KR910016659A - 키랄 나프탈린디카복실레이트 - Google Patents
키랄 나프탈린디카복실레이트 Download PDFInfo
- Publication number
- KR910016659A KR910016659A KR1019910004703A KR910004703A KR910016659A KR 910016659 A KR910016659 A KR 910016659A KR 1019910004703 A KR1019910004703 A KR 1019910004703A KR 910004703 A KR910004703 A KR 910004703A KR 910016659 A KR910016659 A KR 910016659A
- Authority
- KR
- South Korea
- Prior art keywords
- optically active
- compound
- liquid crystal
- alkyl
- alkoxy
- Prior art date
Links
- 150000001875 compounds Chemical class 0.000 claims 8
- 239000004973 liquid crystal related substance Substances 0.000 claims 5
- 125000000217 alkyl group Chemical group 0.000 claims 4
- 239000000203 mixture Substances 0.000 claims 4
- RXOHFPCZGPKIRD-UHFFFAOYSA-N naphthalene-2,6-dicarboxylic acid Chemical class C1=C(C(O)=O)C=CC2=CC(C(=O)O)=CC=C21 RXOHFPCZGPKIRD-UHFFFAOYSA-N 0.000 claims 4
- 125000003342 alkenyl group Chemical group 0.000 claims 3
- 125000003545 alkoxy group Chemical group 0.000 claims 3
- 125000003302 alkenyloxy group Chemical group 0.000 claims 2
- 125000004432 carbon atom Chemical group C* 0.000 claims 2
- 125000004093 cyano group Chemical group *C#N 0.000 claims 2
- 125000001140 1,4-phenylene group Chemical group [H]C1=C([H])C([*:2])=C([H])C([H])=C1[*:1] 0.000 claims 1
- 125000004849 alkoxymethyl group Chemical group 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 claims 1
- 239000012876 carrier material Substances 0.000 claims 1
- 230000003287 optical effect Effects 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/52—Liquid crystal materials characterised by components which are not liquid crystals, e.g. additives with special physical aspect: solvents, solid particles
- C09K19/58—Dopants or charge transfer agents
- C09K19/586—Optically active dopants; chiral dopants
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/76—Esters of carboxylic acids having a carboxyl group bound to a carbon atom of a six-membered aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
- C09K19/06—Non-steroidal liquid crystal compounds
- C09K19/32—Non-steroidal liquid crystal compounds containing condensed ring systems, i.e. fused, bridged or spiro ring systems
- C09K19/322—Compounds containing a naphthalene ring or a completely or partially hydrogenated naphthalene ring
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
- C09K19/42—Mixtures of liquid crystal compounds covered by two or more of the preceding groups C09K19/06 - C09K19/40
- C09K19/44—Mixtures of liquid crystal compounds covered by two or more of the preceding groups C09K19/06 - C09K19/40 containing compounds with benzene rings directly linked
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Liquid Crystal Substances (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Description
Claims (8)
- 하기 일반식(Ⅰ)의 광학 활성 나프탈렌-2,6-디카복실산 에스테르;상기식에서, C*는 키랄 탄소원자를 타나내고 R1은C2-C12-알킬,C|2-C12-알케닐, C2-C12-알콕시 카보닐 또는 C3-C12-알케닐옥시카보닐을 나타낸다.
- 제1항에 있어서, R1이 직쇄 잔기를 나타내는 화합물.
- 제1항 또는 제2항에 있어서, R1이 최대 7개의 탄소원자를 갖는 잔기를 나타내는 화합물.
- 액정 담체 물질과 제1항에 정의된 일반식(Ⅰ)의 하나이상의 광학 활성 화합물을 함유하는 액정 혼합물.
- 제4항에 있어서, 일반식(Ⅰ)의 광학 활성 화합물의 함량이 0.1 내지 30중량% 인 액정 혼합물.
- 제4항 또는 제5항에 있어서, 일반식(Ⅰ)의 하나이상의 광학 활성 화합물과 하기 일반식(Ⅲ) 내지 (ⅩⅠ)의 화합물 그룹으로 부터의 하나이상의 화합물을 함유하는 액정 혼합물:상기식들에서, R2및R6은 각각 독립적으로 알킬 또는 알케닐을 나타내고, R3은 시아노, 알킬, 알콕시, 알케닐, 알케닐옥시, 알콕시 메틸 또는 알케닐옥시메틸을 나타내고, Z1은 단일 공유결합 또는 -CH2CH2-를 나타내고, n은 0또는 1을 나타내고, R4는 알킬, 알콕시, 알케닐 또는 알케닐옥시를 나타내고, R5는 시아노, 알킬, 알콕시를 나타내고, A고리는 1,4-페닐렌 또는 트랜스-1,4-사이클로 헬실렌을 나타내고, Z2는 단일 공유결합, -COO- 또는 -CH2CH2- 를 나타낸다.
- 나프탈렌-2,6-디카복실산 또는 나프탈렌-2,6-디카복실산의 적합한 유도체를 하기 일반식(Ⅱ)의 광학 활성 화합물로 에스테르화시킴을 포함하는, 제1항에 정의된 일반식(Ⅰ)의 광학 활성 나프탈렌-2,6-디카복실산 에스테르의 제조방법.상기식에서, C*및 R1은 제1항에 정의된 의미를 갖는다.
- 광학 또는 전광 목적에 사용하기 위한 제4항에 따른 액정 혼합물의 용도.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH100990 | 1990-03-27 | ||
CH1009/90 | 1990-03-27 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR910016659A true KR910016659A (ko) | 1991-11-05 |
KR100192730B1 KR100192730B1 (ko) | 1999-06-15 |
Family
ID=4200322
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019910004703A KR100192730B1 (ko) | 1990-03-27 | 1991-03-25 | 키랄 나프탈린디카복실레이트 |
Country Status (6)
Country | Link |
---|---|
US (1) | US5230828A (ko) |
EP (1) | EP0449049B1 (ko) |
JP (1) | JP2944244B2 (ko) |
KR (1) | KR100192730B1 (ko) |
DE (1) | DE59104009D1 (ko) |
HK (1) | HK49697A (ko) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0731084B1 (de) * | 1995-03-03 | 2002-09-25 | Rolic AG | Photovernetzbare Naphthylderivate |
KR20020079442A (ko) | 2001-04-13 | 2002-10-19 | 미츠비시 가스 가가쿠 가부시키가이샤 | 광학 활성화합물 및 그것을 함유하는 액정조성물 |
JP2003012610A (ja) | 2001-06-26 | 2003-01-15 | Mitsubishi Gas Chem Co Inc | 光学活性化合物およびそれを含む液晶組成物 |
JP4696549B2 (ja) * | 2004-10-29 | 2011-06-08 | Dic株式会社 | トリフルオロナフタレン誘導体 |
EP2094815B1 (en) * | 2006-12-22 | 2012-06-27 | Rolic AG | Patternable liquid crystal polymer comprising thio-ether units |
CN108717239B (zh) * | 2017-11-20 | 2021-02-19 | 山东蓝贝易书信息科技有限公司 | 易热擦除型液晶膜写字板及制备方法 |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1603075A (en) * | 1977-10-24 | 1981-11-18 | Secr Defence | Liquid crystal esters containing naphthyl groups |
GB8520715D0 (en) * | 1985-08-19 | 1985-09-25 | Secr Defence | Secondary alcohol derivatives |
DE3534778A1 (de) * | 1985-09-30 | 1987-04-02 | Hoechst Ag | Chirale ester mesogener carbonsaeuren, ein verfahren zu deren herstellung und ihre verwendung als dotierstoff in fluessigkristall-phasen |
WO1987005018A2 (fr) * | 1986-02-17 | 1987-08-27 | MERCK Patent Gesellschaft mit beschränkter Haftung | Composes optiquement actifs |
GB8610349D0 (en) * | 1986-04-28 | 1986-06-04 | Bdh Ltd | 6-hydroxy-2-naphthoic acid derivatives |
JPH02209990A (ja) * | 1989-02-10 | 1990-08-21 | Dainippon Ink & Chem Inc | 強誘電性液晶組成物 |
-
1991
- 1991-03-15 EP EP91103983A patent/EP0449049B1/de not_active Expired - Lifetime
- 1991-03-15 DE DE59104009T patent/DE59104009D1/de not_active Expired - Fee Related
- 1991-03-22 US US07/673,545 patent/US5230828A/en not_active Expired - Fee Related
- 1991-03-25 KR KR1019910004703A patent/KR100192730B1/ko not_active IP Right Cessation
- 1991-03-26 JP JP3084337A patent/JP2944244B2/ja not_active Expired - Fee Related
-
1997
- 1997-04-17 HK HK49697A patent/HK49697A/xx not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
JP2944244B2 (ja) | 1999-08-30 |
EP0449049A3 (en) | 1993-01-20 |
DE59104009D1 (de) | 1995-02-09 |
EP0449049A2 (de) | 1991-10-02 |
KR100192730B1 (ko) | 1999-06-15 |
EP0449049B1 (de) | 1994-12-28 |
US5230828A (en) | 1993-07-27 |
JPH04221346A (ja) | 1992-08-11 |
HK49697A (en) | 1997-04-25 |
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