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KR890013274A - Post-dyeing mixture - Google Patents

Post-dyeing mixture Download PDF

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Publication number
KR890013274A
KR890013274A KR1019880001955A KR880001955A KR890013274A KR 890013274 A KR890013274 A KR 890013274A KR 1019880001955 A KR1019880001955 A KR 1019880001955A KR 880001955 A KR880001955 A KR 880001955A KR 890013274 A KR890013274 A KR 890013274A
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KR
South Korea
Prior art keywords
mixture
following formula
homopolymer
hydrogen
monoallylamine
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Application number
KR1019880001955A
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Korean (ko)
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KR950007821B1 (en
Inventor
키슬링 브루노
로빈손 티보어
Original Assignee
예안 크라메르, 한스 루돌프 하우스
산도즈 리미티드
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Priority to KR1019880001955A priority Critical patent/KR950007821B1/en
Publication of KR890013274A publication Critical patent/KR890013274A/en
Application granted granted Critical
Publication of KR950007821B1 publication Critical patent/KR950007821B1/en
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/61—Polyamines polyimines
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
    • D06L4/60—Optical bleaching or brightening

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Coloring (AREA)

Abstract

내용 없음.No content.

Description

염색후 처리용 혼합물Post-dyeing mixture

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (9)

활성성분으로서 하기의 직물 보조제(T)와 중합성 화합물(P)로 구성된 상승 혼합물에 있어서 T는 ⅰ) 50-90℃에서 에피할로히드린 4몰을 8-10몰의 암모니아와 반응시키고, ⅱ) 과량의 암모니아를 제거한뒤 0.1-0.5몰의 에피할로 히드린을 단계(1) 생성물과 반응시켜 생성된 2단계 반응 생성물이며, P는 모노-또는 디-알릴아민의 수용성 동중합체, 또는 모노-, 디- 또는 트리-알릴아민 유니트로 구성된 수용성 공중합체인 것을 특징으로 하는 상승혼합물.In the synergistic mixture composed of the following textile auxiliary (T) and the polymerizable compound (P) as the active ingredient, T is i) reacting 4 moles of epihalohydrin with 8-10 moles of ammonia at 50-90 ° C., Ii) a two-step reaction product produced by removing excess ammonia and then reacting 0.1-0.5 moles of epihalo hydrin with the product of step (1), where P is a water-soluble homopolymer of mono- or di-allylamine, or A synergistic mixture, characterized in that it is a water-soluble copolymer composed of mono-, di- or tri-allylamine units. 제1항에 있어서, T는 에피클로로히드린, 암모니아의 초기 몰비가 4:9인 양으로 반응하여 0.4몰의 에피클로로 히드린과 반응하여 생성된 생성물인 것을 특징으로 하는 혼합물.The mixture according to claim 1, wherein T is a product produced by reacting with 0.4 mol of epichlorohydrin in an amount in which the initial molar ratio of epichlorohydrin and ammonia is 4: 9. 제1항 또는 제2항에 있어서, 수용성 알릴아민 중합체(P)는 a) 모노알릴아민 동중합체 또는 b) 디알릴아민 동중합체 또는 c) 모노알릴아민, 디알리아민 및 트리알릴아민에서 선택된 모노머 유니트의 공중합체로서 상기 (a)의 모노알릴아민 또는 이들의 염은 하기식 (Ⅰ) 또는 하기식 (Ⅱ)로 나타내고, 상기 (b)의 디알릴아민, 또는 이들의 염은 하기식(Ⅲ) 또는 하기식(Ⅳ)로 나타내고, 상기 (c)의 트리알릴아민 또는 이들의 염은 하기식(Ⅴ) 또는 하기식(Ⅵ)로 나타내는 것을 특징으로 하는 혼합물.The monomer of claim 1, wherein the water soluble allylamine polymer (P) is a monomer selected from a) monoallylamine homopolymer or b) diallylamine homopolymer or c) monoallylamine, diallyamine and triallylamine. As the copolymer of the unit, the monoallylamine of the above (a) or a salt thereof is represented by the following formula (I) or the following formula (II), and the diallylamine of the above (b) or a salt thereof is represented by the following formula (III) Or the following formula (IV), wherein the triallylamine of the above (c) or a salt thereof is represented by the following formula (V) or the following formula (VI). 상기식에서 R은 수소 또는 메틸, 바람직하게는 수소, R1및 R2는 각각 수소, C1-4알킬, 벤질, 2-히드록 시에틸, 2-히드록시프로필, 3-히드록시프로필 또는 시클로헥실, R1a, R2a, R3및 R4는 수소를 제외한 R1과 R2와 동일하며, 또는 R1및 R2, R1a및 R2a또는 R3및 R4는 피페리딘, 모르폴린 또는 피롤리딘링을 형성하도록 질소원자에 부착될 수 있으며, AΘ은 음이온이다.Wherein R is hydrogen or methyl, preferably hydrogen, R 1 and R 2 are each hydrogen, C 1-4 alkyl, benzyl, 2-hydroxyethyl, 2-hydroxypropyl, 3-hydroxypropyl or cyclo Hexyl, R 1a , R 2a , R 3 and R 4 are the same as R 1 and R 2 except hydrogen, or R 1 and R 2 , R 1a and R 2a or R 3 and R 4 are piperidine, mor It may be attached to a nitrogen atom to form a polyline or pyrrolidine ring, and A Θ is an anion. 제3항에 있어서, 중합체 P는 R, R1및 R2가 모두 수소인 식(Ⅰ) 또는 식(Ⅲ) 화합물의 동중합체이거나 또는 이러한 두가지 화합물의 공중합체인 것을 특징으로 하는 혼합물.4. A mixture according to claim 3, wherein the polymer P is a homopolymer of formula (I) or formula (III) compounds wherein R, R 1 and R 2 are all hydrogen or a copolymer of these two compounds. 제4항에 있어서, 중합체 P는 모노알릴아민 동중합체인 것을 특징으로 하는 혼합물.The mixture of claim 4 wherein the polymer P is a monoallylamine homopolymer. 전항중 어느 한 항에 있어서, P:T의 중량비는 30:70-70:30인 것을 특징으로 하는 혼합물.A mixture according to any of the preceding claims wherein the weight ratio of P: T is 30: 70-70: 30. 제1항 내지 제6항중 어느 한 항에 있어서, 기재된 혼합물로 기질을 처리하는 단계를 포함하여 히드록시, 아미노- 또는 티올기를 갖는 직물 섬유 또는 가죽섬유로 구성된 염색된, 프린트된 또는 임의적으로 표백된 기질을 후처리하는 방법.7. Dyed, printed or optionally bleached according to any one of claims 1 to 6, comprising treating the substrate with the mixture described, comprising textile fibers or leather fibers having hydroxy, amino- or thiol groups. Method of post-treatment of substrate. 제7항에 있어서, 혼합물을 pH9-13에서 이그저스트 욕으로부터 기질을 적용하는 방법.8. The method of claim 7, wherein the mixture is subjected to a substrate from an exhaust bath at pH 9-13. 제7항 또는 제8항에 있어서, 기질은 산성염료, 직접염료, 반응성 염료 또는 황염료로 염색된 셀룰로오스 직물 섬유로 구성된 것을 특징으로 하는 방법.The method of claim 7 or 8, wherein the substrate is composed of cellulose fabric fibers dyed with acid dyes, direct dyes, reactive dyes or sulfur dyes. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019880001955A 1988-02-26 1988-02-26 Composition for aftertreating dyeing Expired - Fee Related KR950007821B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
KR1019880001955A KR950007821B1 (en) 1988-02-26 1988-02-26 Composition for aftertreating dyeing

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1019880001955A KR950007821B1 (en) 1988-02-26 1988-02-26 Composition for aftertreating dyeing

Publications (2)

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KR890013274A true KR890013274A (en) 1989-09-22
KR950007821B1 KR950007821B1 (en) 1995-07-20

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110382775A (en) * 2017-04-14 2019-10-25 日东纺绩株式会社 Cellulose fibre wet friction fastness enhancer, the manufacturing method of dyeing cellulosic fibre for having used the enhancer and application thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110382775A (en) * 2017-04-14 2019-10-25 日东纺绩株式会社 Cellulose fibre wet friction fastness enhancer, the manufacturing method of dyeing cellulosic fibre for having used the enhancer and application thereof
CN110382775B (en) * 2017-04-14 2022-09-09 日东纺绩株式会社 Wet rubbing fastness improver for cellulose fiber, method for producing dyed cellulose fiber using the same, and use thereof

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Publication number Publication date
KR950007821B1 (en) 1995-07-20

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