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KR900008315A - 일렉트로크롬 시스템용 카운터 전극 - Google Patents

일렉트로크롬 시스템용 카운터 전극 Download PDF

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Publication number
KR900008315A
KR900008315A KR1019890016873A KR890016873A KR900008315A KR 900008315 A KR900008315 A KR 900008315A KR 1019890016873 A KR1019890016873 A KR 1019890016873A KR 890016873 A KR890016873 A KR 890016873A KR 900008315 A KR900008315 A KR 900008315A
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KR
South Korea
Prior art keywords
nickel oxide
electrochromium
oxide layer
lithium
electrochrome
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
KR1019890016873A
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English (en)
Inventor
부포 베르나르
르베 프랑소와
드펜디니 프랑시스
파도 크리스챤
Original Assignee
에스. 르 바그레즈
쎙-고뱅 비뜨라지 인터나쇼날
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 에스. 르 바그레즈, 쎙-고뱅 비뜨라지 인터나쇼날 filed Critical 에스. 르 바그레즈
Publication of KR900008315A publication Critical patent/KR900008315A/ko
Ceased legal-status Critical Current

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Classifications

    • G—PHYSICS
    • G02—OPTICS
    • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/17—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on variable-absorption elements not provided for in groups G02F1/015 - G02F1/169
    • G—PHYSICS
    • G02—OPTICS
    • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/15—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on an electrochromic effect
    • G02F1/153—Constructional details
    • G02F1/155—Electrodes
    • G—PHYSICS
    • G02—OPTICS
    • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/15—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on an electrochromic effect
    • G02F1/1514—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on an electrochromic effect characterised by the electrochromic material, e.g. by the electrodeposited material
    • G02F1/1523—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on an electrochromic effect characterised by the electrochromic material, e.g. by the electrodeposited material comprising inorganic material
    • G02F1/1524—Transition metal compounds

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  • Physics & Mathematics (AREA)
  • Nonlinear Science (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Electrochromic Elements, Electrophoresis, Or Variable Reflection Or Absorption Elements (AREA)
  • Devices For Indicating Variable Information By Combining Individual Elements (AREA)
  • Surface Treatment Of Glass (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Electrodes For Compound Or Non-Metal Manufacture (AREA)

Abstract

내용 없음.

Description

일렉트로크롬 시스템용 카운터 전극
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 본 발명에 따른 프레임 워크내에서의 5개의 곡선을 도시한 도면,
제2도는 제이차 이온의 질량 분광 분석에 의해 얻어진 제1도와 유사한 5개의 곡선을 도시한 도면,
제3도는 이렇게 하여 얻어진 사이클의 일반 형상을 도시한 도면,
제4도는 층당 하나의 사이클만으로 도시한 도면.

Claims (14)

  1. 투명 전기 전도층과, 전이 금속 산화물 특히, 삼산화 텅스텐으로 구성된 일렉트로크롬 재료층, 리듐 이온전도 재료층, 카운터 전극과 다른 전도층으로 코팅된 투명 매질 유체 특히, 유리로 구성된 일렉트로크롬 시스템에 있어서, 카운터 전극이 산화 니켈층으로 구성된 것을 특징으로 하는 일렉트로크롬 시스템.
  2. 제1항에 있어서, 산화 니켈층은 수소를 가진 플라즈마를 가진 음극 반응 스퍼터링에 의해 도포된 것을 특징으로 하는 일렉트로크롬 시스템.
  3. 제2항에 있어서, 산화 니켈층은 약 2mm두께의 니켈 금속 타게트의 기초로부터 자장에 의해 조력되는 음극 반응 스퍼터링에 의해 도포되는 것을 특징으로 하는 일렉트로크롬 시스템.
  4. 제2항 또는 제3항에 있어서, 상기 플라즈마의 산소-수소비가 대략 80대 20인 것을 특징으로 하는 일렉트로크롬 시스템.
  5. 제2항 내지 제4항에 있어서, 대부분의 산화 니켈은 음-극 스퍼터링에 의해 도포된 산화 니켈층의 가성 칼리내에서 감소에 의해 얻어진 Ni(0)B상태에 있는 것을 특징으로 하는 일렉트로크롬 시스템.
  6. 제1항 내지 제4항에 있어서, 대부분의 산화 니켈은 Ni(0)A 상태를 있는 것을 특징으로 하는 일렉트로크롬 시스템.
  7. 제1항 내지 제6항에 있어서, 기준 전극은 60내지 300nm사이의 두께, 양호하게는 80내지 100nm사이의 두께를 가진 것을 특징으로 하는 일렉트로크롬 시스템.
  8. 제1항 내지 제7항에 있어서, 산화 니켈층은 1원자의 니켈 대 1.60원자의 산소의 비율을 가진 것을 특징으로 하는 일렉트로크롬 시스템.
  9. 제1항 내지 제8항에 있어서, 리듐 이온 전도 재료는 탄화프로필렌내에 리듐 과염화물 용액인 것을 특징으로 하는 일렉트로크롬 시스템.
  10. 제1항 내지 제8항에 있어서, 리듐 이온 전도 재료는 매크론-분자 리듐 도체인 것을 특징으로 하는 일렉트로크롬 시스템.
  11. 제10항에 있어서, 이온 도체 재료는 에틸렌 플리옥사이드내에서 리듐 과염화물의 고체 용액인 것을 특징으로 하는 일렉트로크롬 시스템.
  12. 제1항 내지 제8항에 있어서, 이온 도체 재료는 티탄 알콕사이드의 기초로부터 얻어진 리듐 도체 겔인 것을 특징으로 하는 일렉트로크롬 시스템.
  13. 제1항 내지 제12항에 있어서, 시스템은 산화 니켈층의 도포후 12시간 이내에 조립되는 것을 특징으로 하는 일렉트로크롬 시스템.
  14. 제13항에 있어서, 산화 니켈층은 조립전에 강무수화 조건하에서 유지되는 것을 특징으로 하는 일렉트로크롬 시스템.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019890016873A 1988-11-21 1989-11-21 일렉트로크롬 시스템용 카운터 전극 Ceased KR900008315A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR8815086 1988-11-21
FR8815086A FR2639441A1 (fr) 1988-11-21 1988-11-21 Contre-electrode pour systemes electrochromes

Publications (1)

Publication Number Publication Date
KR900008315A true KR900008315A (ko) 1990-06-04

Family

ID=9372020

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019890016873A Ceased KR900008315A (ko) 1988-11-21 1989-11-21 일렉트로크롬 시스템용 카운터 전극

Country Status (10)

Country Link
US (1) US5164855A (ko)
EP (1) EP0373020B1 (ko)
JP (1) JPH02199429A (ko)
KR (1) KR900008315A (ko)
AT (1) ATE111237T1 (ko)
BR (1) BR8905853A (ko)
CA (1) CA2003386A1 (ko)
DE (1) DE68918063T2 (ko)
ES (1) ES2063155T3 (ko)
FR (1) FR2639441A1 (ko)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5274493A (en) * 1989-07-13 1993-12-28 Elf Atochem North America, Inc. Electrochromic element, materials for use in such element, processes for making such element and such materials and use of such element in an electrochromic glass device
US5086351A (en) * 1989-07-13 1992-02-04 M&T Chemicals, Inc. Electrochromic elements, materials for use in such element, processes for making such elements and such materials and use of such element in an electrochromic glass device
US5352504A (en) * 1990-11-14 1994-10-04 Saint-Gobain Vitrage International Electrochromic glazing
FR2690536B1 (fr) * 1992-04-28 1994-06-17 Saint Gobain Vitrage Int Vitrage electrochrome.
US5643369A (en) * 1993-06-24 1997-07-01 Fuji Xerox Co., Ltd. Photoelectric conversion element having an infrared transmissive indium-tin oxide film
JP2961236B2 (ja) * 1995-02-15 1999-10-12 工業技術院長 酸化ニッケル系エレクトロクロミック材料の製造方法
EP0770900A1 (fr) 1995-10-26 1997-05-02 Saint-Gobain Vitrage Vitrage électrochrome
DE19824127A1 (de) * 1998-05-29 1999-12-02 Bayer Ag Elektrochrome Anordnung auf Basis von Poly-(3,4-ethylendioxy-thiophen)-Derivaten in Kombination mit einer Gegenelektrode, die Metalloxide aus der VI. oder VIII. Nebengruppe enthält
FR2793888B1 (fr) * 1999-05-20 2002-06-28 Saint Gobain Vitrage Dispositif electrochimique
US7042615B2 (en) * 2002-05-17 2006-05-09 The Regents Of The University Of California Electrochromic devices based on lithium insertion
US7372610B2 (en) 2005-02-23 2008-05-13 Sage Electrochromics, Inc. Electrochromic devices and methods
US9782949B2 (en) 2008-05-30 2017-10-10 Corning Incorporated Glass laminated articles and layered articles
US7715082B2 (en) * 2008-06-30 2010-05-11 Soladigm, Inc. Electrochromic devices based on lithium insertion
US9664974B2 (en) 2009-03-31 2017-05-30 View, Inc. Fabrication of low defectivity electrochromic devices
US8525019B2 (en) 2010-07-01 2013-09-03 Primestar Solar, Inc. Thin film article and method for forming a reduced conductive area in transparent conductive films for photovoltaic modules
US9454053B2 (en) 2011-12-12 2016-09-27 View, Inc. Thin-film devices and fabrication
CN109491172B (zh) * 2018-12-27 2021-06-18 中国建筑材料科学研究总院有限公司 电致变色器件的离子传导层材料筛选方法

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Publication number Priority date Publication date Assignee Title
FR2442512A1 (fr) * 1978-11-22 1980-06-20 Anvar Nouveaux materiaux elastomeres a conduction ionique
JPS59102216A (ja) * 1982-12-06 1984-06-13 Canon Inc 全固体型エレクトロクロミツク素子の製造方法
JPS6028630A (ja) * 1983-07-27 1985-02-13 Nippon Kogaku Kk <Nikon> リチウムイオンを利用するエレクトロクロミツク表示素子
US4761061A (en) * 1985-09-19 1988-08-02 Asahi Glass Company Ltd. Method for fabrication of electrochromic device and the same fabricated by the method
FR2593321B1 (fr) * 1986-01-23 1990-11-16 Giers Materiau conducteur ionique utilisable comme electrolyte solide de type gel
FR2601150B1 (fr) * 1986-07-04 1991-05-31 Saint Gobain Vitrage Vitrage a transmission variable du type electrochrome
US4805996A (en) * 1986-12-18 1989-02-21 Ford Motor Company Electrochromic optical shutter
DE3643690A1 (de) * 1986-12-20 1988-07-07 Dornier System Gmbh Steuerbare scheibe
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US4923289A (en) * 1988-10-05 1990-05-08 Ford Motor Company Electrochromic devices having a gradient of color intensities

Also Published As

Publication number Publication date
JPH02199429A (ja) 1990-08-07
EP0373020A1 (fr) 1990-06-13
DE68918063T2 (de) 1995-05-11
BR8905853A (pt) 1990-06-12
CA2003386A1 (fr) 1990-05-21
EP0373020B1 (fr) 1994-09-07
FR2639441B1 (ko) 1993-02-26
FR2639441A1 (fr) 1990-05-25
DE68918063D1 (de) 1994-10-13
ATE111237T1 (de) 1994-09-15
US5164855A (en) 1992-11-17
ES2063155T3 (es) 1995-01-01

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