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KR870001491A - Photosensitive microcapsules and ancillary sheets - Google Patents

Photosensitive microcapsules and ancillary sheets Download PDF

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Publication number
KR870001491A
KR870001491A KR1019860005755A KR860005755A KR870001491A KR 870001491 A KR870001491 A KR 870001491A KR 1019860005755 A KR1019860005755 A KR 1019860005755A KR 860005755 A KR860005755 A KR 860005755A KR 870001491 A KR870001491 A KR 870001491A
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photosensitive microcapsule
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photosensitive
absorbent
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KR910008705B1 (en
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디. 데이비스 파울
에프. 힐렌브랜드. 게리
에프. 힐렌브랜드 개리
시. 아데어 파울
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더 메드 코포레이션
로레인 제이. 프랜시스
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    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03CPHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C1/00Photosensitive materials
    • G03C1/52Compositions containing diazo compounds as photosensitive substances
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/002Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor using materials containing microcapsules; Preparing or processing such materials, e.g. by pressure; Devices or apparatus specially designed therefor
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03CPHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C1/00Photosensitive materials
    • G03C1/72Photosensitive compositions not covered by the groups G03C1/005 - G03C1/705

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Materials For Photolithography (AREA)
  • Non-Silver Salt Photosensitive Materials And Non-Silver Salt Photography (AREA)
  • Photosensitive Polymer And Photoresist Processing (AREA)
  • Manufacturing Of Micro-Capsules (AREA)

Abstract

내용 없음.No content.

Description

감광성 미소캅셀 및 조상용 시트Photosensitive microcapsules and ancillary sheets

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is a trivial issue, I did not include the contents of the text.

Claims (30)

유리기 부가중합성 물질 및 흡수제, 고개시제 및 자동산화제를 지니는 광개시제 계로 이루어진 감광성 조성물을 분산상으로서 함유하며, 전술한 흡수제, 공개시제 및 자동산화제가 상이하며, 공개시제는 흡수제와 상호작용하여 유리기를 생성시킬 경우 자동산화제보다 더욱 효율적인 화합물이고, 자동산화제는 산소똔는 산소기와 상호작용하여 유리기를 생성시키는데 있어서 공개시제보다 더욱 효율적인 감광성 미소캅셀.A free radical additive and a photoinitiator system having an absorbent, a spreading agent and an autooxidant as dispersed phases, wherein the absorbent, the disclosed agent and the autoxidizing agent described above are different, and the disclosed agent interacts with the absorbent to generate a free radical Is a more efficient compound than an autoxidant, and an autoxidant is a more efficient photosensitive microcapsule than the open-label in generating free radicals by interacting with oxygen-deficient oxygen groups. 제1항에 있어서, 미소캅셀이 별개의 캅셀벽을 갖는 감광성 미소캅셀.The photosensitive microcapsule of claim 1, wherein the microcapsules have a separate capsule wall. 제2항에 있어서, 유리기 부가중합서어 물질이 에틸렌성 불포화 화합물인 감광성 미소캅셀.The photosensitive microcapsule according to claim 2, wherein the free radical portion is an ethylenically unsaturated compound. 제3항에 있어서,흡수제가 아릴케톤인 감광성 미소캅셀.The photosensitive microcapsule of claim 3, wherein the absorbent is an aryl ketone. 제4항에 있어서, 하나이상의 공개시제 및 자동산화제가 일반식(I)의 N,N-디알킬아닐린인 감광성 미소캅셀.5. The photosensitive microcapsule of claim 4, wherein the at least one open time agent and autoxidizer is N, N-dialkyl aniline of general formula (I). 상기식에서 R1및 R2는 동일 또는 상이하며, 탄소수 1내지 6의 알킬그룹 또는 벤질그룹을 나타내고 X는 -0.9 내지 0.7 범위의 하메트 상수를 갖는 치환체를 나타낸다.Wherein R 1 and R 2 are the same or different and each represents an alkyl group having 1 to 6 carbon atoms or a benzyl group and X represents a substituent having a Hammett constant in the range of -0.9 to 0.7. 제5항에 있어서, X가 수소원자, 시아노그룹, 할로겐원자, 알킬그룹, 아실그룹, 알콕시그룹, 아미노그룹, 디알킬아미노그룹, 아실아미노그룹 및 알키설피도그룹으로 이루어진 그룹중에서 선택되는 감광성 미소캅셀.The photosensitive resin composition according to claim 5, wherein X is selected from the group consisting of a hydrogen atom, a cyano group, a halogen atom, an alkyl group, an acyl group, an alkoxy group, an amino group, a dialkylamino group, an acylamino group, Micro capsule. 제6항에 있어서, 치환체가 -0.5내지 0.5범위의 하메트 σ 상수를 갖는 감광성 미소캅셀.7. The photosensitive microcapsule of claim 6, wherein the substituent has a Hammett? Constant in the range of -0.5 to 0.5. 제7항에 있어서, R1및 R2가 메틸 또는 에틸인 감광성 미소캅셀.A photosensitive microcapsule according to claim 7, wherein R 1 and R 2 are methyl or ethyl. 제6항에 있어서, X가 -0.2 내지 0.5의 하메트 상수 값을 갖는 감광성 미소캅셀.7. A photosensitive microcapsule according to claim 6, wherein X has a Hammett constant value of -0.2 to 0.5. 제9항에 있어서, 아릴케톤이 약 380㎜ 이상의 λmax를 갖는 감광성 미소캅셀.The photosensitive microcapsule of claim 9, wherein the aryl ketone has a? Max of at least about 380 mm. 유리기 부가중합성 물질 : 흡수제, 공개시제 및 자동산화제를 함유하는 광개시제계 : 및 상-형성제를 그의 분산상으로서 함유한느 감광성 미소캅셀 함유층을 그의 표면상에 갖는 지지물로 이루어지며, 전술한 흡수제, 공개시제 및 자동산화제는 상이하고, 공개시제는 흡수제와 상호작용하여 유리기를 생성시키는데 있어서 자동산화제보다 더욱 효율적인 화합물이며, 자동산화제는 산소 또는 산소기와 상호작용하여 유리기를 생성시키는데 있어서 공개시제보다 더욱 효율적인 조상용 시트.A free radical initiator and an autooxidant; and a support having on its surface a photosensitive microcapsule-containing layer containing a phase-former as its dispersed phase, wherein the absorbent, The open tensing agent and the autoxidizing agent are different and the open-labeling agent is a more efficient compound than the autooxidant in interacting with the absorbent to generate the free radicals, and the autoxidizer is a more efficient compound for interacting with oxygen or oxygen radicals to produce free radicals An ancestral sheet. 제11항에 있어서, 미소캅셀이 별개의 캅셀벽을 갖는 조상용 시트.12. An ancestral sheet according to claim 11, wherein the microcapsules have distinct capsule walls. 제12항에 있어서, 유리기부가중합성 물질이 에틸렌성 불포화 화합물인 조사용 시트.13. The conditioned sheet of claim 12, wherein the free base partly weighted material is an ethylenically unsaturated compound. 제13항에 있어서, 흡수제가 아릴케톤인 조상용 시트.14. The ancolenic sheet according to claim 13, wherein the absorbent is an aryl ketone. 제14항에 있어서, 하나이상의 공개시제 및 자동산화제가 일반식(I)로 표시되는 조상용 시트.15. The ancestral sheet according to claim 14, wherein the at least one open time agent and the autooxidant are represented by the general formula (I). 상기식에서 R1및 R2는 동일 또는 상이하며 탄소수 1 내지 6의 알킬그룹 또는 벤질그룹을 나타내며, X는 -0.9 내지 0.7 범위의 하메트 σ 상수를 갖는 치환체를 나타낸다.Wherein R 1 and R 2 are the same or different and each represents an alkyl group or a benzyl group having 1 to 6 carbon atoms and X represents a substituent having a Hammett constant of -0.9 to 0.7. 제15항에 있어서 X가 수소원자, 시아노그룹, 할로겐원자, 알킬그룹, 아실그룹, 알콕시그룹, 아미노그룹, 디알킬아미노그룹, 아실아미도그룹 및 알킬설파이드그룹으로 이루어진 그룹중에서 선택되는 조상용 시트.16. The anionic herzicin according to claim 15, wherein X is a group selected from the group consisting of hydrogen atom, cyano group, halogen atom, alkyl group, acyl group, alkoxy group, amino group, dialkylamino group, acylamido group and alkyl sulfide group . 제16항에 있어서, R1및 R2가 메틸 또는 에틸인 조상용 시트.Of claim 16 wherein, the R 1 and R 2 is methyl or ethyl josangyong sheet on. 제15항에 있어서, X가 -0.2 내지 0.5의 하메트 상수를 갖는 치환체인 조상용 시트.16. The ancols according to claim 15, wherein X is a substituent having a Hammett constant of -0.2 to 0.5. 제13항에 있어서, 아릴케톤이 약 380㎜ 이상의 λmax를 갖는 조상용 시트.14. An ancestral sheet according to claim 13, wherein the aryl ketone has a [lambda] max of at least about 380 mm. 제18항에 있어서, 상형성제가 거의 무색의 전자공여 화합물인 조상용 시트.The ancolenic sheet according to claim 18, wherein the image forming agent is an almost colorless electron donor compound. 제1항에 있어서, 분산상이 거의 무색의 전자공여용 화합물을 추가로 함유하는 감광성 미소캅셀.The photosensitive microcapsule according to claim 1, wherein the dispersed phase further contains an electron-donating compound which is substantially colorless. 제4항에 있어서, 자동산화제가 티올인 감광성 미소캅셀.5. The photosensitive microcapsule of claim 4, wherein the autoxidizer is thiol. 제22항에 있어서, 티올이 2-머캅토벤조티아졸, 6-에톡시-2-머캅토벤조티아졸, 2-머캅토벤조티아졸, 4-메틸-4H-1,2,4-트리아졸-3티올, 2-머캅토-1-메틸이미다졸, 2-머캅토-5-메틸티오-1,3,4-티아디아졸, 5-n-부틸티오-2-머캅토-1,3,4-티아디아졸, 4-메톡시벤젠티올, 1-페닐-1H-테트라졸-5-티올, 4-페닐-4H-1,2,4-테트라졸-3-티올, 2-머캅토벤조티아졸, 펜타에리트리톨 테트라키스(머캅토벤조티아졸). 펜타에리트리톨 테트라키스(3-머캅토프로피오네이트트), 트리메틸올프로판트리스(머캅토아세테이트), 트리메틸오로 프로판 트리스(3-머캅토프로피오네이트), 4-아세트아미도티오페놀, 머캅토석신산, 도데칸티올, 2-머캅토피리딘, 4-머캅토피리딘, 2-머캅토-3H-퀴나졸린 및 2-머캅토티아졸린 으로 이루어진 그룹중에서 선택되는 감광성 미소캅셀.The method of claim 22, wherein the thiol is selected from the group consisting of 2-mercaptobenzothiazole, 6-ethoxy-2-mercaptobenzothiazole, 2- mercaptobenzothiazole, Mercapto-1-methylimidazole, 2-mercapto-5-methylthio-1,3,4-thiadiazole, 5-n-butylthio-2-mercapto- 4-methoxybenzenethiol, 1-phenyl-1H-tetrazole-5-thiol, 4-phenyl- Mercaptobenzothiazole, pentaerythritol tetrakis (mercaptobenzothiazole). (3-mercaptopropionate), trimethylolpropane tris (mercaptoacetate), trimethylolpropane tris (3-mercaptopropionate), 4-acetamidothiophenol, mercaptosilicate A photosensitive microcapsule selected from the group consisting of acetic acid, dodecanethiol, 2-mercaptopyridine, 4-mercaptopyridine, 2-mercapto-3H-quinazoline and 2-mercaptothiazoline. 제4항에 있어서, 자동산화제가 포스핀인 감광성 미소캅셀.5. The photosensitive microcapsule of claim 4, wherein the autoxidizer is a phosphine. 제24항에 있어서, 포스핀이 트리페닐포스핀, 트리에틸포스파이트, 트리에틸포스핀, 트리이소프로필포스파이드 및 트리페닐 포스파이드로 이루어진 그룹중에서 선택되는 감광성 미소캅셀.25. The photosensitive microcapsule of claim 24, wherein the phosphine is selected from the group consisting of triphenylphosphine, triethylphosphite, triethylphosphine, triisopropylphosphide and triphenylphosphide. 제4항에 있어서, 아릴케톤이 벤조페논, 4,4´-디메톡시벤조페논, 4,4´-디크로로벤조페논, 4,4´-비스(디메틸아미노)벤조페논, 벤즈안톤, 9-플루오레논, 크산톤, 2-메틸크산톤, 2-도데실크산톤, 티오크산톤, 2-메틸티오크산톤, 2-도데실티오크산톤, 2-클로로티오크산톤, 2-이소프로필티오크산톤 및 3-신나모일-7-디에틸아미노 쿠마린으로 이루엊니 그룹중에서 선택되는 감광성 미소캅셀.5. The composition of claim 4 wherein the aryl ketone is selected from the group consisting of benzophenone, 4,4'-dimethoxybenzophenone, 4,4'-dichlorobenzophenone, 4,4'-bis (dimethylamino) benzophenone, 2-methylthioxanthone, 2-methylthioxanthone, 2-methylthioxanthone, 2-dodecylthioxanthone, 2-chlorothioxanthone, 2-isopropylthioxanthone, 0.0 > 3-cinnamoyl-7-diethylaminocoumarin. ≪ / RTI > 제26항에 있어서, 공개시제가 에틸 P-디메틸아미노벤조에이트인 감광성 미소캅셀.27. The photosensitive microcapsule of claim 26, wherein the release agent is ethyl P-dimethylaminobenzoate. 제26항에 있어서, 자동산화제가 N,N,2,4,6-펜타메틸아닐린인 감광성 미소캅셀.27. The photosensitive microcapsule of claim 26, wherein the autoxidizer is N, N, 2,4,6-pentamethylaniline. 제26항에 있어서, 자동산화제가 2.6-디에틸-N,N-디에틸아닐린 또는 2.6-디이소프로필-N,N-디에틸아닐린인 감광성 미소 캅셀.27. The photosensitive microcapsule of claim 26, wherein the autoxidizer is 2.6-diethyl-N, N-diethylaniline or 2.6-diisopropyl-N, N-diethylaniline. 제26항에 있어서, 공개시제가 2-머캅토벤즈옥사졸, 6-에톡시-2-머캅토벤조티아졸, 또는 페닐머캅토테트라졸인 감광성 미소캅셀.27. The photosensitive microcapsule of claim 26, wherein the release agent is 2-mercaptobenzoxazole, 6-ethoxy-2-mercaptobenzothiazole, or phenylmercaptotetrazole. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: It is disclosed by the contents of the first application.
KR1019860005755A 1985-07-16 1986-07-16 Photosensitive Microcapsules and Contrast Sheets Expired KR910008705B1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US75540085A 1985-07-16 1985-07-16
US755400 1985-07-16
US755,400 1991-09-05

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KR870001491A true KR870001491A (en) 1987-03-14
KR910008705B1 KR910008705B1 (en) 1991-10-19

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KR (1) KR910008705B1 (en)
CN (1) CN86104557A (en)
DE (1) DE3623522A1 (en)
FR (1) FR2584982A1 (en)
GB (1) GB2180358B (en)

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US4874685A (en) * 1987-11-27 1989-10-17 The Mead Corporation Photocurable composition containing a photoreducible dye a thiol and an N,N'-dialkylaniline
US4954415A (en) * 1989-03-09 1990-09-04 The Mead Corporation Photoinitiator compositions containing O-acylthiohydroxamate or an N-alkoxypyridinethione and photohardenable compositions containing the same
CA2015894A1 (en) * 1989-05-30 1990-11-30 Mohammad Z. Ali High sensitivity photopolymerizable compositions containing hydrogen donating mercaptans
KR910012820A (en) * 1989-12-20 1991-08-08 로레인 제이. 프란시스 Free radically polymerizable composition containing a sulfated agent blend
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GB2180358B (en) 1989-10-04
CN86104557A (en) 1987-04-22
JPS6218537A (en) 1987-01-27
KR910008705B1 (en) 1991-10-19
GB2180358A (en) 1987-03-25
DE3623522A1 (en) 1987-01-29
GB8616853D0 (en) 1986-08-20
FR2584982A1 (en) 1987-01-23

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