KR910011997A - 실리콘 매크로머 및 이로부터 얻어진 열가소성 난연성 실리콘- 폴리페닐렌 에테르 그라프트 공중합체 - Google Patents
실리콘 매크로머 및 이로부터 얻어진 열가소성 난연성 실리콘- 폴리페닐렌 에테르 그라프트 공중합체 Download PDFInfo
- Publication number
- KR910011997A KR910011997A KR1019900021471A KR900021471A KR910011997A KR 910011997 A KR910011997 A KR 910011997A KR 1019900021471 A KR1019900021471 A KR 1019900021471A KR 900021471 A KR900021471 A KR 900021471A KR 910011997 A KR910011997 A KR 910011997A
- Authority
- KR
- South Korea
- Prior art keywords
- organic group
- polyphenylene ether
- monovalent
- silicone
- flame retardant
- Prior art date
Links
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims 7
- 239000003063 flame retardant Substances 0.000 title claims 7
- 229920001955 polyphenylene ether Polymers 0.000 title claims 7
- 229920000578 graft copolymer Polymers 0.000 title claims 6
- 229920001169 thermoplastic Polymers 0.000 title claims 5
- 239000004416 thermosoftening plastic Substances 0.000 title claims 5
- 229920001296 polysiloxane Polymers 0.000 title claims 3
- 125000000962 organic group Chemical group 0.000 claims 15
- NXXYKOUNUYWIHA-UHFFFAOYSA-N 2,6-Dimethylphenol Chemical compound CC1=CC=CC(C)=C1O NXXYKOUNUYWIHA-UHFFFAOYSA-N 0.000 claims 4
- 229910052736 halogen Inorganic materials 0.000 claims 4
- 150000002367 halogens Chemical class 0.000 claims 3
- 238000005691 oxidative coupling reaction Methods 0.000 claims 2
- 229920001577 copolymer Polymers 0.000 claims 1
- 230000008878 coupling Effects 0.000 claims 1
- 238000010168 coupling process Methods 0.000 claims 1
- 238000005859 coupling reaction Methods 0.000 claims 1
- 239000004205 dimethyl polysiloxane Substances 0.000 claims 1
- 125000005843 halogen group Chemical group 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims 1
- -1 polydimethylsiloxane Polymers 0.000 claims 1
- 125000003258 trimethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])[*:1] 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/42—Block-or graft-polymers containing polysiloxane sequences
- C08G77/46—Block-or graft-polymers containing polysiloxane sequences containing polyether sequences
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/12—Polysiloxanes containing silicon bound to hydrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/38—Polysiloxanes modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L101/00—Compositions of unspecified macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Silicon Polymers (AREA)
- Polyethers (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (8)
- 하기 일반식(1)의 페놀-실록산 매크로머 1몰당 하기 일반식(2)의 2,6-디오르가노페놀 20 내지 1000몰을 산화성 커플링 반응시켜 생성되는 열가소성 난연성 실리콘-폴리페닐렌 에테르 그라프트 공중합체.상기 각 식에서, R은 할로겐 또는 동일하거나 상이한 일가 C1-13유기기 중에서 선택된 기이고, R1은 이가 C2-20유기기이고, R2는 동일하거나 상이한 일가 C1-13유기기 중에서 선택된 기이고, R3는 일가 C1-13유기기이고, n은 1 내지 100의 정수이다.
- 제1항에 있어서, 디오르가노페놀이 2,6-크실레놀인 것을 특징으로 하는 난연성 실리콘-폴리페닐렌 에테르 그라프트 공중합체.
- 제1항에 있어서, 실리콘이 폴리디메틸실록산인 것을 특징으로하는 난연성 실리콘-폴리페닐렌 에테르 그라프트 공중합체.
- 하기 일반식(1)의 페놀-실록산 메크로머.상기 각 식에서, R은 할로겐 또는 일가 C1-13유기기 중에서 선택된 기이고, R1은 이가 C2-20유기기이고, R2는 일가 C1-13유기기이고, R3는 일가 C1-13유기기이고, n은 1 내지 100의 정수이다.
- 제4항에 있어서, R 과 R2가 메틸기이고, R1이 트리메틸렌기이고, n이 10 내지 30의 정수인 것을특징으로 하는 페놀-실록산 매크로머.
- 하기 일반식(5)의 페놀-실록산 매크로머와 하기 일반식(3)의 2,6-디오르가노페놀을 산화성 커플링 반응시켜 생성되는 열가소성 난연성 실리콘-폴리페닐렌 에테르 그라프트 공중합체.상기 식에서, R 은 할로겐 또는 동일하거나 상이한 일가 C1-13유기기 중에서 선택된 기이고, R1은 이가 C2-20유기기이고, R2는 동일하거나 상이한 일가 C1-13유기기 중에서 선택된 기이고, n은 1 내지 100의 정수이다.
- 제6항에 있어서, 페놀-실록산 매크로머가 하기 일반식을 갖고, n은 10 내지 30의 정수이고, 2,6-디오르가노페놀이 2,6-크실레놀인 것을 특징으로 하는 열가소성 난연성 실리콘-폴리페닐렌 에테르 그라프트 공중합체.
- 하기 일반식(3)의 2,6-디오르가노페놀을 하기 일반식(1)과 (5)중에서 선택된 페놀-실록산 매크로머와 산화성 커플링 반응시키는 것을 특징으로 하는 열가소성 난연성 실리콘-폴리페닐렌 에테르 그라프트 공중합체의 제조 방법.상기 각식에서, R은 할로겐 또는 동일하거나 상이한 일가 C1-13유기기 중에서 선택된 기이고, R1은 이가 C2-20유기기이고, R2는 동일하거나 상이한 일가 C1-13유기기 중에서 선택된 기이고, R3는 일가 C1-13유기기이고, n은 1 내지 100의 정수이다.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US45512289A | 1989-12-22 | 1989-12-22 | |
| US455,122 | 1989-12-22 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR910011997A true KR910011997A (ko) | 1991-08-07 |
Family
ID=23807502
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019900021471A KR910011997A (ko) | 1989-12-22 | 1990-12-22 | 실리콘 매크로머 및 이로부터 얻어진 열가소성 난연성 실리콘- 폴리페닐렌 에테르 그라프트 공중합체 |
Country Status (6)
| Country | Link |
|---|---|
| EP (1) | EP0433746B1 (ko) |
| JP (1) | JPH04120132A (ko) |
| KR (1) | KR910011997A (ko) |
| CA (1) | CA2025289A1 (ko) |
| DE (1) | DE69018040T2 (ko) |
| ES (1) | ES2069663T3 (ko) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5025074A (en) * | 1990-08-27 | 1991-06-18 | General Electric Company | Flame retardant organopolysiloxane-polycarbonate triblock copolymers |
| EP0515196A3 (en) * | 1991-05-24 | 1993-06-09 | General Electric Company | Method for making silicone polyphenylene ether graft copolymers and products |
| JP2542152B2 (ja) * | 1991-10-30 | 1996-10-09 | ゼネラル・エレクトリック・カンパニイ | 熱可塑性シリコ―ン−ポリフェニレンエ―テルブロック共重合体の製造法 |
| DE69410696T2 (de) * | 1993-05-25 | 1998-12-03 | Dow Corning Corp., Midland, Mich. | Polyimid mit Polsiloxan-Seitenkette |
| US5464922A (en) * | 1993-08-25 | 1995-11-07 | Dow Corning Asia Ltd. | Organopolysiloxane-grafted polybenzobisoxazoles and method for preparing same |
| JP3756576B2 (ja) * | 1995-11-29 | 2006-03-15 | 東レ・ダウコーニング株式会社 | ヒドロキシフェニル基含有ポリオルガノシロキサン |
| JP4018813B2 (ja) | 1998-07-03 | 2007-12-05 | 富士通株式会社 | 携帯電話機 |
| EP2147045A4 (en) * | 2007-05-03 | 2011-05-25 | Cardolite Corp | CARDANOL-BASED DIMERS AND USES THEREOF |
| US8017697B2 (en) * | 2008-06-24 | 2011-09-13 | Sabic Innovative Plastics Ip B.V. | Poly(arylene ether)-polysiloxane composition and method |
| CN104837896B (zh) * | 2012-11-07 | 2017-09-05 | 道康宁东丽株式会社 | 具有降低的铂含量的酚改性聚有机硅氧烷、制备该聚有机硅氧烷的方法和包含该聚有机硅氧烷的有机树脂改性剂 |
| US10294369B2 (en) | 2015-05-13 | 2019-05-21 | Sabic Global Technologies B.V. | Reinforced poly(phenylene ether) compositions, and articles prepared therefrom |
| WO2020008829A1 (ja) | 2018-07-02 | 2020-01-09 | 信越化学工業株式会社 | カルビノール変性オルガノシロキサンの製造方法 |
| JP7180315B2 (ja) * | 2018-07-02 | 2022-11-30 | 信越化学工業株式会社 | カルビノール変性オルガノシロキサンの製造方法 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3522326A (en) * | 1967-10-05 | 1970-07-28 | Gen Electric | Graft copolymers of polyphenylene ethers |
| JPS61252214A (ja) * | 1985-04-30 | 1986-11-10 | Sagami Chem Res Center | グラフト共重合体の製造方法 |
| GB8606634D0 (en) * | 1986-03-18 | 1986-04-23 | Dow Corning Ltd | Catalyst compositions |
| JPH0618884B2 (ja) * | 1988-01-18 | 1994-03-16 | 財団法人相模中央化学研究所 | 二官能性フェニル基を有するポリシロキサン系化合物 |
| JP2769840B2 (ja) * | 1989-03-24 | 1998-06-25 | チッソ株式会社 | 水酸基含有置換基を有するシロキサン化合物 |
-
1990
- 1990-09-13 CA CA002025289A patent/CA2025289A1/en not_active Abandoned
- 1990-12-04 DE DE69018040T patent/DE69018040T2/de not_active Expired - Fee Related
- 1990-12-04 ES ES90123149T patent/ES2069663T3/es not_active Expired - Lifetime
- 1990-12-04 EP EP90123149A patent/EP0433746B1/en not_active Expired - Lifetime
- 1990-12-21 JP JP2412645A patent/JPH04120132A/ja active Pending
- 1990-12-22 KR KR1019900021471A patent/KR910011997A/ko active IP Right Grant
Also Published As
| Publication number | Publication date |
|---|---|
| CA2025289A1 (en) | 1991-06-23 |
| EP0433746A3 (en) | 1992-01-15 |
| EP0433746B1 (en) | 1995-03-22 |
| ES2069663T3 (es) | 1995-05-16 |
| DE69018040D1 (de) | 1995-04-27 |
| EP0433746A2 (en) | 1991-06-26 |
| JPH04120132A (ja) | 1992-04-21 |
| DE69018040T2 (de) | 1995-11-02 |
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| Date | Code | Title | Description |
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Patent event code: PA01091R01D Comment text: Patent Application Patent event date: 19901222 |
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Patent event code: PA02012R01D Patent event date: 19951221 Comment text: Request for Examination of Application Patent event code: PA02011R01I Patent event date: 19901222 Comment text: Patent Application |
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