KR870007528A - 방사능에 오염된 물질로부터 오염을 제거하는 공정 - Google Patents
방사능에 오염된 물질로부터 오염을 제거하는 공정 Download PDFInfo
- Publication number
- KR870007528A KR870007528A KR870000666A KR870000666A KR870007528A KR 870007528 A KR870007528 A KR 870007528A KR 870000666 A KR870000666 A KR 870000666A KR 870000666 A KR870000666 A KR 870000666A KR 870007528 A KR870007528 A KR 870007528A
- Authority
- KR
- South Korea
- Prior art keywords
- process according
- potassium permanganate
- dilute nitric
- nitric acid
- oxalic acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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Classifications
-
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21C—NUCLEAR REACTORS
- G21C9/00—Emergency protection arrangements structurally associated with the reactor, e.g. safety valves provided with pressure equalisation devices
-
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
- G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
- G21F9/001—Decontamination of contaminated objects, apparatus, clothes, food; Preventing contamination thereof
- G21F9/002—Decontamination of the surface of objects with chemical or electrochemical processes
-
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
- G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E30/00—Energy generation of nuclear origin
- Y02E30/30—Nuclear fission reactors
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- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- General Engineering & Computer Science (AREA)
- High Energy & Nuclear Physics (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Food Science & Technology (AREA)
- Plasma & Fusion (AREA)
- Detergent Compositions (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
- Micro-Organisms Or Cultivation Processes Thereof (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Measurement Of Radiation (AREA)
- Superconductors And Manufacturing Methods Therefor (AREA)
- Control Of El Displays (AREA)
- Ceramic Products (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Crystals, And After-Treatments Of Crystals (AREA)
Abstract
Description
Claims (16)
- 오염된 물질표면을 탄산나트륨용액과 소정시간동안 연속적으로 접촉시키고, 오염된 물질표면을 가열과 함께 묽은 질산가 접촉시키면서 과망간산칼륨을 가하고, 오염된 물질 표면을 소정시간동안 옥살산용액(COOH-COOH·2H2O)과 접촉시키고, 마지막으로 상기 물질을 헹구어 건조시키는 단계로 구성된 것을 특징으로 하는 방사능에 오염된 물질의 오염제거 공정.
- 제1항에 있어서, 탄산나트륨 용액을 예열하는 것을 특징으로 하는 공정.
- 제1항 또는 2항에 있어서, 강알카리 탄산나트륨 용액이 사용되는 것을 특징으로 하는 공정.
- 전항중 어느 한항에 있어서, 오염된 물질표면을 탄산나트륨용액과 접촉시키는데 걸리는 시간은5-30분인것을 특징으로 하는 공정.
- 전항중 어느한항에 있어서, 오염된 물질을 탄산나트륨용액과 접촉시키면서 묽은 질산과 과망간산칼륨을 함께 접촉시키는데 걸리는 시간은 처리되는 물질의 최대표면과 방사성 오염물의 종류및 강도를 고려하여 선택되는 것을 특징으로 하는 공정.
- 전항중 어느한항에 있어서, 묽은 질산은 약 70℃의 온도에서 사용되는 것을 특징으로 하는 공정.
- 전항중 어느한항에 있어서, 과망간산칼륨은 1000ℓ당 1kg의 비로 가행지는 것을 특징으로 하는 공정.
- 제1항내지 제6항중 어느한항에 있어서, 과망간산칼륨은 처리되는 물질표면의 크기가 방사성오염물의 종류 및 강도를 고려하여 묽은 질산에 가행지는 것을 특징으로 하는 공정.
- 전항중 어느한항에 있어서, 과망간산칼륨은 그래뉼형태의 묽은 질산에 가행지는 것을 특징으로 하는 공정.
- 전항중 어느한항에 있어서, 옥살산 용액은 사용시에 가열되는 것을 특징으로 하는 공정.
- 전항중 어느한항에 있어서, 옥살산용액의 농도는 회백색 금속 표면을 갖는 오염물질을 생성하기에 충분한 농도인 것을 특징으로 하는 공정.
- 전항중 어느한항에 있어서, 처리된 물질의 행굼은 탈광물수에 의해 수행되는 것을 특징으로 하는 공정.
- 전항중 어느한항에 있어서, 옥살산 과량으로 처리한후에도 오염도가 여전히 존재할경우 묽은 질산및 옥살산처리를 적어도 한번 더 반복하는 것을 특징으로 하는 공정.
- 제13항에 있어서, 상기의 처리를 반복하면 적어도 과망간산 칼륨의 농도가 증가하는 것을 특징으로 하는 공정.
- 전항중 어느한항에 있어서, 오염물질과 여러가지 용액과의 접촉은 침전에 의해 수행되는 것을 특징으로 하는 공정.
- 전항중 어느 한항에 있어서, 오염된 물질을 처리하여 얻어지는 잔여의 생성물을 얻어진혼합물과 중성(pH=7)이 되도록 혼합하는 것을 특징으로 하는 공정.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BE904139 | 1986-01-30 | ||
BE904,139 | 1986-01-30 | ||
BE8660917A BE904139A (nl) | 1986-01-30 | 1986-01-30 | Werkwijze voor de decontaminatie van radioaktief besmette materialen. |
BE904139 | 1986-01-30 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR870007528A true KR870007528A (ko) | 1987-08-19 |
KR900007747B1 KR900007747B1 (ko) | 1990-10-19 |
Family
ID=25661056
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019870000666A Expired KR900007747B1 (ko) | 1986-01-30 | 1987-01-28 | 방사능에 오염된 물질로부터 오염을 제거하는 공정 |
Country Status (11)
Country | Link |
---|---|
US (1) | US4690782A (ko) |
EP (1) | EP0242449B1 (ko) |
JP (1) | JPS62217200A (ko) |
KR (1) | KR900007747B1 (ko) |
CN (1) | CN87100443B (ko) |
AT (1) | ATE59113T1 (ko) |
BE (1) | BE904139A (ko) |
CA (1) | CA1270428A (ko) |
DE (1) | DE3676192D1 (ko) |
ES (1) | ES8707626A1 (ko) |
FI (1) | FI861434A7 (ko) |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ES2045298T3 (es) * | 1988-08-24 | 1994-01-16 | Siemens Ag | Procedimiento para la descontaminacion quimica de la superficie de un componente metalico de una instalacion de reactor nuclear. |
US5205999A (en) * | 1991-09-18 | 1993-04-27 | British Nuclear Fuels Plc | Actinide dissolution |
US5322644A (en) * | 1992-01-03 | 1994-06-21 | Bradtec-Us, Inc. | Process for decontamination of radioactive materials |
GB9222590D0 (en) * | 1992-10-27 | 1992-12-09 | British Nuclear Fuels Plc | The treatment of solid organic wastes |
FR2699936B1 (fr) * | 1992-12-24 | 1995-01-27 | Electricite De France | Procédé de dissolution d'oxydes déposés sur un substrat métallique. |
US5640703A (en) * | 1994-04-18 | 1997-06-17 | British Nuclear Fuels Plc | Treatment of solid wastes |
GB9426023D0 (en) * | 1994-12-22 | 1995-02-22 | Bradtec Ltd | Process for decontaminating radioactive materials |
RU2124768C1 (ru) * | 1996-03-19 | 1999-01-10 | Горно-химический комбинат | Способ дезактивации твердой фазы гетерогенных радиоактивных отходов |
GB9709882D0 (en) * | 1997-05-16 | 1997-07-09 | British Nuclear Fuels Plc | A method for cleaning radioactively contaminated material |
RU2152650C1 (ru) * | 1998-10-13 | 2000-07-10 | Московское государственное предприятие Объединенный эколого-технологический и научно-исследовательский центр по обезвреживанию РАО и охране окружающей среды "Радон" | Способ дезактивации грунтов от радионуклидов цезия |
JP3809577B2 (ja) * | 2001-04-03 | 2006-08-16 | 株式会社日立製作所 | 放射性物質除染方法及び放射性物質除染装置 |
RU2282508C1 (ru) * | 2005-05-30 | 2006-08-27 | Государственное образовательное учреждение высшего профессионального образования "Орловский государственный технический университет" (ОрелГТУ) | Способ очистки почвы от техногенных загрязнений |
EP2758966B1 (de) | 2011-09-20 | 2016-03-16 | Horst-Otto Bertholdt | Verfahren zum abbau einer oxidschicht |
CN102626605B (zh) * | 2012-04-13 | 2014-04-23 | 天津位一新材料科技有限公司 | 去除水中放射性元素的材料及制备和使用方法 |
DE102013102331B3 (de) | 2013-03-08 | 2014-07-03 | Horst-Otto Bertholdt | Verfahren zum Abbau einer Oxidschicht |
EP3494579B1 (de) | 2017-02-14 | 2020-08-26 | Siempelkamp Nis Ingenieurgesellschaft MBH | Verfahren zum abbau einer radionuklidhaltigen oxidschicht |
CN114684904A (zh) * | 2020-12-25 | 2022-07-01 | 中核四0四有限公司 | 一种通过提高酸度除去草酸的方法 |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1074357B (de) * | 1960-01-28 | Mctallgesellschaft Aktiengesellschaft, Frankfurt/M | Alkalisch reagierende, entfettende Reiniger für Metalle | |
DE1546163A1 (de) * | 1965-03-13 | 1970-04-16 | Metallgesellschaft Ag | Verfahren zur Entfernung von OElkohle und anderen organischen Verunreinigungen von Metalloberflaechen |
US3496017A (en) * | 1966-04-28 | 1970-02-17 | Atomic Energy Commission | Method and composition for decontamination of stainless steel surfaces |
US3615817A (en) * | 1969-02-04 | 1971-10-26 | Atomic Energy Commission | Method of decontaminating radioactive metal surfaces |
US3778309A (en) * | 1971-06-25 | 1973-12-11 | Int Nickel Co | Descaling process for alloys containing chromium |
DE2333516C3 (de) * | 1973-07-02 | 1979-05-03 | Kernforschungszentrum Karlsruhe Gmbh, 7500 Karlsruhe | Dekontaminationsmittel für metallische Oberflächen und Verfahren zum Dekontaminieren unter Verwendung derselben |
DE2613351C3 (de) * | 1976-03-29 | 1982-03-25 | Kraftwerk Union AG, 4330 Mülheim | Verfahren zur chemischen Dekontamination von metallischen Bauteilen von Kernreaktoranlagen |
US4145396A (en) * | 1976-05-03 | 1979-03-20 | Rockwell International Corporation | Treatment of organic waste |
US4226640A (en) * | 1978-10-26 | 1980-10-07 | Kraftwerk Union Aktiengesellschaft | Method for the chemical decontamination of nuclear reactor components |
EP0071336B1 (en) * | 1981-06-17 | 1986-03-26 | Central Electricity Generating Board | Process for the chemical dissolution of oxide deposits |
JPS5873777A (ja) * | 1981-10-26 | 1983-05-04 | Kawasaki Steel Corp | ステンレス鋼の酸洗方法 |
US4474541A (en) * | 1983-06-10 | 1984-10-02 | Tecumseh Products Company | Internal crankcase support for a radial compressor |
JPS6057299A (ja) * | 1983-09-09 | 1985-04-03 | 三菱重工業株式会社 | 汚染された金属材料の洗浄方法 |
-
1986
- 1986-01-30 BE BE8660917A patent/BE904139A/nl not_active IP Right Cessation
- 1986-03-28 AT AT86200529T patent/ATE59113T1/de not_active IP Right Cessation
- 1986-03-28 EP EP86200529A patent/EP0242449B1/en not_active Expired - Lifetime
- 1986-03-28 DE DE8686200529T patent/DE3676192D1/de not_active Expired - Fee Related
- 1986-04-01 CA CA000505541A patent/CA1270428A/en not_active Expired - Fee Related
- 1986-04-03 FI FI861434A patent/FI861434A7/fi not_active IP Right Cessation
- 1986-04-03 US US06/847,776 patent/US4690782A/en not_active Expired - Fee Related
- 1986-04-14 ES ES553963A patent/ES8707626A1/es not_active Expired
-
1987
- 1987-01-26 CN CN87100443A patent/CN87100443B/zh not_active Expired
- 1987-01-26 JP JP8715899A patent/JPS62217200A/ja active Pending
- 1987-01-28 KR KR1019870000666A patent/KR900007747B1/ko not_active Expired
Also Published As
Publication number | Publication date |
---|---|
CN87100443A (zh) | 1987-08-12 |
FI861434L (fi) | 1987-07-31 |
DE3676192D1 (de) | 1991-01-24 |
US4690782A (en) | 1987-09-01 |
JPS62217200A (ja) | 1987-09-24 |
ES8707626A1 (es) | 1987-08-01 |
ATE59113T1 (de) | 1990-12-15 |
CN87100443B (zh) | 1988-11-16 |
EP0242449B1 (en) | 1990-12-12 |
ES553963A0 (es) | 1987-08-01 |
CA1270428A (en) | 1990-06-19 |
FI861434A7 (fi) | 1987-07-31 |
EP0242449A1 (en) | 1987-10-28 |
KR900007747B1 (ko) | 1990-10-19 |
FI861434A0 (fi) | 1986-04-03 |
BE904139A (nl) | 1986-05-15 |
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