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KR860008265A - 표백 조성물 및 그 제조방법 - Google Patents

표백 조성물 및 그 제조방법 Download PDF

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Publication number
KR860008265A
KR860008265A KR1019860002451A KR860002451A KR860008265A KR 860008265 A KR860008265 A KR 860008265A KR 1019860002451 A KR1019860002451 A KR 1019860002451A KR 860002451 A KR860002451 A KR 860002451A KR 860008265 A KR860008265 A KR 860008265A
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South Korea
Prior art keywords
support material
bleaching
manganese
composition
peroxy compound
Prior art date
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KR1019860002451A
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English (en)
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KR900000883B1 (ko
Inventor
시리키트 남네드 제임스
Original Assignee
유니레버 엔.브이
에이취. 드 로이
유니레버 엔 브이
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Publication of KR860008265A publication Critical patent/KR860008265A/ko
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39Organic or inorganic per-compounds
    • C11D3/3902Organic or inorganic per-compounds combined with specific additives
    • C11D3/3905Bleach activators or bleach catalysts
    • C11D3/3935Bleach activators or bleach catalysts granulated, coated or protected
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39Organic or inorganic per-compounds
    • C11D3/3902Organic or inorganic per-compounds combined with specific additives
    • C11D3/3905Bleach activators or bleach catalysts
    • C11D3/3932Inorganic compounds or complexes

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  • Chemical & Material Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Catalysts (AREA)
  • Jellies, Jams, And Syrups (AREA)
  • Polysaccharides And Polysaccharide Derivatives (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

내용 없음

Description

표백 조성물 및 그 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (19)

  1. (a) 페록시화합물
    (b) 마그네슘이나 아연중에서 선택한 2가금속 양이온을 흡수한 알루미노 실리케이트 지지물질 및 수용성망간(Ⅱ)염으로 구성된 표백촉매 : 등으로 구성되며, 망간(Ⅱ)대 2가 금속 양이온의 중량비는 약 1 : 20 내지 20 : 1이며, 2가 금속양이온 대 알루미노 실리케이트 지지물질의 비는 약 1 : 1,000 내지 1 : 10의 범위이며, 촉매 대 페록시 화합물의 중량비는 약 1 : 100 내지 1 : 1 인 것을 특징으로 하는 표백조성물.
  2. 청구범위 1에 있어서, 알루미노 실리케이트 지지물질은 제올라이트인 것을 특징으로 하는 표백조성물.
  3. 청구범위 1 또는 2에 있어서, 알루미노 실리케이트 지지물질은 그 미세공동공 규격이 3 내지 10옹스트롬으로 되는 것을 특징으로 하는 표백 조성물.
  4. 청구범위 1에 있어서, 알루미노 실리게이트 지지물질은 실리코알루미노인산염인 것을 특징으로 하는 표백조성물.
  5. 청구범위 1 내지 4에 있어서, 페록시 화합물은 과붕산 나트륨인 것을 특징으로 하는 표백조성물.
  6. 청구범위 1에 있어서, 무기인산염 안정제를 조성물 총량의 약 5내지 35중량%로 첨가된 것으로 구성되는 것을 특징으로 하는 표백조성물.
  7. 청구범위 6에 있어서, 인산염 안정제는 트리폴리포스페이트, 오르토포스페이트, 파이로포스페이트, 및 그 혼합물 족으로부터 선정되는 것을 특징으로 하는 표백조성물.
  8. 청구범위 1에 있어서, 계면활성제, 빌더, 직물 연화제, 엔짐, 무기성충진제, 착색제, 포말촉진제 및 그 혼합물로 구성된 족으로부터 선택된 세제부가물을 함유하는 것을 특징으로 하는 표백조성물.
  9. (a) 망간(Ⅱ) 및 마그네슘 또는 아연중에서 선택한 2가 금속양이온의 수용성 염을 솔벤트에 용해시키고, 그 속에 알루미노실리케이트 지지물질을 현탁시켜 슬러리를 형성시키며, 2가 금속 양이온 대 알루미노 실리케이트 중량비는 1 : 1,000 내지 1 : 10의 범위로 하며, 망간 (Ⅱ)대 2가 금속 양이온의 중양비는 약 1 : 20 내지 20 : 1로 하며,
    (b) pH의 값을 7.0 내지 11.1이 되게 하며,
    (c) 2가 금속염 및 알루미노실리케이트 지지물질의 슬러리 혼합물을 교반시키며,
    (d) 슬러리에서 고체물질을 분리해내고, 이 고체 조성물을 솔벤트로 세척하여 유리 망간(Ⅱ)염의 존재를 제 거하며, 그리고
    (e) 이 고체조성물을 건조시켜 솔벤트 및 습기를 제거하는 등의 과정으로 구성되는 페록시 화합물의 대조시험된 조성물을 만드는 촉매의 제조방법.
  10. 청구범위 9에 있어서, 알루미노실리케이트의 지지물은 제올라이트인 것을 특징으로 하는 페록시화합물 촉매의 제조방법.
  11. 청구범위 9 또는 10에 있어서 알루미노실리케이트 지지물질은 약 3내지 10옹스트롬의 미세동공규격을 구비하는 것을 특징으로 하는 페록시화합물 촉매의 제조방법.
  12. 청구범위 9에 있어서 알루미노 실리케이트 지지물질은 실리코 알루미노 인산염인 것을 특징으로 하는 페록시 화합물 촉매의 제조방법.
  13. 청구범위 9에 있어서, 페록시 화합물은 과붕산 나트륨인 것을 특징으로 하는 페록시 화합물 촉매의 제조방법.
  14. 청구범위 9에 있어서, 솔벤트는 물로 이루어지는 것을 특징으로 하는 페록시 화합물 촉매의 제조방법.
  15. (a) 세탁용액매 리터당 최소한 30mg의 활성산소를 공급할 수 있을 정도로 함유된 페록시화합물과 : (b) 세탁용액 매 리터당 최소한 0.5ppm의 망간(Ⅱ)양이온을 공급할 수 있으며 알루미노 실리케이트지지 물질을 포함하며 그 속에 수용성 망간(Ⅱ)염, 및 마그네슘이나 아연중에서 선택한 2가 양이온 염을 흡수한 상태인 표백촉매로 구성되며 : 망간(Ⅱ)대 2가 금속양이온의 중량비는 약 1 : 20 내지 20 : 1,2가 금속 양이온 대 알루미노실리케이트 지지물질의 비는 약 1 : 1,000 내지 1 : 10이 되는, 조성물로서 기질을 처리하며, 그 기질을 금속에 담그는 과정으로 구성된 기질 표백방법.
  16. 청구범위 15에 있어서, 세탁수 매 리터당 약 0.05 내지 0.30그램의 양으로 함유된 무기 인산염안정제로 구성된 기질 표백방법.
  17. 청구범위 16에 있어서, 또한 인산염은 트리폴리 포스페이트, 오르토포스페이트, 과이로포스페이트 및 그 혼합물로 구성된 족으로부터 선택되는 것을 특징으로 하는 기질표백방법.
  18. 청구범위 15에 있어서, 페록시 화합물은 과붕산 나트리움염으로 된 것을 특징으로 하는 기질표백방법.
  19. 청구범위 17에 있어서, 본 조성물은 또한 계면환성제, 빌더직물연화제, 엔짐, 무기성충진제, 착색제 포말촉진제 및 그 혼합물로 구성된 족으로부터 선택되는 세제부가물을 함유하는 것을 특징으로 하는 기질표백방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019860002451A 1985-04-02 1986-04-01 표백조성물 및 그 제조방법 KR900000883B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US06/719,095 US4601845A (en) 1985-04-02 1985-04-02 Bleaching compositions containing mixed metal cations adsorbed onto aluminosilicate support materials
US719,095 1985-04-02
US719095 1985-04-02

Publications (2)

Publication Number Publication Date
KR860008265A true KR860008265A (ko) 1986-11-14
KR900000883B1 KR900000883B1 (ko) 1990-02-17

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US (1) US4601845A (ko)
EP (1) EP0201113B1 (ko)
JP (1) JPS61268799A (ko)
KR (1) KR900000883B1 (ko)
AT (1) ATE38529T1 (ko)
AU (1) AU566700B2 (ko)
BR (1) BR8601433A (ko)
CA (1) CA1241156A (ko)
DE (1) DE3661140D1 (ko)
ES (1) ES8706478A1 (ko)
TR (1) TR22929A (ko)
ZA (1) ZA862419B (ko)

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Also Published As

Publication number Publication date
JPH0434594B2 (ko) 1992-06-08
ES8706478A1 (es) 1987-06-16
EP0201113B1 (en) 1988-11-09
DE3661140D1 (en) 1988-12-15
BR8601433A (pt) 1986-12-09
AU566700B2 (en) 1987-10-29
EP0201113A1 (en) 1986-11-12
TR22929A (tr) 1988-11-28
ATE38529T1 (de) 1988-11-15
JPS61268799A (ja) 1986-11-28
KR900000883B1 (ko) 1990-02-17
ES553587A0 (es) 1987-06-16
US4601845A (en) 1986-07-22
AU5550986A (en) 1986-10-09
CA1241156A (en) 1988-08-30
ZA862419B (en) 1987-12-30

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