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KR880009792A - 응집된 광물질 및 이의 제조방법 - Google Patents

응집된 광물질 및 이의 제조방법 Download PDF

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KR880009792A
KR880009792A KR1019880001716A KR880001716A KR880009792A KR 880009792 A KR880009792 A KR 880009792A KR 1019880001716 A KR1019880001716 A KR 1019880001716A KR 880001716 A KR880001716 A KR 880001716A KR 880009792 A KR880009792 A KR 880009792A
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silicate
expanded
saturated
compound
layered silicate
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KR1019880001716A
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KR900004777B1 (ko
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존 보온 윌터
앨런 브루베이커 리차아드
니즈닉 가아먼 쉘리
코울러 호스펠드 루이스
쿠운-이잉 코 케네스
마이클 타이먼 토마스
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끌로드 엘르 보드앵
암스트롱 월드 인더스트리이즈 인코포레이팃드
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Publication of KR880009792A publication Critical patent/KR880009792A/ko
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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B35/00—Boron; Compounds thereof
    • C01B35/08—Compounds containing boron and nitrogen, phosphorus, oxygen, sulfur, selenium or tellurium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/20—Silicates
    • C01B33/36—Silicates having base-exchange properties but not having molecular sieve properties
    • C01B33/38—Layered base-exchange silicates, e.g. clays, micas or alkali metal silicates of kenyaite or magadiite type
    • C01B33/44—Products obtained from layered base-exchange silicates by ion-exchange with organic compounds such as ammonium, phosphonium or sulfonium compounds or by intercalation of organic compounds, e.g. organoclay material
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B35/00—Boron; Compounds thereof
    • C01B35/08—Compounds containing boron and nitrogen, phosphorus, oxygen, sulfur, selenium or tellurium
    • C01B35/10—Compounds containing boron and oxygen
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02—Granular materials, e.g. microballoons
    • C04B14/04—Silica-rich materials; Silicates
    • C04B14/20—Mica; Vermiculite
    • C04B14/206—Mica or vermiculite modified by cation-exchange; chemically exfoliated vermiculate
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/62227—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products obtaining fibres
    • C04B35/62231—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products obtaining fibres based on oxide ceramics
    • C04B35/6224—Fibres based on silica
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H13/00—Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
    • D21H13/36—Inorganic fibres or flakes
    • D21H13/38—Inorganic fibres or flakes siliceous
    • D21H13/44—Flakes, e.g. mica, vermiculite
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/02—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of inorganic substances
    • H01B3/04—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of inorganic substances mica
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H13/00—Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
    • D21H13/10—Organic non-cellulose fibres
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H13/00—Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
    • D21H13/36—Inorganic fibres or flakes
    • D21H13/38—Inorganic fibres or flakes siliceous
    • D21H13/40—Inorganic fibres or flakes siliceous vitreous, e.g. mineral wool, glass fibres
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/03—Non-macromolecular organic compounds
    • D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
    • D21H17/07—Nitrogen-containing compounds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63—Inorganic compounds
    • D21H17/66—Salts, e.g. alums
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K1/00—Printed circuits
    • H05K1/02—Details
    • H05K1/03—Use of materials for the substrate
    • H05K1/0313—Organic insulating material
    • H05K1/0353—Organic insulating material consisting of two or more materials, e.g. two or more polymers, polymer + filler, + reinforcement
    • H05K1/0373—Organic insulating material consisting of two or more materials, e.g. two or more polymers, polymer + filler, + reinforcement containing additives, e.g. fillers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S65/00—Glass manufacturing
    • Y10S65/90—Drying, dehydration, minimizing oh groups
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • Y10T428/252—Glass or ceramic [i.e., fired or glazed clay, cement, etc.] [porcelain, quartz, etc.]

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  • Ceramic Engineering (AREA)
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  • Structural Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
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  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Nonwoven Fabrics (AREA)
  • Paper (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

내용 없음.

Description

응집된 광물질 및 이의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (16)

  1. 하기 단계(1)과 (2)를 포함하는 것을 특징으로 하는, 내수성을 나타내는 비-아스베스토스 고온 물품을 제조하기 위해 이용할 수 있는 응집된 광물질의 제조방법. (1) 구조 단위당 약-0.4 내지 약-1 범위의 평균 전하를 갖고 교환성 격자간 이온을 함유한 팽창된, 2:1로 층을 이룬 실리케이트 분산액과 근본적으로 디암모늄 화합물로 이루어진 화합물로부터 유도된 교환양이온 최소한 한가지종을 접촉시키고; 이로인해 (2) 교환성 격자간 이온 최소한 일부와 교환 양이온 최소한 일부 사이의 이온 교환 반응에 의해 실리케이트를 응집시켜 응집된 실리케이트 생성물을 형성하되, 단, 2:1로 층을 이룬 실리케이트는 층의 팽창과 겔의 형성을 야기하기에 충분한 시간동안 2:1로 층을 이룬 실리케이트와 극성 액체를 접촉시킴으로씨 팽창되는 것을 조건으로 한다.
  2. 제1항에 있어서, 디암모늄 화합물이 하기 일반식을 갖는 것을 특징으로하는 방법.
    상기식에서 (1) 각각의 R1이 독립적으로 수소 또는 C1-C8포화 또는 불포화, 직쇄 또는 측쇄 알킬기일 수 있고 (2) R2는 포화, 불포화 선형 또는 분지형 탄화수소 성분이다.
  3. 제2항에 있어서, 팽창된 2:1로 층을 이룬 실리케이드가 합성 겔형성 실리케이트이고 격자간 이온이 Li+및/또는 Na+인것을 특징으로 하는 방법.
  4. 제3항에 있어서, 합성 실리케이트가 바람직하게는 플루오르헥토라이트, 히드록실 헥토라이트, 플루오르플로고파이트 붕소, 히드록실 플로고파이드 붕소, 와 상기 화합물간의 고용체 및 상기 화합물과 탈크, 플루오르탈크, 폴리리티오나이트, 플루오로폴리리티오나이트, 플로고파이트 및 플루오르폴로고파이트로 된 군으로부터 선택된 그밖의 다른 구조적으로 양립할수 있는 종사의 고용체로 이루어진 군으로부터 선택된 운모인 것을 특징으로 하는 방법.
  5. 제2항에 있어서, 각각의 R1이 수소이고 R2가 탄소원자 1 내지 18개, 바람직하게는 탄소원자 10 내지 18개를 갖는 포화 탄화수소 성분인 것을 특징으로 하는 방법.
  6. 제2항에 있어서, 실리케이트가 벌미클라이트인 것을 특징으로 하는 방법.
  7. 제1항에 있어서, 팽창된 2:1로 층을 이룬 실리케이트 분산액이 단계1에서 디암모늄 화합물과 접촉하기전에 필름 형태로 있고/있거나 또한 섬유를 함유하는 것을 특징으로 하는 방법.
  8. 제1항에 있어서, 팽창된 2:1로 층을 이룬 실리케이트 분산액이 고형물 5중량%를 초과하고 바람직하게는 디암모늄 화합물과 접촉하기전에 물품으로 성형되는 것을 특징으로 하는 방법.
  9. 제1항에 있어서, 팽창된 2:1로 층을 이룬 실리케이트 분산액이 디암모늄 화합물과 접촉하기 전에 (a) 부직섬유상 물질과 결합하거나 또는 (b) 직조 섬유상 물질과 결합하는 것을 특징으로 하는 방법.
  10. 제1항에 있어서, 응집된 실리케이트 생성물이 이후 섬유와 결합하는 것을 특징으로 하는 방법.
  11. 제1항에 있어서, 팽창된 2:1로 층을 이룬 실리케이트 분산액이 디암모늄 화합물과 접촉하기전에 에폭시와 같은 유기 올리고머와 결합하는 것을 특징으로 하는 방법.
  12. 구조 단위당 약-0.4 내지 약-1 범위의 평균 전하를 갖고, 근본적으로 이암모늄 화합물로 이루어진 화합물로 부터 유도된 최소한 일부의 격자간 양이온을 함유한, 팽창된 2:1로 층을 이룬 실리케이트 응집괴를 포함하는 것을 특징으로 하는 내수성 실리케이트 구조물질.
  13. 제12항에 있어서, 디암모늄 화합물이 하기 일반식을 갖는 것을 특징으로 하는 물질.
    상기식에서 (1) 각각은 R1은 독립적으로 수소 또는 C1-c8포화 또는 불포화, 직쇄 또는 측쇄 알킬기일 수 있고 (1) R2는 포화 또는 불포화 선형 또는 분지형 탄화수소 성분이다.
  14. 제12항에 있어서, 디암모늄 화합물이 하기 일반식을 갖는 것을 특징으로 하는 물질.
    상기식에서 (1) 각각은 R은 독립적으로 수소, C1-C8포화 또는 불포화, 직쇄 또는 측쇄 알킬기, C3-C6아시클릭 알킬기 또는 아릴기로 부터 선택되는데, 단 이때 각 질소상의 아릴기는 하나보다 많은 조건으로 한다. (2) 각각의 X는 독립적으로 수소, 알킬기 또는 아릴기로부터 선택되고 (3) n은 2 내지 15의 정수를 나타내고, 임의에 따라 n이 3또는 그 이상일때 CX2기는 방향족일 수 있는, 고리를 이룬 성분을 형성할 수 있다.
  15. 제12항에 있어서, 실리케이트가 벌미클라이트인 것을 특징으로 하는 물질.
  16. 제12항에 있어서, 부직 섬유, 에폭시와 같은 유기 올리고마 또는 직조 섬유를 함유하는 것을 특징으로 하는 물질.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019880001716A 1987-02-17 1988-02-17 응집된 광물질 및 이의 제조방법 KR900004777B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US07/015,756 US4877484A (en) 1985-03-25 1987-02-17 Flocced 2:1 layered silicates and water-resistant articles made therefrom
US015756 1987-02-17
US015.756 1987-02-17

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KR880009792A true KR880009792A (ko) 1988-10-05
KR900004777B1 KR900004777B1 (ko) 1990-07-05

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US (1) US4877484A (ko)
JP (1) JPS63242915A (ko)
KR (1) KR900004777B1 (ko)
CN (1) CN88101836A (ko)
AU (1) AU603425B2 (ko)
BE (1) BE1003333A4 (ko)
BR (1) BR8800639A (ko)
DE (1) DE3804088A1 (ko)
ES (1) ES2005781A6 (ko)
FI (1) FI880721A (ko)
FR (1) FR2610914A1 (ko)
GB (1) GB2201667A (ko)
IT (1) IT1215867B (ko)
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AU1173988A (en) 1988-08-18
CN88101836A (zh) 1988-12-07
BR8800639A (pt) 1988-09-27
DE3804088A1 (de) 1988-08-25
ES2005781A6 (es) 1989-03-16
FI880721A (fi) 1988-08-18
SE8800506L (sv) 1988-08-18
AU603425B2 (en) 1990-11-15
US4877484A (en) 1989-10-31
SE8800506D0 (sv) 1988-02-16
IT8819419A0 (it) 1988-02-16
NO880669L (no) 1988-08-18
NL8800401A (nl) 1988-09-16
FR2610914A1 (fr) 1988-08-19
DE3804088C2 (ko) 1989-11-23
IT1215867B (it) 1990-02-22
NO880669D0 (no) 1988-02-16
GB8803540D0 (en) 1988-03-16
BE1003333A4 (fr) 1992-03-03
JPS63242915A (ja) 1988-10-07
JPH0574526B2 (ko) 1993-10-18
GB2201667A (en) 1988-09-07
LU87132A1 (de) 1988-07-14
FI880721A0 (fi) 1988-02-16

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