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KR900701709A - 포화탄화수소 사슬의 산화 - Google Patents

포화탄화수소 사슬의 산화

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Publication number
KR900701709A
KR900701709A KR1019900701455A KR900701455A KR900701709A KR 900701709 A KR900701709 A KR 900701709A KR 1019900701455 A KR1019900701455 A KR 1019900701455A KR 900701455 A KR900701455 A KR 900701455A KR 900701709 A KR900701709 A KR 900701709A
Authority
KR
South Korea
Prior art keywords
carbon atoms
saturated hydrocarbon
hydrocarbon chain
use according
alkyl group
Prior art date
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Granted
Application number
KR1019900701455A
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English (en)
Other versions
KR0151712B1 (ko
Inventor
레나타 코넬리아 휴브렛츠 다이아나
Original Assignee
원본미기재
엑손 케미칼 패턴츠 인코포레이티드
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Publication of KR900701709A publication Critical patent/KR900701709A/ko
Application granted granted Critical
Publication of KR0151712B1 publication Critical patent/KR0151712B1/ko
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/48Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/89Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C27/00Processes involving the simultaneous production of more than one class of oxygen-containing compounds
    • C07C27/10Processes involving the simultaneous production of more than one class of oxygen-containing compounds by oxidation of hydrocarbons
    • C07C27/16Processes involving the simultaneous production of more than one class of oxygen-containing compounds by oxidation of hydrocarbons with other oxidising agents
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/02Monohydroxylic acyclic alcohols
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/28Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of CHx-moieties
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/40Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with ozone; by ozonolysis
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00Systems containing only non-condensed rings
    • C07C2601/12Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14The ring being saturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)
  • Saccharide Compounds (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)

Abstract

내용 없음

Description

포화탄화수소 사슬의 산화
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (17)

  1. 950㎝-1근처의 적외선 흡광 밴드를 가지는 실리칼라이트 촉매를 함유하는 티타늄의 포화 탄화수소의 산화를 위한 용도.
  2. 제1항에 있어서, 촉매는 다음의 일반식(×는 0.0001 내지 0.04이다)×TiO2(1-×)SiO2을 가짐을 특징으로 하는 용도.
  3. 제1항 또는 제2항에 있어서, 포화 탄화수소 사슬은 2내지 18개의 탄소원자를 가지는 알칸임을 특징으로 하는 용도.
  4. 제1항 내지 제3항에 있어서, 포화탄화수소 사슬은 환(ring)구조에 부착된 최소한 2개의 탄소원자를 가지는 알킬그룹인 것을 특징으로 하는 용도.
  5. 제4항에 있어서, 알킬 그룹은 최소한 3개의 탄소원자를 가지는 것을 특징으로 하는 용도.
  6. 제4항 또는 제5항에 있어서, 환 구조는 방향성인 것을 특징으로 하는 용도.
  7. 포화유기그룹을 함유하는 화합물을, 산화제로서 950㎝-1근처의 적외선 흡광 밴드를 가지는 실리칼라이트촉매를 포함하는 티타늄 존재하에 처리하여, 포화 탄화수소 사슬을 산화시키는 방법.
  8. 제7항에 있어서, 촉매는 다음의 일반식(×는 0.0001 내지 0.04이다)×TiO2(1-×)SiO2을 가짐을 특징으로 하는 방법.
  9. 제7항 또는 제8항에 있어서, 산화제는 과산화수소 또는 과산화 유기물염을 특징으로 하는 방법.
  10. 제7항 내지 제9항의 어느 한 항에 있어서, 포화유기그룹을 가지는 화합물은 반응에 이용되는 조건하에서 액상(liquid phase) 또는 농상(dense phase)인 것을 특징으로 하는 방법.
  11. 제7항 내지 제10항의 어느 한 항에 있어서, 포화 탄화수소 사슬은 2내지 18개의 탄소원자를 가지는 알칸임을 특징으로 하는 방법.
  12. 제7항 내지 제10항의 어느 한항에 있어서, 포화 탄화수소 사슬은 환(ring) 구조에 부착된 최소한 2개의 탄소원자를 가지는 알킬그룹인 것을 특징으로 하는 방법.
  13. 제12항에 있어서, 알킬 그룹은 최소한 3개의 탄소원자를 가지는 것을 특징으로 하는 방법.
  14. 제7항 내지 제13항에 있어서, 반응은 용매 존재하에 수행됨을 특징으로 하는 방법.
  15. 제7항 내지 제14항에 있어서, 산화제는 액상 과산화수소임을 특징으로 하는 방법.
  16. 제7항 내지 제15항에 있어서, 용매는 극성 용매임을 특징으로 하는 방법.
  17. 제7항 내지 제16항에 있어서, 반응은 50내지 150℃의 온도로 수행됨을 특징으로 하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019900701455A 1988-11-08 1989-08-11 포화탄화수소 사슬의 산화 Expired - Lifetime KR0151712B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
BE8801275 1988-11-08
BE8801275 1988-11-08

Publications (2)

Publication Number Publication Date
KR900701709A true KR900701709A (ko) 1990-12-04
KR0151712B1 KR0151712B1 (ko) 1998-10-15

Family

ID=3883713

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019900701455A Expired - Lifetime KR0151712B1 (ko) 1988-11-08 1989-08-11 포화탄화수소 사슬의 산화

Country Status (12)

Country Link
US (1) US5021607A (ko)
EP (1) EP0376453B1 (ko)
JP (1) JP3049086B2 (ko)
KR (1) KR0151712B1 (ko)
AT (1) ATE96140T1 (ko)
AU (1) AU628439B2 (ko)
CA (1) CA2002494C (ko)
DE (1) DE68910101T2 (ko)
DK (1) DK163890A (ko)
ES (1) ES2059782T3 (ko)
NO (1) NO173821C (ko)
WO (1) WO1990005126A1 (ko)

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IT1231779B (it) * 1989-08-09 1991-12-21 Eniricerche Spa Procedimento per l'ossidazione di composti paraffinici.
IT1243772B (it) * 1990-08-01 1994-06-28 Eniricerche Spa Procedimento per l'ossidazione di composti paraffinici con ossigeno
GB9118959D0 (en) * 1991-09-04 1991-10-23 Exxon Chemical Patents Inc Zeolite catalyst and catalysed reactions
DE4138155A1 (de) 1991-11-21 1993-05-27 Basf Ag Verfahren zur herstellung von im wesentlichen alkalifreien titansilikat-kristallen mit zeolithstruktur
DK0549013T3 (da) * 1991-11-26 1996-10-14 Eniricerche Spa Fremgangsmåde til oxidation af organiske forbindelser med hydrogenperoxid fremstillet ved en anthraquinon redoxproces
GB9201872D0 (en) * 1992-01-29 1992-03-18 Exxon Chemical Patents Inc Improved oxidation of saturated hydrocarbon chains
DE19607577A1 (de) * 1996-02-29 1997-09-04 Basf Ag Netzkatalysator auf Basis von Titan- oder Vanadiumzeolithen und inerten Netzgeweben zur Beschleunigung von Oxidationsreaktionen
BE1010717A3 (fr) * 1996-10-25 1998-12-01 Solvay Procede de regeneration de catalyseurs.
BE1010716A3 (fr) 1996-10-25 1998-12-01 Solvay Procede de regeneration de catalyseurs de type silicalite au titane.
US6074447A (en) * 1997-02-21 2000-06-13 University Of Hawaii Hydrogen storage
BE1011577A3 (fr) * 1997-11-27 1999-11-09 Solvay Catalyseur d'epoxydation, son utilisation et procede d'epoxydation en presence de catalyseur.
BE1011578A3 (fr) * 1997-11-27 1999-11-09 Solvay Catalyseur d'epoxydation, son utilisation et procede d'epoxydation en presence de ce catalyseur.
IT1299277B1 (it) * 1998-05-19 2000-02-29 Enichem Spa Metodo di attivazione della titanio silicalite e suo impiego per la sintesi di fenolo
RU2137745C1 (ru) * 1998-08-04 1999-09-20 Общество с ограниченной ответственностью "НТЦ ХТ" Способ получения трет-бутилового спирта
RU2139272C1 (ru) * 1998-08-04 1999-10-10 Общество с ограниченной ответственностью "НТЦ ХТ" Способ получения трет-бутилового спирта
DE19925534A1 (de) 1999-06-04 2000-12-07 Degussa Verfahren zur Aufbereitung von Abwässern
DE19939416A1 (de) 1999-08-20 2001-02-22 Basf Ag Verfahren zur Herstellung eines kristallinen, zeolithischen Feststoffs
GB9925971D0 (en) * 1999-11-03 1999-12-29 Exxon Chemical Patents Inc Reduced particulate froming distillate fuels
US6458176B2 (en) 1999-12-21 2002-10-01 Exxonmobil Research And Engineering Company Diesel fuel composition
US6716258B2 (en) 1999-12-21 2004-04-06 Exxonmobil Research And Engineering Company Fuel composition
US6447557B1 (en) 1999-12-21 2002-09-10 Exxonmobil Research And Engineering Company Diesel fuel composition
US6447558B1 (en) 1999-12-21 2002-09-10 Exxonmobil Research And Engineering Company Diesel fuel composition
RU2481389C2 (ru) 2007-02-06 2013-05-10 ЭСТРАДА Марсело АКОСТА Процесс изменения вязкости сырой нефти
RU2378244C1 (ru) * 2008-05-20 2010-01-10 Государственное образовательное учреждение высшего профессионального образования Нижегородский государственный технический университет им. Р.Е. Алексеева (ГОУВПО НГТУ) Способ получения высших жирных спиртов
BR112012032687A2 (pt) 2010-06-25 2017-06-20 Univ College Cardiff Consultants Ltd processo para a oxidação completa ou parcial de hidrocarbonetos
US20130324761A1 (en) * 2011-02-02 2013-12-05 University College Cardiff Consulltants Limited Hydrocarbons selective oxidation with heterogeneous catalysts
TWI426050B (zh) * 2011-04-19 2014-02-11 China Petrochemical Dev Corp Taipei Taiwan A method for preparing titanium-silicon molecular sieve and method for producing cyclohexanone oxime using the molecular sieve
CN102766032B (zh) * 2011-05-05 2014-10-01 中国石油化工股份有限公司 一种环己烷氧化的方法
EP3983368B1 (en) 2019-06-12 2023-08-02 Nouryon Chemicals International B.V. Process for the production of diacyl peroxides
JP7281563B2 (ja) 2019-06-12 2023-05-25 ヌーリオン ケミカルズ インターナショナル ベスローテン フェノーツハップ ペルオキシエステルを生成するためのプロセス
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HUE063677T2 (hu) 2019-06-12 2024-01-28 Nouryon Chemicals Int Bv Eljárás diacil-peroxidok elõállítására
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Also Published As

Publication number Publication date
NO173821B (no) 1993-11-01
JPH03503741A (ja) 1991-08-22
DK163890D0 (da) 1990-07-06
AU628439B2 (en) 1992-09-17
DE68910101D1 (de) 1993-11-25
NO903037D0 (no) 1990-07-06
CA2002494A1 (en) 1990-05-08
KR0151712B1 (ko) 1998-10-15
NO903037L (no) 1990-09-04
WO1990005126A1 (en) 1990-05-17
CA2002494C (en) 2001-07-17
ATE96140T1 (de) 1993-11-15
JP3049086B2 (ja) 2000-06-05
AU4636289A (en) 1990-05-28
DK163890A (da) 1990-08-23
NO173821C (no) 1994-02-09
ES2059782T3 (es) 1994-11-16
DE68910101T2 (de) 1994-06-30
US5021607A (en) 1991-06-04
EP0376453B1 (en) 1993-10-20
EP0376453A1 (en) 1990-07-04

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