KR910021362A - (4e-사이클로헥실-3-부테닐)아릴 유도체 - Google Patents
(4e-사이클로헥실-3-부테닐)아릴 유도체 Download PDFInfo
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- KR910021362A KR910021362A KR1019910001666A KR910001666A KR910021362A KR 910021362 A KR910021362 A KR 910021362A KR 1019910001666 A KR1019910001666 A KR 1019910001666A KR 910001666 A KR910001666 A KR 910001666A KR 910021362 A KR910021362 A KR 910021362A
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Abstract
Description
Claims (13)
- 하기 일반식(Ⅰ)의 화합물 ;상기식에서, n은 0또는 1을 나타내고 ; R1은 R3또는 R3-A3-Z2-그룹을 나타내고 ; R2는 R4또는 -R4-A4-Z3-그룹을 나타내고 ; A1고리는 치환되지 않거나 또는 할로겐-, 시아노-및/또는 메틸 치환된1, 4-페닐렌(여기에서, CH 그룹 1개 또는 2개는 임의로 질소에 의해 치환된다)이고 ; A2, A3및 A4고리는 각각 서로 무관하게 치환되지 않거나 또는 할로겐-, 시아노-및/또는 메틸 치환된1, 4-페닐렌(여기에서 CH그룹 1개 또는 2개는 임의로 질소에 의해 치환된다), 또는 트랜스-1, 4-사이클로헥실렌, 트랜스-1, 3-디옥산-2, 5-디일, 1-시아노-트랜스-1, 4-사이클로헥실렌, 비사이클로〔2,2,2〕옥탄-1, 4-디일, 나프탈렌-2, 6-디일, 테트랄린-2, 6-디일 또는 트랜스-데칼린-2, 6-디일을 나타내고 ; Z1, Z2및 Z3는 각각 서로 무관하게 단일 공유결합, -COO-, -OOC-, -CH2O-, -OCH2-, -CH2CH2-, -C=C-, - (CH2)3O-, -O(CH2)3-, -(CH2)4-, 또는 -CH=CH-CH2-CH2-, -CH2CH2-CH=CH-, CH=CH-CH2O-, 또는 -OCH2-CH=CH의 트랜스형을 나타내고 R3및 R4는 각각 서로무관하게 할로겐, 시아노, -NCS-, -CF3, -OCF3또는 알킬(여기에서, 1개의 )CH-CH〈는 임의로〉C=C〈에 의해 치환되고 /되거나 1개의 메틸렌 그룹 또는 2개의 인접하지 않은 메틸렌그룹은 임의로 -O-, -COO-및/또는 -OOC-에 의해 치환되고 /되거나 1개의 메틸렌 그룹은 임의로-CHX-에 의해 치환된다〉을 나타내고; X는 할로겐, 시아노 또는 메틸을 나타낸다.
- 제1항에 있어서, 하기 일반식(Ⅰ-1)을 갖는 화합물.상기식에서 n, R1, R2, Z1및 A2고리는 제1항에서 정의한의미를 가지며 ; X1및 X2는 각각 독립적으로 수소, 할로겐, 시아노, 또는 메틸을 나타낸다.
- 제1항 또는 제2항에 있어서, A3및 A4가 각각 독립적으로 트랜스-1,4-사이클로헥실렌 또는 치환되지 않거나 할로겐-, 시아노-및/또는 치환된1,4-페닐렌을 나타내는 화합물.
- 제1항 내지 제3항중 어느 한항에 있어서, A2고리가 치환되지 않은 , 1,4-페닐렌을 나타내거나또는 할로겐, 시아노 및/또는 메틸로일 치환되는 2, 3-이치환된1,4-페닐렌, 트랜스-1, 4-사이클로헥실렌, 트랜스-1, 3-디옥산-2, 5-디일, 1-시아노, 트랜스-1, 4-사이클로헥실렌, 비사이클로[2, 2, 2]옥탄-1, 4-디일, 나프탈렌-2, 6-디일, 테트랄린-2, 6-디일, 트랜스-데칼린-2, 6-디일, 피리딘-2, 5-디일, 피라미딘-2, 5-디일 또는 파라진-2,5-디일을 나타내는 화합물.
- 제1항에 내지 제4항중 어느 한항에 있어서, Z1, Z2및 Z3가 각각 단일공유결합을 나타내거나 또는 Z1, Z2, 및 Z3그룹 중하나가 또한 -COO-, -OOC-, -CH2O-, -OCH2-, -CH2CH2-, -C=C-, -(CH2)3O-, -O(CH2)3-, -(CH2)4- 또는 -CH=CH-CH2-CH2-, CH2CH2-CH=CH, CH=CH-CH2O 또는 -OCH2-CH=CH-의 트랜스형태를 나타내는 화합물.
- 제1항 내지 제5항중 어느 한 항에 있어서, 하기 일반식(Ⅰ-7), (Ⅰ-8), (Ⅰ-9), (Ⅰ-10), (Ⅰ-11) 및 (Ⅰ-12)을 갖는 화합물.상기 식에서 R3및 R4는 제1항에 나타낸 의미를 갖고 ; X1, X2, X3및 X4는 각각독립적으로 수소, 할로겐, 시아노 또는 메틸을 나타내고 ; Z4는 단일공유결합, -COO-, -OOC-, -C=C-, 를나타내고 ; Z5는 단일공유결합, -OOC-, -OCH2-, -CH2CH2-, -C=C-, -O(CH2)3-, -(CH2)4-, 또는 -CH2CH2-CH=CH- 또는 -OCH2-CH=CH-의 트랜스형을 나타내고 ; A5고리는 피리딘-2, 5-디일, 피리미딘-2, 5-디일, 파라진-2, 5-디일 , 트랜스-1, 3-디옥산-2, 5-디일, 비사이클로[2, 2, 2]옥탄-1,4-디일, 나프탈렌-2, 6-디일, 테트랄린-2,6-디일 또는 트랜스-데칼린-2,6-디일을 나타낸다.
- 제2항 또는 제6항에 있어서, X1, X2, X3및 X4가 각각 독립적으로 수소 또는 불소를 나타내는 화합물.
- 제1항 내지 제7항중 어느 한항에 있어서, R3및 R4가 각각 독립적으로 하나의〉CH-CH〈가 임의로〉C=C〈로 치환되고 /되거나 하나의 메틸렌 그룹 또는 2개의 비인접 메틸렌그룹이 임의로-O-, -COO- 및/또는 -OOC- 에 의해 치환되고/되거나 하나의 메틸렌그룹이 임의로 -CHX-로 치환된 알킬을 나타내거나 또는 R4가 또한 할로겐, 시아노, -NCS-, CF3또는 -OCF3를 나타내는 화합물.
- 제1항 내지 제8항중 어느 한항에 있어서, R3및 R4가 각각 탄소수 최고 18개, 바람직하게는 최고 12개를 갖는 화합물.
- 제1항 내지 제9항중 어느 한항에 있어서, R3가 알길, 알케닐, 알콕시, 알케닐옥시, 알콕시카보닐, 알케닐옥시카보닐, 알카노일옥시 또는 알케노일옥시, 바람직하게는 알킬 또는 알케닐을 나타내는 화합물.
- 제1항 내지 제10항중 어느 한항에 있어서, R4가 알킬, 알케닐, 알콕시, 알케닐옥시, 알콕시카보닐, 알케닐옥시카보닐, 알카노일옥시, 아케노일옥시, 할로겐, 시아노,-NCS-, -CF3또는 -OCF3를 나타내는 화합물.
- 적어도 하나의 성분이 제1항에 정의된 일반식(Ⅰ)의 화합물인, 적어도 2개의 성분을 갖는 액정 혼합물.
- 전광 목적에 사용하기 위한 제1항에 정의된 일반식(Ⅰ) 화합물용도.※ 참고사항 : 최초출원 내용에 의하여 공개되는 것임.
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CH326/90 | 1990-02-01 | ||
CH32690 | 1990-02-01 |
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KR1019910001666A KR910021362A (ko) | 1990-02-01 | 1991-01-31 | (4e-사이클로헥실-3-부테닐)아릴 유도체 |
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US (1) | US5204018A (ko) |
EP (1) | EP0442306B1 (ko) |
JP (1) | JPH04330019A (ko) |
KR (1) | KR910021362A (ko) |
DE (1) | DE59105136D1 (ko) |
Families Citing this family (15)
Publication number | Priority date | Publication date | Assignee | Title |
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JP3134473B2 (ja) * | 1992-04-03 | 2001-02-13 | チッソ株式会社 | シス−1,4−置換2−ブテン誘導体 |
EP0727406B1 (de) * | 1995-02-16 | 2001-09-05 | MERCK PATENT GmbH | Vinylenverbindungen und flüssigkristallines Medium |
WO1997000233A1 (fr) * | 1995-06-15 | 1997-01-03 | Chisso Corporation | Composes presentant des groupes alcenylene a substitution alkyle et composition de cristaux liquides |
JP4553411B2 (ja) * | 1996-02-23 | 2010-09-29 | チッソ株式会社 | ビニレン化合物および液晶組成物 |
KR20020054611A (ko) * | 2000-12-28 | 2002-07-08 | 구본준, 론 위라하디락사 | 액정 표시 장치 |
JP2004256791A (ja) * | 2003-02-03 | 2004-09-16 | Chisso Corp | 液晶組成物および液晶表示素子 |
JP5680380B2 (ja) * | 2010-11-19 | 2015-03-04 | Agcセイミケミカル株式会社 | 液晶化合物、その製造方法、液晶組成物および液晶電気光学素子 |
JP5680381B2 (ja) * | 2010-11-19 | 2015-03-04 | Agcセイミケミカル株式会社 | 液晶化合物、その製造方法、液晶組成物および液晶電気光学素子 |
JP5849664B2 (ja) | 2011-01-31 | 2016-02-03 | Jnc株式会社 | 液晶性化合物、液晶組成物および液晶表示素子 |
US10203536B2 (en) * | 2014-06-05 | 2019-02-12 | East China University Of Science And Technology | Photo-tunable liquid crystal composition and methods for their fabrication and use |
JP6467807B2 (ja) * | 2014-08-08 | 2019-02-13 | Jnc株式会社 | ブテン結合基を有する液晶性化合物、液晶組成物および液晶表示素子 |
JP6690114B2 (ja) * | 2014-09-25 | 2020-04-28 | Jnc株式会社 | 液晶組成物および液晶表示素子 |
EP3246330A1 (en) | 2016-05-18 | 2017-11-22 | Istituto Europeo di Oncologia S.r.l. | Imidazoles as histone demethylase inhibitors |
EP3668877B1 (en) | 2017-08-18 | 2024-05-01 | Istituto Europeo di Oncologia S.r.l. | Indole derivatives as histone demethylase inhibitors |
CN113717735B (zh) * | 2021-08-12 | 2023-08-08 | 烟台显华科技集团股份有限公司 | 正介电各向异性液晶化合物、液晶组合物及液晶显示器件 |
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GB1551043A (en) * | 1975-04-22 | 1979-08-22 | Secr Defence | Biphenyl compounds containing a cyano group and liquid crystal materials and devices containing such compounds |
DE3225290A1 (de) * | 1982-07-07 | 1984-01-12 | Merck Patent Gmbh | Ringverbindungen |
JPS60118789A (ja) * | 1983-11-30 | 1985-06-26 | Canon Inc | 液晶素子 |
DE3509170C2 (de) * | 1985-03-14 | 1995-01-05 | Merck Patent Gmbh | trans-Ethenylenverbindungen |
DE3632410A1 (de) * | 1986-09-24 | 1988-03-31 | Merck Patent Gmbh | Verfahren zur herstellung von alkylen- bzw. ringverknuepften verbindungen |
FR2612182B1 (fr) * | 1987-03-12 | 1989-06-23 | Centre Nat Rech Scient | Esters phenyliques substitues utilisables comme cristaux liquides ferroelectriques, leur preparation et leur utilisation dans un dispositif de visualisation electro-optique |
US5238600A (en) * | 1988-06-01 | 1993-08-24 | Hoffmann-La Roche Inc. | Ibimethylenoxy containing liquid crystal compounds |
JP2696557B2 (ja) * | 1989-03-07 | 1998-01-14 | チッソ株式会社 | トリフルオロベンゼン誘導体 |
ATE119871T1 (de) * | 1989-09-06 | 1995-04-15 | Merck Patent Gmbh | Fluorbenzolderivate und flüssigkristallines medium. |
-
1991
- 1991-01-22 US US07/643,965 patent/US5204018A/en not_active Expired - Fee Related
- 1991-01-25 DE DE59105136T patent/DE59105136D1/de not_active Expired - Fee Related
- 1991-01-25 EP EP91100965A patent/EP0442306B1/de not_active Expired - Lifetime
- 1991-01-31 KR KR1019910001666A patent/KR910021362A/ko not_active Application Discontinuation
- 1991-02-01 JP JP3031389A patent/JPH04330019A/ja active Pending
Also Published As
Publication number | Publication date |
---|---|
EP0442306A3 (en) | 1992-08-19 |
EP0442306A2 (de) | 1991-08-21 |
EP0442306B1 (de) | 1995-04-12 |
JPH04330019A (ja) | 1992-11-18 |
DE59105136D1 (de) | 1995-05-18 |
US5204018A (en) | 1993-04-20 |
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