KR890000599A - 경화성 수지 조성물 및 이를 포함한 물품 - Google Patents
경화성 수지 조성물 및 이를 포함한 물품 Download PDFInfo
- Publication number
- KR890000599A KR890000599A KR1019880007853A KR880007853A KR890000599A KR 890000599 A KR890000599 A KR 890000599A KR 1019880007853 A KR1019880007853 A KR 1019880007853A KR 880007853 A KR880007853 A KR 880007853A KR 890000599 A KR890000599 A KR 890000599A
- Authority
- KR
- South Korea
- Prior art keywords
- component
- resin composition
- bismaleimide
- cyanate ester
- aromatic
- Prior art date
Links
- 239000011342 resin composition Substances 0.000 title claims 17
- 125000003118 aryl group Chemical group 0.000 claims 20
- 239000004643 cyanate ester Substances 0.000 claims 14
- XQUPVDVFXZDTLT-UHFFFAOYSA-N 1-[4-[[4-(2,5-dioxopyrrol-1-yl)phenyl]methyl]phenyl]pyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C(C=C1)=CC=C1CC1=CC=C(N2C(C=CC2=O)=O)C=C1 XQUPVDVFXZDTLT-UHFFFAOYSA-N 0.000 claims 13
- 229920003192 poly(bis maleimide) Polymers 0.000 claims 13
- 239000000178 monomer Substances 0.000 claims 9
- 150000001412 amines Chemical class 0.000 claims 4
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims 4
- 229920002492 poly(sulfone) Polymers 0.000 claims 4
- XLJMAIOERFSOGZ-UHFFFAOYSA-M cyanate Chemical compound [O-]C#N XLJMAIOERFSOGZ-UHFFFAOYSA-M 0.000 claims 3
- 150000001913 cyanates Chemical class 0.000 claims 3
- -1 cyanogen halide Chemical class 0.000 claims 3
- 229920001470 polyketone Polymers 0.000 claims 3
- 239000003054 catalyst Substances 0.000 claims 2
- JMANVNJQNLATNU-UHFFFAOYSA-N glycolonitrile Natural products N#CC#N JMANVNJQNLATNU-UHFFFAOYSA-N 0.000 claims 2
- 238000010438 heat treatment Methods 0.000 claims 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims 1
- 229920001577 copolymer Polymers 0.000 claims 1
- AJBQAIDJQOJYFQ-UHFFFAOYSA-N methane;pyrrole-2,5-dione Chemical compound C.O=C1NC(=O)C=C1.O=C1NC(=O)C=C1 AJBQAIDJQOJYFQ-UHFFFAOYSA-N 0.000 claims 1
- 229910052698 phosphorus Inorganic materials 0.000 claims 1
- 239000011574 phosphorus Substances 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
- C08G73/10—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
- C08G73/12—Unsaturated polyimide precursors
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L81/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen or carbon only; Compositions of polysulfones; Compositions of derivatives of such polymers
- C08L81/06—Polysulfones; Polyethersulfones
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polyurethanes Or Polyureas (AREA)
Abstract
Description
Claims (15)
- 하기 성분(A),(B) 및 (C)를 포함하는 경화성 수지조성물; 성분(A) 디시아네이트-말단 방향족 폴리설폰 올리고머 및/또는 디시아네이트-말단 방향족 폴리케톤 올리고머; 성분(B) 그 방향족 고리에 결합된 적어도 두 개의 시아네이트 기를 갖는 다관능성 방향족 시아네이트, 상기 시아네이트 에스테르의 프리폴리머 및/또는 시아네이트 에스테르 단량체 및 아민의 프리폴리머; 인 성분(C) 비스말레이미드, 비스말레이미드 프리폴리머 및/또는 비스말레이드 및 아민의 프리폴리머.
- 제1항에 있어서, 상기 디시아네이트-말단 방향족 폴리설폰 올리고머 및/또는 상기 디시아네이트-말단 방향족 폴리케톤 올리고머가 20,000이하의 수평균 분자량을 갖는 수지 조성물.
- 제2항에 있어서, 상기 디시아네이트-말단 방향족 폴리설폰 올리고머 및/또는 상기 디시아네이트-말단 방향족 폴리케톤 올리고머의 수평균 분자량이 1,000-10,000범위에 있는 수지 조성물.
- 제1항 내지 제3항중 어느 한항에 있어서, 세가지 성분이 1:99-99:1범위의 성분 A) 대 총 성분 B) 및 C) 중량비로 존재하는 수지 조성물.
- 제4항에 있어서, 성분 A) 대 총 성분 B) 및 C)의 중량비가 10:90-70:30범위인 수지 조성물.
- 제1항 내지 제5항중 어느 한 항에 있어서, 성분 B 및 C가 1:99-99:1의 성분 B) 대 성분 C)의 중량비로 존재하는 수지 조성물.
- 제6항에 있어서, 성분 B) 대 성분 C)의 중량비가 5:95-95:5범위에 있는 수지 조성물.
- 제1항 내지 제7항중 어느 한 항에 있어서, 상기 성분(A)가 디시아네이트-말단 방향족 폴리설폰올리고머이고, 상기 시아네이트 에스테르 성분(B)가 그 방향족 고리에 결합된 적어도 두 개의 시아네이트기를 갖는 다관능성 방향족 시아네이트 에스테르 단량체의 프리 폴리머이고, 상기 비스말레이미드 성분(C)가 비스말레이미드 및 아민의 프리폴리머인 수지 조성물.
- 제1항 내지 제7항중 어느 한 항에 있어서, 상기 성분(A)가 디시아네이트-말단 방향족 롤리설폰올리고머이고, 상기 시아네이트 에스테르 성분(B)가 그 방향족 고리에 결합된 적어도 두 개의 시아네이트 기를 갖는 다관능성 방향족 시아네이트 에스테르 단량체의 프리폴리머이고, 상기 비스말레이미드 성분(C)가 비스말레이미드 단량체인 수지 조성물.
- 제9항에 있어서, 상기 시아네이트 에스테르 성분(B)가 비스페놀 A 및 시아노겐 할로겐 화물을 반응시켜 제조된 시아네이트 에스테르 단량체의 프로폴리머를 포함하고, 상기 비스말레이미드 성분(C)가 4,4′-비스아미노페닐 메탄 비스말레이미드를 포함하는 수지 조성물.
- 제1항 내지 제7항중 어느 한 항에 있어서, 상기 성분(A)가 디시아네이트-말단방향족 플리케톤 올리고머이고, 상기 시아네이트 에스테르 성분(B)가 그 방향족 고리에 결합된 적어도 두 개의 시아네이트기를 갖는 다관능성 방향족 시아네이트 에스테르 단량체의 프리폴리머이고, 상기 비스말레이미드 성분(C)가 비스말레이미드 및 아민의 프로폴리머인 수지 조성물.
- 제1항 내지 제7항중 어느 한 항에 있어서, 상기 성분(A)가 디시아네이트-말단 방향족 플리케톤 올리고머이고 상기 시아네이트 에스테르 성분(B)가 그 방향족 고리에 결합된 적어도 두 개의 시아네이트 기를 갖는 다관능성 방향족 시아네이트 에스테르 단량체의 프리폴리머이고, 상기 비스말레이미드 성분(C)가 비스말레이미드 단량체인 수지 조성물.
- 제12항에 있어서, 상기 시이네이트 에스테르 성분(B)가 비스페놀 A 및 시아노겐 할로겐화물을 반응시켜 제조된 시아네이트 에스테르 단량체의 프리폴리머를 포함하고, 상기 비스말레이미드 성분(C)가 4.4′-비스아미노 페닐 메탄 비스말레이미드를 포함하느 수지 조성물.
- 제1항 내지 제13항중 한 항에 따른 경화성 수지 조성물을 (a)가열시키고, (b) 촉매 존재하에서 또는 (c) 촉매존재하에 가열시킴으로써 경화시켜 얻은 경화된 수지 조성물.
- 제14항의 경화된 수지 조성물을 함유한 물품.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/068,377 US4749760A (en) | 1987-06-30 | 1987-06-30 | Curable resin compositions |
US068,377 | 1987-06-30 |
Publications (1)
Publication Number | Publication Date |
---|---|
KR890000599A true KR890000599A (ko) | 1989-03-15 |
Family
ID=22082179
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019880007853A KR890000599A (ko) | 1987-06-30 | 1988-06-28 | 경화성 수지 조성물 및 이를 포함한 물품 |
Country Status (8)
Country | Link |
---|---|
US (1) | US4749760A (ko) |
EP (1) | EP0297674B1 (ko) |
JP (1) | JPS6424824A (ko) |
KR (1) | KR890000599A (ko) |
AU (1) | AU602776B2 (ko) |
CA (1) | CA1305820C (ko) |
DE (1) | DE3886454T2 (ko) |
ES (1) | ES2061630T3 (ko) |
Families Citing this family (36)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4902752A (en) * | 1987-10-05 | 1990-02-20 | Hi-Tek Polymers, Inc. | Polycyanate esters of polyhydric phenols blended with thermoplastic polymers |
DE3802979A1 (de) * | 1988-02-02 | 1989-08-10 | Basf Ag | Waermehaertbare harzmischung |
US4916210A (en) * | 1988-10-20 | 1990-04-10 | Shell Oil Company | Resin from alpha, alpha', alpha"-tris(4-cyanatophenyl)-1,3,5-triisopropylbenzene |
US4946928A (en) * | 1989-02-15 | 1990-08-07 | Shell Oil Company | Curable resin from cyanate aromatic ester and propargyl aromatic ether |
US4954195A (en) * | 1989-02-13 | 1990-09-04 | Lockheed Corporation | Production of thermoset composites containing thermoplastic fillers |
US5248757A (en) * | 1989-07-17 | 1993-09-28 | The Dow Chemical Company | Mesogenic cyanate functional maleimides and thermosets thereof |
US5442039A (en) * | 1989-07-17 | 1995-08-15 | The Dow Chemical Company | Mesogenic polycyanates and thermosets thereof |
DE69032965T2 (de) * | 1989-07-17 | 1999-07-08 | The Dow Chemical Co., Midland, Mich. | Mesogene Cyanatgruppen enthaltende Maleimide |
US5248758A (en) * | 1989-07-17 | 1993-09-28 | The Dow Chemical Company | Mesogenic cyanate functional maleimides and thermosets thereof |
US5428125A (en) * | 1989-07-17 | 1995-06-27 | The Dow Chemical Company | Mesogenic polycyanates and thermosets thereof |
US5077380A (en) * | 1989-07-17 | 1991-12-31 | The Dow Chemical Company | Mesogenic cyanate functional maleimides and thermosets thereof |
US4981994A (en) * | 1989-07-31 | 1991-01-01 | Shell Oil Company | Preparation of cyanate esters |
US5208306A (en) * | 1991-03-25 | 1993-05-04 | The Dow Chemical Company | Mesogenic alkenyl functional maleimides and thermosets thereof |
US5159030A (en) * | 1991-03-25 | 1992-10-27 | The Dow Chemical Company | Mesogenic alkenyl functional malemides and thermosets thereof |
US5157105A (en) * | 1991-05-17 | 1992-10-20 | Shell Oil Company | Bisbenzocyclobutene/bisimide/dicyanate ester composition |
US5206321A (en) * | 1991-10-03 | 1993-04-27 | The Dow Chemical Company | Polycyanates containing mesogenic moieties as lateral substituents |
DE102009001806A1 (de) | 2009-03-24 | 2010-09-30 | Evonik Degussa Gmbh | Prepregs und daraus bei niedriger Temperatur hergestellte Formkörper |
DE102009001793A1 (de) | 2009-03-24 | 2010-10-07 | Evonik Degussa Gmbh | Prepregs und daraus hergestellte Formkörper |
DE102010029355A1 (de) | 2010-05-27 | 2011-12-01 | Evonik Degussa Gmbh | Verfahren zur Herstellung von lagerstabilen Polyurethan-Prepregs und daraus hergestellte Formkörper |
DE102010041247A1 (de) | 2010-09-23 | 2012-03-29 | Evonik Degussa Gmbh | Verfahren zur Herstellung von lagerstabilen Polyurethan-Prepregs und daraus hergestellte Formkörper aus Polyurethanzusammensetzung in Lösung |
US9878500B2 (en) | 2011-01-04 | 2018-01-30 | Evonik Degussa Gmbh | Composite semifinished products, molded parts produced therefrom, and molded parts produced directly based on hydroxy-functionalized (meth)acrylates, which are cross-linked by means of uretdiones in a thermosetting manner |
DE102011006163A1 (de) | 2011-03-25 | 2012-09-27 | Evonik Degussa Gmbh | Lagerstabile Polyurethan-Prepregs und daraus hergestellte Formkörper aus Polyurethanzusammensetzung mit flüssigen Harzkomponenten |
JP5790095B2 (ja) * | 2011-04-01 | 2015-10-07 | ソニー株式会社 | 薄膜素子及びその製造方法、並びに、画像表示装置の製造方法 |
DE102011087226A1 (de) | 2011-11-28 | 2013-05-29 | Evonik Degussa Gmbh | Pseudo-thermoplastische, selbstvernetzende Composites |
DE102013204124A1 (de) | 2013-03-11 | 2014-09-11 | Evonik Industries Ag | Composite-Halbzeuge und daraus hergestellte Formteile sowie direkt hergestellte Formteile auf Basis von hydroxyfunktionalisierten (Meth)Acrylaten und Uretdionen die mittels Strahlung duroplastisch vernetzt werden |
CA2930476A1 (en) | 2013-11-19 | 2015-05-28 | Evonik Degussa Gmbh | Mouldings based on diene-functionalized (meth)acrylates and (hetero-)diels-alder dienophiles, with reversible crosslinking |
DE102014207785A1 (de) | 2014-04-25 | 2015-10-29 | Evonik Degussa Gmbh | Verfahren zur Herstellung von lagerstabilen Epoxy-Prepregs und daraus hergestellte Composites auf Basis von radikalisch polymerisierbaren Säuren und Epoxiden |
EP2979851A1 (de) | 2014-07-28 | 2016-02-03 | Evonik Degussa GmbH | Effiziente Herstellung von Composite-Halbzeugen und -Bauteilen im Nasspressverfahren unter Einsatz von hydroxyfunktionalisierten (Meth) Acrylaten, die mittels Isocyanaten oder Uretdionen duroplastisch vernetzt werden |
EP2982704A1 (de) | 2014-08-06 | 2016-02-10 | Evonik Degussa GmbH | Reversibel vernetzte Polymeremulsionen |
EP2993202A1 (de) | 2014-09-08 | 2016-03-09 | Evonik Degussa GmbH | Composite-Halbzeuge und daraus hergestellte Formteile sowie direkt hergestellte Formteile auf Basis von hydroxyfunktionalisierten (Meth)Acrylaten und Uretdionen, die duroplastisch vernetzt werden |
EP3199575A1 (de) | 2016-01-29 | 2017-08-02 | Evonik Degussa GmbH | Neuartiger hetero-diels-alder-vernetzer und deren verwendung in reversibel vernetzenden polymersystemen |
WO2018054684A1 (de) | 2016-09-20 | 2018-03-29 | Evonik Degussa Gmbh | Neuartiger vernetzer-baustein für die verwendung in reversibel vernetzenden polymersystemen |
EP3296347A1 (de) | 2016-09-20 | 2018-03-21 | Evonik Degussa GmbH | Neuartiger dien-baustein für die verwendung in reversibel vernetzenden (hetero-)diels-alder-polymersystemen |
ES2880621T3 (es) | 2016-12-02 | 2021-11-25 | Evonik Degussa Gmbh | Productos preimpregnados de poliuretano 1K estables al almacenamiento y cuerpos moldeados a partir de la composición de poliuretano producidos a partir de estos |
US20190330432A1 (en) | 2018-04-27 | 2019-10-31 | Evonik Degussa Gmbh | Two-component hybrid matrix system made of polyurethanes and polymethacrylates for the production of short-fibre-reinforced semifinished products |
CN118388376A (zh) * | 2024-04-29 | 2024-07-26 | 四平市精细化学品有限公司 | 一种高纯氰酸酯的制备方法 |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
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DE251208C (ko) * | ||||
US3595900A (en) * | 1968-07-01 | 1971-07-27 | Minnesota Mining & Mfg | Cyanatophenyl-terminated polyarylene ethers |
SE421006B (sv) * | 1974-03-19 | 1981-11-16 | Mitsubishi Gas Chemical Co | Herdbar hartskomposition av en cyanatesterkomponent och en bismaleinsyraimidkomponent |
US4046796A (en) * | 1975-02-22 | 1977-09-06 | Bayer Aktiengesellschaft | Process for the production of polyfunctional cyanic acid esters |
JPS51114494A (en) * | 1975-04-02 | 1976-10-08 | Mitsubishi Gas Chem Co Inc | Preparation of cyanic acid eaters of aromatic polycarbonate |
JPS54129100A (en) * | 1978-03-31 | 1979-10-06 | Mitsubishi Gas Chem Co Inc | Thermosetting resin |
US4157360A (en) * | 1978-04-26 | 1979-06-05 | Allied Chemical Corporation | Thermoformable compositions comprising a crosslinked polycyanurate polymer and a thermoplastic polymer |
DE3117903C2 (de) * | 1980-05-06 | 1983-09-29 | Mitsubishi Gas Chemical Co., Inc., Tokyo | Härtbare Harzmasse |
US4691025A (en) * | 1983-12-22 | 1987-09-01 | Amoco Corporation | Bismaleimides and prepreg resins therefrom |
US4581425A (en) * | 1984-08-09 | 1986-04-08 | The Dow Chemical Company | Thermosettable resin composition containing alkenyl phenyl cyanate |
US4683276A (en) * | 1985-10-01 | 1987-07-28 | The Dow Chemical Company | Cyanate functional maleimide thermosetting composition |
US4831086A (en) * | 1987-10-05 | 1989-05-16 | Allied-Signal Inc. | Cyanato group containing phenolic resins, phenolic triazines derived therefrom |
-
1987
- 1987-06-30 US US07/068,377 patent/US4749760A/en not_active Expired - Fee Related
-
1988
- 1988-06-07 CA CA000568783A patent/CA1305820C/en not_active Expired - Fee Related
- 1988-06-28 KR KR1019880007853A patent/KR890000599A/ko not_active Application Discontinuation
- 1988-06-28 AU AU18485/88A patent/AU602776B2/en not_active Ceased
- 1988-06-28 EP EP88201335A patent/EP0297674B1/en not_active Expired - Lifetime
- 1988-06-28 ES ES88201335T patent/ES2061630T3/es not_active Expired - Lifetime
- 1988-06-28 JP JP63158251A patent/JPS6424824A/ja active Pending
- 1988-06-28 DE DE88201335T patent/DE3886454T2/de not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
DE3886454D1 (de) | 1994-02-03 |
DE3886454T2 (de) | 1994-05-11 |
CA1305820C (en) | 1992-07-28 |
EP0297674A2 (en) | 1989-01-04 |
US4749760A (en) | 1988-06-07 |
EP0297674A3 (en) | 1990-12-19 |
AU602776B2 (en) | 1990-10-25 |
AU1848588A (en) | 1989-01-05 |
EP0297674B1 (en) | 1993-12-22 |
JPS6424824A (en) | 1989-01-26 |
ES2061630T3 (es) | 1994-12-16 |
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