KR860008265A - 표백 조성물 및 그 제조방법 - Google Patents
표백 조성물 및 그 제조방법 Download PDFInfo
- Publication number
- KR860008265A KR860008265A KR1019860002451A KR860002451A KR860008265A KR 860008265 A KR860008265 A KR 860008265A KR 1019860002451 A KR1019860002451 A KR 1019860002451A KR 860002451 A KR860002451 A KR 860002451A KR 860008265 A KR860008265 A KR 860008265A
- Authority
- KR
- South Korea
- Prior art keywords
- support material
- bleaching
- manganese
- composition
- peroxy compound
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims 18
- 238000004061 bleaching Methods 0.000 title claims 12
- 238000004519 manufacturing process Methods 0.000 title claims 3
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims 15
- -1 peroxy compound Chemical class 0.000 claims 15
- 229910000323 aluminium silicate Inorganic materials 0.000 claims 13
- 239000000463 material Substances 0.000 claims 11
- 238000000034 method Methods 0.000 claims 11
- 229910052751 metal Inorganic materials 0.000 claims 9
- 239000002184 metal Substances 0.000 claims 9
- 150000001768 cations Chemical class 0.000 claims 8
- WAEMQWOKJMHJLA-UHFFFAOYSA-N Manganese(2+) Chemical class [Mn+2] WAEMQWOKJMHJLA-UHFFFAOYSA-N 0.000 claims 7
- 239000003054 catalyst Substances 0.000 claims 7
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims 4
- 239000002904 solvent Substances 0.000 claims 4
- 239000000758 substrate Substances 0.000 claims 4
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 3
- 229910052749 magnesium Inorganic materials 0.000 claims 3
- 239000011777 magnesium Substances 0.000 claims 3
- 239000002002 slurry Substances 0.000 claims 3
- 239000003381 stabilizer Substances 0.000 claims 3
- 238000005406 washing Methods 0.000 claims 3
- 239000011701 zinc Substances 0.000 claims 3
- 229910052725 zinc Inorganic materials 0.000 claims 3
- 229910019142 PO4 Inorganic materials 0.000 claims 2
- 229910021536 Zeolite Inorganic materials 0.000 claims 2
- 239000007844 bleaching agent Substances 0.000 claims 2
- 239000003086 colorant Substances 0.000 claims 2
- 239000003599 detergent Substances 0.000 claims 2
- 239000002979 fabric softener Substances 0.000 claims 2
- 239000006260 foam Substances 0.000 claims 2
- 239000011256 inorganic filler Substances 0.000 claims 2
- 229910003475 inorganic filler Inorganic materials 0.000 claims 2
- 229910052816 inorganic phosphate Inorganic materials 0.000 claims 2
- 239000010452 phosphate Substances 0.000 claims 2
- 150000003839 salts Chemical class 0.000 claims 2
- 229960001922 sodium perborate Drugs 0.000 claims 2
- 235000019832 sodium triphosphate Nutrition 0.000 claims 2
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 claims 2
- 239000008247 solid mixture Substances 0.000 claims 2
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical group [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 claims 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 2
- 239000010457 zeolite Substances 0.000 claims 2
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 125000004122 cyclic group Chemical group 0.000 claims 1
- XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical compound [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 claims 1
- 235000011180 diphosphates Nutrition 0.000 claims 1
- 238000001035 drying Methods 0.000 claims 1
- 125000000864 peroxy group Chemical group O(O*)* 0.000 claims 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 claims 1
- 239000011148 porous material Substances 0.000 claims 1
- 239000007787 solid Substances 0.000 claims 1
- 238000003756 stirring Methods 0.000 claims 1
- 239000004094 surface-active agent Substances 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3935—Bleach activators or bleach catalysts granulated, coated or protected
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3932—Inorganic compounds or complexes
Landscapes
- Chemical & Material Sciences (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
- Catalysts (AREA)
- Jellies, Jams, And Syrups (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Description
Claims (19)
- (a) 페록시화합물(b) 마그네슘이나 아연중에서 선택한 2가금속 양이온을 흡수한 알루미노 실리케이트 지지물질 및 수용성망간(Ⅱ)염으로 구성된 표백촉매 : 등으로 구성되며, 망간(Ⅱ)대 2가 금속 양이온의 중량비는 약 1 : 20 내지 20 : 1이며, 2가 금속양이온 대 알루미노 실리케이트 지지물질의 비는 약 1 : 1,000 내지 1 : 10의 범위이며, 촉매 대 페록시 화합물의 중량비는 약 1 : 100 내지 1 : 1 인 것을 특징으로 하는 표백조성물.
- 청구범위 1에 있어서, 알루미노 실리케이트 지지물질은 제올라이트인 것을 특징으로 하는 표백조성물.
- 청구범위 1 또는 2에 있어서, 알루미노 실리케이트 지지물질은 그 미세공동공 규격이 3 내지 10옹스트롬으로 되는 것을 특징으로 하는 표백 조성물.
- 청구범위 1에 있어서, 알루미노 실리게이트 지지물질은 실리코알루미노인산염인 것을 특징으로 하는 표백조성물.
- 청구범위 1 내지 4에 있어서, 페록시 화합물은 과붕산 나트륨인 것을 특징으로 하는 표백조성물.
- 청구범위 1에 있어서, 무기인산염 안정제를 조성물 총량의 약 5내지 35중량%로 첨가된 것으로 구성되는 것을 특징으로 하는 표백조성물.
- 청구범위 6에 있어서, 인산염 안정제는 트리폴리포스페이트, 오르토포스페이트, 파이로포스페이트, 및 그 혼합물 족으로부터 선정되는 것을 특징으로 하는 표백조성물.
- 청구범위 1에 있어서, 계면활성제, 빌더, 직물 연화제, 엔짐, 무기성충진제, 착색제, 포말촉진제 및 그 혼합물로 구성된 족으로부터 선택된 세제부가물을 함유하는 것을 특징으로 하는 표백조성물.
- (a) 망간(Ⅱ) 및 마그네슘 또는 아연중에서 선택한 2가 금속양이온의 수용성 염을 솔벤트에 용해시키고, 그 속에 알루미노실리케이트 지지물질을 현탁시켜 슬러리를 형성시키며, 2가 금속 양이온 대 알루미노 실리케이트 중량비는 1 : 1,000 내지 1 : 10의 범위로 하며, 망간 (Ⅱ)대 2가 금속 양이온의 중양비는 약 1 : 20 내지 20 : 1로 하며,(b) pH의 값을 7.0 내지 11.1이 되게 하며,(c) 2가 금속염 및 알루미노실리케이트 지지물질의 슬러리 혼합물을 교반시키며,(d) 슬러리에서 고체물질을 분리해내고, 이 고체 조성물을 솔벤트로 세척하여 유리 망간(Ⅱ)염의 존재를 제 거하며, 그리고(e) 이 고체조성물을 건조시켜 솔벤트 및 습기를 제거하는 등의 과정으로 구성되는 페록시 화합물의 대조시험된 조성물을 만드는 촉매의 제조방법.
- 청구범위 9에 있어서, 알루미노실리케이트의 지지물은 제올라이트인 것을 특징으로 하는 페록시화합물 촉매의 제조방법.
- 청구범위 9 또는 10에 있어서 알루미노실리케이트 지지물질은 약 3내지 10옹스트롬의 미세동공규격을 구비하는 것을 특징으로 하는 페록시화합물 촉매의 제조방법.
- 청구범위 9에 있어서 알루미노 실리케이트 지지물질은 실리코 알루미노 인산염인 것을 특징으로 하는 페록시 화합물 촉매의 제조방법.
- 청구범위 9에 있어서, 페록시 화합물은 과붕산 나트륨인 것을 특징으로 하는 페록시 화합물 촉매의 제조방법.
- 청구범위 9에 있어서, 솔벤트는 물로 이루어지는 것을 특징으로 하는 페록시 화합물 촉매의 제조방법.
- (a) 세탁용액매 리터당 최소한 30mg의 활성산소를 공급할 수 있을 정도로 함유된 페록시화합물과 : (b) 세탁용액 매 리터당 최소한 0.5ppm의 망간(Ⅱ)양이온을 공급할 수 있으며 알루미노 실리케이트지지 물질을 포함하며 그 속에 수용성 망간(Ⅱ)염, 및 마그네슘이나 아연중에서 선택한 2가 양이온 염을 흡수한 상태인 표백촉매로 구성되며 : 망간(Ⅱ)대 2가 금속양이온의 중량비는 약 1 : 20 내지 20 : 1,2가 금속 양이온 대 알루미노실리케이트 지지물질의 비는 약 1 : 1,000 내지 1 : 10이 되는, 조성물로서 기질을 처리하며, 그 기질을 금속에 담그는 과정으로 구성된 기질 표백방법.
- 청구범위 15에 있어서, 세탁수 매 리터당 약 0.05 내지 0.30그램의 양으로 함유된 무기 인산염안정제로 구성된 기질 표백방법.
- 청구범위 16에 있어서, 또한 인산염은 트리폴리 포스페이트, 오르토포스페이트, 과이로포스페이트 및 그 혼합물로 구성된 족으로부터 선택되는 것을 특징으로 하는 기질표백방법.
- 청구범위 15에 있어서, 페록시 화합물은 과붕산 나트리움염으로 된 것을 특징으로 하는 기질표백방법.
- 청구범위 17에 있어서, 본 조성물은 또한 계면환성제, 빌더직물연화제, 엔짐, 무기성충진제, 착색제 포말촉진제 및 그 혼합물로 구성된 족으로부터 선택되는 세제부가물을 함유하는 것을 특징으로 하는 기질표백방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US06/719,095 US4601845A (en) | 1985-04-02 | 1985-04-02 | Bleaching compositions containing mixed metal cations adsorbed onto aluminosilicate support materials |
US719,095 | 1985-04-02 | ||
US719095 | 1985-04-02 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR860008265A true KR860008265A (ko) | 1986-11-14 |
KR900000883B1 KR900000883B1 (ko) | 1990-02-17 |
Family
ID=24888731
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019860002451A KR900000883B1 (ko) | 1985-04-02 | 1986-04-01 | 표백조성물 및 그 제조방법 |
Country Status (12)
Country | Link |
---|---|
US (1) | US4601845A (ko) |
EP (1) | EP0201113B1 (ko) |
JP (1) | JPS61268799A (ko) |
KR (1) | KR900000883B1 (ko) |
AT (1) | ATE38529T1 (ko) |
AU (1) | AU566700B2 (ko) |
BR (1) | BR8601433A (ko) |
CA (1) | CA1241156A (ko) |
DE (1) | DE3661140D1 (ko) |
ES (1) | ES8706478A1 (ko) |
TR (1) | TR22929A (ko) |
ZA (1) | ZA862419B (ko) |
Families Citing this family (54)
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US4623357A (en) * | 1985-04-02 | 1986-11-18 | Lever Brothers Company | Bleach compositions |
US4711748A (en) * | 1985-12-06 | 1987-12-08 | Lever Brothers Company | Preparation of bleach catalyst aggregates of manganese cation impregnated aluminosilicates by high velocity granulation |
US4655782A (en) * | 1985-12-06 | 1987-04-07 | Lever Brothers Company | Bleach composition of detergent base powder and agglomerated manganese-alluminosilicate catalyst having phosphate salt distributed therebetween |
EP0224952A3 (en) * | 1985-12-06 | 1988-09-14 | Unilever N.V. | Bleach catalyst aggregates of manganese cation impregnated aluminosilicates |
BE905631A (fr) * | 1986-03-28 | 1987-02-16 | Golden Trade Srl | Procede pour decolorer de maniere non uniforme des tissus ou des vetements et produit decolore par ce procede. |
US4731196A (en) * | 1986-10-28 | 1988-03-15 | Ethyl Corporation | Process for making bleach activator |
US5298027A (en) * | 1987-03-13 | 1994-03-29 | Inax Corporation | Methods of bleaching jeans |
US4900323A (en) * | 1987-11-05 | 1990-02-13 | Ocean Wash, Inc. | Chemical and method for bleaching textiles |
US4919842A (en) * | 1987-11-05 | 1990-04-24 | Dickson Glen A | Chemical for bleaching textiles |
US5141664A (en) * | 1987-12-30 | 1992-08-25 | Lever Brothers Company, A Division Of Conopco, Inc. | Clear detergent gel compositions having opaque particles dispersed therein |
US5273547A (en) * | 1988-04-29 | 1993-12-28 | Carus Corporation | Sorel cementitious composition which time releases permanganate ion |
US5152804A (en) * | 1988-04-29 | 1992-10-06 | Carus Corporation | Permanganate-containing pellets and method of manufacture |
US5261924A (en) * | 1988-04-29 | 1993-11-16 | Carus Corporation | Layered cementitous composition which time releases permanganate ion |
US5006124A (en) * | 1989-12-15 | 1991-04-09 | Fmc Corporation | Wet processing of denim |
US5322637A (en) * | 1990-11-09 | 1994-06-21 | O'grady Richard | Composition, bleaching element, method for making a bleaching element and method for inhibiting the yellowing of intentionally distressed clothing manufactured from dyed cellulose fabric |
DE4216405A1 (de) * | 1992-05-18 | 1993-11-25 | Henkel Kgaa | Pumpfähige alkalische Reinigerkonzentrate |
US5653770A (en) * | 1993-08-11 | 1997-08-05 | Polo Ralph Lauren Corporation | Antique-looking and feeling fabrics and garments and method of making same |
JP3009471B2 (ja) * | 1994-04-07 | 2000-02-14 | ザ、プロクター、エンド、ギャンブル、カンパニー | 金属含有漂白触媒と酸化防止剤とを含む漂白組成物 |
US5686014A (en) * | 1994-04-07 | 1997-11-11 | The Procter & Gamble Company | Bleach compositions comprising manganese-containing bleach catalysts |
US5560748A (en) * | 1994-06-10 | 1996-10-01 | The Procter & Gamble Company | Detergent compositions comprising large pore size redox catalysts |
GB2294268A (en) | 1994-07-07 | 1996-04-24 | Procter & Gamble | Bleaching composition for dishwasher use |
US5578136A (en) | 1994-08-31 | 1996-11-26 | The Procter & Gamble Company | Automatic dishwashing compositions comprising quaternary substituted bleach activators |
US5968881A (en) * | 1995-02-02 | 1999-10-19 | The Procter & Gamble Company | Phosphate built automatic dishwashing compositions comprising catalysts |
AU711960B2 (en) * | 1995-02-02 | 1999-10-28 | Procter & Gamble Company, The | Automatic dishwashing compositions comprising cobalt chelated catalysts |
BR9607127A (pt) * | 1995-02-02 | 1997-11-04 | Procter & Gamble | Composições para lavagem automática de pratos compreendendo catalísadores de cobalto(III) |
ATE203051T1 (de) * | 1995-06-16 | 2001-07-15 | Procter & Gamble | Maschinengeschirrspülmittel, die kobaltkatalysatoren enthalten |
ATE203563T1 (de) * | 1995-06-16 | 2001-08-15 | Procter & Gamble | Bleichmittelzusammensetzungen, die kobaltkatalysatoren enthalten |
US5945392A (en) * | 1995-06-20 | 1999-08-31 | Procter & Gamble Company | Nonaqueous, particulate-containing detergent compositions |
US5703034A (en) * | 1995-10-30 | 1997-12-30 | The Procter & Gamble Company | Bleach catalyst particles |
EP0778342A1 (en) | 1995-12-06 | 1997-06-11 | The Procter & Gamble Company | Detergent compositions |
EP0825250A1 (en) * | 1996-08-21 | 1998-02-25 | The Procter & Gamble Company | Bleaching compositions |
US5904734A (en) * | 1996-11-07 | 1999-05-18 | S. C. Johnson & Son, Inc. | Method for bleaching a hard surface using tungsten activated peroxide |
DE19721886A1 (de) | 1997-05-26 | 1998-12-03 | Henkel Kgaa | Bleichsystem |
AU1463799A (en) | 1997-11-21 | 1999-06-15 | Procter & Gamble Company, The | Product applicator |
WO2003093405A2 (en) | 2002-05-02 | 2003-11-13 | The Procter & Gamble Company | Detergent compositions and components thereof |
BRPI0407114B1 (pt) | 2003-02-03 | 2018-09-11 | Unilever Nv | composição para lavagem de roupa |
US20070138674A1 (en) | 2005-12-15 | 2007-06-21 | Theodore James Anastasiou | Encapsulated active material with reduced formaldehyde potential |
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CA2685102A1 (en) * | 2007-04-25 | 2008-11-06 | Reckitt Benckiser N.V. | Composition |
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ES2343727B1 (es) * | 2010-03-31 | 2011-03-17 | Fmc Foret, S.A. | Composicion activadora de peroxidos para el lavado en frio, procedimiento de preparacion y uso de la misma. |
US8980816B2 (en) | 2012-01-04 | 2015-03-17 | The Procter & Gamble Company | Fibrous structures comprising particles and methods for making same |
EP3075832B1 (en) | 2015-03-30 | 2021-04-14 | Dalli-Werke GmbH & Co. KG | Manganese-amino acid compounds in cleaning compositions |
EP3535370B1 (en) | 2016-11-01 | 2020-09-09 | The Procter & Gamble Company | Methods of using leuco colorants as bluing agents in laundry care compositions |
JP6790257B2 (ja) | 2016-11-01 | 2020-11-25 | ザ プロクター アンド ギャンブル カンパニーThe Procter & Gamble Company | 洗濯ケア組成物における青味剤としてのロイコ着色剤、その包装、キット及び方法 |
US11697905B2 (en) | 2017-01-27 | 2023-07-11 | The Procter & Gamble Company | Active agent-containing articles that exhibit consumer acceptable article in-use properties |
DE112018000558T5 (de) | 2017-01-27 | 2019-10-10 | The Procter & Gamble Company | Wirkstoff enthaltende Gegenstände, die für den Verbraucher annehmbare gebräuchliche Gegenstandseigenschaften aufweisen |
US11697904B2 (en) | 2017-01-27 | 2023-07-11 | The Procter & Gamble Company | Active agent-containing articles that exhibit consumer acceptable article in-use properties |
US11697906B2 (en) | 2017-01-27 | 2023-07-11 | The Procter & Gamble Company | Active agent-containing articles and product-shipping assemblies for containing the same |
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JP7364677B2 (ja) | 2018-12-14 | 2023-10-18 | ザ プロクター アンド ギャンブル カンパニー | 粒子を含む起泡性繊維構造体及びその製造方法 |
US11485934B2 (en) | 2019-08-02 | 2022-11-01 | The Procter & Gamble Company | Foaming compositions for producing a stable foam and methods for making same |
US20210148044A1 (en) | 2019-11-15 | 2021-05-20 | The Procter & Gamble Company | Graphic-Containing Soluble Articles and Methods for Making Same |
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US2820690A (en) * | 1954-07-26 | 1958-01-21 | Becco Chemical Division Food M | Process of bleaching cotton with hydrogen peroxide bleach stabilized with calcium ormagnesium orthophosphate |
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DE3066202D1 (en) * | 1979-11-03 | 1984-02-23 | Procter & Gamble | Granular laundry compositions |
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FI822428L (fi) * | 1981-07-15 | 1983-01-16 | Unilever Nv | Rengoeringsblandning |
GR76237B (ko) * | 1981-08-08 | 1984-08-04 | Procter & Gamble | |
US4481129A (en) * | 1981-12-23 | 1984-11-06 | Lever Brothers Company | Bleach compositions |
US4478733A (en) * | 1982-12-17 | 1984-10-23 | Lever Brothers Company | Detergent compositions |
US4488980A (en) * | 1982-12-17 | 1984-12-18 | Lever Brothers Company | Detergent compositions |
US4536183A (en) * | 1984-04-09 | 1985-08-20 | Lever Brothers Company | Manganese bleach activators |
-
1985
- 1985-04-02 US US06/719,095 patent/US4601845A/en not_active Expired - Fee Related
-
1986
- 1986-03-20 EP EP86200445A patent/EP0201113B1/en not_active Expired
- 1986-03-20 AT AT86200445T patent/ATE38529T1/de not_active IP Right Cessation
- 1986-03-20 DE DE8686200445T patent/DE3661140D1/de not_active Expired
- 1986-03-26 CA CA000505248A patent/CA1241156A/en not_active Expired
- 1986-03-31 JP JP61074119A patent/JPS61268799A/ja active Granted
- 1986-04-01 BR BR8601433A patent/BR8601433A/pt not_active IP Right Cessation
- 1986-04-01 KR KR1019860002451A patent/KR900000883B1/ko not_active IP Right Cessation
- 1986-04-01 ES ES553587A patent/ES8706478A1/es not_active Expired
- 1986-04-01 AU AU55509/86A patent/AU566700B2/en not_active Ceased
- 1986-04-02 TR TR173/86A patent/TR22929A/xx unknown
- 1986-04-02 ZA ZA862419A patent/ZA862419B/xx unknown
Also Published As
Publication number | Publication date |
---|---|
JPH0434594B2 (ko) | 1992-06-08 |
ES8706478A1 (es) | 1987-06-16 |
EP0201113B1 (en) | 1988-11-09 |
DE3661140D1 (en) | 1988-12-15 |
BR8601433A (pt) | 1986-12-09 |
AU566700B2 (en) | 1987-10-29 |
EP0201113A1 (en) | 1986-11-12 |
TR22929A (tr) | 1988-11-28 |
ATE38529T1 (de) | 1988-11-15 |
JPS61268799A (ja) | 1986-11-28 |
KR900000883B1 (ko) | 1990-02-17 |
ES553587A0 (es) | 1987-06-16 |
US4601845A (en) | 1986-07-22 |
AU5550986A (en) | 1986-10-09 |
CA1241156A (en) | 1988-08-30 |
ZA862419B (en) | 1987-12-30 |
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