KR880002817A - 히드록시알킬 카르바메이트와 그 제조방법 및 용도 - Google Patents
히드록시알킬 카르바메이트와 그 제조방법 및 용도 Download PDFInfo
- Publication number
- KR880002817A KR880002817A KR1019870008898A KR870008898A KR880002817A KR 880002817 A KR880002817 A KR 880002817A KR 1019870008898 A KR1019870008898 A KR 1019870008898A KR 870008898 A KR870008898 A KR 870008898A KR 880002817 A KR880002817 A KR 880002817A
- Authority
- KR
- South Korea
- Prior art keywords
- blend
- polymer
- coating composition
- compound
- reacted
- Prior art date
Links
- -1 Hydroxyalkyl Carbamate Chemical compound 0.000 title claims 5
- 238000000034 method Methods 0.000 title claims 3
- 239000000203 mixture Substances 0.000 claims 11
- 229920000642 polymer Polymers 0.000 claims 10
- 239000008199 coating composition Substances 0.000 claims 6
- 150000001875 compounds Chemical class 0.000 claims 5
- 239000003431 cross linking reagent Substances 0.000 claims 4
- 229920001228 polyisocyanate Polymers 0.000 claims 4
- 239000005056 polyisocyanate Substances 0.000 claims 4
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims 3
- 125000006702 (C1-C18) alkyl group Chemical group 0.000 claims 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 2
- 150000001412 amines Chemical class 0.000 claims 2
- 239000001257 hydrogen Substances 0.000 claims 2
- 229910052739 hydrogen Inorganic materials 0.000 claims 2
- 239000011541 reaction mixture Substances 0.000 claims 2
- BNCADMBVWNPPIZ-UHFFFAOYSA-N 2-n,2-n,4-n,4-n,6-n,6-n-hexakis(methoxymethyl)-1,3,5-triazine-2,4,6-triamine Chemical group COCN(COC)C1=NC(N(COC)COC)=NC(N(COC)COC)=N1 BNCADMBVWNPPIZ-UHFFFAOYSA-N 0.000 claims 1
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 claims 1
- 239000004971 Cross linker Substances 0.000 claims 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims 1
- 229920000877 Melamine resin Polymers 0.000 claims 1
- 208000000474 Poliomyelitis Diseases 0.000 claims 1
- 239000004721 Polyphenylene oxide Substances 0.000 claims 1
- 150000005676 cyclic carbonates Chemical class 0.000 claims 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims 1
- OJURWUUOVGOHJZ-UHFFFAOYSA-N methyl 2-[(2-acetyloxyphenyl)methyl-[2-[(2-acetyloxyphenyl)methyl-(2-methoxy-2-oxoethyl)amino]ethyl]amino]acetate Chemical compound C=1C=CC=C(OC(C)=O)C=1CN(CC(=O)OC)CCN(CC(=O)OC)CC1=CC=CC=C1OC(C)=O OJURWUUOVGOHJZ-UHFFFAOYSA-N 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- 239000000178 monomer Substances 0.000 claims 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 1
- 229920000768 polyamine Polymers 0.000 claims 1
- 229920000728 polyester Polymers 0.000 claims 1
- 229920000570 polyether Polymers 0.000 claims 1
- 229920005862 polyol Polymers 0.000 claims 1
- 150000003077 polyols Chemical class 0.000 claims 1
- 239000001294 propane Substances 0.000 claims 1
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical group CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G71/00—Macromolecular compounds obtained by reactions forming a ureide or urethane link, otherwise, than from isocyanate radicals in the main chain of the macromolecule
- C08G71/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/06—Polyurethanes from polyesters
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Polyurethanes Or Polyureas (AREA)
- Polyesters Or Polycarbonates (AREA)
- Paints Or Removers (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (19)
- 하기 일반식을 갖는 히드록시 알킬 카르바메이트 화합물여기에서 R1과 R2는 각각 수소 또는 C1-C18알킬기, 또는 C5나 C6의 시클로-지방족 부분이며, R4와 R5는 각각 수소 또는 C1-C18알킬기, 또는 페닐기, 또는 -CH2-OR1부분이고, R3는또는 각각 C1-C10의 직쇄 또는 측쇄 또는 시클로-지방족 알킬렌 부분, 또는 -O-CH2-CH2-CH2-부분이다.
- 직쇄 또는 측쇄 폴리에스테르를 기제로 한 폴리오과 반응시킨 제1항의 화합물의 중합체.
- 디카르복실산의 디메틸 에스테르와 반응시킨, 말단 히드록실기를 갖는 제1항의 화합물의 중합체.
- 다른 히도록시알킬 카르바메이트와 반응시킨 제1항의 화합물의 중합체.
- 제2항의 중합체와 가교 결합제로서의, 메틸을 폴리아민 또는 폴리이소시아네이트 화합물과의 블렌드.
- 제2항의 중합체와 가교 결합제로서의, 폴리이소시아 네이트 및/또는 블로킹된 폴리아소시아네트의 블렌드.
- 제2항의 중합체와 가교 결합제로서, 알킬화된 폴리메틸을 멜라민과의 블렌드.
- 가교 결합제로서, 메틸을 폴리아민을 포함하는 제4항의 중합체의 블렌드.
- 가교 결합제로서, 폴리이소시아네이트를 포함하는 제4항의 중합체의 블렌드.
- 제8항에 있어서, 가교 결합제가 헥사키스메톡시 메틸 멜라민인 블렌드
- 알콜 아민과 시클릭 카르보네이트를 유리 아민 함량이 반응 혼합물의 약 1중량% 아래가 될때까지 약 25℃와 200℃ 사이의 온도에서 적어도 동량이나 또는 카르보네이트를 과량으로 하여 반응시키고 본질적으로 모든 카르보네이트가 제거될 때까지 반응 혼합물을 스트리핑 시키는 것으로 구성되는 알카놀아민 히드록실 알킬 카르바메이크를 생산하는 방법.
- 제11항에 있어서, 아민이 3-아미노-2, 2-디메틸-1-프로판을 이고 카르보네이트가 프로필렌 카르보네이트인 방법.
- 제5항의 블렌드를 포함하는 코우팅 조성물.
- 제6항의 블렌드를 포함하는 코우팅 조성물.
- 제7항의 블렌드를 포함하는 코우팅 조성물.
- 제8항의 블렌드를 포함하는 코우팅 조성물.
- 제9항의 블렌드를 포함하는 코우팅 조성물.
- 단량체 및/또는 중합체 형태로 제1항의 히드록시 알킬 카르 바메이트 화합물을 포함하는 코우팅 조성물.
- 직쇄 또는 측쇄 폴리에테르-기제의 폴리올과 반응시킨 제1항의 화합물의 중합체.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US89626086A | 1986-08-14 | 1986-08-14 | |
US896260 | 1986-08-14 |
Publications (1)
Publication Number | Publication Date |
---|---|
KR880002817A true KR880002817A (ko) | 1988-05-11 |
Family
ID=25405905
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019870008898A KR880002817A (ko) | 1986-08-14 | 1987-08-13 | 히드록시알킬 카르바메이트와 그 제조방법 및 용도 |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP0257848A3 (ko) |
JP (1) | JPS6348255A (ko) |
KR (1) | KR880002817A (ko) |
AU (1) | AU7678887A (ko) |
Families Citing this family (26)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4859780A (en) * | 1988-02-26 | 1989-08-22 | Ciba-Geigy Corporation | Hydrophilic modifier monomers |
US5155201A (en) * | 1989-07-13 | 1992-10-13 | Akzo N.V. | Polyurethane polyols and high solids coatings therefrom |
US5175227A (en) * | 1989-07-13 | 1992-12-29 | Akzo N.V. | Acid etch resistant coatings containing polyurethane polyols |
US5130405A (en) * | 1989-07-13 | 1992-07-14 | Akzo N.V. | Acid etch resistant coatings |
DE3991770T (ko) * | 1989-11-14 | 1992-01-30 | ||
US5356669A (en) * | 1992-10-23 | 1994-10-18 | Basf Corporation | Composite color-plus-clear coating utilizing carbamate-functional polymer composition in the clearcoat |
AU673561B2 (en) | 1992-10-30 | 1996-11-14 | Ppg Industries Ohio, Inc. | Aminoplast-curable film-forming compositions providing filmshaving resistance to acid etching |
US6235858B1 (en) | 1992-10-30 | 2001-05-22 | Ppg Industries Ohio, Inc. | Aminoplast curable film-forming compositions providing films having resistance to acid etching |
TW242644B (ko) * | 1992-10-30 | 1995-03-11 | Ppg Industries Inc | |
US6103816A (en) * | 1992-10-30 | 2000-08-15 | Ppg Industries Ohio, Inc. | Aqueous aminoplast curable film-forming compositions providing films having resistance to acid etching |
US5709950A (en) * | 1994-04-29 | 1998-01-20 | Ppg Industries, Inc. | Color-plus-clear composite coatings that contain polymers having carbamate functionality |
CA2188832C (en) * | 1994-04-29 | 2000-06-20 | Steven V. Barancyk | Flexible aminoplast-curable film-forming compositions providing films having resistance to acid etching |
US5976701A (en) * | 1994-04-29 | 1999-11-02 | Ppg Industries Ohio, Inc. | Flexible aminoplast-curable film-forming compositions and composite coating |
KR100422518B1 (ko) | 1995-06-07 | 2004-05-20 | 아크조 노벨 엔.브이. | 폴리우레탄폴리올과점도가감소된그의코팅재 |
US5593733A (en) * | 1995-11-21 | 1997-01-14 | Ppg Industries, Inc. | Coating composition containing polyester polymers with terminal carbamate groups and polymeric polyol derived from ethylenically unsaturated monomers |
US5859174A (en) * | 1996-07-22 | 1999-01-12 | Ppg Industries, Inc. | Amide functional monomers and acrylic polymers with amide functionality |
US5780559A (en) * | 1996-07-22 | 1998-07-14 | Ppg Industries, Inc. | Curable film-forming compositions containing amide functional polymers |
US5959040A (en) * | 1996-09-04 | 1999-09-28 | Ppg Industries Ohio, Inc. | Film-forming composition suitable for use as a monocoat |
US5759694A (en) * | 1996-09-04 | 1998-06-02 | Ppg Industries, Inc. | Carbamate functional polymers and oligomers and coating compositions containing same |
US6258898B1 (en) * | 1996-12-23 | 2001-07-10 | Basf Corporation | Amino resins functionalized with carbamate groups and coating compositions containing the same |
CA2361330A1 (en) | 1999-03-17 | 2000-09-21 | E.I. Du Pont De Nemours And Company | High solids clear coating composition |
US6855779B1 (en) | 1999-03-17 | 2005-02-15 | E. I. Du Pont De Nemours And Company | High solid epoxy, melamine and isocyanate compositions |
AU762095B2 (en) | 1999-03-17 | 2003-06-19 | E.I. Du Pont De Nemours And Company | High solids acid etch and mar resistant clear coating composition |
ES2251369T3 (es) | 1999-03-17 | 2006-05-01 | E.I. Du Pont De Nemours And Company | Composicion de recubrimiento transparente de alto contenido en solidos. |
EP2465842A1 (de) | 2010-12-17 | 2012-06-20 | Sika Technology AG | Amine mit sekundären aliphatischen Aminogruppen |
US11053191B2 (en) | 2018-01-09 | 2021-07-06 | Ppg Industries Ohio, Inc. | Hydroxy functional alkyl carbamate crosslinkers |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3595814A (en) * | 1968-11-14 | 1971-07-27 | Jefferson Chem Co Inc | Urethanes containing monocarbamate chain extenders |
DE2725318A1 (de) * | 1977-06-04 | 1978-12-14 | Bayer Ag | Verfahren zur herstellung von allophanatgruppen aufweisenden polyisocyanaten |
US4520167A (en) * | 1984-02-17 | 1985-05-28 | American Cyanamid Co. | Hydroxyalkyl carbamate diluent for coating compositions and compositions containing the same |
-
1987
- 1987-08-03 EP EP87306866A patent/EP0257848A3/en not_active Withdrawn
- 1987-08-10 JP JP62198355A patent/JPS6348255A/ja active Pending
- 1987-08-12 AU AU76788/87A patent/AU7678887A/en not_active Abandoned
- 1987-08-13 KR KR1019870008898A patent/KR880002817A/ko not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
EP0257848A3 (en) | 1989-01-11 |
AU7678887A (en) | 1988-02-18 |
EP0257848A2 (en) | 1988-03-02 |
JPS6348255A (ja) | 1988-02-29 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PA0109 | Patent application |
Patent event code: PA01091R01D Comment text: Patent Application Patent event date: 19870813 |
|
PG1501 | Laying open of application | ||
PC1203 | Withdrawal of no request for examination | ||
WITN | Application deemed withdrawn, e.g. because no request for examination was filed or no examination fee was paid |