KR880009091A - 폴리아미드/이오노머/유리섬유 블렌드를 포함하는 열가소성 성형 조성물 및 그로부터 만들어진 성형물품 - Google Patents
폴리아미드/이오노머/유리섬유 블렌드를 포함하는 열가소성 성형 조성물 및 그로부터 만들어진 성형물품 Download PDFInfo
- Publication number
- KR880009091A KR880009091A KR1019880000598A KR880000598A KR880009091A KR 880009091 A KR880009091 A KR 880009091A KR 1019880000598 A KR1019880000598 A KR 1019880000598A KR 880000598 A KR880000598 A KR 880000598A KR 880009091 A KR880009091 A KR 880009091A
- Authority
- KR
- South Korea
- Prior art keywords
- component
- composition
- mole percent
- nylon
- carboxylic acid
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims 25
- 239000003365 glass fiber Substances 0.000 title claims 2
- 238000009757 thermoplastic moulding Methods 0.000 title claims 2
- 239000004952 Polyamide Substances 0.000 title 1
- 229920000554 ionomer Polymers 0.000 title 1
- 229920002647 polyamide Polymers 0.000 title 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims 8
- -1 2-ethoxyethyl Chemical group 0.000 claims 5
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims 4
- 239000005977 Ethylene Substances 0.000 claims 4
- 229920001577 copolymer Polymers 0.000 claims 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims 2
- 229920002292 Nylon 6 Polymers 0.000 claims 2
- 229920002302 Nylon 6,6 Polymers 0.000 claims 2
- 125000005907 alkyl ester group Chemical group 0.000 claims 2
- 125000006176 2-ethylbutyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(C([H])([H])*)C([H])([H])C([H])([H])[H] 0.000 claims 1
- 125000004200 2-methoxyethyl group Chemical group [H]C([H])([H])OC([H])([H])C([H])([H])* 0.000 claims 1
- JHWNWJKBPDFINM-UHFFFAOYSA-N Laurolactam Chemical compound O=C1CCCCCCCCCCCN1 JHWNWJKBPDFINM-UHFFFAOYSA-N 0.000 claims 1
- 239000004677 Nylon Substances 0.000 claims 1
- 229920000299 Nylon 12 Polymers 0.000 claims 1
- 229920000305 Nylon 6,10 Polymers 0.000 claims 1
- 229920000572 Nylon 6/12 Polymers 0.000 claims 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims 1
- 125000004432 carbon atom Chemical group C* 0.000 claims 1
- 230000009477 glass transition Effects 0.000 claims 1
- 229920001519 homopolymer Polymers 0.000 claims 1
- 239000000155 melt Substances 0.000 claims 1
- 238000002844 melting Methods 0.000 claims 1
- 230000008018 melting Effects 0.000 claims 1
- 229910021645 metal ion Inorganic materials 0.000 claims 1
- 238000000034 method Methods 0.000 claims 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 1
- 125000003136 n-heptyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 1
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 claims 1
- 229920001778 nylon Polymers 0.000 claims 1
- ANISOHQJBAQUQP-UHFFFAOYSA-N octyl prop-2-enoate Chemical compound CCCCCCCCOC(=O)C=C ANISOHQJBAQUQP-UHFFFAOYSA-N 0.000 claims 1
- 230000000737 periodic effect Effects 0.000 claims 1
- 229920006114 semi-crystalline semi-aromatic polyamide Polymers 0.000 claims 1
- 229920001169 thermoplastic Polymers 0.000 claims 1
- 239000004416 thermosoftening plastic Substances 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/06—Polyamides derived from polyamines and polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/14—Glass
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing atoms other than carbon or hydrogen
- C08L23/0869—Copolymers of ethene with unsaturated hydrocarbons containing atoms other than carbon or hydrogen with unsaturated acids, e.g. [meth]acrylic acid; with unsaturated esters, e.g. [meth]acrylic acid esters
- C08L23/0876—Salts thereof, i.e. ionomers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
Claims (16)
- 하기(a)-(c)의 용융 블랜드를 포함하는 열가소성 성형 조성물. (a) 적어도 160℃의 융점을 갖는 적어도 하나의 열가소성 반-결정질 폴리아미드. (b)에틸렌, 적어도 하나의 불포화 카르복실산 및,-40℃미만의 유리전이 온도를 갖는 단일 중합체를 형성할 수 있는 능력이 있는 적어도 하나의 연화 공단량체를 반응으로 부터 유도되는, 원소 주기율표의 Ia, Ib, IIa, IIb, IIIa, IVa, VIb와 VIII족로부터 선택된 금속 이온로 3-90%중화된 적어도 하나의 이온성 공중합체. (c) 유리 섬유 [여기서 성분(b) 대 성분(a)의 중량이 0.9-1.3이고, 성분(c)의 양은 총 조성물의 2-20중량%이다.]
- 제1항에 있어서, 성분(b) 대 성분(a)의 중량비가 0.95-1.15인 조성물.
- 제2항에 있어서, 성분(c)의 양이 총 조성물의 5-12중량%인 조성물.
- 제1항에 있어서, 성분(b) 대 성분(a)의 중량비가 1.0-1.1인 조성물.
- 제4항에 있어서, 성분(c)의 양이 총 조성물의 8-10중량%인 조성물.
- 제1항에 있어서, 성분(a)가 나일론 69. 나일론 610, 나일론 612, 나일론 6, 나일론 12 및 이들의 블렌드로부터 선택되는 조성물.
- 제6항에 있어서, 성분(a)가 나일론 66과 나일론 66 및 나일론 6의 블렌드로부터 선택되는 조성물.
- 제1항에 있어서, 성분(b)내의 불포화 카르복실산이 3-8개의 탄소원자를 갖는 카르복실산인 조성물.
- 제8항에 있어서, 성분(b)내의 불포화 카르복실산이 아크릴 산과 메타크릴산과 이들의 블렌드로부터 선택되는 조성물.
- 제9항에 있어서 성분(b)내의 불포화 카르복실산이 메타크릴산인 조성물.
- 제1항에 있어서, 성분(b)내의 연화공단량체가 아크릴 산의 알킬 에스테르로부터 선택되고 이 알킬 에스테르는 2-에톡시에틸, 2-에틸부틸, 2-메톡시에틸, 3-에톡시프로필, 3-메톡시부틸, 4-티아펜틸, 3-메톡시프로필, n-부틸, n-헥실, n-헵틸 및 n-옥틸 아크릴레이트로부터 선택되는 조성물.
- 제11항에 있어서, 성분(b)내의 연화공단량체가 n-부틸 아크릴레이트인 조성물.
- 제1항에 있어서, 이온성 공중합체 성분(b)가 70-99.2몰 퍼센트의 에틸렌 단위, 0.35-12몰 퍼센트가 카르복실산 단위, 및 0.45-12몰 퍼센트의 연화 공단량체 단위를 함유하는 조성물.
- 제13항에 있어서, 이온성 공중합체 성분(b)가 77-98.25몰 퍼센트의 에틸렌 단위, 1-9.5몰 퍼센트의 카르복실산 단위 및 0.75-9.0몰 퍼센트의 연화 공단량체 단위를 함유하는 조성물.
- 제13항에 있어서, 이온성 공중합체 성분(b)가 81-96.8몰 퍼센트의 에틸렌 단위, 2-9몰 퍼센트의 카르복실산 단위 및 1.2-7몰 퍼센트의 연화 공단량체 단위를 포함하는 조성물.
- 제1항의 조성물로 부터 제조된 성형 물품.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US725487A | 1987-01-27 | 1987-01-27 | |
US7254 | 1987-01-27 | ||
US007,254 | 1987-01-27 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR880009091A true KR880009091A (ko) | 1988-09-14 |
KR910004094B1 KR910004094B1 (ko) | 1991-06-22 |
Family
ID=21725105
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019880000598A KR910004094B1 (ko) | 1987-01-27 | 1988-01-26 | 폴리아미드/이오노머/유리섬유 블렌드를 포함하는 열가소성 성형 조성물 및 그로부터 만들어진 성형물품 |
Country Status (7)
Country | Link |
---|---|
EP (1) | EP0276828A1 (ko) |
JP (1) | JPS63193946A (ko) |
KR (1) | KR910004094B1 (ko) |
CN (1) | CN88100594A (ko) |
BR (1) | BR8800310A (ko) |
DK (1) | DK35388A (ko) |
ZA (1) | ZA88556B (ko) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100977588B1 (ko) * | 2008-11-03 | 2010-08-23 | 주식회사 이폴리머 | 폴리아미드/이오노머 블렌드 수지 조성물 또는 이들의 반응물 |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA1338025C (en) * | 1988-08-29 | 1996-01-30 | Andri Elia Elia | Toughened nylons characterized by low mold deposit |
JPH0781016B2 (ja) * | 1991-03-18 | 1995-08-30 | 東レ株式会社 | ポリアミド吹込成形品 |
DE9311731U1 (de) * | 1993-08-06 | 1993-10-14 | Hoechst Ag, 65929 Frankfurt | Spritzgußformteil aus Thermoplastwerkstoff |
US5688868A (en) * | 1996-08-26 | 1997-11-18 | E. I. Du Pont De Nemours And Company | Process for preparing blends of polyamide and ionic copolymers |
US5866658A (en) * | 1996-08-26 | 1999-02-02 | E. I. Du Pont De Nemours And Company | High performance ionomer blends |
ES2222952T3 (es) * | 2001-06-13 | 2005-02-16 | Getinge Skarhamn Ab | Dispositivo para un autoclave. |
US8198355B2 (en) * | 2006-06-15 | 2012-06-12 | E. I. Du Pont De Nemours And Company | Nanocomposite compositions of polyamides and sepiolite-type clays |
JP6447177B2 (ja) * | 2014-02-03 | 2019-01-09 | 東レ株式会社 | 熱可塑性樹脂組成物 |
CN110760184A (zh) * | 2019-09-27 | 2020-02-07 | 金旸(厦门)新材料科技有限公司 | 一种改善涂料附着效果的聚酰胺材料及其制备方法和应用 |
CN112143218B (zh) * | 2020-09-03 | 2022-07-01 | 金旸(厦门)新材料科技有限公司 | 一种高热变形温度增强增韧ppa材料 |
CN114213821B (zh) * | 2021-11-26 | 2024-01-23 | 金发科技股份有限公司 | 一种聚酰胺复合材料及其制备方法和应用 |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS51106157A (ja) * | 1975-03-17 | 1976-09-20 | Asahi Dow Ltd | Jugotaisoseibutsu |
JPS5715069A (en) * | 1980-06-30 | 1982-01-26 | Toray Ind Inc | Under-hood part for automobile |
US4310638A (en) * | 1980-08-20 | 1982-01-12 | Monsanto Company | Nylon modified acrylic copolymer rubber |
JPS5761051A (en) * | 1980-09-10 | 1982-04-13 | Unitika Ltd | Impact-resisting, heat-resisting, flame-retardant polyamide resin composition |
US4404325A (en) * | 1981-05-11 | 1983-09-13 | Allied Corporation | High impact nylon composition containing copolymer esters and ionic copolymers |
JPS58176246A (ja) * | 1982-04-09 | 1983-10-15 | Asahi Chem Ind Co Ltd | ポリアミド樹脂組成物 |
JPH07108949B2 (ja) * | 1984-02-15 | 1995-11-22 | 東レ株式会社 | ブロー中空成形品 |
JPH0618929B2 (ja) * | 1984-03-28 | 1994-03-16 | チッソ株式会社 | ガラス繊維強化ポリプロピレン組成物 |
-
1988
- 1988-01-26 JP JP63013731A patent/JPS63193946A/ja active Pending
- 1988-01-26 DK DK035388A patent/DK35388A/da unknown
- 1988-01-26 KR KR1019880000598A patent/KR910004094B1/ko not_active IP Right Cessation
- 1988-01-27 BR BR8800310A patent/BR8800310A/pt not_active Application Discontinuation
- 1988-01-27 CN CN198888100594A patent/CN88100594A/zh active Pending
- 1988-01-27 ZA ZA88556A patent/ZA88556B/xx unknown
- 1988-01-27 EP EP88101163A patent/EP0276828A1/en not_active Withdrawn
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100977588B1 (ko) * | 2008-11-03 | 2010-08-23 | 주식회사 이폴리머 | 폴리아미드/이오노머 블렌드 수지 조성물 또는 이들의 반응물 |
Also Published As
Publication number | Publication date |
---|---|
ZA88556B (en) | 1989-09-27 |
CN88100594A (zh) | 1988-09-28 |
KR910004094B1 (ko) | 1991-06-22 |
DK35388A (da) | 1988-07-28 |
DK35388D0 (da) | 1988-01-26 |
BR8800310A (pt) | 1988-09-06 |
EP0276828A1 (en) | 1988-08-03 |
JPS63193946A (ja) | 1988-08-11 |
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