KR900004838A - 혼화성 중합체 혼합물 - Google Patents
혼화성 중합체 혼합물 Download PDFInfo
- Publication number
- KR900004838A KR900004838A KR1019890013213A KR890013213A KR900004838A KR 900004838 A KR900004838 A KR 900004838A KR 1019890013213 A KR1019890013213 A KR 1019890013213A KR 890013213 A KR890013213 A KR 890013213A KR 900004838 A KR900004838 A KR 900004838A
- Authority
- KR
- South Korea
- Prior art keywords
- polymer mixture
- polymer
- weight
- copolymer
- styrene
- Prior art date
Links
- 229920002959 polymer blend Polymers 0.000 title claims abstract 25
- 229920001577 copolymer Polymers 0.000 claims abstract description 14
- 229920000642 polymer Polymers 0.000 claims abstract 12
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims abstract 6
- 239000000178 monomer Substances 0.000 claims abstract 4
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract 3
- 239000001257 hydrogen Substances 0.000 claims abstract 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims abstract 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 5
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 3
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims 4
- 125000001931 aliphatic group Chemical group 0.000 claims 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 3
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 2
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims 2
- 239000005062 Polybutadiene Substances 0.000 claims 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 claims 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 1
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 claims 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 1
- 229920002857 polybutadiene Polymers 0.000 claims 1
- 229920001195 polyisoprene Polymers 0.000 claims 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- 238000010586 diagram Methods 0.000 description 1
- -1 polyethylene methacrylate Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/08—Copolymers of styrene
- C08L25/14—Copolymers of styrene with unsaturated esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/08—Homopolymers or copolymers of acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/10—Homopolymers or copolymers of methacrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Description
Claims (23)
- (A) 일반식(I)의 공중합체 1 내지 99중량% 및 (B) 하나이상의 일반식(Ⅱ)의 단량체로부터 제조된 폴리알킬 메타크릴레이트 99 내지 1중량%로 필수적으로 구성된, 2개의 중합체의 혼화성 중합체 혼합물.상기식에서, R1은 C1-4지방족 탄화수소 그룹이고; R2는 수소 또는 메틸이며; R3는 C2-8비-사이클릭 지방족 탄화수소 그룹이고; χ는 공중합체(I)의 양을 기준으로 10 내지 90중량%이며; y는 공중합체(I)의 양을 기준으로 90 내지 10중량%이다.
- 제1항에 있어서, 공중합체(I) 5 내지 95중량% 및 폴리알킬 메타크릴레이트 95 내지 5중량%로 필수적으로 구성된 중합체 혼합물.
- 제1항에 있어서, 공중합체(I) 25 내지 75중량% 및 폴리알킬 메타크릴레이트 75 내지 25중량%로 필수적으로 구성된 중합체 혼합물.
- 제1항에 있어서, R1이 C2-4지방족 탄화수소 그룹인 중합체 혼합물.
- 제1항에 있어서, R2가 수소인 중합체 혼합물.
- 제1항에 있어서, 상기 폴리알킬 메타크릴레이트가 일반식(Ⅱ)의 단량체로부터 유도된 단위 80중량%이상을 함유하는 중합체 혼합물.
- 제1항에 있어서, 공중합체(I)이 n-부틸아크릴 레이트 및 스티렌의 공중합체인 중합체 혼합물.
- 제7항에 있어서, n-부틸아크릴레이트:스티렌의 비가 40:80 내지 80:20의 범위내인 중합체 혼합물.
- 제7항에 있어서, R3가 이소부틸인 중합체 혼합물.
- 제7항에 있어서, R3가 n-프로필인 중합체 혼합물.
- 제7항에 있어서, R3가 n-헥실인 중합체 혼합물.
- 제7항에 있어서, R3가 에틸인 중합체 혼합물.
- 제7항에 있어서, R3가 n-부틸인 중합체 혼합물.
- 제1항에 있어서, 공중합체(I)이 에틸아크릴 레이트 및 스티렌의 공중합체를 함유하는 중합체 혼합물.
- 제14항에 있어서, 에틸아크릴레이트: 스티렌의 비가 70:30 내지 20:80의 범위내인 중합체 혼합물.
- 제14항에 있어서, R3가 에틸인 중합체 혼합물.
- 제1항에 있어서, 상기 공중합체(I)가 메틸아크릴 레이트 및 스티렌의 공중합체를 함유하는 중합체 혼합물.
- 제17항에 있어서, 메틸아크릴레이트:스티렌의 비가 50:50 내지 20:80의 범위내인 중합체 혼합물.
- 제17항에 있어서, R3가 에틸인 중합체 혼합물.
- 제1항의 혼화성 중합체 혼합물 40 내지 99중량%, 및 상기 공중합체(I), 폴리알킬 메타크릴레이트 및 상기 혼화성 중합체 혼합물과 비혼화성인 제3의 중합체 60 내지 1중량%를 함유하는 중합체 조성물.
- 제20항에 있어서, 상기 혼화성 중합체 혼합물 70 내지 95중량% 및 상기 제3의 중합체 30 내지 5중량%를 함유하는 중합체 조성물.
- 제20항에 있어서, 1n25 DPM-n25 DPI〈0.01(여기서, n25 DPM가 혼화성 중합체 혼합물의 굴절률이고 n25 DP가 제3의 중합체의 굴절률이다)인 중합체 조성물.
- 제20항에 있어서, 상기 제3의 중합체가 폴리부타디엔 또는 폴리이소프렌인 중합체 조성물.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE3831499A DE3831499A1 (de) | 1988-09-16 | 1988-09-16 | Vertraegliche polymermischungen (ii) |
DEP3831499.1 | 1988-09-16 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR900004838A true KR900004838A (ko) | 1990-04-13 |
KR0150777B1 KR0150777B1 (ko) | 1998-10-15 |
Family
ID=6363075
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019890013213A KR0150777B1 (ko) | 1988-09-16 | 1989-09-12 | 혼화성 중합체 혼합물 |
Country Status (8)
Country | Link |
---|---|
US (1) | US5109072A (ko) |
EP (1) | EP0359185B1 (ko) |
JP (1) | JP2839571B2 (ko) |
KR (1) | KR0150777B1 (ko) |
AT (1) | ATE106925T1 (ko) |
CA (1) | CA1339041C (ko) |
DE (2) | DE3831499A1 (ko) |
ES (1) | ES2056171T3 (ko) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20200099181A (ko) * | 2017-12-19 | 2020-08-21 | 헨켈 아게 운트 코. 카게아아 | 플라스틱 부품, 특히 접착제 어플리케이션의 제조를 위한 장치 및 방법 |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4105793A1 (de) * | 1991-02-23 | 1992-08-27 | Roehm Gmbh | Vertraegliche polymermischungen |
DE4231995A1 (de) * | 1992-09-24 | 1994-03-31 | Roehm Gmbh | Lichtstreuende Polystyrolformmasse und daraus hergestellte Formkörper |
JP2952456B2 (ja) * | 1993-01-19 | 1999-09-27 | 三洋化成工業株式会社 | 顔料分散用樹脂組成物 |
DE4443557A1 (de) * | 1994-12-07 | 1996-06-13 | Roehm Gmbh | Hochwärmeformbeständige, spannungsrißbeständige Polymethacrylat-Formmassen |
WO2008087964A1 (ja) * | 2007-01-17 | 2008-07-24 | Soken Chemical & Engineering Co., Ltd. | 近赤外線吸収フィルム用バインダー樹脂およびこれを利用する近赤外線吸収フィルター |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE192502C (ko) * | ||||
GB1125382A (en) * | 1964-09-11 | 1968-08-28 | Goodyear Tire & Rubber | Clear impact resistant resin |
JPS5433574A (en) * | 1977-08-19 | 1979-03-12 | Asahi Chem Ind Co Ltd | Composite material |
JPH0786164B2 (ja) * | 1986-01-14 | 1995-09-20 | 電気化学工業株式会社 | 熱可塑性樹脂組成物 |
-
1988
- 1988-09-16 DE DE3831499A patent/DE3831499A1/de not_active Withdrawn
-
1989
- 1989-09-01 CA CA000610216A patent/CA1339041C/en not_active Expired - Fee Related
- 1989-09-12 KR KR1019890013213A patent/KR0150777B1/ko not_active IP Right Cessation
- 1989-09-12 EP EP89116822A patent/EP0359185B1/de not_active Expired - Lifetime
- 1989-09-12 ES ES89116822T patent/ES2056171T3/es not_active Expired - Lifetime
- 1989-09-12 US US07/406,288 patent/US5109072A/en not_active Expired - Lifetime
- 1989-09-12 AT AT89116822T patent/ATE106925T1/de not_active IP Right Cessation
- 1989-09-12 DE DE58907820T patent/DE58907820D1/de not_active Expired - Fee Related
- 1989-09-14 JP JP1237376A patent/JP2839571B2/ja not_active Expired - Fee Related
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20200099181A (ko) * | 2017-12-19 | 2020-08-21 | 헨켈 아게 운트 코. 카게아아 | 플라스틱 부품, 특히 접착제 어플리케이션의 제조를 위한 장치 및 방법 |
Also Published As
Publication number | Publication date |
---|---|
DE58907820D1 (de) | 1994-07-14 |
DE3831499A1 (de) | 1990-04-05 |
EP0359185A2 (de) | 1990-03-21 |
KR0150777B1 (ko) | 1998-10-15 |
EP0359185B1 (de) | 1994-06-08 |
EP0359185A3 (de) | 1992-01-08 |
US5109072A (en) | 1992-04-28 |
JPH02115250A (ja) | 1990-04-27 |
ES2056171T3 (es) | 1994-10-01 |
JP2839571B2 (ja) | 1998-12-16 |
CA1339041C (en) | 1997-04-01 |
ATE106925T1 (de) | 1994-06-15 |
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