KR870007094A - 벤조일아세트 산 에스테르 유도체의 제조방법 - Google Patents
벤조일아세트 산 에스테르 유도체의 제조방법 Download PDFInfo
- Publication number
- KR870007094A KR870007094A KR870000410A KR870000410A KR870007094A KR 870007094 A KR870007094 A KR 870007094A KR 870000410 A KR870000410 A KR 870000410A KR 870000410 A KR870000410 A KR 870000410A KR 870007094 A KR870007094 A KR 870007094A
- Authority
- KR
- South Korea
- Prior art keywords
- acid ester
- ester derivative
- preparing
- benzoylacetic acid
- formula
- Prior art date
Links
- -1 benzoylacetic acid ester Chemical class 0.000 title claims 4
- 150000002148 esters Chemical class 0.000 claims 3
- 125000000217 alkyl group Chemical group 0.000 claims 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims 1
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 claims 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims 1
- 229910052801 chlorine Inorganic materials 0.000 claims 1
- 239000000460 chlorine Substances 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- 230000000911 decarboxylating effect Effects 0.000 claims 1
- 125000005843 halogen group Chemical group 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C61/00—Compounds having carboxyl groups bound to carbon atoms of rings other than six-membered aromatic rings
- C07C61/16—Unsaturated compounds
- C07C61/22—Unsaturated compounds having a carboxyl group bound to a six-membered ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
- C07C67/333—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
- C07C67/343—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
- C07C67/317—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups
- C07C67/32—Decarboxylation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/66—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety
- C07C69/73—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of unsaturated acids
- C07C69/738—Esters of keto-carboxylic acids or aldehydo-carboxylic acids
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Quinoline Compounds (AREA)
Abstract
Description
Claims (1)
- 하기 일반식(Ⅱ)의 화합물을 말론 산 에스테르와 축합시켜 하기 일반식(Ⅲ)의 벤조일말론 산 에스테르유도체를 수득하고 이 에스테르(Ⅲ)을 탈카복실화시켜 목적하는 화합물을 수득함을 특징으로 하여 하기 일반식(Ⅰ)의 벤조일아세트 산 에스테르 유도체를 제조하는 방법.상기식에서, R은 저급 알킬 그룹이고, X는 할로겐원자이며, Y는 염소 또는 브롬원자이고, R'는 독립적으로 저급 알킬 그룹이다.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP9649 | 1986-01-20 | ||
JP964986 | 1986-01-20 | ||
JP9649/86 | 1986-01-20 | ||
JP286524/86 | 1986-12-01 | ||
JP61286524A JPS62246541A (ja) | 1986-01-20 | 1986-12-01 | ベンゾイル酢酸エステル誘導体とその製造方法 |
JP286524 | 1986-12-01 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR870007094A true KR870007094A (ko) | 1987-08-14 |
KR950004041B1 KR950004041B1 (ko) | 1995-04-22 |
Family
ID=11726061
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019870000410A KR950004041B1 (ko) | 1986-01-20 | 1987-01-20 | 벤조일아세트산 에스테르 유도체의 제조방법 |
Country Status (2)
Country | Link |
---|---|
JP (1) | JPS62246541A (ko) |
KR (1) | KR950004041B1 (ko) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0342849A3 (en) * | 1988-05-19 | 1990-03-14 | Pfizer Inc. | Intermediates for preparing 1,4-dihydro-4-oxo-quinoline-3-carboxylic acid esters |
KR100372563B1 (ko) * | 1996-12-16 | 2003-11-20 | 주식회사 엘지생명과학 | 퀴놀론계항생제중간체인베타-케토에스테르유도체의제조방법 |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3142854A1 (de) * | 1981-10-29 | 1983-05-11 | Bayer Ag, 5090 Leverkusen | 1-cyclopropyl-6-fluor-1,4-dihydro-4-oxo-7-piperazino-chinolin-3-carbonsaeuren, verfahren zu ihrer herstellung sowie diese enthaltende antibakterielle mittel |
DE3308908A1 (de) * | 1983-03-12 | 1984-09-13 | Bayer Ag, 5090 Leverkusen | Bakterizide mittel |
US4533663A (en) * | 1984-04-26 | 1985-08-06 | Abbott Laboratories | Quino-benzothiazine antibacterial compounds |
DE3420743A1 (de) * | 1984-06-04 | 1985-12-05 | Bayer Ag, 5090 Leverkusen | 7-amino-1-cyclopropyl-6,8-dihalogen-1,4-dihydro-4-oxo-3-chinolincarbonsaeuren, verfahren zu ihrer herstellung sowie diese enthaltende antibakterielle mittel |
-
1986
- 1986-12-01 JP JP61286524A patent/JPS62246541A/ja active Pending
-
1987
- 1987-01-20 KR KR1019870000410A patent/KR950004041B1/ko not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
JPS62246541A (ja) | 1987-10-27 |
KR950004041B1 (ko) | 1995-04-22 |
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