KR920002221A - 백금-흑연 촉매 및 이들의 용도 - Google Patents
백금-흑연 촉매 및 이들의 용도 Download PDFInfo
- Publication number
- KR920002221A KR920002221A KR1019910012206A KR910012206A KR920002221A KR 920002221 A KR920002221 A KR 920002221A KR 1019910012206 A KR1019910012206 A KR 1019910012206A KR 910012206 A KR910012206 A KR 910012206A KR 920002221 A KR920002221 A KR 920002221A
- Authority
- KR
- South Korea
- Prior art keywords
- graphite
- platinum
- catalyst according
- support
- catalyst
- Prior art date
Links
- 229910002804 graphite Inorganic materials 0.000 title claims 14
- 239000010439 graphite Substances 0.000 title claims 14
- 239000003054 catalyst Substances 0.000 title claims 11
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 5
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 claims 2
- 239000002245 particle Substances 0.000 claims 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims 2
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical class ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 claims 1
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 claims 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 1
- 238000009903 catalytic hydrogenation reaction Methods 0.000 claims 1
- 238000005984 hydrogenation reaction Methods 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 238000000034 method Methods 0.000 claims 1
- 150000007522 mineralic acids Chemical class 0.000 claims 1
- 229910052697 platinum Inorganic materials 0.000 claims 1
- 229910052711 selenium Inorganic materials 0.000 claims 1
- 239000011669 selenium Substances 0.000 claims 1
- 229910052717 sulfur Inorganic materials 0.000 claims 1
- 239000011593 sulfur Substances 0.000 claims 1
- 231100000331 toxic Toxicity 0.000 claims 1
- 230000002588 toxic effect Effects 0.000 claims 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/18—Carbon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/42—Platinum
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B21/00—Nitrogen; Compounds thereof
- C01B21/082—Compounds containing nitrogen and non-metals and optionally metals
- C01B21/14—Hydroxylamine; Salts thereof
- C01B21/1409—Preparation
- C01B21/1418—Preparation by catalytic reduction of nitrogen oxides or nitrates with hydrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Description
Claims (8)
- 흑연 지지물의 1내지 600㎛의 입자크기 및 다음 입자크기분포를 갖는 것을 특징으로 하는, 백금함량이 0.01내지 5%w/w인 백금-흑연 촉매 : 183내지 600㎛15%v/v±15%절대68.3 내지 183㎛ 30%v/v±20%31.0 내지 68.3㎛ 25%v/v±20% 17.1 내지 31.0㎛ 15%v/v±10% 5.2 내지 17.1㎛ 12%v/v10% 〈5.2㎛ 5%v/v±5%.
- 제1항에 잇어서, 흑연 지지물이 1.7 내지 2.2g/㎖의 겉보기 밀도를 가짐을 특징으로 하는 백금-흑연촉매.
- 제1항 또는 2항에 있어서, 흑연 지지물이 50 내지 250N/㎟의 압축강도를 가짐을 특징으로 하는 백금-흑연촉매.
- 제1 내지 3항에 있어서, 흑연지지물이 1 내지 40%의 다공도를 가짐을 특징으로 하는 백금-흑연 촉매.
- 제1 내지 4항에 있어서, 흑연 지지물이 1 내지 300㎡/g의 BET표면적을 가짐을 특징으로 하는 백금-흑연촉매.
- 제1 내지 5항에 있어서, 촉매가 황 및/또는 셀레늄에 의해 부분적으로 독성화됨을 특징으로 하는 백금-흑연촉매.
- 제1 내지 6항중 어느 한 항에 기재된 백금-흑연 촉매를 수소화반응 촉매로서 사용하는 방법.
- 제1 내지 6항중 어느 한 항에 기재된 백금-흑연 촉매를 사용하는 수성 무기산중에서 산화질소를 촉매 수소화반응시켜 히드록실암모늄염을 제조하는 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEP4022853.3 | 1990-07-18 | ||
DE4022853A DE4022853A1 (de) | 1990-07-18 | 1990-07-18 | Platin-graphittraeger-katalysatoren und deren verwendung |
Publications (2)
Publication Number | Publication Date |
---|---|
KR920002221A true KR920002221A (ko) | 1992-02-28 |
KR100208911B1 KR100208911B1 (ko) | 1999-07-15 |
Family
ID=6410529
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019910012206A KR100208911B1 (ko) | 1990-07-18 | 1991-07-18 | 흑연상백금촉매 및 이들의 용도 |
Country Status (6)
Country | Link |
---|---|
US (1) | US5120699A (ko) |
EP (1) | EP0467192B1 (ko) |
JP (1) | JP3253319B2 (ko) |
KR (1) | KR100208911B1 (ko) |
DE (2) | DE4022853A1 (ko) |
ES (1) | ES2044662T3 (ko) |
Families Citing this family (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4236203A1 (de) * | 1992-10-27 | 1994-04-28 | Bayer Ag | Verfahren zur Herstellung von chlorsubstituierten aromatischen Aminen und von Katalysatoren |
TW322432B (ko) * | 1993-06-14 | 1997-12-11 | Degussa | |
JPH07155618A (ja) * | 1993-12-06 | 1995-06-20 | Hitachi Ltd | 担持金属触媒、及びその製造方法 |
DE19502580A1 (de) * | 1995-01-27 | 1996-08-01 | Basf Ag | Verfahren zur Herstellung eines Hydrierungskatalysators |
DE19544403A1 (de) * | 1995-11-29 | 1997-06-05 | Basf Ag | Herstellung eines Hydrierungskatalysators unter Verwendung von M(OR)¶m¶X¶n¶ |
US6338809B1 (en) | 1997-02-24 | 2002-01-15 | Superior Micropowders Llc | Aerosol method and apparatus, particulate products, and electronic devices made therefrom |
US6660680B1 (en) | 1997-02-24 | 2003-12-09 | Superior Micropowders, Llc | Electrocatalyst powders, methods for producing powders and devices fabricated from same |
US6103393A (en) * | 1998-02-24 | 2000-08-15 | Superior Micropowders Llc | Metal-carbon composite powders, methods for producing powders and devices fabricated from same |
US6780350B1 (en) | 1997-02-24 | 2004-08-24 | Superior Micropowders Llc | Metal-carbon composite powders, methods for producing powders and devices fabricated from same |
US20030006517A1 (en) * | 1998-02-24 | 2003-01-09 | Kodas Toivo T. | Methods for the production of patterned and unpatterned metal-carbon features |
US6753108B1 (en) * | 1998-02-24 | 2004-06-22 | Superior Micropowders, Llc | Energy devices and methods for the fabrication of energy devices |
US6967183B2 (en) * | 1998-08-27 | 2005-11-22 | Cabot Corporation | Electrocatalyst powders, methods for producing powders and devices fabricated from same |
US7138354B2 (en) * | 1998-02-24 | 2006-11-21 | Cabot Corporation | Method for the fabrication of an electrocatalyst layer |
US6517964B2 (en) * | 2000-11-30 | 2003-02-11 | Graftech Inc. | Catalyst support material for fuel cell |
US6455723B1 (en) * | 2001-10-02 | 2002-09-24 | E. I. Du Pont De Nemours And Company | Aminonitrile production |
JP2006012476A (ja) * | 2004-06-23 | 2006-01-12 | Nissan Motor Co Ltd | 燃料電池用膜−電極接合体 |
US20070160899A1 (en) * | 2006-01-10 | 2007-07-12 | Cabot Corporation | Alloy catalyst compositions and processes for making and using same |
WO2008048349A2 (en) * | 2006-03-06 | 2008-04-24 | National Institute Of Aerospace Associates | Depositing nanometer-sized metal particles onto substrates |
EP1980583A1 (en) * | 2007-04-10 | 2008-10-15 | Solvay Solexis S.p.A. | A method for preparing carbonylic perfluoropolyethers |
EP3271071A1 (en) * | 2015-03-20 | 2018-01-24 | BASF Corporation | Pt and/or pd egg-shell catalyst and use thereof |
RU2690931C1 (ru) * | 2018-12-24 | 2019-06-06 | Публичное акционерное общество "КуйбышевАзот" | Способ получения гидроксиламинсульфата |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE956038C (de) * | 1954-04-01 | 1957-01-10 | Basf Ag | Verfahren zur Herstellung von Hydroxylammoniumsalzen |
DE1667045A1 (de) * | 1967-05-13 | 1971-06-03 | Bayer Ag | Verfahren zur Herstellung eines besonders fuer die NO-Hydrierung zu Hydroxylamin geeigneten Platinkatalysators |
CH583588A5 (ko) * | 1973-10-10 | 1977-01-14 | Inventa Ag | |
CH585580A5 (ko) * | 1974-01-14 | 1977-03-15 | Inventa Ag | |
NL7502968A (nl) * | 1975-03-13 | 1976-09-15 | Stamicarbon | Werkwijze voor het bereiden van edelmetaal- katalysatoren. |
NL7609656A (nl) * | 1976-08-31 | 1978-03-02 | Stamicarbon | Werkwijze voor de bereiding van een hydroxyl- aminezout. |
NL7808519A (nl) * | 1978-08-17 | 1980-02-19 | Stamicarbon | Werkwijze voor het bereiden van een hydroxylaminezout. |
NL7902291A (nl) * | 1979-03-23 | 1980-09-25 | Stamicarbon | Werkwijze voor de bereiding van een hydroxylaminezout en daarbij te gebruiken katalysator. |
DE3108257A1 (de) * | 1981-03-05 | 1982-09-16 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von hydroxylammoniumsalzen |
US4659686A (en) * | 1983-12-22 | 1987-04-21 | E. I. Du Pont De Nemours And Company | Method for treating carbon supports for hydrogenation catalysts |
JPS62163746A (ja) * | 1986-01-13 | 1987-07-20 | Nippon Engeruharudo Kk | 白金合金電極触媒およびそれを使用した酸電解質燃料電池用電極 |
DE3713733A1 (de) * | 1987-04-24 | 1988-11-17 | Basf Ag | Verfahren zur herstellung von hydroxylammoniumsalzen |
JP2668927B2 (ja) * | 1987-09-22 | 1997-10-27 | 住友化学工業株式会社 | ヒドロキシルアンモニウム塩の製造法およびその触媒 |
DE3809554A1 (de) * | 1988-03-22 | 1989-10-12 | Basf Ag | Verfahren zur herstellung von hydroxylammoniumsalzen |
-
1990
- 1990-07-18 DE DE4022853A patent/DE4022853A1/de not_active Withdrawn
-
1991
- 1991-07-08 JP JP16688391A patent/JP3253319B2/ja not_active Expired - Fee Related
- 1991-07-09 DE DE91111373T patent/DE59100453D1/de not_active Expired - Lifetime
- 1991-07-09 EP EP91111373A patent/EP0467192B1/de not_active Expired - Lifetime
- 1991-07-09 ES ES91111373T patent/ES2044662T3/es not_active Expired - Lifetime
- 1991-07-16 US US07/730,758 patent/US5120699A/en not_active Expired - Lifetime
- 1991-07-18 KR KR1019910012206A patent/KR100208911B1/ko not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
KR100208911B1 (ko) | 1999-07-15 |
ES2044662T3 (es) | 1994-01-01 |
JP3253319B2 (ja) | 2002-02-04 |
JPH04227059A (ja) | 1992-08-17 |
EP0467192A1 (de) | 1992-01-22 |
DE59100453D1 (de) | 1993-11-11 |
US5120699A (en) | 1992-06-09 |
DE4022853A1 (de) | 1992-01-23 |
EP0467192B1 (de) | 1993-10-06 |
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