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KR890000535A - N-(폴리옥시알킬)-n- (알킬)아민으로부터 제조된 탄성체(5) - Google Patents

N-(폴리옥시알킬)-n- (알킬)아민으로부터 제조된 탄성체(5) Download PDF

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KR890000535A
KR890000535A KR1019880007881A KR880007881A KR890000535A KR 890000535 A KR890000535 A KR 890000535A KR 1019880007881 A KR1019880007881 A KR 1019880007881A KR 880007881 A KR880007881 A KR 880007881A KR 890000535 A KR890000535 A KR 890000535A
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KR1019880007881A
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KR930007874B1 (ko
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마이클 저킨 리차드
바크스비 니글
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티모티 엔.비숍
유니온 카바이드 코포레이션
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6666—Compounds of group C08G18/48 or C08G18/52
    • C08G18/667—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/6681—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/32 or C08G18/3271 and/or polyamines of C08G18/38
    • C08G18/6685—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/32 or C08G18/3271 and/or polyamines of C08G18/38 with compounds of group C08G18/3225 or polyamines of C08G18/38
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3225—Polyamines
    • C08G18/3228—Polyamines acyclic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/50—Polyethers having heteroatoms other than oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/50—Polyethers having heteroatoms other than oxygen
    • C08G18/5021—Polyethers having heteroatoms other than oxygen having nitrogen
    • C08G18/5024—Polyethers having heteroatoms other than oxygen having nitrogen containing primary and/or secondary amino groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2120/00—Compositions for reaction injection moulding processes

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Polyethers (AREA)

Abstract

내용 없음

Description

N-(플리옥시알킬)-N-(알킬)아민으로부터 제조된 탄성체(5)
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (26)

  1. 하기 일반식의 N-(폴리옥시알킬)-N-(알킬)아민을 연쇄 연장제의 존재하에서 이소시아네이트와 반응시킴을 특징으로하여, 탄성체를 제조하는 방법.
    R[H](hz)[(P)p(S)s(T)t]z-(hz)
    상기식에서, R은 쩨레비티노프(Zerewitinoff)활성 수소원자를 함유하는 화합물을 기본으로 하는 개시제 라디칼이고, H는 일반식
    의 그룹이며, P는 일반식
    의 그룹이고, S는 일반식
    의 그룹이며, T는 일반식
    의 그룹이고, a는 0 내지 175이며, b는 0 내지 175이고, c는 0 내지 30이며, n은 1 내지 3이고, 단 n이 1인 경우 a+b+c는 반드시 2 이상이어야 하고, R'는 탄소수 2 내지 18의 알킬그룹이며, R"는 수소 또는 탄소수 18이하의 알킬그룹이고, R"' 및 R""는 각각 독립적으로 탄소수 2 내지 12의 알킬그룹이며, h는 0 내지 0.7이고, P는 0 내지 0.5이며, S는 0.5 내지 1이고, t는 0 내지 0.15이며,Z는 2 내지 6이며, 단 Z가 2이고 a가 0인 경우에 b는 반드시 22보다 커야 한다.
  2. 제 1 항에 있어서, R이 탄소원자 2 내지 6개를 함유하며, a는 0 내지 150이며, b는 20 내지 115이고, c가 0 내지 15이며, R'가 탄소수 2의 알킬그룹이며, Rc'가 탄소수 2 내지 6의 알킬그룹인 방법.
  3. 제 2 항에 있어서, R이 탄소원자 3 내지 6개를 함유하며, a가 0 내지 90이고, b가 25 내지 98이고, c가 0 내지 2이고, R"'가 이소프로필그룹이며, Z가 3 내지 6인 방법.
  4. 제 1 항에 있어서, R이 18 내지 400의 분자량을 갖는 방법.
  5. 제 1 항에 있어서, R이 탄소원자 3 내지 6개를 함유하는 방법.
  6. 제 5 항에 있어서, R이인 방법.
  7. 제 1 항에 있어서, N-(폴리옥시알킬)-N-(알킬)아민이 1,000 내지 10,000의 당량을 갖는 방법.
  8. 제 1 항의 방법에 따라 제조된 탄성체.
  9. 제 2 항의 방법에 따라 제조된 탄성체.
  10. 제 3 항의 방법에 따라 제조된 탄성체.
  11. 제 4 항의 방법에 따라 제조된 탄성체.
  12. 제 5 항의 방법에 따라 제조된 탄성체.
  13. 제 6 항의 방법에 따라 제조된 탄성체.
  14. 제 7 항의 방법에 따라 제조된 탄성체.
  15. 당량이 약 1,000 내지 10,000인 하기 일반식의 N-(폴리옥시알킬)-N-(알킬)아민을 연쇄 연장제의 존재하에서 이소시아네이트 반응시킴을 특징으로하여, 폴리우레아 및/또는 폴리우레탄-우레아 탄성체를 제조하는 방법.
    R[H](hz)[(P)p(S)s(T)t]z-(hz)
    상기식에서, R은 쩨레비티노프(Zerewitinoff) 활성 수소원자를 함유하는 화합물을 기본으로 하는 개시제 라디칼이며, H는 일반식
    의 그룹이고, P는 일반식
    의 그룹이며, S는 일반식
    의 그룹이며, T는 일반식
    의 그룹이며, a는 0 내지 175이며, b는 0 내지 175이고, c는 0 내지 30이며, n은 1 내지 3이고, 단 n은 1인 경우 a+b+c는 반드시 2 이상이어야 하고, R'는 탄소수 2 내지 18의 알킬그룹이며, R"는 수소 또는 탄소수 18이하의 알킬그룹이고, R"' 및 R""는 각각 독립적으로 탄소수 2 내지 12의 알킬 또는 아릴그룹이며, h는 0 내지 0.3이고, P는 0 내지 0.4이며, S는 0.7 내지 1이고, t는 0 내지 0.05이며,Z는 3 내지 6이다.
  16. 제 5 항에 있어서, a는 0 내지 150이고, b는 20 내지 115이고, c가 0 내지 15이고, R'가 탄소수 2의 알킬그룹이며, R"'가 탄소수 원자 2 내지 6를 함유하는 방법.
  17. 제15항에 있어서, R이 탄소원자 3 내지 6개를 함유하고, a가 0 내지 90이고, b가 25 내지 98이고, c가 0 내지 2이며, R"'가 이소프로필그룹인 방법.
  18. 제16항에 있어서, R이 18 내지 400의 분자량을 갖는 방법.
  19. 제18항에 있어서, R이인 방법.
  20. 제15항의 방법에 따라 제조된 탄성체.
  21. 제16항의 방법에 따라 제조된 탄성체.
  22. 제17항의 방법에 따라 제조된 탄성체.
  23. 제18항의 방법에 따라 제조된 탄성체.
  24. 제19항의 방법에 따라 제조된 탄성체.
  25. 제 1 항의 방법에 따라 제조된 주조(cast) 탄성체.
  26. 제 1 항의 방법에 따라 제조된 반응사출성형 탄성체.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019880007881A 1987-06-30 1988-06-29 N-(폴리옥시알킬)-n-(알킬)아민으로부터 제조된 탄성체 KR930007874B1 (ko)

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Application Number Priority Date Filing Date Title
US6781987A 1987-06-30 1987-06-30
US067819 1987-06-30
US067,819 1987-06-30
US07/176,221 US4902768A (en) 1987-06-30 1988-03-31 Elastomers prepared from N-(polyoxyalkyl)-N-(alkyl)amines
US176221 1988-03-31
US176,221 1988-05-31

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KR890000535A true KR890000535A (ko) 1989-03-15
KR930007874B1 KR930007874B1 (ko) 1993-08-21

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US (1) US4902768A (ko)
EP (1) EP0298359B1 (ko)
JP (1) JP2612746B2 (ko)
KR (1) KR930007874B1 (ko)
AT (1) ATE156845T1 (ko)
AU (1) AU609833B2 (ko)
BR (1) BR8803203A (ko)
CA (1) CA1337135C (ko)
DE (1) DE3855995T2 (ko)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4904751A (en) * 1987-12-21 1990-02-27 Texaco Chemical Company N,N'-dialkyl substituted polyoxyalklene amines as curing agents for blocked isocyanates
DE3825637A1 (de) * 1988-07-28 1990-03-08 Rwe Dea Ag Sekundaere polyetheramine, ihre herstellung und verwendung zur herstellung von polyharnstoffen
DE3919696A1 (de) * 1989-06-16 1991-01-10 Bayer Ag Reaktivklebstoffe auf polyurethanbasis
CA2020349C (en) * 1989-09-05 2001-10-09 Dudley J. Ii Primeaux Aliphatic spray polyurea elastomers
DE4000013A1 (de) * 1990-01-02 1991-07-04 Basf Ag Verfahren zur herstellung von elastischen, kompakten oder zelligen formkoerpern auf der grundlage von n-benzylharnstoffgruppen gebunden enthaltenden elastomeren, derartige elastomere und hierfuer geeignete n-benzyl-polyoxyalkylen-polyamine
US5171818A (en) * 1990-03-23 1992-12-15 Bruce Wilson Sprayable aliphatic polyurea-polyurethane coating compositions and methods
US5082917A (en) * 1990-05-29 1992-01-21 Texaco Chemical Co. Piperazine derivatives as chain extenders in polyurea elastomer systems and method making same
US5059672A (en) * 1990-06-25 1991-10-22 Thare Coat, Inc. Elastomeric reaction products of aromatic isocyanate, aliphatic isocyanate and aromatic diamine components
JPH0551524A (ja) * 1991-08-21 1993-03-02 Nippon Paint Co Ltd 反応射出成形用ポリウレア樹脂組成物
US5239041A (en) * 1992-04-08 1993-08-24 Texaco Chemical Company Hindered amines to slow down reactivity in producing rim elastomers
DE4218791A1 (de) * 1992-06-06 1993-12-09 Basf Ag Verfahren zur Herstellung von Urethan- und Harnstoffgruppen enthaltenden, kompakten oder zelligen Elastomeren oder Formkörpern hieraus
US5693864A (en) * 1992-10-07 1997-12-02 Bayer Corporation Process for the production of secondary amine terminated polyethers
US5874623A (en) * 1993-08-02 1999-02-23 Bayer Corporation Process for the production of polyether aminoalcohols
US5510535A (en) * 1994-11-22 1996-04-23 Bayer Corporation Ether-linked amine-terminated polyethers and a process for their production
US5672761A (en) * 1996-05-02 1997-09-30 Bayer Corporation Method for reducing the viscosity of high viscosity polyether polyols
US5739397A (en) * 1996-05-30 1998-04-14 Bayer Corporation Process for the production of secondary amines and the amines produced by the process
EP1246704A4 (en) * 1998-06-18 2004-09-15 Mackinac Investors Llc METHOD FOR DAMPING NOISE, VIBRATION AND SHARPNESS OF A SUBSTRATE AND COMPOSITION THEREFOR
DE19924089C1 (de) * 1999-05-26 2001-01-25 Bayer Ag Verfahren zur kontinuierlichen Herstellung von thermoplastisch verarbeitbaren Polyurethanen mit verbessertem Erweichungsverhalten
US6635737B1 (en) 2000-05-26 2003-10-21 Williamette Valley Company Polymers derived from low unsaturation polyamines
US20070043197A1 (en) * 2003-07-07 2007-02-22 Huntsman Petrochemical Corporation Polyurea polymers from secondary polyether polyamines
US7423112B2 (en) 2004-05-27 2008-09-09 Bayer Materialscience Llc Polyether polyols containing pendant amine groups and a process for their preparation
US9822088B2 (en) * 2011-03-30 2017-11-21 The United States Of America As Represented By The Administrator Of Nasa Anisotropic copoly(imide oxetane) coatings and articles of manufacture, copoly(imide oxetane)s containing pendant fluorocarbon moieties, oligomers and processes therefor

Family Cites Families (88)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US28715A (en) * 1860-06-12 Improvement in soldering handles of cutlery
US29118A (en) * 1860-07-10 Improved signal-lantern
US2160058A (en) * 1938-03-26 1939-05-30 Rohm & Haas Process for preparing hexadecyl amines
US2629740A (en) * 1948-05-04 1953-02-24 American Cyanamid Co Polyether amines and a process for their production
US2636902A (en) * 1949-01-07 1953-04-28 Ici Ltd Production of amines
US2888439A (en) * 1957-08-16 1959-05-26 Du Pont Polyurethane diamines
US2888440A (en) * 1957-08-16 1959-05-26 Du Pont Polyurethane diamines
US3231619A (en) * 1959-12-18 1966-01-25 Jefferson Chem Co Inc Basic primary amino polyether compositions
DE1302398B (ko) * 1960-06-08 1970-10-15
US3236895A (en) * 1960-12-12 1966-02-22 Dow Chemical Co Polyoxyalkylenepolyamines
NL122820C (ko) * 1960-12-19
US3269999A (en) * 1962-02-27 1966-08-30 Jefferson Chem Co Inc Corrosion inhibitors from amine residue
US3267050A (en) * 1962-05-21 1966-08-16 Union Carbide Corp Foamed organic polyisocyanate-amine reaction products
NL293505A (ko) * 1962-05-31
FR1358187A (fr) * 1962-05-31 1964-04-10 Gen Tire & Rubber Co Perfectionnements à la production de mousses de polyuréthanes et matières similaires
DE1215373B (de) * 1962-07-12 1966-04-28 Bayer Ag Verfahren zur Herstellung von linearen oder verzweigten Polypropylenglykolaethern mit Aminogruppen
US3309182A (en) * 1962-09-17 1967-03-14 Exxon Research Engineering Co Polyether diamine as stabilizer for petroleum distillate fuels
USRE29118E (en) 1963-02-06 1977-01-18 Method of preparing polyurethanes from liquid, stable, reactive, film-forming polymer/polyol mixtures formed by polymerizing an ethylenically unsaturated monomer in a polyol
US3358243A (en) * 1963-03-25 1967-12-12 Sperry Rand Corp Laser having interferometer controlled oscillatory modes
US3352916A (en) * 1964-04-15 1967-11-14 Atlas Chem Ind Aminated polyoxyalkylene fatty amines
US3373204A (en) * 1964-04-15 1968-03-12 Atlas Chem Ind Process for preparing oxyalkylene amines
US3347926A (en) * 1964-04-15 1967-10-17 Atlas Chem Ind Ammonolysis process for producing aliphatic amines
USRE28715E (en) 1964-08-12 1976-02-17 Polyurethanes, reactive solutions and methods and their production
US3359243A (en) * 1964-12-15 1967-12-19 Monsanto Co Linear polyurea elastomers
US3383417A (en) * 1964-12-21 1968-05-14 Jefferson Chem Co Inc Method for the preparation of aminoethylethanolamine
US3390184A (en) * 1965-06-01 1968-06-25 Jefferson Chem Co Inc Production of primary amines by ammonolysis
GB1159962A (en) * 1965-08-11 1969-07-30 Ici Ltd Improvements in or relating to the Manufacture of Polymeric Material
US3436359A (en) * 1965-10-14 1969-04-01 Minnesota Mining & Mfg Polyether polyprimary polyamines and elastomeric products thereof
FR1466708A (fr) * 1966-01-27 1967-01-20 Hoechst Ag Procédé de préparation d'éthers polyglycoliques portant des groupes amino secondaires terminaux
DE1593845A1 (de) * 1967-01-18 1971-02-25 Hoechst Ag Verfahren zur Reinigung von Polyaminen
NL6803556A (ko) * 1967-03-16 1968-09-17
DE1694152C3 (de) * 1967-05-12 1979-09-13 Bayer Ag, 5090 Leverkusen Verfahren zur Herstellung von mikroporösen Flächengebilden
US3666788A (en) * 1969-08-22 1972-05-30 Jefferson Chem Co Inc Cyanoalkylated polyoxyalkylene polyamines
US3645969A (en) * 1970-06-22 1972-02-29 Union Carbide Corp Curable polyepoxide compositions containing as a curing agent a mixture of a polyglycol polyamine and an alkylene polyamine
US3654370A (en) * 1970-08-28 1972-04-04 Jefferson Chem Co Inc Process for preparing polyoxyalkylene polyamines
US3660319A (en) * 1970-12-08 1972-05-02 Jefferson Chem Co Inc Tertiary polyoxyalkylenepolyamines
US3832323A (en) * 1973-03-12 1974-08-27 Jefferson Chem Co Inc Thixotropic b-component for polyurethane elastomers
US3838076A (en) * 1973-03-12 1974-09-24 Jefferson Chem Co Inc Polyurethane foams from partially aminated polyether polyols
US3847992A (en) * 1973-03-12 1974-11-12 Jefferson Chem Co Inc Partially aminated polyoxyalkylene polyols
US4332720A (en) * 1976-05-24 1982-06-01 Texaco Development Corporation N,N'-Polyoxyalkylene bis(lactam carboxylic acids)
US4118422A (en) * 1976-08-23 1978-10-03 Texaco Development Corp. Polyols from 2,3-morpholinediones
US4184024A (en) * 1976-08-23 1980-01-15 Texaco Development Corp. Polyurethanes prepared from polyols from 2,3-morpholinediones
US4075130A (en) * 1976-08-30 1978-02-21 Texaco Development Corporation Polyoxypropylene polyamine derivatives as defoamers
US4119615A (en) * 1976-09-24 1978-10-10 Texaco Development Corporation Thermoplastic adhesive polyoxamide from polyoxypropylene polyamine
US4115361A (en) * 1976-11-22 1978-09-19 Texaco Development Corp. Polyether urea epoxy additives
US4062820A (en) * 1976-12-06 1977-12-13 Emery Industries, Inc. Thermoplastic reinforcing adhesives and substrates coated therewith
US4153581A (en) * 1977-09-01 1979-05-08 The Dow Chemical Company Method of producing amines from alcohols, aldehydes, ketones and mixtures thereof
US4152353A (en) * 1977-08-29 1979-05-01 The Dow Chemical Company Method of producing amines from alcohols, aldehydes, ketones and mixtures thereof
US4146700A (en) * 1978-03-27 1979-03-27 Texaco Development Corp. Diamides of polyoxyalkylenepolyamine-urea condensates as epoxy resin additives
US4146701A (en) * 1978-03-27 1979-03-27 Texaco Development Corp. Polyether diureide epoxy additives
US4191706A (en) * 1978-04-13 1980-03-04 Texaco Development Corp. Aromatic amine-amides and use as chain-extenders
US4247301A (en) * 1978-06-19 1981-01-27 Chevron Research Company Deposit control and dispersant additives
US4180644A (en) * 1978-07-31 1979-12-25 Texaco Development Corp. Polyurethane chain-extenders
US4390645A (en) * 1979-11-23 1983-06-28 The Dow Chemical Company Stable dispersions of polymers in polyfunctional compounds having a plurality of active hydrogens and polyurethanes therefrom
US4269945A (en) * 1980-01-24 1981-05-26 The Dow Chemical Company Reaction injection molded polyurethanes employing aliphatic amine chain extenders
US4286074A (en) * 1980-04-04 1981-08-25 Basf Wyandotte Corporation Amine-terminated graft copolymer dispersions and polyurethanes prepared therefrom
US4304889A (en) * 1980-07-11 1981-12-08 Texaco Inc. Solvent resistant epoxy coatings
JPS5736115A (en) * 1980-08-12 1982-02-26 Mitsui Tekisako Chem Kk Curing agent composition for polyurethane
DE3112118A1 (de) * 1981-03-27 1982-10-07 Bayer Ag, 5090 Leverkusen Polymerisathaltige polyetherpolyamine, verfahren zur herstellung dieser polyamine und deren verwendung als aufbaukomponente zur herstellung von polyurethanen
CA1221383A (en) * 1981-08-07 1987-05-05 Werner Rasshofer Polyamines, a process for the production of polyamines and their use in the production of polyurethanes
DE3147736A1 (de) * 1981-12-02 1983-06-09 Bayer Ag, 5090 Leverkusen Verfahren zur herstellung von elastischen formkoerpern
EP0084141B1 (de) * 1982-01-02 1986-03-05 Bayer Ag Polymerisathaltige, aromatische Polyether-Polyamine, Verfahren zur Herstellung dieser Polyamine und deren Verwendung als Aufbaukomponente zur Herstellung von Polyurethanen
US4471138A (en) * 1982-01-18 1984-09-11 Exxon Research And Engineering Co. Severely sterically hindered secondary aminoether alcohols
US4417075A (en) * 1982-01-18 1983-11-22 Exxon Research And Engineering Co. Di-(Secondary and tertiaryalkylaminoalkoxy)alkanes
US4431754A (en) * 1982-03-01 1984-02-14 The Dow Chemical Company Low viscosity polymer polyols via dilution
US4396729A (en) * 1982-04-23 1983-08-02 Texaco Inc. Reaction injection molded elastomer containing an internal mold release made by a two-stream system
US4444910A (en) * 1982-04-23 1984-04-24 Texaco Inc. Reaction injection molded elastomers made using a polyurethane organometallic catalyst amine terminated polyethers amine terminated chain extender and aromatic polyisocyanate
US4433067A (en) * 1982-04-23 1984-02-21 Texaco Inc. Reaction injection molded elastomers prepared from amine terminated polyethers, amine terminated chain extender and aromatic polyisocyanate
US4588840A (en) * 1982-04-26 1986-05-13 The Dow Chemical Company Oxyalkylene aromatic amines
DE3223396A1 (de) * 1982-06-23 1983-12-29 Bayer Ag, 5090 Leverkusen Polymermodifizierte polyamine, ein verfahren zu ihrer herstellung und ihre verwendung zur herstellung von polyurethanen
US4605773A (en) * 1982-08-10 1986-08-12 Diamond Shamrock Chemicals Company Low-foaming, pH sensitive, alkylamine polyether surface active agents and methods for using
DE3242925A1 (de) * 1982-11-20 1984-05-24 Bayer Ag, 5090 Leverkusen Verfahren zur herstellung von mikrozellularen formkoerpern
US4530941A (en) * 1983-01-26 1985-07-23 The Dow Chemical Company Reaction injection molded polyurethanes employing high molecular weight polyols
US4448904A (en) * 1983-06-08 1984-05-15 Texaco Inc. Reaction injection molded elastomer using a methylene bis(phenyliscoyanate) containing 2,4' isomer in amounts greater than about 10 percent
US4474900A (en) * 1983-06-08 1984-10-02 Texaco Inc. Reaction injection molded elastomers
US4474901A (en) * 1983-06-08 1984-10-02 Texaco Inc. Reaction injection molded elastomers made using high molecular weight amine terminated polyethers and small amounts of low molecular weight amine terminated polyethers
JPS604519A (ja) * 1983-06-24 1985-01-11 Asahi Glass Co Ltd 反応射出成形方法
US4642320A (en) * 1983-11-02 1987-02-10 The Dow Chemical Company Reaction injection molded polyureas employing high molecular weight amine-terminated polyethers
US4578447A (en) * 1983-12-28 1986-03-25 Ex-Cell-O Corporation Rim nylon-based urethane block polymer composition
US4513133A (en) * 1984-02-13 1985-04-23 Texaco Inc. Reaction injection molded elastomers containing low molecular weight organic acids
US4499254A (en) * 1984-02-13 1985-02-12 Texaco Inc. Reaction injection molded elastomers containing high molecular weight organic acids
US4487912A (en) * 1984-02-13 1984-12-11 Texaco Inc. Reaction injection molded elastomers containing acid amides
US4487908A (en) * 1984-02-13 1984-12-11 Texaco Inc. Reaction injection molded elastomers containing anhydrides
US4526972A (en) * 1984-06-27 1985-07-02 Texaco Inc. Ultraviolet light stabilizing sterically hindered polyoxyalkylene amines
US4686242A (en) * 1985-03-25 1987-08-11 The Dow Chemical Company Polyurea polymers prepared from urea containing prepolymers
US4705814A (en) * 1986-11-06 1987-11-10 Texaco Inc. Reaction product of polyoxyalkylene polyamine and an aliphatic isocyanate
US4732919A (en) * 1986-11-06 1988-03-22 Texaco Inc. Reaction injection molded elastomer made from a quasi-prepolymer of a polyoxyalkylene polyamine and an aromatic isocyanate
US4845133A (en) * 1987-04-07 1989-07-04 The Dow Chemical Company Flexible polyurea or polyurea-polyurethane foams prepared from high equivalent weight amine-terminated compounds

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KR930007874B1 (ko) 1993-08-21
JP2612746B2 (ja) 1997-05-21
DE3855995D1 (de) 1997-09-18
EP0298359B1 (en) 1997-08-13
ATE156845T1 (de) 1997-08-15
AU1854488A (en) 1989-01-05
EP0298359A2 (en) 1989-01-11
BR8803203A (pt) 1989-01-31
AU609833B2 (en) 1991-05-09
CA1337135C (en) 1995-09-26
EP0298359A3 (en) 1989-01-25
DE3855995T2 (de) 1997-12-18
JPS6481816A (en) 1989-03-28
US4902768A (en) 1990-02-20

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