KR900701709A - 포화탄화수소 사슬의 산화 - Google Patents
포화탄화수소 사슬의 산화Info
- Publication number
- KR900701709A KR900701709A KR1019900701455A KR900701455A KR900701709A KR 900701709 A KR900701709 A KR 900701709A KR 1019900701455 A KR1019900701455 A KR 1019900701455A KR 900701455 A KR900701455 A KR 900701455A KR 900701709 A KR900701709 A KR 900701709A
- Authority
- KR
- South Korea
- Prior art keywords
- carbon atoms
- saturated hydrocarbon
- hydrocarbon chain
- use according
- alkyl group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C27/00—Processes involving the simultaneous production of more than one class of oxygen-containing compounds
- C07C27/10—Processes involving the simultaneous production of more than one class of oxygen-containing compounds by oxidation of hydrocarbons
- C07C27/16—Processes involving the simultaneous production of more than one class of oxygen-containing compounds by oxidation of hydrocarbons with other oxidising agents
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
- C07C31/02—Monohydroxylic acyclic alcohols
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/28—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of CHx-moieties
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/40—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with ozone; by ozonolysis
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/14—The ring being saturated
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)
- Saccharide Compounds (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Abstract
Description
Claims (17)
- 950㎝-1근처의 적외선 흡광 밴드를 가지는 실리칼라이트 촉매를 함유하는 티타늄의 포화 탄화수소의 산화를 위한 용도.
- 제1항에 있어서, 촉매는 다음의 일반식(×는 0.0001 내지 0.04이다)×TiO2(1-×)SiO2을 가짐을 특징으로 하는 용도.
- 제1항 또는 제2항에 있어서, 포화 탄화수소 사슬은 2내지 18개의 탄소원자를 가지는 알칸임을 특징으로 하는 용도.
- 제1항 내지 제3항에 있어서, 포화탄화수소 사슬은 환(ring)구조에 부착된 최소한 2개의 탄소원자를 가지는 알킬그룹인 것을 특징으로 하는 용도.
- 제4항에 있어서, 알킬 그룹은 최소한 3개의 탄소원자를 가지는 것을 특징으로 하는 용도.
- 제4항 또는 제5항에 있어서, 환 구조는 방향성인 것을 특징으로 하는 용도.
- 포화유기그룹을 함유하는 화합물을, 산화제로서 950㎝-1근처의 적외선 흡광 밴드를 가지는 실리칼라이트촉매를 포함하는 티타늄 존재하에 처리하여, 포화 탄화수소 사슬을 산화시키는 방법.
- 제7항에 있어서, 촉매는 다음의 일반식(×는 0.0001 내지 0.04이다)×TiO2(1-×)SiO2을 가짐을 특징으로 하는 방법.
- 제7항 또는 제8항에 있어서, 산화제는 과산화수소 또는 과산화 유기물염을 특징으로 하는 방법.
- 제7항 내지 제9항의 어느 한 항에 있어서, 포화유기그룹을 가지는 화합물은 반응에 이용되는 조건하에서 액상(liquid phase) 또는 농상(dense phase)인 것을 특징으로 하는 방법.
- 제7항 내지 제10항의 어느 한 항에 있어서, 포화 탄화수소 사슬은 2내지 18개의 탄소원자를 가지는 알칸임을 특징으로 하는 방법.
- 제7항 내지 제10항의 어느 한항에 있어서, 포화 탄화수소 사슬은 환(ring) 구조에 부착된 최소한 2개의 탄소원자를 가지는 알킬그룹인 것을 특징으로 하는 방법.
- 제12항에 있어서, 알킬 그룹은 최소한 3개의 탄소원자를 가지는 것을 특징으로 하는 방법.
- 제7항 내지 제13항에 있어서, 반응은 용매 존재하에 수행됨을 특징으로 하는 방법.
- 제7항 내지 제14항에 있어서, 산화제는 액상 과산화수소임을 특징으로 하는 방법.
- 제7항 내지 제15항에 있어서, 용매는 극성 용매임을 특징으로 하는 방법.
- 제7항 내지 제16항에 있어서, 반응은 50내지 150℃의 온도로 수행됨을 특징으로 하는 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BE8801275 | 1988-11-08 | ||
BE8801275 | 1988-11-08 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR900701709A true KR900701709A (ko) | 1990-12-04 |
KR0151712B1 KR0151712B1 (ko) | 1998-10-15 |
Family
ID=3883713
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019900701455A Expired - Lifetime KR0151712B1 (ko) | 1988-11-08 | 1989-08-11 | 포화탄화수소 사슬의 산화 |
Country Status (12)
Country | Link |
---|---|
US (1) | US5021607A (ko) |
EP (1) | EP0376453B1 (ko) |
JP (1) | JP3049086B2 (ko) |
KR (1) | KR0151712B1 (ko) |
AT (1) | ATE96140T1 (ko) |
AU (1) | AU628439B2 (ko) |
CA (1) | CA2002494C (ko) |
DE (1) | DE68910101T2 (ko) |
DK (1) | DK163890A (ko) |
ES (1) | ES2059782T3 (ko) |
NO (1) | NO173821C (ko) |
WO (1) | WO1990005126A1 (ko) |
Families Citing this family (33)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IT1231779B (it) * | 1989-08-09 | 1991-12-21 | Eniricerche Spa | Procedimento per l'ossidazione di composti paraffinici. |
IT1243772B (it) * | 1990-08-01 | 1994-06-28 | Eniricerche Spa | Procedimento per l'ossidazione di composti paraffinici con ossigeno |
GB9118959D0 (en) * | 1991-09-04 | 1991-10-23 | Exxon Chemical Patents Inc | Zeolite catalyst and catalysed reactions |
DE4138155A1 (de) | 1991-11-21 | 1993-05-27 | Basf Ag | Verfahren zur herstellung von im wesentlichen alkalifreien titansilikat-kristallen mit zeolithstruktur |
DK0549013T3 (da) * | 1991-11-26 | 1996-10-14 | Eniricerche Spa | Fremgangsmåde til oxidation af organiske forbindelser med hydrogenperoxid fremstillet ved en anthraquinon redoxproces |
GB9201872D0 (en) * | 1992-01-29 | 1992-03-18 | Exxon Chemical Patents Inc | Improved oxidation of saturated hydrocarbon chains |
DE19607577A1 (de) * | 1996-02-29 | 1997-09-04 | Basf Ag | Netzkatalysator auf Basis von Titan- oder Vanadiumzeolithen und inerten Netzgeweben zur Beschleunigung von Oxidationsreaktionen |
BE1010717A3 (fr) * | 1996-10-25 | 1998-12-01 | Solvay | Procede de regeneration de catalyseurs. |
BE1010716A3 (fr) | 1996-10-25 | 1998-12-01 | Solvay | Procede de regeneration de catalyseurs de type silicalite au titane. |
US6074447A (en) * | 1997-02-21 | 2000-06-13 | University Of Hawaii | Hydrogen storage |
BE1011577A3 (fr) * | 1997-11-27 | 1999-11-09 | Solvay | Catalyseur d'epoxydation, son utilisation et procede d'epoxydation en presence de catalyseur. |
BE1011578A3 (fr) * | 1997-11-27 | 1999-11-09 | Solvay | Catalyseur d'epoxydation, son utilisation et procede d'epoxydation en presence de ce catalyseur. |
IT1299277B1 (it) * | 1998-05-19 | 2000-02-29 | Enichem Spa | Metodo di attivazione della titanio silicalite e suo impiego per la sintesi di fenolo |
RU2137745C1 (ru) * | 1998-08-04 | 1999-09-20 | Общество с ограниченной ответственностью "НТЦ ХТ" | Способ получения трет-бутилового спирта |
RU2139272C1 (ru) * | 1998-08-04 | 1999-10-10 | Общество с ограниченной ответственностью "НТЦ ХТ" | Способ получения трет-бутилового спирта |
DE19925534A1 (de) | 1999-06-04 | 2000-12-07 | Degussa | Verfahren zur Aufbereitung von Abwässern |
DE19939416A1 (de) | 1999-08-20 | 2001-02-22 | Basf Ag | Verfahren zur Herstellung eines kristallinen, zeolithischen Feststoffs |
GB9925971D0 (en) * | 1999-11-03 | 1999-12-29 | Exxon Chemical Patents Inc | Reduced particulate froming distillate fuels |
US6458176B2 (en) | 1999-12-21 | 2002-10-01 | Exxonmobil Research And Engineering Company | Diesel fuel composition |
US6716258B2 (en) | 1999-12-21 | 2004-04-06 | Exxonmobil Research And Engineering Company | Fuel composition |
US6447557B1 (en) | 1999-12-21 | 2002-09-10 | Exxonmobil Research And Engineering Company | Diesel fuel composition |
US6447558B1 (en) | 1999-12-21 | 2002-09-10 | Exxonmobil Research And Engineering Company | Diesel fuel composition |
RU2481389C2 (ru) | 2007-02-06 | 2013-05-10 | ЭСТРАДА Марсело АКОСТА | Процесс изменения вязкости сырой нефти |
RU2378244C1 (ru) * | 2008-05-20 | 2010-01-10 | Государственное образовательное учреждение высшего профессионального образования Нижегородский государственный технический университет им. Р.Е. Алексеева (ГОУВПО НГТУ) | Способ получения высших жирных спиртов |
BR112012032687A2 (pt) | 2010-06-25 | 2017-06-20 | Univ College Cardiff Consultants Ltd | processo para a oxidação completa ou parcial de hidrocarbonetos |
US20130324761A1 (en) * | 2011-02-02 | 2013-12-05 | University College Cardiff Consulltants Limited | Hydrocarbons selective oxidation with heterogeneous catalysts |
TWI426050B (zh) * | 2011-04-19 | 2014-02-11 | China Petrochemical Dev Corp Taipei Taiwan | A method for preparing titanium-silicon molecular sieve and method for producing cyclohexanone oxime using the molecular sieve |
CN102766032B (zh) * | 2011-05-05 | 2014-10-01 | 中国石油化工股份有限公司 | 一种环己烷氧化的方法 |
EP3983368B1 (en) | 2019-06-12 | 2023-08-02 | Nouryon Chemicals International B.V. | Process for the production of diacyl peroxides |
JP7281563B2 (ja) | 2019-06-12 | 2023-05-25 | ヌーリオン ケミカルズ インターナショナル ベスローテン フェノーツハップ | ペルオキシエステルを生成するためのプロセス |
WO2020249692A1 (en) * | 2019-06-12 | 2020-12-17 | Nouryon Chemicals International B.V. | Method for isolating carboxylic acid from an aqueous side stream |
HUE063677T2 (hu) | 2019-06-12 | 2024-01-28 | Nouryon Chemicals Int Bv | Eljárás diacil-peroxidok elõállítására |
ES2963382T3 (es) | 2019-06-12 | 2024-03-26 | Nouryon Chemicals Int Bv | Proceso para la producción de peróxidos de diacilo |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2808442A (en) * | 1953-06-16 | 1957-10-01 | Shell Dev | Production of hydroxy ethers |
IT1152296B (it) * | 1982-07-28 | 1986-12-31 | Anic Spa | Procedimento per la sintesi di monometileteri dei glicoli |
IT1152298B (it) * | 1982-07-28 | 1986-12-31 | Anic Spa | Procedimento per l'ossidazione di alcooli ad aldeidi e/o chetoni |
IT1184316B (it) * | 1985-02-05 | 1987-10-28 | Enichem Sintesi | Procedimento per la monoepossidazione di composti contenenti due doppi legami |
DE3780476T2 (de) * | 1986-01-28 | 1992-12-17 | Enichem Sintesi | Verfahren zur epoxydation von olefinischen verbindungen. |
DE3801106A1 (de) * | 1988-01-16 | 1989-07-27 | Basf Ag | Verfahren zur herstellung von phenylethanolen |
-
1989
- 1989-08-11 KR KR1019900701455A patent/KR0151712B1/ko not_active Expired - Lifetime
- 1989-11-08 ES ES89311569T patent/ES2059782T3/es not_active Expired - Lifetime
- 1989-11-08 DE DE68910101T patent/DE68910101T2/de not_active Expired - Lifetime
- 1989-11-08 CA CA002002494A patent/CA2002494C/en not_active Expired - Lifetime
- 1989-11-08 JP JP2500222A patent/JP3049086B2/ja not_active Expired - Lifetime
- 1989-11-08 AU AU46362/89A patent/AU628439B2/en not_active Expired
- 1989-11-08 WO PCT/GB1989/001328 patent/WO1990005126A1/en active Application Filing
- 1989-11-08 AT AT89311569T patent/ATE96140T1/de not_active IP Right Cessation
- 1989-11-08 EP EP89311569A patent/EP0376453B1/en not_active Expired - Lifetime
- 1989-11-11 US US07/536,679 patent/US5021607A/en not_active Expired - Lifetime
-
1990
- 1990-07-06 NO NO903037A patent/NO173821C/no not_active IP Right Cessation
- 1990-07-06 DK DK163890A patent/DK163890A/da not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
NO173821B (no) | 1993-11-01 |
JPH03503741A (ja) | 1991-08-22 |
DK163890D0 (da) | 1990-07-06 |
AU628439B2 (en) | 1992-09-17 |
DE68910101D1 (de) | 1993-11-25 |
NO903037D0 (no) | 1990-07-06 |
CA2002494A1 (en) | 1990-05-08 |
KR0151712B1 (ko) | 1998-10-15 |
NO903037L (no) | 1990-09-04 |
WO1990005126A1 (en) | 1990-05-17 |
CA2002494C (en) | 2001-07-17 |
ATE96140T1 (de) | 1993-11-15 |
JP3049086B2 (ja) | 2000-06-05 |
AU4636289A (en) | 1990-05-28 |
DK163890A (da) | 1990-08-23 |
NO173821C (no) | 1994-02-09 |
ES2059782T3 (es) | 1994-11-16 |
DE68910101T2 (de) | 1994-06-30 |
US5021607A (en) | 1991-06-04 |
EP0376453B1 (en) | 1993-10-20 |
EP0376453A1 (en) | 1990-07-04 |
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