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KR870006111A - 고분자 폴리부틸렌테레프탈레이트의 연속 제조방법 - Google Patents

고분자 폴리부틸렌테레프탈레이트의 연속 제조방법 Download PDF

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Publication number
KR870006111A
KR870006111A KR860010838A KR860010838A KR870006111A KR 870006111 A KR870006111 A KR 870006111A KR 860010838 A KR860010838 A KR 860010838A KR 860010838 A KR860010838 A KR 860010838A KR 870006111 A KR870006111 A KR 870006111A
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KR
South Korea
Prior art keywords
butanediol
terephthalic acid
esterification
catalyst
polybutylene terephthalate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
KR860010838A
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KR930006048B1 (ko
Inventor
하인체 헬뭇트
빌 헬므 후릿쯔
Original Assignee
크라우스 콤펠루, 한스 조첸 로테
데이비 맥키 악티엔 게젤샤프트
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Publication of KR870006111A publication Critical patent/KR870006111A/ko
Application granted granted Critical
Publication of KR930006048B1 publication Critical patent/KR930006048B1/ko
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/16—Dicarboxylic acids and dihydroxy compounds
    • C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyesters Or Polycarbonates (AREA)

Abstract

내용 없음

Description

고분자 폴리부틸렌테레프탈레이트의 연속 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
첨부도면은 본 발명의 공정 유통도임.
* 도면의 주요부분에 대한 부호의 설명
3 : 탱크, 7 …… 펌프, 8 …… 에스테르화 반응기, 11 …… 반응기, 14 …… 증축합반응기

Claims (7)

  1. 유기-주석 및/또는 유기-티탄 화합물 존재하에 테레프탈산과 1,4-부탄디올의 액상 에스테르화 반응후 얻어진 에스테르화 생성물의 중축합반응에 의한 고분자 폴리부틸렌테레프탈레이트의 연속적 제조방법에 있어서, 다음 단계를 포함하는 것을 특징으로 하는 고분자 폴리부틸렌테레프탈레이트의 제조방법 :
    a) 초기 공정 단계로서 상기 촉매를 함유하는 테레프탈산/1,4-부탄디올을 제1에스테르화반응기에 연속적으로 공급하는 단계 ;
    b) 225 내지 260℃ 및 10.1 내지 최고 1바아아의 절대압에서 제1단계동안 에스테르화를 실시하는 단계 ;
    c) 230 내지 260℃ 및 10 내지 200밀리바아의 압력에서 제2단계동안 제1단계로부터 생성된 에스테르화 생성물을 예비축합시키는 단계 ;
    d) 240 내지 265℃ 및 0.25 내지 25밀리바아의 압력에서 상기 예비축합물을 연속적으로 중축합시키는 단계 ;
    e) 상기 제1및 그 다음 단계에서 유기된 1,4-부탄디올을 응축시키는 단계 ;
    f) 상기 응축된 1,4-부탄디올로부터 물 및 테트라하이드로푸란을 제거하는 단계 및 ;
    g) 테레프탈산에 대해 새롭고 재순환된 1,4-부탄디올의 총몰비 2 내지 3.8에서 상기 제1에스트로화 반응기로 상기 1,4-부탄디올을 재순환시키는 단계.
  2. 제1항에 있어서, 제2단계동안, 1,4-부탄디올에 함유된 유기-주석 또는 유기-티탄 촉매의 용액이 테레프탈산에 대해 Ti 또는 Sn 0.002 내지 0.02중량%의 양으로 상기 에스테르화 생성물에 연속적으로 공급되는 것을 특징으로 하는 방법.
  3. 제1항에 있어서, 촉매가 테트라부틸-O-티타네이트인 것을 특징으로 하는 방법.
  4. 제1항에 있어서, 촉매가 알킬주석산 또는 그의 무수물인 것을 특징으로 하는 방법.
  5. 제1항에 있어서, 예비축합물의 온도를 중축합단계 d로 도입하기 전에 낮추는 것을 특징으로 하는 방법.
  6. 제1항에 있어서, 단계 c 및 d가 한반응기중에서 단일단계에서 동시에 실시되는 것을 특징으로 하는 방법.
  7. 제1항에 있어서, 단계 b의 온도 및 압력범위가 각각 235 내지 250℃ 및 0.3 내지 0.6바아이며, 단계 g의 몰비가 2.5 내지 3.5인 것을 특징으로 하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019860010838A 1985-12-17 1986-12-17 고분자 폴리 부틸렌테레프탈레이트의 연속 제조방법 Expired - Fee Related KR930006048B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE3544551A DE3544551C2 (de) 1985-12-17 1985-12-17 Verfahren zur kontinuierlichen Herstellung von hochmolekularem Polybutylenterephthalat
DE3544551.3 1985-12-17
DEP8544551.3 1985-12-17

Publications (2)

Publication Number Publication Date
KR870006111A true KR870006111A (ko) 1987-07-09
KR930006048B1 KR930006048B1 (ko) 1993-07-03

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019860010838A Expired - Fee Related KR930006048B1 (ko) 1985-12-17 1986-12-17 고분자 폴리 부틸렌테레프탈레이트의 연속 제조방법

Country Status (7)

Country Link
US (1) US4680376A (ko)
JP (1) JPH07100734B2 (ko)
KR (1) KR930006048B1 (ko)
DE (1) DE3544551C2 (ko)
FR (1) FR2591604B1 (ko)
GB (1) GB2184129B (ko)
NL (1) NL185518C (ko)

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Also Published As

Publication number Publication date
GB2184129A (en) 1987-06-17
FR2591604B1 (fr) 1992-07-31
GB2184129B (en) 1989-10-11
DE3544551A1 (de) 1987-06-19
NL8600567A (nl) 1987-07-16
GB8621598D0 (en) 1986-10-15
DE3544551C2 (de) 2002-02-28
FR2591604A1 (fr) 1987-06-19
JPH07100734B2 (ja) 1995-11-01
KR930006048B1 (ko) 1993-07-03
US4680376A (en) 1987-07-14
JPS62195017A (ja) 1987-08-27
NL185518C (nl) 1990-05-01
NL185518B (nl) 1989-12-01

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