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KR880013989A - Polycondensation Reaction Catalyst - Google Patents

Polycondensation Reaction Catalyst Download PDF

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KR880013989A
KR880013989A KR870005240A KR870005240A KR880013989A KR 880013989 A KR880013989 A KR 880013989A KR 870005240 A KR870005240 A KR 870005240A KR 870005240 A KR870005240 A KR 870005240A KR 880013989 A KR880013989 A KR 880013989A
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dicarboxylic acid
monomer
aromatic glycol
acid
monomers
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나오야 오가파
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칼 에이취 크루코우
더 굳이어 타이어 앤드 러버 컴패니
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/182—Phosphorus; Compounds thereof with silicon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0255—Phosphorus containing compounds
    • B01J31/0267—Phosphines or phosphonium compounds, i.e. phosphorus bonded to at least one carbon atom, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, the other atoms bonded to phosphorus being either carbon or hydrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/166—Catalysts not provided for in the groups C08G18/18 - C08G18/26
    • C08G18/168—Organic compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/87—Non-metals or inter-compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
    • C08G69/04—Preparatory processes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
    • C08G69/26—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids
    • C08G69/28—Preparatory processes

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Polyamides (AREA)
  • Polyesters Or Polycarbonates (AREA)

Abstract

내용 없음No content

Description

중축합 반응촉매Polycondensation Reaction Catalyst

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (21)

4가 실리콘 원자 및, 3가 또는 5가인 원자에 직접 결합된 적어도 1개의 2가 산소원자를 함유하는 적어도 1개의 실리콘-인 화합물; 적어도 1개의 산 수용체; 및 적어도 2개의 할로겐 원자가 직접 결합된 적어도 1개의 탄소원자를 함유하는 적어도 1개의 할로겐화 유기 화합물을 함유하는, 축합 중합체의 합성에 특히 유용한 촉매계.At least one silicon-phosphorous compound containing a tetravalent silicon atom and at least one divalent oxygen atom directly bonded to a trivalent or pentavalent atom; At least one acid receptor; And a catalyst system particularly useful for the synthesis of condensation polymers, containing at least one halogenated organic compound containing at least one carbon atom directly bonded to at least two halogen atoms. 적어도 1개의 디카복실산을, 4가 실리콘 원자 및, 3가 또는 5가인 원자에 직접 결합된 적어도 1개의 2가 산소원자를 함유하는 실리콘-인 화합물; 적어도 1개의 산 수용체, 및 2개 이상의 할로겐 원자가 직접 결합된 적어도 1개의 탄소원자를 함유하는 적어도 1개의 할로겐화 유기 화합물의 존재 하에, 적어도 1개의 방향족 글리콜과 중합시킴을 특징으로 하여, 폴리에스테르를 합성시키는 방법.Silicon-phosphorus compounds containing at least one dicarboxylic acid containing a tetravalent silicon atom and at least one divalent oxygen atom directly bonded to a trivalent or pentavalent atom; Polymerizing a polyester, characterized by polymerizing with at least one aromatic glycol in the presence of at least one acid acceptor and at least one halogenated organic compound containing at least one carbon atom to which two or more halogen atoms are directly bonded. Way. 적어도 1개의 디카복실산을, 4가 실리콘 원자 및, 3가 또는 5가인 원자에 직접 결합된 적어도 1개의2가 산소원자를 함유하는 실리콘-인 화합물; 적어도 1개의 산 수용체, 및 적어도 2개의 할로겐 원자가 직접 결합된 적어도 1개의 탄소원자를 함유하는 적어도 1개의 할로겐화 유기 화합물의 존재 하에, 적어도 1개의 디아민과 중합시킴을 특징으로 하여, 폴리아미드를 합성시키는 방법.Silicon-phosphorus compounds containing at least one dicarboxylic acid containing at least one divalent oxygen atom bonded directly to a tetravalent silicon atom and a trivalent or pentavalent atom; A method of synthesizing a polyamide, characterized in that it polymerizes with at least one diamine in the presence of at least one acid acceptor and at least one halogenated organic compound containing at least one carbon atom directly bonded to at least two halogen atoms. . 제 2 항에 있어서, 실리콘-인 화합물 중인 원자 대 디카복실산 모노머 및 방향족 글리콜모노머의 총 몰량의 볼비가 약 0.8:1 내지 약 2:1인 방법.The process of claim 2 wherein the ratio of the total molar amount of atoms in the silicon-phosphorous compound to the dicarboxylic acid monomer and the aromatic glycol monomer is from about 0.8: 1 to about 2: 1. 제 4 항에 있어서, 할로겐화 유기 화합물 중 반응성 할로겐원자 대 디카복실산 모노머 및 방향족 글리콜 모노머의 총 몰량의 몰비가 적어도 약 1:1인 방법.The method of claim 4 wherein the molar ratio of the total molar amount of reactive halogen atoms to dicarboxylic acid monomers and aromatic glycol monomers in the halogenated organic compound is at least about 1: 1. 제 5 항에 있어서, 산 수용체 중 산 수용체 그룹 대 디카복살산 모노머 및 방향족 글리콜 모노머의 총 몰량의 몰비가 적어도 약1:1인 방법.6. The method of claim 5 wherein the molar ratio of the total molar amount of acid acceptor group to dicarboxylic acid monomer and aromatic glycol monomer in the acid acceptor is at least about 1: 1. 제 3 항에 있어서, 실리콘-인 화합물 중 포스포러스 원자 대 디카복실산 모노머 및 방향족 글리콜 모노머의 총 몰량의 몰비가 약 0.8 내지 약 2:1인 방법.4. The process of claim 3 wherein the molar ratio of the total molar amount of phosphorus atoms to dicarboxylic acid monomers and aromatic glycol monomers in the silicon-phosphorous compound is from about 0.8 to about 2: 1. 제 7 항에 있어서, 할로겐화 유기 화합물 중 반응성 할로겐 원자 대 디카복살산 모노머 및 방향족 글리콜 모노머의 총 몰량의 몰비가 적어도 약 1:1인 방법.8. The process of claim 7, wherein the molar ratio of the total molar amount of reactive halogen atoms to dicarboxylic acid monomers and aromatic glycol monomers in the halogenated organic compound is at least about 1: 1. 제 8 항에 있어서, 산 수용체 중 산 수용체 그룹 대 디카복살산 모노머 및 방향족 글리콜 모노머의 총 몰량의 몰비가 적어도 약 1:1인 방법.The method of claim 8, wherein the molar ratio of the total molar amount of acid acceptor group to dicarboxylic acid monomer and aromatic glycol monomer in the acid acceptor is at least about 1: 1. 제 6 항에 있어서, 산 수용체가 적어도 pka 5의 염기이고; 할로겐화 유기 화합물이 적어도 3개의 할로겐 원자가 직접 결합된 적어도 1개의 탄소원자를 함유하는 방법.7. The compound of claim 6, wherein the acid acceptor is at least a base of pka 5; A halogenated organic compound contains at least one carbon atom to which at least three halogen atoms are directly bonded. 제 9 항에 있어서, 상기 방법을 약 50 내지 약 80℃의 온도에서 수행하고; 산 수용체가 적어도 pka 5의 유기 염기이고; 할로겐화 유기 화합물이 적어도 3개의 할로겐 원자가 직접 결합된 적어도 1개의 탄소원자를 함유하는 방법.The method of claim 9, wherein the method is performed at a temperature of about 50 to about 80 ° C .; The acid acceptor is at least an organic base of pka 5; A halogenated organic compound contains at least one carbon atom to which at least three halogen atoms are directly bonded. 적어도 1개의 디카복실산을, 측위(pendamt)디페닐 포스핀 디할라이드 그룹을 갖는 적어도 1개의 중합체 물질, 및 적어도 1개의 산소용체의 존재 하에, 적어도 1개의 방향족 글리콜과 중합시킴을 특징으로 하여, 폴리에스테르를 합성시키는 방법.Polymerizing at least one dicarboxylic acid with at least one aromatic glycol in the presence of at least one polymeric material having a pendant diphenyl phosphine dihalide group, and at least one oxygen solution, Method of synthesizing esters. 제12항에 있어서, 중합체 물질 중 인 원자 대 디카복실산 모노 및 방향족 글리콜 모노머의 총 몰량의 몰비가 약 0.8내지 약 2:1인 방법.The method of claim 12 wherein the molar ratio of the total molar amount of phosphorus atoms to dicarboxylic acid mono and aromatic glycol monomers in the polymeric material is from about 0.8 to about 2: 1. 제13항에 있어서, 산 수용체의 pka가 적어도 5의이고, 산 수용체 중 산 수용체 그룹 대 디카복실산 모노머 및 방향족 글리콜 모노머의 총 몰량의 몰비가 적어도 1:1인 방법.The method of claim 13, wherein the pka of the acid acceptor is at least 5 and the molar ratio of the total molar amount of the acid acceptor group to the dicarboxylic acid monomer and the aromatic glycol monomer in the acid acceptor is at least 1: 1. 제14항에 있어서, 중합체 물질 중 반응성 할로겐 원자 대 디카복실산 모노머 및 방향족 글리콜모노머의 총 몰량의 몰비가 적어도 약1:1이고; 산 수용체의 pka가 5내지 12인 방법.The molar ratio of the total molar amount of the reactive halogen atom to the dicarboxylic acid monomer and the aromatic glycol monomer in the polymer material is at least about 1: 1; The pka of the acid receptor is 5-12. 제15항에 있어서, 중합체 물질이 다음 일반식을 갖는 방법The method of claim 15, wherein the polymeric material has the general formula 상기 식에서, m은 정수이고; X는 할로겐 원자이다.Wherein m is an integer; X is a halogen atom. 적어도 1개의 디카복실산 모노머를, 측위 디페닐 포스핀 디할라이드 그룹을 갖는 유리 비이드(beads), 및 적어도 1개의 산 수용체의 존재 하에, 적어도 1개의 방향족 글리콜 모노머와 중합시킴을 특징으로 하여, 폴리에스테르를 합성시키는 방법.At least one dicarboxylic acid monomer is polymerized with at least one aromatic glycol monomer in the presence of free beads having positional diphenyl phosphine dihalide groups, and at least one acid acceptor. Method of synthesizing esters. 제17항에 있어서, 측위 디페닐 포스핀 디할라이드 그룹 중 인 원자 대 디카복실산 모노머 및 방향족 글리콜 모노머의 총 몰량의 몰비가 약 0.8내지 약2:1인 방법.18. The method of claim 17, wherein the molar ratio of the total molar amount of phosphorus atoms to dicarboxylic acid monomers and aromatic glycol monomers in the positioning diphenyl phosphine dihalide group is from about 0.8 to about 2: 1. 제18항에 있어서, 산 수용체의 pka가 적어도 5이고; 산 수용체 중 산 수용체 그룹 대 디카복실산 모노머 및 방향족 그릴콜 모노머의 총 몰량의 몰비가 적어도 약 1:1이고; 중합체 물질 중 반응성 할로겐 원자 대 디카복실산 모노머 및 방향족 글리콜 모노머의 총 몰량의 몰비가 적어도 약 1:1인 방법.The method of claim 18, wherein the pka of the acid receptor is at least 5; The molar ratio of the total molar amount of acid acceptor group to dicarboxylic acid monomer and aromatic glycol monomer in the acid acceptor is at least about 1: 1; And wherein the molar ratio of the total molar amount of reactive halogen atoms to dicarboxylic acid monomers and aromatic glycol monomers in the polymeric material is at least about 1: 1. 제19항에 있어서, 산 수용체의 pka가 5 내지 12이고; 상기 방법을 50 내지 80℃의 온도에서 수행하여; 측의 디페닐 포스핀 디할라이드 그룹 중 인 원자 대 디카복실산 모노머 및 방향족 글리콜 모노머의 총 몰량의 몰비가 약1.0:1내지 1:5인 방법.The method of claim 19, wherein the pka of the acid receptor is 5 to 12; The method is carried out at a temperature of from 50 to 80 ° C .; And wherein the molar ratio of the total molar amount of phosphorus atoms to dicarboxylic acid monomers and aromatic glycol monomers in the diphenyl phosphine dihalide group on the side is from about 1.0: 1 to 1: 5. 제10항에 있어서, 실리콘-인 화합물 중 인 원자 대 디카복실산 모노머 및 방향족 글리콜 모노머의 총 몰량의 몰비가 약 1.2:1 내지 1:5:1이고; 산 수용체의 pka가 5내지 12인 방법.The molar ratio of the total molar amount of the phosphorus atom to the dicarboxylic acid monomer and the aromatic glycol monomer in the silicon-phosphorous compound is about 1.2: 1 to 1: 5: 1; The pka of the acid receptor is 5-12. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR870005240A 1987-05-04 1987-05-25 Polycondensation Reaction Catalyst Ceased KR880013989A (en)

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US4895817A (en) * 1986-05-09 1990-01-23 The Goodyear Tire & Rubber Company Polycondensation catalyst
US4895922A (en) * 1988-05-05 1990-01-23 The Goodyear Tire & Rubber Company Low temperature synthesis of polyesteramides
US5279818A (en) * 1992-10-13 1994-01-18 Dow Corning Corporation Permanent waving with silicones

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GB1401771A (en) * 1971-11-12 1975-07-30 Ici Ltd Polyesters
US4077944A (en) * 1977-02-28 1978-03-07 Union Carbide Corporation Catalytic production of polyesters
US4143057A (en) * 1977-02-28 1979-03-06 Union Carbide Corporation Coordination complexes as catalysts
US4668762A (en) * 1986-05-09 1987-05-26 The Goodyear Tire & Rubber Company Polycondensation catalyst

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