구항 1에서 청구된 바와같은 중합방지제의 사용을 포함하는 것을 특징으로 하는 비닐화합물의 중합 방지법.
- 제3항에 있어서, 중합방지제로서 디티오카르바민산 망간 이외의 망간염, 동(銅)염 및 벤젠 유도체를 이루어진 군에서 선택되는 1종 이상과의 공동사용을 포함하는 것을 특징으로 하는 비닐 화합물의 중합방지법.
- 상기 청구항 2에서 청구된 바와같은 중합방지제의 사용을 포함하는 것을 특징으로 하는 비닐화합물의 중합방법.
- 제5항에 있어서, 중합방지제로서 망산염, 동(銅)염 및 벤젠 유도체로 이루어진 군에서 선택되는 1종 이상과의 공동 사용을 포함하는 것을 특징으로 하는 비닐화합물의 중합 방지법.
- 중합방제로서 디티오카르바민산 동과 망간염의 공동사용을 포함하는 것을 특징으로 하는 비닐화합물의 중합방지법.
- 제7항에 있어서, 상기 중합방지제와 벤젠 유도체의 공동 사용을 포함하는 것을 특징으로 하는 비닐화합물의 중합방지법.
- 제3항 내지 제8항중 어느 한 항에 있어서, 비닐화합물이 아크릴산, 메타크릴산, 아크릴산, 에스테르, 메타크릴산 에스테르, 아크릴로니트릴 및 스티렌으로 이루어진 군에서 선택되는 어느 하나인 것을 특징으로 하는 비닐화합물의 중합 방지법.* 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (12)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP02-305058 | 1990-11-09 | ||
JP?02-305058 | 1990-11-09 | ||
JP30505890 | 1990-11-09 | ||
JP02-304860 | 1990-11-10 | ||
JP30486090 | 1990-11-10 | ||
JP?02-304860 | 1990-11-10 | ||
JP03-105926 | 1991-05-10 | ||
JP10592691 | 1991-05-10 | ||
JP?03-105926 | 1991-05-10 | ||
JP03-143585 | 1991-06-14 | ||
JP?03-143585 | 1991-06-14 | ||
JP14358591 | 1991-06-14 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR920009855A true KR920009855A (ko) | 1992-06-25 |
KR950003113B1 KR950003113B1 (ko) | 1995-04-01 |
Family
ID=27469376
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019910019840A KR950003113B1 (ko) | 1990-11-09 | 1991-11-08 | 비닐화합물의 중합방지제 및 중합 방지법 |
Country Status (9)
Country | Link |
---|---|
US (1) | US5371280A (ko) |
EP (1) | EP0485169B1 (ko) |
KR (1) | KR950003113B1 (ko) |
AU (1) | AU643085B2 (ko) |
BR (1) | BR9104888A (ko) |
CA (1) | CA2055085A1 (ko) |
DE (1) | DE69111382T2 (ko) |
ES (1) | ES2077811T3 (ko) |
MX (1) | MX9101965A (ko) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20210049878A (ko) * | 2018-08-24 | 2021-05-06 | 비엘 테크놀러지스 인크. | 중합을 억제하기 위한 상승작용적 컴비네이션 |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TW294658B (ko) * | 1994-06-02 | 1997-01-01 | Nippon Catalytic Chem Ind | |
CN1069305C (zh) * | 1994-09-09 | 2001-08-08 | 出光石油化学株式会社 | 防止乙烯基化合物聚合的方法 |
US5648573A (en) * | 1995-06-12 | 1997-07-15 | Betzdearborn Inc. | Compositions and methods for inhibiting vinyl aromatic monomer polymerization |
US6046357A (en) * | 1998-10-02 | 2000-04-04 | Celanese International Corporation | Stabilization and transport of α,β-unsaturated carboxylic acid and removal of stabilizer |
DE60233590D1 (de) * | 2001-12-19 | 2009-10-15 | Nippon Catalytic Chem Ind | Acrylsäurezusammensetzung und verfahren zu ihrer herstellung, verfahren zur herstellung von wasserabsorbierendem harz, bei dem diese acrylsäurezusammendes harz |
JP3992643B2 (ja) * | 2003-05-09 | 2007-10-17 | 株式会社日本触媒 | (メタ)アクリル酸および/またはそのエステルの蒸留方法 |
US20080021241A1 (en) * | 2004-11-12 | 2008-01-24 | Carlson Curtis I Jr | Process for production of methacrylic acid |
JP5378207B2 (ja) * | 2007-05-29 | 2013-12-25 | 株式会社日本触媒 | (メタ)アクリル酸の製造方法 |
EP2135656A1 (en) * | 2008-05-30 | 2009-12-23 | Rohm and Haas Company | Method for production of purified (Meth)acrylic acid |
BRPI0914378A2 (pt) * | 2008-12-23 | 2015-10-20 | Du Pont | processo para a produção de ésteres acrílicos e metacrílicos de poli(trimetileno éter)glicol |
US9809899B2 (en) | 2014-08-07 | 2017-11-07 | Macdermid Acumen, Inc. | Treatment for electroplating racks to avoid rack metallization |
CN112266428B (zh) * | 2020-10-27 | 2023-03-17 | 益丰新材料股份有限公司 | 一种应用于uv光固树脂阻聚剂的制备方法 |
Family Cites Families (18)
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US2829152A (en) * | 1956-03-20 | 1958-04-01 | Goodrich Co B F | Stabilization of acrylonitrile |
NL230587A (ko) * | 1957-08-17 | |||
US2977345A (en) * | 1958-01-02 | 1961-03-28 | Exxon Research Engineering Co | Accelerator system for steam curing polymers |
US3322802A (en) * | 1963-05-27 | 1967-05-30 | Vanderbilt Co R T | Metal salts of organodithiocarbamateorganothiocarbamoyl sulfinates and the preparation thereof |
US3390198A (en) * | 1965-12-16 | 1968-06-25 | Koppers Co Inc | Tertiary-butyl-5-methyl catechol as polymerization inhibitor for hot styrene |
GB1314232A (en) * | 1969-06-24 | 1973-04-18 | Du Pont | Hydrocarbon copolymers |
US3879343A (en) * | 1969-06-24 | 1975-04-22 | Du Pont | Stabilizing hydrocarbon copolymers of bicyclic monomers against gelation during bulk processing |
GB1410474A (en) * | 1971-12-14 | 1975-10-15 | Albright & Wilson | Distillation of halogen containing aromatic compounds |
JPS5234606B2 (ko) * | 1972-12-22 | 1977-09-05 | ||
US4061595A (en) * | 1976-03-15 | 1977-12-06 | Engelhard Minerals & Chemicals Corporation | Production of sulfur recovery catalyst from bauxite fines |
US4348515A (en) * | 1980-09-17 | 1982-09-07 | W. R. Grace & Co. | Heat activated thiuram containing curable compositions |
JPS5761015A (en) * | 1980-09-30 | 1982-04-13 | Matsushita Electric Works Ltd | Production of phenol resin |
US4532011A (en) * | 1984-03-02 | 1985-07-30 | The Goodyear Tire & Rubber Company | Inhibiting polymerization of vinylaromatic monomers |
JPS61176672A (ja) * | 1985-02-01 | 1986-08-08 | Tokyo Organ Chem Ind Ltd | 防汚塗料組成物 |
US4663480A (en) * | 1985-06-05 | 1987-05-05 | Mallinckrodt, Inc. | Inhibiting polymerization of ethylenically unsaturated monomers with Mn(NO2)2 |
US4621310A (en) * | 1985-07-18 | 1986-11-04 | Richard Keating | Heating luminaire protector |
AU1891388A (en) * | 1987-07-31 | 1989-02-02 | Hoechst Celanese Corporation | Inhibition of polymerization during distillation of monomers |
EP0368956A4 (en) * | 1988-04-25 | 1990-09-26 | National Starch And Chemical Corporation | Quaternary ammonium dithiocarbamate compounds |
-
1991
- 1991-11-05 EP EP91310219A patent/EP0485169B1/en not_active Expired - Lifetime
- 1991-11-05 DE DE69111382T patent/DE69111382T2/de not_active Expired - Fee Related
- 1991-11-05 US US07/788,326 patent/US5371280A/en not_active Expired - Lifetime
- 1991-11-05 ES ES91310219T patent/ES2077811T3/es not_active Expired - Lifetime
- 1991-11-06 CA CA002055085A patent/CA2055085A1/en not_active Abandoned
- 1991-11-07 MX MX9101965A patent/MX9101965A/es unknown
- 1991-11-08 AU AU87086/91A patent/AU643085B2/en not_active Ceased
- 1991-11-08 KR KR1019910019840A patent/KR950003113B1/ko not_active IP Right Cessation
- 1991-11-11 BR BR919104888A patent/BR9104888A/pt not_active Application Discontinuation
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20210049878A (ko) * | 2018-08-24 | 2021-05-06 | 비엘 테크놀러지스 인크. | 중합을 억제하기 위한 상승작용적 컴비네이션 |
Also Published As
Publication number | Publication date |
---|---|
DE69111382T2 (de) | 1996-03-28 |
MX9101965A (es) | 1993-08-01 |
DE69111382D1 (de) | 1995-08-24 |
CA2055085A1 (en) | 1992-05-10 |
AU8708691A (en) | 1992-06-11 |
ES2077811T3 (es) | 1995-12-01 |
US5371280A (en) | 1994-12-06 |
KR950003113B1 (ko) | 1995-04-01 |
AU643085B2 (en) | 1993-11-04 |
EP0485169A1 (en) | 1992-05-13 |
BR9104888A (pt) | 1992-06-23 |
EP0485169B1 (en) | 1995-07-19 |
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