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KR910007852A - 올레핀의 히드로 포르밀화 방법 - Google Patents

올레핀의 히드로 포르밀화 방법 Download PDF

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Publication number
KR910007852A
KR910007852A KR1019900016731A KR900016731A KR910007852A KR 910007852 A KR910007852 A KR 910007852A KR 1019900016731 A KR1019900016731 A KR 1019900016731A KR 900016731 A KR900016731 A KR 900016731A KR 910007852 A KR910007852 A KR 910007852A
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South Korea
Prior art keywords
compound
reactor system
organic
olefin
phosphine
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KR1019900016731A
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KR0152655B1 (ko
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지히로 미야자와
히로시 미까미
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에또오 다께또시
미쓰비시가세이 가부시끼가이샤
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/02—Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

내용 없음

Description

올레핀의 히드로 포르밀화 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (7)

  1. 3가 유기인 화합물을 리간드로 갖는 로듐 촉매 존재하에 올레핀을 일산화탄소 및 수소와 반응시키는 히드로포르밀화 방법에 있어서, 히드로 포르밀화 반응을 2단계 반응기 계, 즉 액상의 혼합 특성이 실질적으로 완전한 혼합형인 반응기 또는 반응기들로 이루어진 제1단계 반응기계, 및 촉매 용액 순환형의 반응기계로서, 액상의 혼합 특성을 확산 모델로 나타낼때 식(I)
    (식중는 평균유속(㎝/초)이고, L은 반응층의 길이(㎝)이며,는 평균확산 계수(㎠/초)이다)로 정의되는 무차원수 U(이후 “유동 혼합 파라메타”로 약칭한다)가 0.4이상인 피스톤 유동형의 혼합 특성을 갖는 반응기 또는 반응기들로 이루어진 제2단계 반응기계에 의해 수행하며, 제1단계 반응기계에서 유출된 기체상 혼합물 또는 기체-액체 혼합물을 미반응 올레핀을 함유하는 스트림 및 기타 스트림으로 분리하고, 미반응올레핀을 함유하는 스트림의 일부 또는 전체를 제2단계 반응기 계에 공급함을 특징으로 하는, 올레핀의 히드로 프로밀화 방법.
  2. 제1항에 있어서, 올레핀이 2 내지 5탄소원자를 갖는 올레핀 또는 2내지 5탄소원자를 갖는 올레핀의 혼합물인 방법.
  3. 제1항에 있어서, 3가 유기인 화합물이 트리 알킬포스핀, 트리알릴 포스핀, 트리시클로알킬 포스핀, 알킬아릴 포스핀, 시클로알킬아릴포스핀, 알킬시클로알킬 포스핀 및 포스파이트의 군에서 선택된 방법.
  4. 제1항에 있어서, 3가 유기인 화합물이 로듐에 대해 다좌 배위성의 것인 방법.
  5. 제4항에 있어서, 다좌배위성 유기인 화합물이(디페닐 포스피노)포르판인 방법.
  6. 제1항에 있어서, 로듐원이 로듐 착체, 유기염, 무기염 및 산화물의 군에서 선택된 방법.
  7. 제4항에 있어서, 다좌 배위성 유기인 화합물이 하기 일반식으로 표시되는 화합물인 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임
KR1019900016731A 1989-10-19 1990-10-19 올레핀의 히드로 포르밀화 방법 KR0152655B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP272275/1989 1989-10-19
JP27227589 1989-10-19
JP1-272275 1989-10-19

Publications (2)

Publication Number Publication Date
KR910007852A true KR910007852A (ko) 1991-05-30
KR0152655B1 KR0152655B1 (ko) 1998-10-15

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KR1019900016731A KR0152655B1 (ko) 1989-10-19 1990-10-19 올레핀의 히드로 포르밀화 방법

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Country Link
US (1) US5105018A (ko)
EP (1) EP0423769B1 (ko)
JP (1) JP2893902B2 (ko)
KR (1) KR0152655B1 (ko)
BR (1) BR9005296A (ko)
CA (1) CA2027991C (ko)
DE (1) DE69017346T2 (ko)
ES (1) ES2075865T3 (ko)

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Also Published As

Publication number Publication date
EP0423769B1 (en) 1995-03-01
EP0423769A2 (en) 1991-04-24
CA2027991C (en) 2001-04-24
BR9005296A (pt) 1991-09-17
CA2027991A1 (en) 1991-04-20
ES2075865T3 (es) 1995-10-16
JP2893902B2 (ja) 1999-05-24
US5105018A (en) 1992-04-14
DE69017346T2 (de) 1995-10-12
JPH03204831A (ja) 1991-09-06
EP0423769A3 (en) 1991-07-24
DE69017346D1 (de) 1995-04-06
KR0152655B1 (ko) 1998-10-15

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