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KR910004744A - 고굴절율의 유기질 안경으로 중합가능한 액체조성물 - Google Patents

고굴절율의 유기질 안경으로 중합가능한 액체조성물 Download PDF

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Publication number
KR910004744A
KR910004744A KR1019900011925A KR900011925A KR910004744A KR 910004744 A KR910004744 A KR 910004744A KR 1019900011925 A KR1019900011925 A KR 1019900011925A KR 900011925 A KR900011925 A KR 900011925A KR 910004744 A KR910004744 A KR 910004744A
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South Korea
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weight
composition
component
oligomer
organic glasses
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KR1019900011925A
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KR940003957B1 (ko
Inventor
리베티 프랑코
렌찌 피오렌쯔
로마노 우고
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말레싼드로 디 마티아
에니켐신테시스 쏘시에떼 퍼 아찌오니
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
    • C08F218/24—Esters of carbonic or haloformic acids, e.g. allyl carbonate

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  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Optics & Photonics (AREA)
  • General Physics & Mathematics (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

내용 없음.

Description

고굴절율의 유기질 안경으로 중합가능한 액체조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (11)

  1. A) 다음 구조식(I)으로 나타낼 수 있는 20 내지 80중량%의 카본 알릴 유도체의 단량체 및 올리고머의 혼합물과,
  3. 여기서, X=할로겐(불소제외); a와 b는 서로 무관하며 1 또는 2이고; n은 최소한 10중량% 혼합물이 카본알릴올리고머 유도체를 구성하는 조건에서 1 내지 5의 값으로 예상한다(n>1), 또한, B) 성분(A)와 공중합반응할 수 있고 디알릴 이스프탈레이트, 디알릴 테레프탈레이트, 트리알릴 시안우레이트 또한 트리알릴 이소시아누레이트 중에서 선택된 80 내지 20중량%의 액체단량체를 포함하는 것을 특징으로 하는 보관기간동안 안정하고 고굴절율의 유기질 안경으로 중합할 수 있는 액체조성물.
  4. 제1항에 있어서, 성분(A)가 X=Br이고 a=b=1인 경우의 구조식(I)에 상응하는 테트라브로모 비스페놀 A디에톡시레이트 비스(알릴카보네이트) 단량체와 올리고머이고 올리고머(n>1) 함량이 15 내지 30중량%까지 변하는 것을 특징으로 하는 액체조성물.
  5. 제1항에 있어서, 35 내지 65중량%의 성분(A)와 65 내지 35중량%의 성분(B)를 함유하는 것을 특징으로 화는 조성물.
  6. 제1항에 있어서, 또한 약 30 내지 100℃의 온도에서 자유라디칼을 발생할 수 있는 중합반응 개시제를 성분(A)와 (B)를 합한 100 중량비율당 2 내지 8중량비율로 함유하는 것을 특징으로 하는 조성물.
  7. 제4항에 있어서, 개시제의 양이 성분(A)와 (B)를 합한 100중량비율당 3 내지 5 중량비율까지 변하는 것을 특징으로 하는 조성물.
  8. 제4항에 있어서, 개시제를 디이소프로필 페톡시 지카보네이트, 디시크로헥실 페록시 디카보네이트, 디-sec-부틸 페톡시 카보네이트, 디벤조일 페록시드와 tert-부틸 페르벤조에이트 중에서 선택하는 것을 특징으로 하는 조성물.
  9. 제1항에 있어서, 또한 안정제, 분리제, 염료, 안료 또한 자외선이나 적외선 흡수제중 선택된 하나나 그 이상의 첨가제를 성분(A)와 (B)를 합한 100 중량비율당 1 중량비율을 초과하지 않는 범위로 함유하는 것을 특징으로 하는 조성물.
  10. 제1항 내지 제9항 조성물을 주조법으로 중합반응하여 제조한 유기질 안경.
  11. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019900011925A 1989-08-03 1990-08-03 고굴절율의 유기절 유리용 중합가능한 액체조성물 KR940003957B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IT8921440A IT1231775B (it) 1989-08-03 1989-08-03 Composizione liquida polimerizzabile in vetri organici ad elevato indice di rifrazione.
IT21440A/89 1989-08-03

Publications (2)

Publication Number Publication Date
KR910004744A true KR910004744A (ko) 1991-03-29
KR940003957B1 KR940003957B1 (ko) 1994-05-09

Family

ID=11181829

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019900011925A KR940003957B1 (ko) 1989-08-03 1990-08-03 고굴절율의 유기절 유리용 중합가능한 액체조성물

Country Status (13)

Country Link
US (1) US5059663A (ko)
EP (1) EP0411694B1 (ko)
JP (1) JPH0370721A (ko)
KR (1) KR940003957B1 (ko)
AT (1) ATE105845T1 (ko)
AU (1) AU631230B2 (ko)
BR (1) BR9003904A (ko)
DE (1) DE69008964T2 (ko)
DK (1) DK0411694T3 (ko)
ES (1) ES2054221T3 (ko)
IE (1) IE902797A1 (ko)
IT (1) IT1231775B (ko)
MX (1) MX170690B (ko)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH1081720A (ja) * 1996-09-05 1998-03-31 Nof Corp 注型重合用樹脂組成物及び光学材料
WO2023168562A1 (zh) * 2022-03-07 2023-09-14 上纬创新育成股份有限公司 含碳酸酯的不饱和化合物、其制备方法、其制备的固化物及降解固化物的方法

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1130285B (it) * 1980-03-05 1986-06-11 Anic Spa Procedimento per la sintesi di allil carbonati di alcoli poliidrici e loro derivati
JPS60104041A (ja) * 1983-11-11 1985-06-08 Tokuyama Soda Co Ltd アリルカ−ボネ−トの製造方法
JPS617314A (ja) * 1984-06-20 1986-01-14 Kureha Chem Ind Co Ltd 高屈折率レンズ
JPS6183212A (ja) * 1984-10-01 1986-04-26 Tokuyama Soda Co Ltd 高屈折率樹脂
IT1191615B (it) * 1985-05-15 1988-03-23 Enichem Sintesi Procedimento per la preparazione di sostituti di vetri ottici e composizione liquida polimerizzabile adatta allo scopo
US4622376A (en) * 1985-06-27 1986-11-11 Ppg Industries, Inc. Composition of aromatic poly(allylcarbonate), styrene materials, and crosslinker containing three or more ethylenically unsaturated groups for producing polymer of high refractive index and low yellowness
IT1203364B (it) * 1987-03-16 1989-02-15 Enichem Sintesi Composizione liquida polimerizzabile per la produzione di articoli ottici ad elevato indice di rifrazione

Also Published As

Publication number Publication date
DE69008964D1 (de) 1994-06-23
EP0411694A2 (en) 1991-02-06
ES2054221T3 (es) 1994-08-01
US5059663A (en) 1991-10-22
EP0411694A3 (en) 1991-10-09
AU631230B2 (en) 1992-11-19
DE69008964T2 (de) 1994-11-03
EP0411694B1 (en) 1994-05-18
IT8921440A0 (it) 1989-08-03
KR940003957B1 (ko) 1994-05-09
JPH0370721A (ja) 1991-03-26
IE902797A1 (en) 1991-02-27
IT1231775B (it) 1991-12-21
DK0411694T3 (da) 1994-07-18
ATE105845T1 (de) 1994-06-15
BR9003904A (pt) 1991-09-03
AU5986090A (en) 1991-02-07
MX170690B (es) 1993-09-07

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